Poly(2,6-diphenyl-p-phenylene oxide) (PPPO) is a porous

polymer A polymer (; Greek ''poly-'', "many" + '' -mer'', "part") is a substance or material consisting of very large molecules called macromolecules, composed of many repeating subunits. Due to their broad spectrum of properties, both synthetic and ...

resin In polymer chemistry and materials science, resin is a solid or highly viscous substance of plant or synthetic origin that is typically convertible into polymers. Resins are usually mixtures of organic compounds. This article focuses on n ...

based on

oxidative polymerisation Redox (reduction–oxidation, , ) is a type of chemical reaction in which the oxidation states of substrate change. Oxidation is the loss of electrons or an increase in the oxidation state, while reduction is the gain of electrons or a ...

of 2,6-diphenylphenol. It is mostly known by its trademark Tenax.

Properties

Poly(2,6-diphenylphenylene oxide) is a low bleeding material with a low level of impurities, and has a high thermal stability (up to 350 °C). Before use poly(2,6-diphenylphenylene oxide) should be thermally conditioned with a high purity gas at elevated temperatures to remove any residual components. During conditioning or thermal desorption the presence of oxygen should be avoided. Poly(2,6-diphenylphenylene oxide) reacts with oxidising agents such as

chlorine Chlorine is a chemical element with the symbol Cl and atomic number 17. The second-lightest of the halogens, it appears between fluorine and bromine in the periodic table and its properties are mostly intermediate between them. Chlorine is ...

ozone Ozone (), or trioxygen, is an inorganic molecule with the chemical formula . It is a pale blue gas with a distinctively pungent smell. It is an allotrope of oxygen that is much less stable than the diatomic allotrope , breaking down in the lo ...

nitrogen oxides Nitrogen oxide may refer to a binary compound of oxygen and nitrogen, or a mixture of such compounds: Charge-neutral *Nitric oxide (NO), nitrogen(II) oxide, or nitrogen monoxide *Nitrogen dioxide (), nitrogen(IV) oxide * Nitrogen trioxide (), or ...

and

sulfur oxide Sulfur oxide refers to many types of sulfur and oxygen containing compounds such as SO, SO2, SO3, S7O2, S6O2, S2O2, etc. Sulfur oxide (SO''x'') refers to one or more of the following: * Lower sulfur oxides (S''n''O, S7O2 and S6O2) * Sulfur mono ...

s forming

acetophenone Acetophenone is the organic compound with the formula C6H5C(O)CH3. It is the simplest aromatic ketone. This colorless, viscous liquid is a precursor to useful resins and fragrances. Production Acetophenone is formed as a byproduct of the cumene ...

benzaldehyde Benzaldehyde (C6H5CHO) is an organic compound consisting of a benzene ring with a formyl substituent. It is the simplest aromatic aldehyde and one of the most industrially useful. It is a colorless liquid with a characteristic almond-like odor. ...

and

phenol Phenol (also called carbolic acid) is an aromatic organic compound with the molecular formula . It is a white crystalline solid that is volatile. The molecule consists of a phenyl group () bonded to a hydroxy group (). Mildly acidic, it ...

. Therefore, control of blanks is essential and storage time of samples on poly(2,6-diphenylphenylene oxide) is less than a month. Pre-filters based on sodium thiosulphate or

Teflon Polytetrafluoroethylene (PTFE) is a synthetic fluoropolymer of tetrafluoroethylene that has numerous applications. It is one of the best-known and widely applied PFAS. The commonly known brand name of PTFE-based composition is Teflon by Chem ...

may be appropriate to use. The breakthrough volumes are low for very volatile substances. This problem is partly solved by graphitised poly(2,6-diphenylphenylene oxide). Although the polymer has a low affinity for water, high humidity in air may lower the breakthrough volumes of substances.

Use

Poly(2,6-diphenylphenylene oxide) is used for trapping of volatiles and semi-volatiles from air such as environmental air and human breath, and for personal exposure monitoring. It is also used for determining the emission of chemical substances from plants, soil and commercial products. Volatile substances in liquid or solid matrices can be made available by the

purge and trap In history, religion and political science, a purge is a position removal or execution of people who are considered undesirable by those in power from a government, another organization, their team leaders, or society as a whole. A group undertak ...

technique. The polymer is of particularly used for concentration of high boiling compounds such as

alcohols In chemistry, an alcohol is a type of organic compound that carries at least one hydroxyl () functional group bound to a saturated carbon atom. The term ''alcohol'' originally referred to the primary alcohol ethanol (ethyl alcohol), which i ...

polyethylene glycol Polyethylene glycol (PEG; ) is a polyether compound derived from petroleum with many applications, from industrial manufacturing to medicine. PEG is also known as polyethylene oxide (PEO) or polyoxyethylene (POE), depending on its molecular w ...

diol A diol is a chemical compound containing two hydroxyl groups ( groups). An aliphatic diol is also called a glycol. This pairing of functional groups is pervasive, and many subcategories have been identified. The most common industrial diol is ...

monoamine Monoamine neurotransmitters are neurotransmitters and neuromodulators that contain one amino group connected to an aromatic ring by a two-carbon chain (such as -CH2-CH2-). Examples are dopamine, norepinephrine and serotonin. All monoamines ar ...

s and

diamine A diamine is an amine with exactly two amino groups. Diamines are used as monomers to prepare polyamides, polyimides, and polyureas. The term ''diamine'' refers mostly to primary diamines, as those are the most reactive. In terms of quantiti ...

s, ethanolamines,

amide In organic chemistry, an amide, also known as an organic amide or a carboxamide, is a compound with the general formula , where R, R', and R″ represent organic groups or hydrogen atoms. The amide group is called a peptide bond when it is ...

aldehyde In organic chemistry, an aldehyde () is an organic compound containing a functional group with the structure . The functional group itself (without the "R" side chain) can be referred to as an aldehyde but can also be classified as a formyl group ...

ketone In organic chemistry, a ketone is a functional group with the structure R–C(=O)–R', where R and R' can be a variety of carbon-containing substituents. Ketones contain a carbonyl group –C(=O)– (which contains a carbon-oxygen double bon ...

s and

chlorinated aromatics In chemistry, halogenation is a chemical reaction that entails the introduction of one or more halogens into a compound. Halide-containing compounds are pervasive, making this type of transformation important, e.g. in the production of polymers, ...

. Poly(2,6-diphenylphenylene oxide) is used as food simulant for testing the release of chemical substances from food contact materials into

food Food is any substance consumed by an organism for nutritional support. Food is usually of plant, animal, or fungal origin, and contains essential nutrients, such as carbohydrates, fats, proteins, vitamins, or minerals. The substance is ...

.Consolidated text
of European COUNCIL DIRECTIVE of 18 October 1982 laying down the basic rules necessary for testing migration of the constituents of plastic materials and articles intended to come into contact with foodstuffs (82/711/EEC) Office for Official Publications of the European Communities 01/09/1997

Trademarks

Tenax is a registered trademark of Buchem B.V. * Tenax GC (replaced by Tenax TA) * Tenax TA (mesh 20-35, 35-60, 60-80, 80-100, 100-200) * Tenax GR: 23% graphite (mesh 20-35, 35-60, 60-80, 80-100)

References

External links

Buchem B.V.
*Henry J. McDermott, Shirley A. Ness (2004
Air monitoring for toxic exposures
2nd Ed, John Wiley and Sons, 172-173, , *Șerban Moldoveanu, Víctor David (2002
Sample preparation in chromatography
Journal of Chromatography Library 65, Elsevier, 277-278, , {{ISBN, 978-0-444-50394-7 Organic polymers