Potassium Bicarbonate
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Potassium bicarbonate ( IUPAC name: potassium hydrogencarbonate, also known as potassium acid carbonate) is the
inorganic compound An inorganic compound is typically a chemical compound that lacks carbon–hydrogen bonds⁠that is, a compound that is not an organic compound. The study of inorganic compounds is a subfield of chemistry known as ''inorganic chemistry''. Inorgan ...
with the chemical formula KHCO3. It is a white solid.


Production and reactivity

It is manufactured by treating an aqueous solution of potassium carbonate or
potassium hydroxide Potassium hydroxide is an inorganic compound with the formula K OH, and is commonly called caustic potash. Along with sodium hydroxide (NaOH), KOH is a prototypical strong base. It has many industrial and niche applications, most of which utili ...
with
carbon dioxide Carbon dioxide is a chemical compound with the chemical formula . It is made up of molecules that each have one carbon atom covalent bond, covalently double bonded to two oxygen atoms. It is found in a gas state at room temperature and at norma ...
: :K2CO3 + CO2 + H2O → 2 KHCO3 Decomposition of the bicarbonate occurs between : :2 KHCO3 → K2CO3 + CO2 + H2O This reaction is employed to prepare high purity potassium carbonate.


Uses


Food and drink

This compound is a source of
carbon dioxide Carbon dioxide is a chemical compound with the chemical formula . It is made up of molecules that each have one carbon atom covalent bond, covalently double bonded to two oxygen atoms. It is found in a gas state at room temperature and at norma ...
for leavening in baking. It can substitute for
baking soda Sodium bicarbonate (IUPAC name: sodium hydrogencarbonate), commonly known as baking soda or bicarbonate of soda (or simply “bicarb” especially in the UK) is a chemical compound with the formula NaHCO3. It is a salt (chemistry), salt compose ...
(sodium bicarbonate) for those with a low-sodium diet, and it is an ingredient in low-sodium baking powders. As an inexpensive, nontoxic base, it is widely used in diverse application to regulate pH or as a
reagent In chemistry, a reagent ( ) or analytical reagent is a substance or compound added to a system to cause a chemical reaction, or test if one occurs. The terms ''reactant'' and ''reagent'' are often used interchangeably, but reactant specifies a ...
. Examples include as
buffering agent A buffer solution is a solution where the pH does not change significantly on dilution or if an acid or base is added at constant temperature. Its pH changes very little when a small amount of strong acid or base is added to it. Buffer solution ...
in medications, an additive in
winemaking Winemaking, wine-making, or vinification is the production of wine, starting with the selection of the fruit, its Ethanol fermentation, fermentation into alcohol, and the bottling of the finished liquid. The history of wine-making stretches over ...
. Potassium bicarbonate is often added to
bottled water Bottled water is drinking water (e.g., Water well, well water, distilled water, Reverse osmosis, reverse osmosis water, mineral water, or Spring (hydrology), spring water) packaged in Plastic bottle, plastic or Glass bottle, glass water bott ...
to improve taste, and is also used in
club soda Club soda is a form of carbonated water manufactured in North America, commonly used as a drink mixer. Sodium bicarbonate, potassium sulfate, potassium bicarbonate, potassium citrate, or sodium citrate is added to artificially replicate constitu ...
.


Medical uses and health

Higher
potassium Potassium is a chemical element; it has Symbol (chemistry), symbol K (from Neo-Latin ) and atomic number19. It is a silvery white metal that is soft enough to easily cut with a knife. Potassium metal reacts rapidly with atmospheric oxygen to ...
intake may prevent development of
kidney stone disease Kidney stone disease (known as nephrolithiasis, renal calculus disease, or urolithiasis) is a crystallopathy and occurs when there are too many minerals in the urine and not enough liquid or hydration. This imbalance causes tiny pieces of cry ...
. Higher potassium intake is associated with a reduced risk of
stroke Stroke is a medical condition in which poor cerebral circulation, blood flow to a part of the brain causes cell death. There are two main types of stroke: brain ischemia, ischemic, due to lack of blood flow, and intracranial hemorrhage, hemor ...
.


Fire extinguishers

Potassium bicarbonate is used as a fire suppression agent ("BC dry chemical") in some dry chemical
fire extinguisher A fire extinguisher is a handheld active fire protection device usually filled with a dry or wet chemical used to extinguish or control small fires, often in emergencies. It is not intended for use on an out-of-control fire, such as one which ha ...
s, as the principal component of the Purple-K dry chemical, and in some applications of condensed aerosol fire suppression. It is the only dry chemical fire suppression agent recognized by the U.S.
National Fire Protection Association The National Fire Protection Association (NFPA) is a U.S.-based international nonprofit organization devoted to eliminating death, injury, property damage, and economic loss due to fire, electrical, and related hazards. , the NFPA claims to have 5 ...
for firefighting at airport crash rescue sites. It is about twice as effective in fire suppression as
sodium bicarbonate Sodium bicarbonate ( IUPAC name: sodium hydrogencarbonate), commonly known as baking soda or bicarbonate of soda (or simply “bicarb” especially in the UK) is a chemical compound with the formula NaHCO3. It is a salt composed of a sodium cat ...
.


Agriculture

Potassium bicarbonate has widespread use in crops, especially for neutralizing acidic soil. Potassium bicarbonate is an effective
fungicide Fungicides are pesticides used to kill parasitic fungi or their spores. Fungi can cause serious damage in agriculture, resulting in losses of yield and quality. Fungicides are used both in agriculture and to fight fungal infections in animals, ...
against
powdery mildew Powdery mildew is a fungus, fungal disease that affects a wide range of plants. Powdery mildew diseases are caused by many different species of Ascomycota, ascomycete fungi in the order Erysiphales. Powdery mildew is one of the easier plant disea ...
and
apple scab Apple scab is a common disease of plants in the rose family (Rosaceae) that is caused by the ascomycete fungus ''Venturia inaequalis''. While this disease affects several plant genera, including '' Sorbus, Cotoneaster,'' and '' Pyrus'', it is ...
, allowed for use in
organic farming Organic farming, also known as organic agriculture or ecological farming or biological farming,Labelling, article 30 o''Regulation (EU) 2018/848 of the European Parliament and of the Council of 30 May 2024 on organic production and labelling of ...
. Potassium bicarbonate is a contact killer for Spanish moss when mixed
cup A cup is an open-top vessel (container) used to hold liquids for drinking, typically with a flattened hemispherical shape, and often with a capacity of about . Cups may be made of pottery (including porcelain), glass, metal, wood, stone, pol ...
per
gallon The gallon is a unit of volume in British imperial units and United States customary units. The imperial gallon (imp gal) is defined as , and is or was used in the United Kingdom and its former colonies, including Ireland, Canada, Australia ...
.


History

The word ''saleratus'', from
Latin Latin ( or ) is a classical language belonging to the Italic languages, Italic branch of the Indo-European languages. Latin was originally spoken by the Latins (Italic tribe), Latins in Latium (now known as Lazio), the lower Tiber area aroun ...
''sal æratus'' meaning "aerated salt", first used in the nineteenth century, refers to both potassium bicarbonate and sodium bicarbonate.


References


External links


Potassium Bicarbonate Handbook

OMRI Potassium Bicarbonate

Safety Data sheet - potassium bicarbonate
* {{Authority control Potassium compounds Acid salts Fire suppression agents