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Power-to-X (also P2X and P2Y and P2Z) is a number of
electricity Electricity is the set of physical phenomena associated with the presence and motion of matter that has a property of electric charge. Electricity is related to magnetism, both being part of the phenomenon of electromagnetism, as described ...
conversion,
energy storage Energy storage is the capture of energy produced at one time for use at a later time to reduce imbalances between energy demand and energy production. A device that stores energy is generally called an accumulator or battery. Energy comes in ...
, and reconversion pathways that use surplus
electric power Electric power is the rate at which electrical energy is transferred by an electric circuit. The SI unit of power is the watt, one joule per second. Standard prefixes apply to watts as with other SI units: thousands, millions and billions of ...
, typically during periods where fluctuating
renewable energy Renewable energy is energy that is collected from renewable resources that are naturally replenished on a human timescale. It includes sources such as sunlight, wind, the movement of water, and geothermal heat. Although most renewable energy ...
generation exceeds load. Power-to-X conversion technologies allow for the decoupling of power from the electricity sector for use in other sectors (such as transport or chemicals), possibly using power that has been provided by additional investments in generation. The term is widely used in Germany and may have originated there. The X in the terminology can refer to one of the following: power-to-
ammonia Ammonia is an inorganic compound of nitrogen and hydrogen with the formula . A stable binary hydride, and the simplest pnictogen hydride, ammonia is a colourless gas with a distinct pungent smell. Biologically, it is a common nitrogenous wa ...
, power-to-
chemicals A chemical substance is a form of matter having constant chemical composition and characteristic properties. Some references add that chemical substance cannot be separated into its constituent elements by physical separation methods, i.e., with ...
, power-to-fuel,
power-to-gas Power-to-gas (often abbreviated P2G) is a technology that uses electric power to produce a gaseous fuel. When using surplus power from wind generation, the concept is sometimes called windgas. Most P2G systems use electrolysis to produce hydrogen ...
, power-to-hydrogen, power-to-
liquid A liquid is a nearly incompressible fluid that conforms to the shape of its container but retains a (nearly) constant volume independent of pressure. As such, it is one of the four fundamental states of matter (the others being solid, gas, an ...
, power-to-methane, power to food, power-to-power, and power-to- syngas. Electric vehicle charging, space heating and cooling, and water heating can be shifted in time to match generation, forms of
demand response Demand response is a change in the power consumption of an electric utility customer to better match the demand for power with the supply. Until the 21st century decrease in the cost of pumped storage and batteries electric energy could not be ...
that some term power-to-mobility and power-to-
heat In thermodynamics, heat is defined as the form of energy crossing the boundary of a thermodynamic system by virtue of a temperature difference across the boundary. A thermodynamic system does not ''contain'' heat. Nevertheless, the term is al ...
. Collectively power-to-X schemes which use surplus power fall under the heading of flexibility measures and are particularly useful in energy systems with high shares of renewable generation and/or with strong
decarbonization Climate change mitigation is action to limit climate change by reducing emissions of greenhouse gases or removing those gases from the atmosphere. The recent rise in global average temperature is mostly caused by emissions from fossil fuels bur ...
targets. A large number of pathways and technologies are encompassed by the term. In 2016 the German government funded a €30million first-phase research project into power-to-X options.


Electricity storage concepts

Surplus electric power can be converted to other forms of
energy In physics, energy (from Ancient Greek: ἐνέργεια, ''enérgeia'', “activity”) is the quantitative property that is transferred to a body or to a physical system, recognizable in the performance of work and in the form of heat ...
for storage and reconversion. Direct current
electrolysis of water Electrolysis of water, also known as electrochemical water splitting, is the process of using electricity to decompose water into oxygen and hydrogen gas by electrolysis. Hydrogen gas released in this way can be used as hydrogen fuel, or rem ...
(efficiency 80–85% at best) can be used to produce
hydrogen Hydrogen is the chemical element with the symbol H and atomic number 1. Hydrogen is the lightest element. At standard conditions hydrogen is a gas of diatomic molecules having the formula . It is colorless, odorless, tasteless, non-toxi ...
which can, in turn, be converted to
methane Methane ( , ) is a chemical compound with the chemical formula (one carbon atom bonded to four hydrogen atoms). It is a group-14 hydride, the simplest alkane, and the main constituent of natural gas. The relative abundance of methane on ...
(CH4) via
methanation Methanation is the conversion of carbon monoxide and carbon dioxide (COx) to methane (CH4) through hydrogenation. The methanation reactions of COx were first discovered by Sabatier and Senderens in 1902. CO''x'' methanation has many practical a ...
. Another possibility is converting the hydrogen, along with CO2 to methanol. Both these fuels can be stored and used to produce electricity again, hours to months later. Reconversion technologies include
gas turbines A gas turbine, also called a combustion turbine, is a type of continuous flow internal combustion engine. The main parts common to all gas turbine engines form the power-producing part (known as the gas generator or core) and are, in the directi ...
, CCGT plant,
reciprocating engine A reciprocating engine, also often known as a piston engine, is typically a heat engine that uses one or more reciprocating pistons to convert high temperature and high pressure into a rotating motion. This article describes the common featu ...
s and
fuel cell A fuel cell is an electrochemical cell that converts the chemical energy of a fuel (often hydrogen) and an oxidizing agent (often oxygen) into electricity through a pair of redox reactions. Fuel cells are different from most batteries in requ ...
s. Power-to-power refers to the round-trip reconversion efficiency. For hydrogen storage, the round-trip efficiency remains limited at 35–50%. Electrolysis is expensive and power-to-gas processes need substantial full-load hours (say 30%) to be economic. However, while round-trip conversion efficiency of power-to-power is lower than with batteries and electrolysis can be expensive, storage of the fuels themselves is quite inexpensive. This means that large amounts of energy can be stored for long periods of time with power-to-power, which is ideal for seasonal storage. This could be particularly useful for systems with high
variable renewable energy Variable renewable energy (VRE) or intermittent renewable energy sources (IRES) are renewable energy sources that are not dispatchable due to their fluctuating nature, such as wind power and solar power, as opposed to controllable renewable ener ...
penetration, since many areas have significant seasonal variability of solar, wind, and
run-of-the-river Run-of-river hydroelectricity (ROR) or run-of-the-river hydroelectricity is a type of hydroelectric generation plant whereby little or no water storage is provided. Run-of-the-river power plants may have no water storage at all or a limited amou ...
-hydroelectric generation. Grid-dedicated
battery storage A battery storage power station is a type of energy storage power station that uses a group of batteries to store electrical energy. Battery storage is the fastest responding dispatchable source of power on electric grids, and it is used to sta ...
is not normally considered a power-to-X concept.


Sector coupling concepts

Hydrogen and methane can also be used as downstream
fuel A fuel is any material that can be made to react with other substances so that it releases energy as thermal energy or to be used for work. The concept was originally applied solely to those materials capable of releasing chemical energy but ...
s, fed into the
natural gas Natural gas (also called fossil gas or simply gas) is a naturally occurring mixture of gaseous hydrocarbons consisting primarily of methane in addition to various smaller amounts of other higher alkanes. Low levels of trace gases like carbon di ...
grid, or used to make synthetic fuel. Alternatively they can be used as a chemical
feedstock A raw material, also known as a feedstock, unprocessed material, or primary commodity, is a basic material that is used to produce goods, finished goods, energy, or intermediate materials that are feedstock for future finished products. As feedst ...
, as can
ammonia Ammonia is an inorganic compound of nitrogen and hydrogen with the formula . A stable binary hydride, and the simplest pnictogen hydride, ammonia is a colourless gas with a distinct pungent smell. Biologically, it is a common nitrogenous wa ...
(). Power-to-heat involves contributing to the heat sector, either by resistance heating or via a
heat pump A heat pump is a device that can heat a building (or part of a building) by transferring thermal energy from the outside using a refrigeration cycle. Many heat pumps can also operate in the opposite direction, cooling the building by removing h ...
. Resistance heaters have unity efficiency, and the corresponding
coefficient of performance The coefficient of performance or COP (sometimes CP or CoP) of a heat pump, refrigerator or air conditioning system is a ratio of useful heating or cooling provided to work (energy) required. Higher COPs equate to higher efficiency, lower energy ( ...
(COP) of heat pumps is 2–5. Back-up immersion heating of both domestic hot water and
district heating District heating (also known as heat networks or teleheating) is a system for distributing heat generated in a centralized location through a system of insulated pipes for residential and commercial heating requirements such as space heating ...
offers a cheap way of using surplus renewable energy and will often displace carbon-intensive fossil fuels for the task. Large-scale heat pumps in district heating systems with thermal energy storage are an especially attractive option for power-to-heat: they offer exceptionally high efficiency for balancing excess wind and solar power, and they can be profitable investments. Power-to-mobility refers to the charging of battery
electric vehicle An electric vehicle (EV) is a vehicle that uses one or more electric motors for propulsion. It can be powered by a collector system, with electricity from extravehicular sources, or it can be powered autonomously by a battery (sometimes ch ...
s (EV). Given the expected uptake of EVs, dedicated dispatch will be required. As vehicles are idle for most of the time, shifting the charging time can offer considerable flexibility: the charging window is a relatively long 8–12hours, whereas the charging duration is around 90minutes. The EV batteries can also be discharged to the grid to make them work as electricity storage devices, but this causes additional wear to the battery. Heat pumps with hot water storage and electric vehicles have been found to have higher potential on reduction of emissions and fossil fuel use than several other power-to-X or electricity storage schemes for using surplus wind and solar power. However, while power-to-heat and power-to-mobility through electrification (heat pumps and electric vehicles) have a high emissions reduction potential, if the goal is a 100% clean system, there are some end uses which cannot be economically electrified. These end uses include long-distance shipping (trucking, airplanes, barges) and high heat industrial processes. In these cases, using fuels synthesized from clean electricity might be the best option. Biofuels are another option, but they compete with agriculture for water and space. According to the German concept of sector coupling interconnecting all the energy-using sectors will require the digitalisation and automation of numerous processes to synchronise supply and demand.


See also

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Energy storage Energy storage is the capture of energy produced at one time for use at a later time to reduce imbalances between energy demand and energy production. A device that stores energy is generally called an accumulator or battery. Energy comes in ...
*
Grid energy storage Grid energy storage (also called large-scale energy storage) is a collection of methods used for energy storage on a large scale within an electrical power grid. Electrical energy is stored during times when electricity is plentiful and inexpe ...
*
Power-to-gas Power-to-gas (often abbreviated P2G) is a technology that uses electric power to produce a gaseous fuel. When using surplus power from wind generation, the concept is sometimes called windgas. Most P2G systems use electrolysis to produce hydrogen ...
* Power-to-heat *
Electrofuel Electrofuels, also known as e-fuels or synthetic fuels, are a type of drop-in replacement fuel. They are manufactured using captured carbon dioxide or carbon monoxide, together with hydrogen obtained from sustainable electricity sources such as w ...


References

{{Electricity generation Energy policy Energy policy of Germany Energy storage Power engineering