Quantum Oscillations
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In
condensed matter physics Condensed matter physics is the field of physics that deals with the macroscopic and microscopic physical properties of matter, especially the solid and liquid State of matter, phases, that arise from electromagnetic forces between atoms and elec ...
, quantum oscillations describes a series of related
experimental An experiment is a procedure carried out to support or refute a hypothesis, or determine the efficacy or likelihood of something previously untried. Experiments provide insight into cause-and-effect by demonstrating what outcome occurs whe ...
techniques used to map the
Fermi surface In condensed matter physics, the Fermi surface is the surface in reciprocal space which separates occupied electron states from unoccupied electron states at zero temperature. The shape of the Fermi surface is derived from the periodicity and sym ...
of a
metal A metal () is a material that, when polished or fractured, shows a lustrous appearance, and conducts electrical resistivity and conductivity, electricity and thermal conductivity, heat relatively well. These properties are all associated wit ...
in the presence of a strong
magnetic field A magnetic field (sometimes called B-field) is a physical field that describes the magnetic influence on moving electric charges, electric currents, and magnetic materials. A moving charge in a magnetic field experiences a force perpendicular ...
. These techniques are based on the principle of
Landau quantization In quantum mechanics, the energies of Cyclotron motion#Cyclotron resonance, cyclotron orbits of charged particles in a uniform magnetic field are quantized to discrete values, thus known as Landau levels. These levels are Degenerate energy level, d ...
of
Fermions In particle physics, a fermion is a subatomic particle that follows Fermi–Dirac statistics. Fermions have a half-integer spin ( spin , spin , etc.) and obey the Pauli exclusion principle. These particles include all quarks and leptons and ...
moving in a magnetic field. For a gas of free fermions in a strong magnetic field, the energy levels are quantized into bands, called the ''Landau levels'', whose separation is proportional to the strength of the magnetic field. In a quantum oscillation experiment, the external magnetic field is varied, which causes the Landau levels to pass over the Fermi surface, which in turn results in oscillations of the electronic
density of states In condensed matter physics, the density of states (DOS) of a system describes the number of allowed modes or quantum state, states per unit energy range. The density of states is defined as where N(E)\delta E is the number of states in the syste ...
at the
Fermi level The Fermi level of a solid-state body is the thermodynamic work required to add one electron to the body. It is a thermodynamic quantity usually denoted by ''μ'' or ''E''F for brevity. The Fermi level does not include the work required to re ...
; this produces oscillations in the many material properties which depend on this, including resistance (the
Shubnikov–de Haas effect An oscillation in the Electrical conductivity, conductivity of a material that occurs at low temperatures in the presence of very intense magnetic fields, the Shubnikov–de Haas effect (SdH) is a macroscopic manifestation of the inherent quantum me ...
), Hall resistance, and
magnetic susceptibility In electromagnetism, the magnetic susceptibility (; denoted , chi) is a measure of how much a material will become magnetized in an applied magnetic field. It is the ratio of magnetization (magnetic moment per unit volume) to the applied magnet ...
(the de Haas–van Alphen effect). Observation of quantum oscillations in a material is considered a signature of
Fermi liquid Fermi liquid theory (also known as Landau's Fermi-liquid theory) is a theoretical model of interacting fermions that describes the normal state of the conduction electrons in most metals at sufficiently low temperatures. The theory describes the ...
behaviour. Quantum oscillations have been used to study high temperature superconducting materials such as
cuprates Cuprates are a class of compounds that contain copper (Cu) atom(s) in an anion. They can be broadly categorized into two main types: 1. Inorganic cuprates: These compounds have a general formula of . Some of them are non-stoichiometric. Many ...
and
pnictides , - ! colspan=2 style="text-align:left;" , ↓ Period , - ! 2 , , - ! 3 , , - ! 4 , , - ! 5 , , - ! 6 , , - ! 7 , , - , colspan="2", ---- ''Legend'' A pnictogen ( or ; from "to choke" and -gen, "generator") is any o ...
. Studies using these experiments have shown that the ground state of underdoped cuprates behave similar to a
Fermi liquid Fermi liquid theory (also known as Landau's Fermi-liquid theory) is a theoretical model of interacting fermions that describes the normal state of the conduction electrons in most metals at sufficiently low temperatures. The theory describes the ...
, and display characteristics such as Landau
quasiparticle In condensed matter physics, a quasiparticle is a concept used to describe a collective behavior of a group of particles that can be treated as if they were a single particle. Formally, quasiparticles and collective excitations are closely relate ...
s. In 2021 this technique has been used to observe a predicted state called "electron–phonon fluid", a similar particle-quasiparticle state already known is the exciton–polariton fluid.


Experiment

When a magnetic field is applied to a system of free charged
fermions In particle physics, a fermion is a subatomic particle that follows Fermi–Dirac statistics. Fermions have a half-integer spin ( spin , spin , etc.) and obey the Pauli exclusion principle. These particles include all quarks and leptons and ...
, their energy states are quantized into the so-called Landau levels, given by \varepsilon_l=\frac\left(\ell +\frac\right) for integer-valued \ell, where B is the external magnetic field and e,m^* are the fermion charge and effective mass respectively. When the external magnetic field B is increased in an isolated system, the Landau levels expand, and eventually "fall off" the Fermi surface. This leads to oscillations in the observed energy of the highest occupied level, and hence in many physical properties (including Hall conductivity, resistivity, and susceptibility). The periodicity of these oscillations can be measured, and in turn can be used to determine the cross-sectional area of the Fermi surface. If the axis of the magnetic field is varied at constant magnitude, similar oscillations are observed. The oscillations occur whenever the Landau orbits touch the Fermi surface. In this way, the complete geometry of the Fermi sphere can be mapped.


Underdoped cuprates

Studies of underdoped cuprate compounds such as YBa2Cu3O6+''x'' through probes such as
ARPES Angle-resolved photoemission spectroscopy (ARPES) is an experimental technique used in condensed matter physics to probe the allowed energies and momenta of the electrons in a material, usually a crystalline solid. It is based on the photoelec ...
have indicated that these phases show characteristics of non-Fermi liquids, and in particular, the absence of well-defined Landau
quasiparticle In condensed matter physics, a quasiparticle is a concept used to describe a collective behavior of a group of particles that can be treated as if they were a single particle. Formally, quasiparticles and collective excitations are closely relate ...
s.{{cite journal, last1=Damascelli, first1=Andrea, last2=Hussain, first2=Zahid, author3=Zhi-Xun Shen, title=Angle-resolved photoemission studies of the cuprate superconductors, journal=Reviews of Modern Physics, year=2003, volume=75, issue=2, pages=473, doi=10.1103/RevModPhys.75.473, arxiv = cond-mat/0208504 , bibcode = 2003RvMP...75..473D , s2cid=118433150 However, quantum oscillations have been observed in these materials at low temperatures, if their superconductivity is suppressed by a sufficiently high magnetic field, which is evidence for the presence of well-defined quasiparticles with fermionic statistics. These experimental results thus disagree with those from ARPES and other probes.


See also

* de Haas–van Alphen effect *
Shubnikov–de Haas effect An oscillation in the Electrical conductivity, conductivity of a material that occurs at low temperatures in the presence of very intense magnetic fields, the Shubnikov–de Haas effect (SdH) is a macroscopic manifestation of the inherent quantum me ...
* Landau levels


References

Condensed matter physics Experimental physics Magnetism