Potassium octachlorodimolybdate (systematically named potassium bis(tetrachloromolybdate)(''Mo''–''Mo'')(4−)) is an

inorganic compound An inorganic compound is typically a chemical compound that lacks carbon–hydrogen bonds⁠that is, a compound that is not an organic compound. The study of inorganic compounds is a subfield of chemistry known as ''inorganic chemistry''. Inorgan ...

with the

chemical formula A chemical formula is a way of presenting information about the chemical proportions of atoms that constitute a particular chemical compound or molecule, using chemical element symbols, numbers, and sometimes also other symbols, such as pare ...

. It is known as a red-coloured, microcrystalline solid. The anion is of historic interest as one of the earliest illustrations of a quadruple bonding. The salt is usually obtained as the pink-coloured dihydrate. The compound is prepared in two steps from molybdenum hexacarbonyl: : : The reaction of the acetate with HCl was first described as providing trimolybdenum compounds, but subsequent crystallographic analysis confirmed that the salt contains the

anion An ion () is an atom or molecule with a net electrical charge. The charge of an electron is considered to be negative by convention and this charge is equal and opposite to the charge of a proton, which is considered to be positive by conven ...

, with D_4h symmetry, in which the two Mo atoms are linked by a quadruple bond. Each Mo atom is bounded with four

ligands In coordination chemistry, a ligand is an ion or molecule with a functional group that binds to a central metal atom to form a coordination complex. The bonding with the metal generally involves formal donation of one or more of the ligand's ...

by a single bond. Each group is a regular square pyramid, with an Mo atom at the

apex The apex is the highest point of something. The word may also refer to: Arts and media Fictional entities * Apex (comics) A-Bomb Abomination Absorbing Man Abraxas Abyss Abyss is the name of two characters appearing in Ameri ...

, and four Cl atoms at the vertices of the

square In geometry, a square is a regular polygon, regular quadrilateral. It has four straight sides of equal length and four equal angles. Squares are special cases of rectangles, which have four equal angles, and of rhombuses, which have four equal si ...

base of the

pyramid A pyramid () is a structure whose visible surfaces are triangular in broad outline and converge toward the top, making the appearance roughly a pyramid in the geometric sense. The base of a pyramid can be of any polygon shape, such as trian ...

. The Mo–Mo distance is 214 pm.

References

{{Molybdates Potassium compounds Molybdenum compounds Chloro complexes Chemical compounds containing metal–metal bonds