Petrichor
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Petrichor ( ) is the earthy
scent An odor (American English) or odour (English in the Commonwealth of Nations, Commonwealth English; American and British English spelling differences#-our, -or, see spelling differences) is a smell or a scent caused by one or more volatilized ...
produced when
rain Rain is a form of precipitation where water drop (liquid), droplets that have condensation, condensed from Water vapor#In Earth's atmosphere, atmospheric water vapor fall under gravity. Rain is a major component of the water cycle and is res ...
falls on dry
soil Soil, also commonly referred to as earth, is a mixture of organic matter, minerals, gases, water, and organisms that together support the life of plants and soil organisms. Some scientific definitions distinguish dirt from ''soil'' by re ...
. The word was coined by
Isabel Joy Bear Isabel Joy Bear (4 January 1927 – 8 April 2021) was an Australian chemist who worked at CSIRO for over forty years. She was the first woman to be awarded the Royal Australian Chemical Institute Leighton Medal. She was inducted into the Victo ...
and
Richard Grenfell Thomas Richard Grenfell Thomas (29 March 1901 – 16 May 1974) was an Australian mineralogist and biochemist. He was a senior research scientist in the Commonwealth Scientific and Industrial Research Organisation (CSIRO), ending his career as chief ...
, the ethereal fluid that is the blood of the gods in
Greek mythology Greek mythology is the body of myths originally told by the Ancient Greece, ancient Greeks, and a genre of ancient Greek folklore, today absorbed alongside Roman mythology into the broader designation of classical mythology. These stories conc ...
.


Origins

A brief note on the phenomenon by (1833–1908) appeared in ''The Chemical News'' on 17 April 1891Phipson, T.L., Cause of the Odour Emitted by the Soil of a Garden after a Summer Shower", ''The Chemical News'', Vol.63, No.1638, (17 April 1891, p.179.
/ref> and was re-published in its entirety, a month later, in ''
The Scientific American ''Scientific American'', informally abbreviated ''SciAm'' or sometimes ''SA'', is an American popular science magazine. Many scientists, including Albert Einstein and Nikola Tesla, have contributed articles to it, with more than 150 Nobel Pri ...
'', in which he wrote, "This subject, with which I was occupied more than twenty-five years ago, appears from a paragraph in the last number of the ''Chemical News'' to have recently attracted the attention of Professor Berthelot and onsieur G.Andre." Phipson was referring to a short paper read by Berthelot and André at the meeting of the French Académie des Sciences on 23 April 1891, and printed in Volume 112 (1891) of ''Comptes Rendus'', entitled "Sur l'odeur propre de la terre" ("On the earth's own smell"). Phipson continues, "I find, on referring to my old notes, which are dated 1865, that it is doubtful whether I ever published the results of these observations; and as the distinguished chemists I have just named have not quite solved the problem, I hasten to give the results I obtained so long ago." He then theorizes that the odour "... was due to the presence of organic substances closely related to the essential oils of plants ..." and that these substances consist of "... the fragrance emitted by thousands of flowers ..." absorbed into the pores of the soil, and only released when displaced by rain. After attempts to isolate it, he found that it "... appeared to be very similar to, if not identical with, bromo-cedren derived from essence of cedar." The phenomenon was first scientifically described in a March 1964 paper by Australian researchers
Isabel Bear Isabel Joy Bear (4 January 1927 – 8 April 2021) was an Australian chemist who worked at CSIRO for over forty years. She was the first woman to be awarded the Royal Australian Chemical Institute Leighton Medal. She was inducted into the Victo ...
and Dick Thomas, published in the journal ''
Nature Nature is an inherent character or constitution, particularly of the Ecosphere (planetary), ecosphere or the universe as a whole. In this general sense nature refers to the Scientific law, laws, elements and phenomenon, phenomena of the physic ...
''. Thomas coined the term "petrichor" to refer to what had previously been known as "argillaceous odour". The authors describe how the smell derives from an oil exuded by certain
plant Plants are the eukaryotes that form the Kingdom (biology), kingdom Plantae; they are predominantly Photosynthesis, photosynthetic. This means that they obtain their energy from sunlight, using chloroplasts derived from endosymbiosis with c ...
s during dry periods, whereupon it is absorbed by
clay Clay is a type of fine-grained natural soil material containing clay minerals (hydrous aluminium phyllosilicates, e.g. kaolinite, ). Most pure clay minerals are white or light-coloured, but natural clays show a variety of colours from impuriti ...
-based soils and rocks. During rain, the oil is released into the air along with another compound,
geosmin Geosmin ( ) is an irregular sesquiterpenoid with a distinct earthy or musty odor, which most people can easily smell. The geosmin odor detection threshold in humans is very low, ranging from 0.006 to 0.01 micrograms per liter in water. Geosmin, a ...
, a metabolic by-product of certain
actinobacteria The Actinomycetota (or Actinobacteria) are a diverse phylum of Gram-positive bacteria with high GC content. They can be terrestrial or aquatic. They are of great importance to land flora because of their contributions to soil systems. In soil t ...
, such as ''
Streptomyces ''Streptomyces'', from στρεπτός (''streptós''), meaning "twisted", and μύκης (''múkés''), meaning "fungus", is the largest genus of Actinomycetota, and the type genus of the family Streptomycetaceae. Over 700 species of ''St ...
'', which is emitted by wet soil, producing the distinctive scent;
ozone Ozone () (or trioxygen) is an Inorganic compound, inorganic molecule with the chemical formula . It is a pale blue gas with a distinctively pungent smell. It is an allotrope of oxygen that is much less stable than the diatomic allotrope , break ...
may also be present if there is lightning. In a follow-up paper, Bear and Thomas (1965) showed that the oil slows seed germination and early plant growth.


Mechanism

When a raindrop lands on a porous surface, air from the pores forms small bubbles, which float to the surface and release
aerosol An aerosol is a suspension (chemistry), suspension of fine solid particles or liquid Drop (liquid), droplets in air or another gas. Aerosols can be generated from natural or Human impact on the environment, human causes. The term ''aerosol'' co ...
s. Such aerosols carry the scent, as well as bacteria and viruses from the soil. Raindrops that move slower tend to produce more aerosols; this explains why petrichor is more common after light rains. Members of the
Actinomycetes The Actinomycetales is an Scientific classification, order of Actinomycetota. A member of the order is often called an actinomycete. Actinomycetales are generally Gram-positive bacteria, gram-positive and anaerobic and have mycelia in a filamento ...
, gram-positive bacteria, are responsible for producing these aerosols. The
human nose The human nose is the first organ of the respiratory system. It is also the principal organ in the olfactory system. The shape of the nose is determined by the nasal bones and the nasal cartilages, including the nasal septum, which separates ...
is sensitive to
geosmin Geosmin ( ) is an irregular sesquiterpenoid with a distinct earthy or musty odor, which most people can easily smell. The geosmin odor detection threshold in humans is very low, ranging from 0.006 to 0.01 micrograms per liter in water. Geosmin, a ...
and can detect it at concentrations as low as 0.4 parts per billion. Some scientists believe that humans may appreciate the rain scent because ancestors relied on rainy weather for survival.
Camel A camel (from and () from Ancient Semitic: ''gāmāl'') is an even-toed ungulate in the genus ''Camelus'' that bears distinctive fatty deposits known as "humps" on its back. Camels have long been domesticated and, as livestock, they provid ...
s in the desert also rely on petrichor to locate sources of water such as
oases In ecology, an oasis (; : oases ) is a fertile area of a desert or semi-desert environmentDimethyl sulfide Dimethyl sulfide (DMS) or methylthiomethane is an organosulfur compound with the formula . It is the simplest thioether and has a characteristic disagreeable odor. It is a flammable liquid that boils at . It is a component of the smell produc ...
– One of the molecules responsible for the odour of the sea *
Geosmin Geosmin ( ) is an irregular sesquiterpenoid with a distinct earthy or musty odor, which most people can easily smell. The geosmin odor detection threshold in humans is very low, ranging from 0.006 to 0.01 micrograms per liter in water. Geosmin, a ...
– a compound that contributes to the smell petrichor * Mitti attar – a perfume that recreates the loamy smell of a first rain


Citations


General and cited references

*


External links


"Petrichor"
at A Word a Day
From the ''Oxford English Dictionary''
* * {{citation , url= http://www.straightdope.com/columns/read/3023/what-s-that-smell-right-before-it-rains-plus , title= What's that smell right before it rains? , first= Cecil , last= Adams , author-link= Cecil Adams , date= 2011-11-18 , access-date= 2018-01-04 , website=
The Straight Dope ''The Straight Dope'' was a question-and-answer newspaper column written under the pseudonym Cecil Adams. Contributions were made by multiple authors, and it was illustrated (also pseudonymously) by Slug Signorino. It was first published in 197 ...
, publisher=
Sun-Times Media Group Sun-Times Media Group (formerly Hollinger International) was a Chicago-based newspaper holding company. The company formerly owned the ''Chicago Sun-Times'' until its acquisition by ownership group ST Acquisition Holdings in 2017. History Sun- ...

Petrichor, U.K. Met office.

Why Is the Smell After It Rains So Appealing? The Petrichor phenomenon

Petrichor – Why we Love the Smell of Rain
1964 neologisms Rain Olfaction Precipitation Soil