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Plastic explosive is a soft and hand-moldable solid form of
explosive material An explosive (or explosive material) is a reactive substance that contains a great amount of potential energy that can produce an explosion if released suddenly, usually accompanied by the production of light, heat, sound, and pressure. An exp ...
. Within the field of
explosives engineering Explosives engineering is the field of science and engineering which is related to examining the behavior and usage of explosive materials. Topics Some of the topics that explosives engineers study, research, and work on include: * Developmen ...
, plastic explosives are also known as putty explosives or blastics. Plastic explosives are especially suited for explosive
demolition Demolition (also known as razing and wrecking) is the science and engineering in safely and efficiently tearing down buildings and other artificial structures. Demolition contrasts with deconstruction (building), deconstruction, which inv ...
. Common plastic explosives include
Semtex Semtex is a general-purpose plastic explosive containing RDX and PETN. It is used in commercial blasting, demolition, and in certain military applications. Semtex was developed and manufactured in Czechoslovakia, originally under the name B 1 a ...
and C-4. The first manufactured plastic explosive was
gelignite Gelignite (), also known as blasting gelatin or simply "jelly", is an explosive material consisting of collodion-cotton (a type of nitrocellulose or guncotton) dissolved in either nitroglycerine or nitroglycol and mixed with wood pulp and Potassi ...
in 1875, invented by
Alfred Nobel Alfred Bernhard Nobel ( ; ; 21 October 1833 – 10 December 1896) was a Swedish chemist, inventor, engineer, and businessman. He is known for inventing dynamite, as well as having bequeathed his fortune to establish the Nobel Prizes. He also m ...
.


Usage

Plastic explosives are especially suited for explosive demolition of obstacles and
fortification A fortification (also called a fort, fortress, fastness, or stronghold) is a military construction designed for the defense of territories in warfare, and is used to establish rule in a region during peacetime. The term is derived from Lati ...
s by
combat engineer A combat engineer (also called pioneer or sapper) is a type of soldier who performs military engineering tasks in support of land forces combat operations. Combat engineers perform a variety of military engineering, Tunnel warfare, tunnel and l ...
s as they can be easily formed into ideal shapes for cutting structural members and have a high enough
velocity of detonation Explosive velocity, also known as detonation velocity or velocity of detonation (VoD), is the velocity at which the shock wave front travels through a detonation, detonated explosive. Explosive velocities are always higher than the local speed of s ...
and density for metal cutting work. An early use of plastic explosives was in the warhead of the Petard demolition mortar of the British Armoured Vehicle Royal Engineers (AVRE) which was used to destroy concrete fortifications encountered during
Operation Overlord Operation Overlord was the codename for the Battle of Normandy, the Allies of World War II, Allied operation that launched the successful liberation of German-occupied Western Front (World War II), Western Europe during World War II. The ope ...
(D-Day). The original use of Nobel 808 supplied by the SOE was for sabotage of German installations and railways in
Occupied Europe German-occupied Europe, or Nazi-occupied Europe, refers to the sovereign countries of Europe which were wholly or partly militarily occupied and civil-occupied, including puppet states, by the (armed forces) and the government of Nazi Germany at ...
. They are generally not used for ordinary blasting as they tend to be significantly more expensive than other materials that perform just as well. A common commercial use of plastic explosives is for shock hardening high
manganese Manganese is a chemical element; it has Symbol (chemistry), symbol Mn and atomic number 25. It is a hard, brittle, silvery metal, often found in minerals in combination with iron. Manganese was first isolated in the 1770s. It is a transition m ...
percentage steel, a material typically used for train rail components and earth digging implements. Reactive armor in tanks uses plastic explosives sandwiched between two plates of steel. Incoming high explosive shaped charge anti-tank rounds pierce the outer steel plate, then detonate the plastic explosive. This disrupts the energy from the incoming round and shields the tank.


History

The first plastic explosive was
gelignite Gelignite (), also known as blasting gelatin or simply "jelly", is an explosive material consisting of collodion-cotton (a type of nitrocellulose or guncotton) dissolved in either nitroglycerine or nitroglycol and mixed with wood pulp and Potassi ...
, invented by
Alfred Nobel Alfred Bernhard Nobel ( ; ; 21 October 1833 – 10 December 1896) was a Swedish chemist, inventor, engineer, and businessman. He is known for inventing dynamite, as well as having bequeathed his fortune to establish the Nobel Prizes. He also m ...
in 1875. Prior to
World War I World War I or the First World War (28 July 1914 – 11 November 1918), also known as the Great War, was a World war, global conflict between two coalitions: the Allies of World War I, Allies (or Entente) and the Central Powers. Fighting to ...
, the British explosives chemist Oswald Silberrad obtained British and U.S. patents for a series of plastic explosives called "Nitrols", composed of nitrated
aromatics Aromatic compounds or arenes are organic compounds "with a chemistry typified by benzene" and "cyclically conjugated." The word "aromatic" originates from the past grouping of molecules based on odor, before their general chemical properties were ...
,
collodion Collodion is a flammable, syrupy solution of nitrocellulose in Diethyl ether, ether and Alcohol (chemistry), alcohol. There are two basic types: flexible and non-flexible. The flexible type is often used as a surgical dressing or to hold dressings ...
, and oxidising inorganic salts. The language of the patents indicate that at this time, Silberrad saw no need to explain to "those versed in the art" either what he meant by plasticity or why it may be advantageous, as he only explains why his plastic explosive is superior to others of that type. One of the simplest plastic explosives was Nobel's Explosive No. 808, of the gelignite type, also known as ''Nobel 808'' (often just called ''Explosive 808'' in the
British Armed Forces The British Armed Forces are the unified military, military forces responsible for the defence of the United Kingdom, its British Overseas Territories, Overseas Territories and the Crown Dependencies. They also promote the UK's wider interests ...
during the
Second World War World War II or the Second World War (1 September 1939 – 2 September 1945) was a World war, global conflict between two coalitions: the Allies of World War II, Allies and the Axis powers. World War II by country, Nearly all of the wo ...
), developed by the British company Nobel Chemicals Ltd well before World War II. It had the appearance of green plasticine with a distinctive smell of almonds. During World War II it was extensively used by the British
Special Operations Executive Special Operations Executive (SOE) was a British organisation formed in 1940 to conduct espionage, sabotage and reconnaissance in German-occupied Europe and to aid local Resistance during World War II, resistance movements during World War II. ...
(SOE) at Aston House for sabotage missions. It is also the explosive used in HESH
anti-tank Anti-tank warfare refers to the military strategies, tactics, and weapon systems designed to counter and destroy enemy armored vehicles, particularly tanks. It originated during World War I following the first deployment of tanks in 1916, and ...
shells and was an essential factor in the devising of the Gammon grenade. Captured SOE-supplied Nobel 808 was the explosive used in the failed
20 July plot The 20 July plot, sometimes referred to as Operation Valkyrie, was a failed attempt to assassinate Adolf Hitler, the chancellor and leader of Nazi Germany, and overthrow the Nazi regime on 20 July 1944. The plotters were part of the German r ...
assassination attempt on
Adolf Hitler Adolf Hitler (20 April 1889 – 30 April 1945) was an Austrian-born German politician who was the dictator of Nazi Germany from 1933 until Death of Adolf Hitler, his suicide in 1945. Adolf Hitler's rise to power, He rose to power as the lea ...
in 1944. During and after World War II a number of new
RDX RDX (Research Department Explosive or Royal Demolition Explosive) or hexogen, among other names, is an organic compound with the formula (CH2N2O2)3. It is white, odorless, and tasteless, widely used as an explosive. Chemically, it is classified ...
-based explosives were developed, including Compositions C, C2, and eventually C3. Together with RDX, these incorporate various plasticizers to decrease sensitivity and make the composition plastic. The origin of the obsolete term "plastique" dates back to the Nobel 808 explosive introduced to the U.S. by the British in 1940. The samples of explosive brought to the U.S. by the Tizard Mission had already been packaged by the SOE ready for dropping via parachute container to the
French Resistance The French Resistance ( ) was a collection of groups that fought the German military administration in occupied France during World War II, Nazi occupation and the Collaboration with Nazi Germany and Fascist Italy#France, collaborationist Vic ...
and were therefore labeled in French, as ''Explosif Plastique''. It is still referred to by this name in France and also by some Americans.


Types


Composition C

The British used a plastic explosive during World War II as a demolition charge. The specific explosive, Composition C, was 88.3% RDX and 11.7% non-oily, non-explosive plasticizer. The material was plastic between , but was brittle at colder temperatures and gummy at higher temperatures. Composition C was superseded by Composition C2, which used a mixture of 80% RDX and 20% plasticizer. Composition C2 had a wider temperature range at which it remained plastic, from . Composition C2 was replaced by Composition C3, which was a mixture of 77% RDX and 23% explosive plasticizer. C3 was effective but proved to be too brittle in cold weather and was replaced with C4. There are three classes of C4, with varying amounts of RDX and polyisobutylene.


Semtex

File:C4 explosive.jpg, A demolition charge of C4 explosive File:USMC-100609-M-0761B-014.jpg, A Marine shapes a charge of C4 to cut through solid steel at a demolitions range File:Semtex H 1.jpg, Two blocks of
Semtex Semtex is a general-purpose plastic explosive containing RDX and PETN. It is used in commercial blasting, demolition, and in certain military applications. Semtex was developed and manufactured in Czechoslovakia, originally under the name B 1 a ...
-1H (note the characteristic orange color) and an American M112 charge containing C4


List of plastic explosives

*
Australia Australia, officially the Commonwealth of Australia, is a country comprising mainland Australia, the mainland of the Australia (continent), Australian continent, the island of Tasmania and list of islands of Australia, numerous smaller isl ...
: PE4, PE4-MC *
Austria Austria, formally the Republic of Austria, is a landlocked country in Central Europe, lying in the Eastern Alps. It is a federation of nine Federal states of Austria, states, of which the capital Vienna is the List of largest cities in Aust ...
: KNAUERIT SPEZIAL *
Czech Republic The Czech Republic, also known as Czechia, and historically known as Bohemia, is a landlocked country in Central Europe. The country is bordered by Austria to the south, Germany to the west, Poland to the northeast, and Slovakia to the south ...
:
Semtex Semtex is a general-purpose plastic explosive containing RDX and PETN. It is used in commercial blasting, demolition, and in certain military applications. Semtex was developed and manufactured in Czechoslovakia, originally under the name B 1 a ...
-1H (orange-colored), Semtex 1A (red-colored), Semtex 10 (also called Pl Np 10; black-colored), Pl Hx 30 (gray-colored) *
Finland Finland, officially the Republic of Finland, is a Nordic country in Northern Europe. It borders Sweden to the northwest, Norway to the north, and Russia to the east, with the Gulf of Bothnia to the west and the Gulf of Finland to the south, ...
: PENO *
France France, officially the French Republic, is a country located primarily in Western Europe. Overseas France, Its overseas regions and territories include French Guiana in South America, Saint Pierre and Miquelon in the Atlantic Ocean#North Atlan ...
: Hexomax, Composition C-4 PLASTRITE (FORMEX P1, Pla Np 87) *
Germany Germany, officially the Federal Republic of Germany, is a country in Central Europe. It lies between the Baltic Sea and the North Sea to the north and the Alps to the south. Its sixteen States of Germany, constituent states have a total popu ...
: Sprengkörper DM12, P8301, Seismoplast 1 (Sprengmasse, formbar) *
Netherlands , Terminology of the Low Countries, informally Holland, is a country in Northwestern Europe, with Caribbean Netherlands, overseas territories in the Caribbean. It is the largest of the four constituent countries of the Kingdom of the Nether ...
: Knaverit S1 (light orange-colored) *
Greece Greece, officially the Hellenic Republic, is a country in Southeast Europe. Located on the southern tip of the Balkan peninsula, it shares land borders with Albania to the northwest, North Macedonia and Bulgaria to the north, and Turkey to th ...
: C3, C4 *
India India, officially the Republic of India, is a country in South Asia. It is the List of countries and dependencies by area, seventh-largest country by area; the List of countries by population (United Nations), most populous country since ...
: PEK-1 *
Israel Israel, officially the State of Israel, is a country in West Asia. It Borders of Israel, shares borders with Lebanon to the north, Syria to the north-east, Jordan to the east, Egypt to the south-west, and the Mediterranean Sea to the west. Isr ...
: Semtex *
Italy Italy, officially the Italian Republic, is a country in Southern Europe, Southern and Western Europe, Western Europe. It consists of Italian Peninsula, a peninsula that extends into the Mediterranean Sea, with the Alps on its northern land b ...
: T-4 Plastico *
Norway Norway, officially the Kingdom of Norway, is a Nordic countries, Nordic country located on the Scandinavian Peninsula in Northern Europe. The remote Arctic island of Jan Mayen and the archipelago of Svalbard also form part of the Kingdom of ...
: NM91 ( HMX), C4, DPX10 (PE8) *
Pakistan Pakistan, officially the Islamic Republic of Pakistan, is a country in South Asia. It is the List of countries and dependencies by population, fifth-most populous country, with a population of over 241.5 million, having the Islam by country# ...
: PE-3A *
Poland Poland, officially the Republic of Poland, is a country in Central Europe. It extends from the Baltic Sea in the north to the Sudetes and Carpathian Mountains in the south, bordered by Lithuania and Russia to the northeast, Belarus and Ukrai ...
: PMW, NITROLIT *
Russia Russia, or the Russian Federation, is a country spanning Eastern Europe and North Asia. It is the list of countries and dependencies by area, largest country in the world, and extends across Time in Russia, eleven time zones, sharing Borders ...
: PVV-5A Plastic Explosive *
Slovakia Slovakia, officially the Slovak Republic, is a landlocked country in Central Europe. It is bordered by Poland to the north, Ukraine to the east, Hungary to the south, Austria to the west, and the Czech Republic to the northwest. Slovakia's m ...
: CHEMEX (Composition C-4 equivalent), TVAREX 4A, Pl Hx 30 *
South Africa South Africa, officially the Republic of South Africa (RSA), is the Southern Africa, southernmost country in Africa. Its Provinces of South Africa, nine provinces are bounded to the south by of coastline that stretches along the Atlantic O ...
: PE9 (Composition C-4 equivalent) *
Spain Spain, or the Kingdom of Spain, is a country in Southern Europe, Southern and Western Europe with territories in North Africa. Featuring the Punta de Tarifa, southernmost point of continental Europe, it is the largest country in Southern Eur ...
: PG2, PG4, GOMA 0, GOMA 1, GOMA 2 *
Sweden Sweden, formally the Kingdom of Sweden, is a Nordic countries, Nordic country located on the Scandinavian Peninsula in Northern Europe. It borders Norway to the west and north, and Finland to the east. At , Sweden is the largest Nordic count ...
: Sprängdeg m/46, NSP711 (
PETN Pentaerythritol tetranitrate (PETN), also known as PENT, pentyl, PENTA (''ПЕНТА'', primarily in Russian), TEN (tetraeritrit nitrate), corpent, or penthrite (or, rarely and primarily in German, as ''nitropenta''), is an explosive material. ...
-based), NSH711 (cyclonite-based) *
Switzerland Switzerland, officially the Swiss Confederation, is a landlocked country located in west-central Europe. It is bordered by Italy to the south, France to the west, Germany to the north, and Austria and Liechtenstein to the east. Switzerland ...
: PLASTEX produced by SSE *
Turkey Turkey, officially the Republic of Türkiye, is a country mainly located in Anatolia in West Asia, with a relatively small part called East Thrace in Southeast Europe. It borders the Black Sea to the north; Georgia (country), Georgia, Armen ...
: Composition C-4 *
United Kingdom The United Kingdom of Great Britain and Northern Ireland, commonly known as the United Kingdom (UK) or Britain, is a country in Northwestern Europe, off the coast of European mainland, the continental mainland. It comprises England, Scotlan ...
** MOD (Ministry of Defence) explosives: PE2 (sheet explosive, superseded by SX2), PE3A (superseded by PE4), PE4 (pure to off-white slab, block, or stick, superseded by PE7 and PE8 in MOD usage), SX2 (sheet explosive, superseded by SX4), PE7 (pure to off-white slab or block, Hexomax variant), PE8 (pure to off-white slab or block, current in-service slab charge), SX4 (sheet explosive), DPX (DPX1 used in L26A1 Bangalore Torpedo Demolition Charge, DPX9 used in SABREX and as a key component of SX4) ** Non-MOD explosives: Composition C-4 (M5A1 and M112 charges produced by Mondial Defence Systems), Semtex (Several variants including Razor produced by Mondial Defence Systems, PW4 variant produced by Chemring)) *
United States The United States of America (USA), also known as the United States (U.S.) or America, is a country primarily located in North America. It is a federal republic of 50 U.S. state, states and a federal capital district, Washington, D.C. The 48 ...
: Composition C-4 (pure white block or sheet, current in-service charges designated as M112 and M118), PETN and RDX based Sheet Explosive (Primasheet, Durasheet), DURABLOCK Advanced Demolition Explosive(ADX) Produced by Donovan Commercial Industries *
Yugoslavia , common_name = Yugoslavia , life_span = 1918–19921941–1945: World War II in Yugoslavia#Axis invasion and dismemberment of Yugoslavia, Axis occupation , p1 = Kingdom of SerbiaSerbia , flag_p ...
/
Serbia , image_flag = Flag of Serbia.svg , national_motto = , image_coat = Coat of arms of Serbia.svg , national_anthem = () , image_map = , map_caption = Location of Serbia (gree ...
: PP–01 (Composition C-4 equivalent)


See also

* Convention on the Marking of Plastic Explosives


References


External links

* * {{Commons category-inline British inventions Explosives