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In
mathematical physics Mathematical physics refers to the development of mathematical methods for application to problems in physics. The '' Journal of Mathematical Physics'' defines the field as "the application of mathematics to problems in physics and the developm ...
and
mathematics Mathematics is an area of knowledge that includes the topics of numbers, formulas and related structures, shapes and the spaces in which they are contained, and quantities and their changes. These topics are represented in modern mathematics ...
, the Pauli matrices are a set of three complex matrices which are Hermitian, involutory and
unitary Unitary may refer to: Mathematics * Unitary divisor * Unitary element * Unitary group * Unitary matrix * Unitary morphism * Unitary operator * Unitary transformation * Unitary representation In mathematics, a unitary representation of a grou ...
. Usually indicated by the Greek letter
sigma Sigma (; uppercase Σ, lowercase σ, lowercase in word-final position ς; grc-gre, σίγμα) is the eighteenth letter of the Greek alphabet. In the system of Greek numerals, it has a value of 200. In general mathematics, uppercase Σ is used a ...
(), they are occasionally denoted by tau () when used in connection with isospin symmetries. \begin \sigma_1 = \sigma_\mathrm &= \begin 0&1\\ 1&0 \end \\ \sigma_2 = \sigma_\mathrm &= \begin 0& -i \\ i&0 \end \\ \sigma_3 = \sigma_\mathrm &= \begin 1&0\\ 0&-1 \end \\ \end These matrices are named after the physicist
Wolfgang Pauli Wolfgang Ernst Pauli (; ; 25 April 1900 – 15 December 1958) was an Austrian theoretical physicist and one of the pioneers of quantum physics. In 1945, after having been nominated by Albert Einstein, Pauli received the Nobel Prize in Physics ...
. In
quantum mechanics Quantum mechanics is a fundamental theory in physics that provides a description of the physical properties of nature at the scale of atoms and subatomic particles. It is the foundation of all quantum physics including quantum chemistry, ...
, they occur in the
Pauli equation In quantum mechanics, the Pauli equation or Schrödinger–Pauli equation is the formulation of the Schrödinger equation for spin-½ particles, which takes into account the interaction of the particle's spin with an external electromagnetic f ...
which takes into account the interaction of the
spin Spin or spinning most often refers to: * Spinning (textiles), the creation of yarn or thread by twisting fibers together, traditionally by hand spinning * Spin, the rotation of an object around a central axis * Spin (propaganda), an intentionally ...
of a particle with an external
electromagnetic field An electromagnetic field (also EM field or EMF) is a classical (i.e. non-quantum) field produced by (stationary or moving) electric charges. It is the field described by classical electrodynamics (a classical field theory) and is the classical ...
. They also represent the interaction states of two polarization filters for horizontal/vertical polarization, 45 degree polarization (right/left), and circular polarization (right/left). Each Pauli matrix is Hermitian, and together with the identity matrix (sometimes considered as the zeroth Pauli matrix ), the Pauli matrices form a basis for the real
vector space In mathematics and physics, a vector space (also called a linear space) is a set whose elements, often called '' vectors'', may be added together and multiplied ("scaled") by numbers called ''scalars''. Scalars are often real numbers, but can ...
of Hermitian matrices. This means that any Hermitian matrix can be written in a unique way as a linear combination of Pauli matrices, with all coefficients being real numbers. Hermitian operators represent observables in quantum mechanics, so the Pauli matrices span the space of observables of the complex -dimensional
Hilbert space In mathematics, Hilbert spaces (named after David Hilbert) allow generalizing the methods of linear algebra and calculus from (finite-dimensional) Euclidean vector spaces to spaces that may be infinite-dimensional. Hilbert spaces arise natural ...
. In the context of Pauli's work, represents the observable corresponding to spin along the th coordinate axis in three-dimensional
Euclidean space Euclidean space is the fundamental space of geometry, intended to represent physical space. Originally, that is, in Euclid's ''Elements'', it was the three-dimensional space of Euclidean geometry, but in modern mathematics there are Euclidea ...
\mathbb^3. The Pauli matrices (after multiplication by to make them anti-Hermitian) also generate transformations in the sense of
Lie algebra In mathematics, a Lie algebra (pronounced ) is a vector space \mathfrak g together with an operation called the Lie bracket, an alternating bilinear map \mathfrak g \times \mathfrak g \rightarrow \mathfrak g, that satisfies the Jacobi identi ...
s: the matrices form a basis for the real Lie algebra \mathfrak(2), which exponentiates to the special unitary group SU(2). The
algebra Algebra () is one of the broad areas of mathematics. Roughly speaking, algebra is the study of mathematical symbols and the rules for manipulating these symbols in formulas; it is a unifying thread of almost all of mathematics. Elementary ...
generated by the three matrices is
isomorphic In mathematics, an isomorphism is a structure-preserving mapping between two structures of the same type that can be reversed by an inverse mapping. Two mathematical structures are isomorphic if an isomorphism exists between them. The word i ...
to the
Clifford algebra In mathematics, a Clifford algebra is an algebra generated by a vector space with a quadratic form, and is a unital associative algebra. As -algebras, they generalize the real numbers, complex numbers, quaternions and several other hyperco ...
of , and the (unital associative) algebra generated by is effectively identical (isomorphic) to that of
quaternion In mathematics, the quaternion number system extends the complex numbers. Quaternions were first described by the Irish mathematician William Rowan Hamilton in 1843 and applied to mechanics in three-dimensional space. Hamilton defined a quater ...
s (\mathbb).


Algebraic properties

All three of the Pauli matrices can be compacted into a single expression: : \sigma_j = \begin \delta_ & \delta_ - i\,\delta_\\ \delta_ + i\,\delta_ & -\delta_ \end where the solution to is the "
imaginary unit The imaginary unit or unit imaginary number () is a solution to the quadratic equation x^2+1=0. Although there is no real number with this property, can be used to extend the real numbers to what are called complex numbers, using addition an ...
", and is the
Kronecker delta In mathematics, the Kronecker delta (named after Leopold Kronecker) is a function of two variables, usually just non-negative integers. The function is 1 if the variables are equal, and 0 otherwise: \delta_ = \begin 0 &\text i \neq j, \\ 1 & ...
, which equals +1 if and 0 otherwise. This expression is useful for "selecting" any one of the matrices numerically by substituting values of , in turn useful when any of the matrices (but no particular one) is to be used in algebraic manipulations. The matrices are ''involutory'': :\sigma_1^2 = \sigma_2^2 = \sigma_3^2 = -i\,\sigma_1 \sigma_2 \sigma_3 = \begin 1 & 0 \\ 0 & 1 \end = I where is the
identity matrix In linear algebra, the identity matrix of size n is the n\times n square matrix with ones on the main diagonal and zeros elsewhere. Terminology and notation The identity matrix is often denoted by I_n, or simply by I if the size is immaterial or ...
. The
determinant In mathematics, the determinant is a scalar value that is a function of the entries of a square matrix. It characterizes some properties of the matrix and the linear map represented by the matrix. In particular, the determinant is nonzero if a ...
s and traces of the Pauli matrices are: :\begin \det \sigma_j &~=\, -1\,, \\ \operatorname \sigma_j &~=~~~\; 0 ~. \end From which, we can deduce that each matrix has
eigenvalues In linear algebra, an eigenvector () or characteristic vector of a linear transformation is a nonzero vector that changes at most by a scalar factor when that linear transformation is applied to it. The corresponding eigenvalue, often denote ...
+1 and −1. With the inclusion of the identity matrix, (sometimes denoted ), the Pauli matrices form an orthogonal basis (in the sense of Hilbert–Schmidt) of the
Hilbert space In mathematics, Hilbert spaces (named after David Hilbert) allow generalizing the methods of linear algebra and calculus from (finite-dimensional) Euclidean vector spaces to spaces that may be infinite-dimensional. Hilbert spaces arise natural ...
of Hermitian matrices, \mathcal_2 over \mathbb, and the Hilbert space of all complex matrices, \mathcal_(\mathbb).


Eigenvectors and eigenvalues

Each of the ( Hermitian) Pauli matrices has two
eigenvalues In linear algebra, an eigenvector () or characteristic vector of a linear transformation is a nonzero vector that changes at most by a scalar factor when that linear transformation is applied to it. The corresponding eigenvalue, often denote ...
, and . The corresponding normalized eigenvectors are: :\begin \psi_ &= \frac\sqrt \begin 1 \\ 1 \end \; , & \psi_ &= \frac\sqrt \begin 1 \\ -1 \end \; , \\ \psi_ &= \frac\sqrt \begin 1 \\ i \end \; , & \psi_ &= \frac\sqrt \begin 1 \\ -i \end \; , \\ \psi_ &= \begin 1 \\ 0 \end \; , & \psi_ &= \begin 0 \\ 1 \end ~. \end


Pauli vector

The Pauli vector is defined by \vec = \sigma_1 \hat_1 + \sigma_2 \hat_2 + \sigma_3 \hat_3 ~, where \hat_1, \hat_2, and \hat_3 are an equivalent notation for the more familiar \hat, \hat, and \hat; the subscripted notation \hat_1, \hat_2, \hat_3 is more compact than the old \hat, \hat, \hat form. The Pauli vector provides a mapping mechanism from a vector basis to a Pauli matrix basis as follows, \begin \vec \cdot \vec &= \left(a_k \hat_k\right) \cdot \left(\sigma_\ell \hat_\ell \right) = a_k \sigma_\ell \hat_k \cdot \hat_\ell \\ \\ &= a_k \sigma_\ell \delta_ = a_k \sigma_k \\ \\ &= ~ a_1\; \begin 0 & 1 \\ 1 & 0 \end ~ + ~ a_2\; \begin 0 & -i \\ i & \;\;0 \end ~ + ~ a_3\; \begin 1 & 0 \\ 0 & -1 \end ~ = ~ \begin a_3 & a_1 - i a_2 \\ a_1 + i a_2 & -a_3 \end \end using
Einstein's summation convention In mathematics, especially the usage of linear algebra in Mathematical physics, Einstein notation (also known as the Einstein summation convention or Einstein summation notation) is a notational convention that implies summation over a set of ...
. More formally, this defines a map from \mathbb^3 to the vector space of traceless Hermitian 2\times 2 matrices. This map encodes structures of \mathbb^3 as a normed vector space and as a Lie algebra (with the
cross-product In mathematics, the cross product or vector product (occasionally directed area product, to emphasize its geometric significance) is a binary operation on two vectors in a three-dimensional oriented Euclidean vector space (named here E), and is ...
as its Lie bracket) via functions of matrices, making the map an isomorphism of Lie algebras. This makes the Pauli matrices intertwiners from the point of view of representation theory. Another way to view the Pauli vector is as a 2\times 2 Hermitian traceless matrix-valued dual vector, that is, an element of \text_(\mathbb) \otimes (\mathbb^3)^* which maps \vec a \mapsto \vec a \cdot \vec \sigma.


Completeness relation

Each component of \vec a can be recovered from the matrix (see completeness relation below) \frac \operatorname \Bigl( \bigl( \vec \cdot \vec \bigr) \vec \Bigr) = \vec ~. This constitutes an inverse to the map \vec a \mapsto \vec a \cdot \vec \sigma, making it manifest that the map is a bijection.


Determinant

The norm is given by the determinant (up to a minus sign) \det \bigl( \vec \cdot \vec \bigr) = -\vec \cdot \vec = -\left, \vec\^2. Then considering the conjugation action of an \text(2) matrix U on this space of matrices, :U * \vec a \cdot \vec \sigma := U \; \vec a \cdot \vec \sigma \; U^, we find \det(U * \vec a \cdot \vec\sigma) = \det(\vec a \cdot \vec \sigma), and that U * \vec a \cdot \vec \sigma is Hermitian and traceless. It then makes sense to define U * \vec a \cdot \vec\sigma = \vec a' \cdot \vec\sigma where \vec a' has the same norm as \vec a, and therefore interpret U as a rotation of 3-dimensional space. In fact, it turns out that the ''special'' restriction on U implies that the rotation is orientation preserving. This allows the definition of a map R: \text(2) \rightarrow \text(3) given by :U * \vec a \cdot \vec \sigma = \vec a' \cdot \vec \sigma =: (R(U)\vec a) \cdot \vec \sigma, where R(U)\in \text(3). This map is the concrete realization of the double cover of \text(3) by \text(2), and therefore shows that \text(2) \cong \text(3). The components of R(U) can be recovered using the tracing process above: :R(U)_ = \frac\text\left(\sigma_i U \sigma_j U^\right)


Cross-product

The cross-product is given by the matrix commutator (up to a factor of 2i) vec a \cdot \vec \sigma, \vec b \cdot \vec \sigma= 2i (\vec a \times \vec b) \cdot \vec \sigma. In fact, the existence of a norm follows from the fact that \mathbb^3 is a Lie algebra: see
Killing form In mathematics, the Killing form, named after Wilhelm Killing, is a symmetric bilinear form that plays a basic role in the theories of Lie groups and Lie algebras. Cartan's criteria (criterion of solvability and criterion of semisimplicity) sho ...
. This cross-product can be used to prove the orientation-preserving property of the map above.


Eigenvalues and eigenvectors

The eigenvalues of \vec a \cdot \vec \sigma are \pm , \vec, . This follows immediately from tracelessness and explicitly computing the determinant. More abstractly, without computing the determinant which requires explicit properties of the Pauli matrices, this follows from (\vec a \cdot \vec \sigma)^2 - , \vec a, ^2 = 0, since this can be factorised into (\vec a \cdot \vec \sigma - , \vec a, )(\vec a \cdot \vec \sigma + , \vec a, )= 0. A standard result in linear algebra (a linear map which satisfies a polynomial equation written in distinct linear factors is diagonal) means this implies \vec a \cdot \vec \sigma is diagonal with possible eigenvalues \pm , \vec a, . The tracelessness of \vec a \cdot \vec \sigma means it has exactly one of each eigenvalue. Its normalized eigenvectors are \psi_+ = \frac \begin a_3 + , \vec, \\ a_1 + ia_2 \end; \qquad \psi_- = \frac \begin ia_2 - a_1 \\ a_3 + , \vec, \end ~ .


Pauli 4-vector

The Pauli 4-vector, used in spinor theory, is written \sigma^\mu with components :\sigma^\mu = (I, \vec\sigma). This defines a map from \mathbb^ to the vector space of Hermitian matrices, :x_\mu \mapsto x_\mu\sigma^\mu, which also encodes the Minkowski metric (with ''mostly minus'' convention) in its determinant: :\det (x_\mu\sigma^\mu) = \eta(x,x). This 4-vector also has a completeness relation. It is convenient to define a second Pauli 4-vector :\bar\sigma^\mu = (I, -\vec\sigma). and allow raising and lowering using the Minkowski metric tensor. The relation can then be written x_\nu = \frac \operatorname \Bigl( \bar\sigma_\nu\bigl( x_\mu \sigma^\mu \bigr) \Bigr) ~. Similarly to the Pauli 3-vector case, we can find a matrix group which acts as isometries on \mathbb^; in this case the matrix group is \text(2,\mathbb), and this shows \text(2,\mathbb) \cong \text(1,3). Similarly to above, this can be explicitly realized for S \in \text(2,\mathbb) with components :\Lambda(S)^\mu_\nu = \frac\text\left(\bar\sigma_\nu S \sigma^\mu S^\right). In fact, the determinant property follows abstractly from trace properties of the \sigma^\mu. For 2\times 2 matrices, the following identity holds: :\det(A + B) = \det(A) + \det(B) + \text(A)\text(B) - \text(AB). That is, the 'cross-terms' can be written as traces. When A,B are chosen to be different \sigma^\mu, the cross-terms vanish. It then follows, now showing summation explicitly, \det\left(\sum_\mu x_\mu \sigma^\mu\right) = \sum_\mu \det\left(x_\mu\sigma^\mu\right). Since the matrices are 2 \times 2, this is equal to \sum_\mu x_\mu^2 \det(\sigma^\mu) = \eta(x,x).


(Anti-)Commutation relations

The Pauli matrices obey the following
commutation Commute, commutation or commutative may refer to: * Commuting, the process of travelling between a place of residence and a place of work Mathematics * Commutative property, a property of a mathematical operation whose result is insensitive to th ...
relations: : sigma_i, \sigma_j= 2 i \varepsilon_\,\sigma_k ~ , where the
structure constant In mathematics, the structure constants or structure coefficients of an algebra over a field are used to explicitly specify the product of two basis vectors in the algebra as a linear combination. Given the structure constants, the resulting pro ...
is the Levi-Civita symbol and Einstein summation notation is used. These commutation relations make the Pauli matrices the generators of a representation of the Lie algebra (\mathbb^3, \times) \cong \mathfrak(2) \cong \mathfrak(3). They also satisfy the anticommutation relations: :\ = 2 \delta_\,I ~ , where is the
Kronecker delta In mathematics, the Kronecker delta (named after Leopold Kronecker) is a function of two variables, usually just non-negative integers. The function is 1 if the variables are equal, and 0 otherwise: \delta_ = \begin 0 &\text i \neq j, \\ 1 & ...
, and is the identity matrix. These anti-commutation relations make the Pauli matrices the generators of a representation of the
Clifford algebra In mathematics, a Clifford algebra is an algebra generated by a vector space with a quadratic form, and is a unital associative algebra. As -algebras, they generalize the real numbers, complex numbers, quaternions and several other hyperco ...
for \mathbb^3, denoted \text_3(\mathbb). The usual construction of generators \sigma_ = \frac sigma_i,\sigma_j/math> of \mathfrak(3) using the Clifford algebra recovers the commutation relations above, up to unimportant numerical factors. A few explicit commutators and anti-commutators are given below as examples:


Relation to dot and cross product

Pauli vectors elegantly map these commutation and anticommutation relations to corresponding vector products. Adding the commutator to the anticommutator gives : \begin \left sigma_j, \sigma_k\right+ \ &= (\sigma_j \sigma_k - \sigma_k \sigma_j ) + (\sigma_j \sigma_k + \sigma_k \sigma_j) \\ 2i\varepsilon_\,\sigma_\ell + 2 \delta_I &= 2\sigma_j \sigma_k \end so that,
Contracting A contract is a legally enforceable agreement between two or more parties that creates, defines, and governs mutual rights and obligations between them. A contract typically involves the transfer of goods, services, money, or a promise to tr ...
each side of the equation with components of two -vectors and (which commute with the Pauli matrices, i.e., for each matrix and vector component (and likewise with ) yields :~~ \begin a_j b_k \sigma_j \sigma_k & = a_j b_k \left(i\varepsilon_\,\sigma_\ell + \delta_I\right) \\ a_j \sigma_j b_k \sigma_k & = i\varepsilon_\,a_j b_k \sigma_\ell + a_j b_k \delta_I \end ~.~ Finally, translating the index notation for the
dot product In mathematics, the dot product or scalar productThe term ''scalar product'' means literally "product with a scalar as a result". It is also used sometimes for other symmetric bilinear forms, for example in a pseudo-Euclidean space. is an alg ...
and
cross product In mathematics, the cross product or vector product (occasionally directed area product, to emphasize its geometric significance) is a binary operation on two vectors in a three-dimensional oriented Euclidean vector space (named here E), and ...
results in If is identified with the pseudoscalar then the right hand side becomes a \cdot b + a \wedge b which is also the definition for the product of two vectors in geometric algebra. If we define the spin operator as , then satisfies the commutation relation:\mathbf \times \mathbf = i\hbar \mathbfOr equivalently, the Pauli vector satisfies:\frac \times \frac = i\frac


Some trace relations

The following traces can be derived using the commutation and anticommutation relations. :\begin \operatorname\left(\sigma_j \right) &= 0 \\ \operatorname\left(\sigma_j \sigma_k \right) &= 2\delta_ \\ \operatorname\left(\sigma_j \sigma_k \sigma_\ell \right) &= 2i\varepsilon_ \\ \operatorname\left(\sigma_j \sigma_k \sigma_\ell \sigma_m \right) &= 2\left(\delta_\delta_ - \delta_\delta_ + \delta_\delta_\right) \end If the matrix is also considered, these relationships become :\begin \operatorname\left(\sigma_\alpha \right) &= 2\delta_ \\ \operatorname\left(\sigma_\alpha \sigma_\beta \right) &= 2\delta_ \\ \operatorname\left(\sigma_\alpha \sigma_\beta \sigma_\gamma \right) &= 2 \sum_ \delta_ \delta_ - 4 \delta_ \delta_ \delta_ + 2i\varepsilon_ \\ \operatorname\left(\sigma_\alpha \sigma_\beta \sigma_\gamma \sigma_\mu \right) &= 2\left(\delta_\delta_ - \delta_\delta_ + \delta_\delta_\right) + 4\left(\delta_ \delta_ \delta_ + \delta_ \delta_ \delta_\right) - 8 \delta_ \delta_ \delta_ \delta_ + 2 i \sum_ \varepsilon_ \delta_ \end where Greek indices and assume values from and the notation \sum_ is used to denote the sum over the cyclic permutation of the included indices.


Exponential of a Pauli vector

For :\vec = a\hat, \quad , \hat, = 1, one has, for even powers, :(\hat \cdot \vec)^ = I which can be shown first for the case using the anticommutation relations. For convenience, the case is taken to be by convention. For odd powers, :\left(\hat \cdot \vec\right)^ = \hat \cdot \vec \, . Matrix exponentiating, and using the Taylor series for sine and cosine, :\begin e^ &= \sum_^\infty \\ &= \sum_^\infty + i\sum_^\infty \\ &= I\sum_^\infty + i (\hat\cdot \vec) \sum_^\infty\\ \end. In the last line, the first sum is the cosine, while the second sum is the sine; so, finally, which is analogous to
Euler's formula Euler's formula, named after Leonhard Euler, is a mathematical formula in complex analysis that establishes the fundamental relationship between the trigonometric functions and the complex exponential function. Euler's formula states that ...
, extended to
quaternions In mathematics, the quaternion number system extends the complex numbers. Quaternions were first described by the Irish mathematician William Rowan Hamilton in 1843 and applied to mechanics in three-dimensional space. Hamilton defined a quater ...
. Note that :\det a(\hat \cdot \vec)= a^2, while the determinant of the exponential itself is just , which makes it the generic group element of SU(2). A more abstract version of formula for a general matrix can be found in the article on matrix exponentials. A general version of for an analytic (at ''a'' and −''a'') function is provided by application of Sylvester's formula, :f(a(\hat \cdot \vec)) = I\frac + \hat \cdot \vec \frac ~.


The group composition law of

A straightforward application of formula provides a parameterization of the composition law of the group . One may directly solve for in :\begin e^ e^ &= I\left(\cos a \cos b - \hat \cdot \hat \sin a \sin b\right) + i\left(\hat \sin a \cos b + \hat \sin b \cos a - \hat \times \hat ~ \sin a \sin b \right) \cdot \vec \\ &= I\cos + i \left(\hat \cdot \vec\right) \sin c \\ &= e^, \end which specifies the generic group multiplication, where, manifestly, :\cos c = \cos a \cos b - \hat \cdot \hat \sin a \sin b~, the spherical law of cosines. Given , then, :\hat = \frac\left(\hat \sin a \cos b + \hat \sin b \cos a - \hat\times\hat \sin a \sin b\right) ~. Consequently, the composite rotation parameters in this group element (a closed form of the respective BCH expansion in this case) simply amount to (Of course, when \hat is parallel to \hat, so is \hat, and .)


Adjoint action

It is also straightforward to likewise work out the adjoint action on the Pauli vector, namely rotation of any angle a along any axis \hat n: : R_n(-a) ~ \vec ~ R_n(a) = e^ ~ \vec ~ e^ = \vec\cos (a) + \hat \times \vec ~ \sin(a) + \hat ~ \hat \cdot \vec ~ (1 - \cos(a)) ~ . Taking the dot product of any unit vector with the above formula generates the expression of any single qubit operator under any rotation. For example, it can be shown that R_y\mathord\left(-\frac\right)\, \sigma_x\, R_y\mathord\left(\frac\right) = \hat \cdot \left(\hat \times \vec\right) = \sigma_z.


Completeness relation

An alternative notation that is commonly used for the Pauli matrices is to write the vector index in the superscript, and the matrix indices as subscripts, so that the element in row and column of the -th Pauli matrix is In this notation, the ''completeness relation'' for the Pauli matrices can be written :\vec_\cdot\vec_\equiv \sum_^3 \sigma^k_\,\sigma^k_ = 2\,\delta_ \,\delta_ - \delta_\,\delta_~. As noted above, it is common to denote the 2 × 2 unit matrix by so The completeness relation can alternatively be expressed as \sum_^3 \sigma^k_\,\sigma^k_ = 2\,\delta_\,\delta_ ~ . The fact that any Hermitian complex 2 × 2 matrices can be expressed in terms of the identity matrix and the Pauli matrices also leads to the Bloch sphere representation of 2 × 2 mixed states’ density matrix, ( positive semidefinite 2 × 2 matrices with unit trace. This can be seen by first expressing an arbitrary Hermitian matrix as a real linear combination of as above, and then imposing the positive-semidefinite and trace conditions. For a pure state, in polar coordinates, \vec = \begin\sin\theta \cos\phi & \sin\theta \sin\phi & \cos\theta\end, the
idempotent Idempotence (, ) is the property of certain operations in mathematics and computer science whereby they can be applied multiple times without changing the result beyond the initial application. The concept of idempotence arises in a number of pl ...
density matrix \tfrac \left(\mathbf + \vec \cdot \vec\right) = \begin \cos^2\left(\frac\right) & e^\sin\left(\frac\right)\cos\left(\frac\right) \\ e^\sin\left(\frac\right)\cos\left(\frac\right) & \sin^2\left(\frac\right) \end acts on the state eigenvector \begin\cos\left(\frac\right) & e^\,\sin\left(\frac\right) \end with eigenvalue +1, hence it acts like a
projection operator In linear algebra and functional analysis, a projection is a linear transformation P from a vector space to itself (an endomorphism) such that P\circ P=P. That is, whenever P is applied twice to any vector, it gives the same result as if it wer ...
.


Relation with the permutation operator

Let be the transposition (also known as a permutation) between two spins and living in the
tensor product In mathematics, the tensor product V \otimes W of two vector spaces and (over the same field) is a vector space to which is associated a bilinear map V\times W \to V\otimes W that maps a pair (v,w),\ v\in V, w\in W to an element of V \otime ...
space :P_ \left, \sigma_j \sigma_k \right\rangle = \left, \sigma_k \sigma_j \right\rangle ~. This operator can also be written more explicitly as Dirac's spin exchange operator, :P_ = \frac\,\left(\vec_j \cdot \vec_k + 1\right) ~ . Its eigenvalues are therefore 1 or −1. It may thus be utilized as an interaction term in a Hamiltonian, splitting the energy eigenvalues of its symmetric versus antisymmetric eigenstates.


SU(2)

The group SU(2) is the
Lie group In mathematics, a Lie group (pronounced ) is a group that is also a differentiable manifold. A manifold is a space that locally resembles Euclidean space, whereas groups define the abstract concept of a binary operation along with the addi ...
of
unitary Unitary may refer to: Mathematics * Unitary divisor * Unitary element * Unitary group * Unitary matrix * Unitary morphism * Unitary operator * Unitary transformation * Unitary representation In mathematics, a unitary representation of a grou ...
matrices with unit determinant; its
Lie algebra In mathematics, a Lie algebra (pronounced ) is a vector space \mathfrak g together with an operation called the Lie bracket, an alternating bilinear map \mathfrak g \times \mathfrak g \rightarrow \mathfrak g, that satisfies the Jacobi identi ...
is the set of all anti-Hermitian matrices with trace 0. Direct calculation, as above, shows that the
Lie algebra In mathematics, a Lie algebra (pronounced ) is a vector space \mathfrak g together with an operation called the Lie bracket, an alternating bilinear map \mathfrak g \times \mathfrak g \rightarrow \mathfrak g, that satisfies the Jacobi identi ...
\mathfrak_2 is the 3-dimensional real algebra spanned by the set . In compact notation, : \mathfrak(2) = \operatorname \~. As a result, each can be seen as an infinitesimal generator of SU(2). The elements of SU(2) are exponentials of linear combinations of these three generators, and multiply as indicated above in discussing the Pauli vector. Although this suffices to generate SU(2), it is not a proper representation of , as the Pauli eigenvalues are scaled unconventionally. The conventional normalization is so that : \mathfrak(2) = \operatorname \left\~. As SU(2) is a compact group, its Cartan decomposition is trivial.


SO(3)

The Lie algebra \mathfrak(2) is
isomorphic In mathematics, an isomorphism is a structure-preserving mapping between two structures of the same type that can be reversed by an inverse mapping. Two mathematical structures are isomorphic if an isomorphism exists between them. The word i ...
to the Lie algebra \mathfrak(3), which corresponds to the Lie group SO(3), the group of
rotation Rotation, or spin, is the circular movement of an object around a '' central axis''. A two-dimensional rotating object has only one possible central axis and can rotate in either a clockwise or counterclockwise direction. A three-dimensional ...
s in three-dimensional space. In other words, one can say that the are a realization (and, in fact, the lowest-dimensional realization) of ''infinitesimal'' rotations in three-dimensional space. However, even though \mathfrak(2) and \mathfrak(3) are isomorphic as Lie algebras, and are not isomorphic as Lie groups. is actually a double cover of , meaning that there is a two-to-one group homomorphism from to , see relationship between SO(3) and SU(2).


Quaternions

The real linear span of is isomorphic to the real algebra of
quaternions In mathematics, the quaternion number system extends the complex numbers. Quaternions were first described by the Irish mathematician William Rowan Hamilton in 1843 and applied to mechanics in three-dimensional space. Hamilton defined a quater ...
, \mathbb, represented by the span of the basis vectors \left\ . The isomorphism from \mathbb to this set is given by the following map (notice the reversed signs for the Pauli matrices): : \mathbf \mapsto I, \quad \mathbf \mapsto - \sigma_2\sigma_3 = - i\,\sigma_1, \quad \mathbf \mapsto - \sigma_3\sigma_1 = - i\,\sigma_2, \quad \mathbf \mapsto - \sigma_1\sigma_2 = - i\,\sigma_3. Alternatively, the isomorphism can be achieved by a map using the Pauli matrices in reversed order, : \mathbf \mapsto I, \quad \mathbf \mapsto i\,\sigma_3 \, , \quad \mathbf \mapsto i\,\sigma_2 \, , \quad \mathbf \mapsto i\,\sigma_1 ~ . As the set of versors forms a group isomorphic to , gives yet another way of describing . The two-to-one homomorphism from to may be given in terms of the Pauli matrices in this formulation.


Physics


Classical mechanics

In
classical mechanics Classical mechanics is a physical theory describing the motion of macroscopic objects, from projectiles to parts of machinery, and astronomical objects, such as spacecraft, planets, stars, and galaxies. For objects governed by classi ...
, Pauli matrices are useful in the context of the Cayley-Klein parameters. The matrix corresponding to the position \vec of a point in space is defined in terms of the above Pauli vector matrix, :P = \vec \cdot \vec = x\,\sigma_x + y\,\sigma_y + z\,\sigma_z ~. Consequently, the transformation matrix for rotations about the -axis through an angle may be written in terms of Pauli matrices and the unit matrix as :Q_\theta = \boldsymbol\,\cos\frac + i\,\sigma_x \sin\frac ~. Similar expressions follow for general Pauli vector rotations as detailed above.


Quantum mechanics

In
quantum mechanics Quantum mechanics is a fundamental theory in physics that provides a description of the physical properties of nature at the scale of atoms and subatomic particles. It is the foundation of all quantum physics including quantum chemistry, ...
, each Pauli matrix is related to an
angular momentum operator In quantum mechanics, the angular momentum operator is one of several related operators analogous to classical angular momentum. The angular momentum operator plays a central role in the theory of atomic and molecular physics and other quantum p ...
that corresponds to an observable describing the
spin Spin or spinning most often refers to: * Spinning (textiles), the creation of yarn or thread by twisting fibers together, traditionally by hand spinning * Spin, the rotation of an object around a central axis * Spin (propaganda), an intentionally ...
of a spin particle, in each of the three spatial directions. As an immediate consequence of the Cartan decomposition mentioned above, are the generators of a
projective representation In the field of representation theory in mathematics, a projective representation of a group ''G'' on a vector space ''V'' over a field ''F'' is a group homomorphism from ''G'' to the projective linear group \mathrm(V) = \mathrm(V) / F^*, where ...
(spin representation) of the
rotation group SO(3) In mechanics and geometry, the 3D rotation group, often denoted SO(3), is the group of all rotations about the origin of three-dimensional Euclidean space \R^3 under the operation of composition. By definition, a rotation about the origin is ...
acting on non-relativistic particles with spin . The states of the particles are represented as two-component
spinors In geometry and physics, spinors are elements of a complex vector space that can be associated with Euclidean space. Like geometric vectors and more general tensors, spinors transform linearly when the Euclidean space is subjected to a sli ...
. In the same way, the Pauli matrices are related to the isospin operator. An interesting property of spin particles is that they must be rotated by an angle of 4 in order to return to their original configuration. This is due to the two-to-one correspondence between SU(2) and SO(3) mentioned above, and the fact that, although one visualizes spin up/down as the north/south pole on the 2-sphere they are actually represented by
orthogonal In mathematics, orthogonality is the generalization of the geometric notion of '' perpendicularity''. By extension, orthogonality is also used to refer to the separation of specific features of a system. The term also has specialized meanings in ...
vectors in the two dimensional complex
Hilbert space In mathematics, Hilbert spaces (named after David Hilbert) allow generalizing the methods of linear algebra and calculus from (finite-dimensional) Euclidean vector spaces to spaces that may be infinite-dimensional. Hilbert spaces arise natural ...
. For a spin particle, the spin operator is given by , the fundamental representation of SU(2). By taking
Kronecker product In mathematics, the Kronecker product, sometimes denoted by ⊗, is an operation on two matrices of arbitrary size resulting in a block matrix. It is a generalization of the outer product (which is denoted by the same symbol) from vectors to ...
s of this representation with itself repeatedly, one may construct all higher irreducible representations. That is, the resulting
spin operator Spin is a conserved quantity carried by elementary particles, and thus by composite particles (hadrons) and atomic nuclei. Spin is one of two types of angular momentum in quantum mechanics, the other being ''orbital angular momentum''. The orbita ...
s for higher spin systems in three spatial dimensions, for arbitrarily large ''j'', can be calculated using this
spin operator Spin is a conserved quantity carried by elementary particles, and thus by composite particles (hadrons) and atomic nuclei. Spin is one of two types of angular momentum in quantum mechanics, the other being ''orbital angular momentum''. The orbita ...
and ladder operators. They can be found in . The analog formula to the above generalization of Euler's formula for Pauli matrices, the group element in terms of spin matrices, is tractable, but less simple. Also useful in the
quantum mechanics Quantum mechanics is a fundamental theory in physics that provides a description of the physical properties of nature at the scale of atoms and subatomic particles. It is the foundation of all quantum physics including quantum chemistry, ...
of multiparticle systems, the general
Pauli group In physics and mathematics, the Pauli group G_1 on 1 qubit is the 16-element matrix group consisting of the 2 × 2 identity matrix I and all of the Pauli matrices :X = \sigma_1 = \begin 0&1\\ 1&0 \end,\quad Y = \sigma_2 = \begin ...
is defined to consist of all -fold
tensor In mathematics, a tensor is an algebraic object that describes a multilinear relationship between sets of algebraic objects related to a vector space. Tensors may map between different objects such as vectors, scalars, and even other tensor ...
products of Pauli matrices.


Relativistic quantum mechanics

In relativistic quantum mechanics, the spinors in four dimensions are 4 × 1 (or 1 × 4) matrices. Hence the Pauli matrices or the Sigma matrices operating on these spinors have to be 4 × 4 matrices. They are defined in terms of 2 × 2 Pauli matrices as :\mathsf_k = \begin \mathsf_k & 0 \\ 0 & \mathsf_k \end. It follows from this definition that the \; \mathsf_k \; matrices have the same algebraic properties as the matrices. However, relativistic angular momentum is not a three-vector, but a second order four-tensor. Hence \mathsf_k needs to be replaced by the generator of Lorentz transformations on spinors. By the antisymmetry of angular momentum, the are also antisymmetric. Hence there are only six independent matrices. The first three are the \; \Sigma_\equiv \epsilon_\mathsf_j ~. The remaining three, \;-i\,\Sigma_ \equiv \mathsf_k\;, where the Dirac matrices are defined as :\mathsf_k = \begin 0 & \mathsf_k\\ \mathsf_k & 0\end~. The relativistic spin matrices are written in compact form in terms of commutator of gamma matrices as :\Sigma_ = \frac\left gamma_\mu, \gamma_\nu\right.


Quantum information

In
quantum information Quantum information is the information of the state of a quantum system. It is the basic entity of study in quantum information theory, and can be manipulated using quantum information processing techniques. Quantum information refers to both ...
, single- qubit quantum gates are 2 × 2 unitary matrices. The Pauli matrices are some of the most important single-qubit operations. In that context, the Cartan decomposition given above is called the "Z–Y decomposition of a single-qubit gate". Choosing a different Cartan pair gives a similar "X–Y ''decomposition of a single-qubit gate".


See also

* Algebra of physical space *
Spinors in three dimensions In mathematics, the spinor concept as specialised to three dimensions can be treated by means of the traditional notions of dot product and cross product. This is part of the detailed algebraic discussion of the rotation group SO(3). Formulation ...
* Gamma matrices ** *
Angular momentum In physics, angular momentum (rarely, moment of momentum or rotational momentum) is the rotational analog of linear momentum. It is an important physical quantity because it is a conserved quantity—the total angular momentum of a closed syst ...
* Gell-Mann matrices * Poincaré group * Generalizations of Pauli matrices * Bloch sphere *
Euler's four-square identity In mathematics, Euler's four-square identity says that the product of two numbers, each of which is a sum of four squares, is itself a sum of four squares. Algebraic identity For any pair of quadruples from a commutative ring, the following expre ...
* For higher spin generalizations of the Pauli matrices, see * Exchange matrix (the first Pauli matrix is an exchange matrix of order two)


Remarks


Notes


References

* * * {{Matrix classes Lie groups Matrices Rotational symmetry Articles containing proofs Mathematical physics