Permanent Markers
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A permanent marker or indelible marker is a type of
marker pen A marker pen, fine liner, marking pen, felt-tip pen, felt pen, flow marker, sign pen (in South Korea), vivid (in New Zealand), flomaster (in East Slavs, East and South Slavs, South Slavic countries), texta (in Australia), sketch pen (in South ...
that is used to create permanent or semi-permanent writing on an object.


Description

In general, permanent marker ink comprises a main carrier
solvent A solvent (from the Latin language, Latin ''wikt:solvo#Latin, solvō'', "loosen, untie, solve") is a substance that dissolves a solute, resulting in a Solution (chemistry), solution. A solvent is usually a liquid but can also be a solid, a gas ...
, a
glyceride Glycerides, also known as acylglycerols, are esters formed from glycerol and fatty acids, and are generally very hydrophobic. Glycerol has three hydroxyl functional groups, which can be esterified with one, two, or three fatty acids to form mo ...
, a pyrrolidone, a
resin A resin is a solid or highly viscous liquid that can be converted into a polymer. Resins may be biological or synthetic in origin, but are typically harvested from plants. Resins are mixtures of organic compounds, predominantly terpenes. Commo ...
, and a
colorant A colourant/colour additive (British spelling) or colorant/color additive (American spelling) is a substance that is added or applied in order to change the colour of a material or surface. Colourants can be used for many purposes including printin ...
, making it water resistant. It is capable of writing on a variety of surfaces from paper to metal to stone. They come in a variety of tip sizes (ultra fine to wide), shapes (chisel point, bullet tip, and wide bristle), and colors (metallic, or
ultraviolet Ultraviolet radiation, also known as simply UV, is electromagnetic radiation of wavelengths of 10–400 nanometers, shorter than that of visible light, but longer than X-rays. UV radiation is present in sunlight and constitutes about 10% of ...
reactive). Most markers have alcohol-based solvents. Other types, called paint markers, contain
volatile organic compounds Volatile organic compounds (VOCs) are organic compounds that have a high vapor pressure at room temperature. They are common and exist in a variety of settings and products, not limited to house mold, upholstered furniture, arts and crafts sup ...
which evaporate to dry the ink, and are similar to
spray paint Spray paint (formally aerosol paint) is paint that comes in a sealed, pressurized can and is released in an aerosol spray when a valve button is depressed. The propellant is what the container of pressurized gas is called. When the pressure hol ...
. Due to solvents such as
toluene Toluene (), also known as toluol (), is a substituted aromatic hydrocarbon with the chemical formula , often abbreviated as , where Ph stands for the phenyl group. It is a colorless, water Water is an inorganic compound with the c ...
and
xylene In organic chemistry, xylene or xylol (; IUPAC name: dimethylbenzene) are any of three organic compounds with the formula . They are derived from the substitution of two hydrogen atoms with methyl groups in a benzene ring; which hydrogens are su ...
often being present in permanent markers, they have a potential for abuse as a
recreational drug Recreational drug use is the use of one or more psychoactive drugs to induce an altered state of consciousness, either for pleasure or for some other casual purpose or pastime. When a psychoactive drug enters the user's body, it induces an Sub ...
. The permanent marker was invented in 1952 by
Sidney Rosenthal Sidney Rosenthal (1907–1979), from Richmond Hill, New York, is credited with inventing what is now known as a Magic Marker in 1953. References 1907 births 1979 deaths 20th-century American engineers 20th-century American inventors ...
.


Applications


General purpose

Permanent markers are used for writing on metals, plastics, ceramics, wood, stone, cardboard etc. However, the mark made by them is semi-permanent on some surfaces. Most permanent marker ink can be erased from some plastic surfaces (like
polypropylene Polypropylene (PP), also known as polypropene, is a thermoplastic polymer used in a wide variety of applications. It is produced via chain-growth polymerization from the monomer Propene, propylene. Polypropylene belongs to the group of polyolefin ...
and
teflon Polytetrafluoroethylene (PTFE) is a synthetic fluoropolymer of tetrafluoroethylene, and has numerous applications because it is chemically inert. The commonly known brand name of PTFE-based composition is Teflon by Chemours, a spin-off from ...
) with little rubbing pressure. They can be used on ordinary paper, but the ink tends to bleed through and become visible on the other side.


Use in microscopy

In addition to being used for labelling microscopy slides, permanent markers can be used to do a negative stain of a bacterial sample. This means the background is stained with the marker, but the bacteria are not. The bacteria can be seen because they are unstained (lighter) while the background is stained (darker).


Removal

Permanent markers are generally used on hard, non-porous surfaces, because instead of staining they form a surface layer that, despite their name, can be removed by high pressure cleaning,
paint thinner Paint thinners are diluents — solvents used to adjust the viscosity of paint, as well as similar preparations such as varnish and lacquer, by dilution. For water-based paints, such as acrylic paints, water is the primary solvent, but notably, ...
s, or
organic solvents A solvent (from the Latin language, Latin ''wikt:solvo#Latin, solvō'', "loosen, untie, solve") is a substance that dissolves a solute, resulting in a Solution (chemistry), solution. A solvent is usually a liquid but can also be a solid, a gas ...
such as
acetone Acetone (2-propanone or dimethyl ketone) is an organic compound with the chemical formula, formula . It is the simplest and smallest ketone (). It is a colorless, highly Volatile organic compound, volatile, and flammable liquid with a charact ...
,
xylene In organic chemistry, xylene or xylol (; IUPAC name: dimethylbenzene) are any of three organic compounds with the formula . They are derived from the substitution of two hydrogen atoms with methyl groups in a benzene ring; which hydrogens are su ...
, or
toluene Toluene (), also known as toluol (), is a substituted aromatic hydrocarbon with the chemical formula , often abbreviated as , where Ph stands for the phenyl group. It is a colorless, water Water is an inorganic compound with the c ...
. When used indoors,
isopropyl alcohol Isopropyl alcohol (IUPAC name propan-2-ol and also called isopropanol or 2-propanol) is a colorless, flammable, organic compound with a pungent alcoholic odor. Isopropyl alcohol, an organic polar molecule, is miscible in water, ethanol, an ...
,
ethanol Ethanol (also called ethyl alcohol, grain alcohol, drinking alcohol, or simply alcohol) is an organic compound with the chemical formula . It is an Alcohol (chemistry), alcohol, with its formula also written as , or EtOH, where Et is the ps ...
, and
ethyl acetate Ethyl acetate commonly abbreviated EtOAc, ETAC or EA) is the organic compound with the formula , simplified to . This flammable, colorless liquid has a characteristic sweet smell (similar to pear drops) and is used in glues, nail polish removers, ...
are preferred cleaners, as their fumes are much less hazardous than toluene and xylene, the main components of
paint thinner Paint thinners are diluents — solvents used to adjust the viscosity of paint, as well as similar preparations such as varnish and lacquer, by dilution. For water-based paints, such as acrylic paints, water is the primary solvent, but notably, ...
, or the longer-chain hydrocarbons found in
mineral spirits White spirit (AU, UK and Ireland)Primarily in the United Kingdom and Australia. In New Zealand "white spirit" can also refer to Coleman fuel ( white gas). or mineral spirits (US, Canada), also known as mineral turpentine (AU/NZ/ZA), turpentine s ...
. Other common non-polar solvents include
benzene Benzene is an Organic compound, organic chemical compound with the Chemical formula#Molecular formula, molecular formula C6H6. The benzene molecule is composed of six carbon atoms joined in a planar hexagonal Ring (chemistry), ring with one hyd ...
,
turpentine Turpentine (which is also called spirit of turpentine, oil of turpentine, terebenthine, terebenthene, terebinthine and, colloquially, turps) is a fluid obtainable by the distillation of resin harvested from living trees, mainly pines. Principall ...
and other
terpene Terpenes () are a class of natural products consisting of compounds with the formula (C5H8)n for n ≥ 2. Terpenes are major biosynthetic building blocks. Comprising more than 30,000 compounds, these unsaturated hydrocarbons are produced predomi ...
s (which constitute essential oils of many plants with strong scents), most
ether In organic chemistry, ethers are a class of compounds that contain an ether group, a single oxygen atom bonded to two separate carbon atoms, each part of an organyl group (e.g., alkyl or aryl). They have the general formula , where R and R ...
s,
chloroform Chloroform, or trichloromethane (often abbreviated as TCM), is an organochloride with the formula and a common solvent. It is a volatile, colorless, sweet-smelling, dense liquid produced on a large scale as a precursor to refrigerants and po ...
and
dichloromethane Dichloromethane (DCM, methylene chloride, or methylene bichloride) is an organochlorine compound with the formula . This colorless, volatile liquid with a chloroform-like, sweet odor is widely used as a solvent. Although it is not miscible with ...
,
hydrocarbon In organic chemistry, a hydrocarbon is an organic compound consisting entirely of hydrogen and carbon. Hydrocarbons are examples of group 14 hydrides. Hydrocarbons are generally colourless and Hydrophobe, hydrophobic; their odor is usually fain ...
fuels, and
diacetone alcohol Diacetone alcohol is an organic compound with the formula CH3C(O)CH2C(OH)(CH3)2, sometimes called DAA. This colorless liquid is a common synthetic intermediate used for the preparation of other compounds, and is also used as a solvent. Synthesi ...
, among many others. Many of these solvents are toxic, carcinogenic, or flammable, and should only be used with adequate ventilation. While these methods work well for non-porous surfaces, removing permanent marker from
porous materials In materials science, a porous medium or a porous material is a material containing pores (voids). The skeletal portion of the material is often called the "matrix" or "frame". The pores are typically filled with a fluid (liquid or gas). The sk ...
like fabric or carpet requires a different approach. Most brands of "OLFA" marker wipe off easily with acetone-free nail polish remover, the kind containing
ethyl acetate Ethyl acetate commonly abbreviated EtOAc, ETAC or EA) is the organic compound with the formula , simplified to . This flammable, colorless liquid has a characteristic sweet smell (similar to pear drops) and is used in glues, nail polish removers, ...
, a relatively non-toxic organic solvent. A permanent marker can also be removed by drawing over it with a dry erase marker on non-porous surfaces such as a
whiteboard A whiteboard (also known as marker board, dry-erase board, dry-wipe board, and pen-board) is a glossy, usually white surface for making non-permanent markings. Whiteboards are analogous to blackboards, but with a smoother surface allowing for ...
, as dry erase markers also contain a non-polar solvent. Most dry-erase board cleaner solutions also contain effective organic solvents like
2-butoxyethanol 2-Butoxyethanol is an organic compound with the chemical formula (Bu = ). This colorless liquid has a sweet, ether-like odor, as it derives from the family of glycol ethers, and is a butyl ether of ethylene glycol. As a relatively nonvolatile, ...
to remove the pigment.


Laws

Due to their potential to be used for
vandalism Vandalism is the action involving deliberate destruction of or damage to public or private property. The term includes property damage, such as graffiti and defacement directed towards any property without permission of the owner. The t ...
, some locales, such as
Florida Florida ( ; ) is a U.S. state, state in the Southeastern United States, Southeastern region of the United States. It borders the Gulf of Mexico to the west, Alabama to the northwest, Georgia (U.S. state), Georgia to the north, the Atlantic ...
,
California California () is a U.S. state, state in the Western United States that lies on the West Coast of the United States, Pacific Coast. It borders Oregon to the north, Nevada and Arizona to the east, and shares Mexico–United States border, an ...
,
New York City New York, often called New York City (NYC), is the most populous city in the United States, located at the southern tip of New York State on one of the world's largest natural harbors. The city comprises five boroughs, each coextensive w ...
, and
Berwyn, Illinois Berwyn () is a suburban city in Cook County, Illinois, United States, Coterminous municipality, coterminous with Berwyn Township, Illinois, Berwyn Township, which was formed in 1908 after breaking off from Cicero Township, Cook County, Illinois, ...
, have laws against possessing permanent markers in public, and prohibit sales of them to people under age 20.


See also

*
List of pen types, brands and companies A list is a set of discrete items of information collected and set forth in some format for utility, entertainment, or other purposes. A list may be memorialized in any number of ways, including existing only in the mind of the list-maker, but ...
*
Inhalants Inhalants are a broad range of household and industrial chemicals whose volatile vapors or pressurized gases can be concentrated and breathed in via the nose or mouth to produce intoxication, in a manner not intended by the manufacturer. They ...


Notes and references

{{DEFAULTSORT:Permanent Marker Visual arts materials Pens Writing implements