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In
physics Physics is the scientific study of matter, its Elementary particle, fundamental constituents, its motion and behavior through space and time, and the related entities of energy and force. "Physical science is that department of knowledge whi ...
, an observable is a
physical property A physical property is any property of a physical system that is measurable. The changes in the physical properties of a system can be used to describe its changes between momentary states. A quantifiable physical property is called ''physical ...
or
physical quantity A physical quantity (or simply quantity) is a property of a material or system that can be Quantification (science), quantified by measurement. A physical quantity can be expressed as a ''value'', which is the algebraic multiplication of a ''nu ...
that can be measured. In
classical mechanics Classical mechanics is a Theoretical physics, physical theory describing the motion of objects such as projectiles, parts of Machine (mechanical), machinery, spacecraft, planets, stars, and galaxies. The development of classical mechanics inv ...
, an observable is a real-valued "function" on the set of all possible system states, e.g., position and
momentum In Newtonian mechanics, momentum (: momenta or momentums; more specifically linear momentum or translational momentum) is the product of the mass and velocity of an object. It is a vector quantity, possessing a magnitude and a direction. ...
. In
quantum mechanics Quantum mechanics is the fundamental physical Scientific theory, theory that describes the behavior of matter and of light; its unusual characteristics typically occur at and below the scale of atoms. Reprinted, Addison-Wesley, 1989, It is ...
, an observable is an operator, or gauge, where the property of the
quantum state In quantum physics, a quantum state is a mathematical entity that embodies the knowledge of a quantum system. Quantum mechanics specifies the construction, evolution, and measurement of a quantum state. The result is a prediction for the system ...
can be determined by some sequence of operations. For example, these operations might involve submitting the system to various electromagnetic fields and eventually reading a value. Physically meaningful observables must also satisfy transformation laws that relate observations performed by different observers in different frames of reference. These transformation laws are
automorphism In mathematics, an automorphism is an isomorphism from a mathematical object to itself. It is, in some sense, a symmetry of the object, and a way of mapping the object to itself while preserving all of its structure. The set of all automorphism ...
s of the
state space In computer science, a state space is a discrete space representing the set of all possible configurations of a system. It is a useful abstraction for reasoning about the behavior of a given system and is widely used in the fields of artificial ...
, that is
bijective In mathematics, a bijection, bijective function, or one-to-one correspondence is a function between two sets such that each element of the second set (the codomain) is the image of exactly one element of the first set (the domain). Equival ...
transformations that preserve certain mathematical properties of the space in question.


Quantum mechanics

In
quantum mechanics Quantum mechanics is the fundamental physical Scientific theory, theory that describes the behavior of matter and of light; its unusual characteristics typically occur at and below the scale of atoms. Reprinted, Addison-Wesley, 1989, It is ...
, observables manifest as self-adjoint operators on a separable
complex Complex commonly refers to: * Complexity, the behaviour of a system whose components interact in multiple ways so possible interactions are difficult to describe ** Complex system, a system composed of many components which may interact with each ...
Hilbert space In mathematics, a Hilbert space is a real number, real or complex number, complex inner product space that is also a complete metric space with respect to the metric induced by the inner product. It generalizes the notion of Euclidean space. The ...
representing the quantum state space. Observables assign values to outcomes of ''particular measurements'', corresponding to the eigenvalue of the operator. If these outcomes represent physically allowable states (i.e. those that belong to the Hilbert space) the eigenvalues are real; however, the converse is not necessarily true. As a consequence, only certain measurements can determine the value of an observable for some state of a quantum system. In classical mechanics, ''any'' measurement can be made to determine the value of an observable. The relation between the state of a quantum system and the value of an observable requires some
linear algebra Linear algebra is the branch of mathematics concerning linear equations such as :a_1x_1+\cdots +a_nx_n=b, linear maps such as :(x_1, \ldots, x_n) \mapsto a_1x_1+\cdots +a_nx_n, and their representations in vector spaces and through matrix (mathemat ...
for its description. In the
mathematical formulation of quantum mechanics The mathematical formulations of quantum mechanics are those mathematical formalisms that permit a rigorous description of quantum mechanics. This mathematical formalism uses mainly a part of functional analysis, especially Hilbert spaces, whic ...
, up to a phase constant, pure states are given by non-zero vectors in a
Hilbert space In mathematics, a Hilbert space is a real number, real or complex number, complex inner product space that is also a complete metric space with respect to the metric induced by the inner product. It generalizes the notion of Euclidean space. The ...
''V''. Two vectors v and w are considered to specify the same state if and only if \mathbf = c\mathbf for some non-zero c \in \Complex. Observables are given by self-adjoint operators on ''V''. Not every self-adjoint operator corresponds to a physically meaningful observable. Also, not all physical observables are associated with non-trivial self-adjoint operators. For example, in quantum theory, mass appears as a parameter in the Hamiltonian, not as a non-trivial operator. In the case of transformation laws in quantum mechanics, the requisite automorphisms are unitary (or antiunitary) linear transformations of the Hilbert space ''V''. Under Galilean relativity or
special relativity In physics, the special theory of relativity, or special relativity for short, is a scientific theory of the relationship between Spacetime, space and time. In Albert Einstein's 1905 paper, Annus Mirabilis papers#Special relativity, "On the Ele ...
, the mathematics of frames of reference is particularly simple, considerably restricting the set of physically meaningful observables. In quantum mechanics, measurement of observables exhibits some seemingly unintuitive properties. Specifically, if a system is in a state described by a vector in a
Hilbert space In mathematics, a Hilbert space is a real number, real or complex number, complex inner product space that is also a complete metric space with respect to the metric induced by the inner product. It generalizes the notion of Euclidean space. The ...
, the measurement process affects the state in a non-deterministic but statistically predictable way. In particular, after a measurement is applied, the state description by a single vector may be destroyed, being replaced by a statistical ensemble. The irreversible nature of measurement operations in quantum physics is sometimes referred to as the measurement problem and is described mathematically by quantum operations. By the structure of quantum operations, this description is mathematically equivalent to that offered by the relative state interpretation where the original system is regarded as a subsystem of a larger system and the state of the original system is given by the partial trace of the state of the larger system. In quantum mechanics, dynamical variables A such as position, translational (linear)
momentum In Newtonian mechanics, momentum (: momenta or momentums; more specifically linear momentum or translational momentum) is the product of the mass and velocity of an object. It is a vector quantity, possessing a magnitude and a direction. ...
, orbital angular momentum, spin, and
total angular momentum In quantum mechanics, the total angular momentum quantum number parametrises the total angular momentum of a given particle, by combining its orbital angular momentum and its intrinsic angular momentum (i.e., its spin). If s is the particle's ...
are each associated with a self-adjoint operator \hat that acts on the state of the quantum system. The eigenvalues of operator \hat correspond to the possible values that the dynamical variable can be observed as having. For example, suppose , \psi_\rangle is an eigenket ( eigenvector) of the observable \hat, with eigenvalue a, and exists in a
Hilbert space In mathematics, a Hilbert space is a real number, real or complex number, complex inner product space that is also a complete metric space with respect to the metric induced by the inner product. It generalizes the notion of Euclidean space. The ...
. Then \hat, \psi_a\rangle = a, \psi_a\rangle. This eigenket equation says that if a
measurement Measurement is the quantification of attributes of an object or event, which can be used to compare with other objects or events. In other words, measurement is a process of determining how large or small a physical quantity is as compared to ...
of the observable \hat is made while the system of interest is in the state , \psi_a\rangle, then the observed value of that particular measurement must return the eigenvalue a with certainty. However, if the system of interest is in the general state , \phi\rangle \in \mathcal (and , \phi\rangle and , \psi_a\rangle are
unit vector In mathematics, a unit vector in a normed vector space is a Vector (mathematics and physics), vector (often a vector (geometry), spatial vector) of Norm (mathematics), length 1. A unit vector is often denoted by a lowercase letter with a circumfle ...
s, and the
eigenspace In linear algebra, an eigenvector ( ) or characteristic vector is a Vector (mathematics and physics), vector that has its direction (geometry), direction unchanged (or reversed) by a given linear map, linear transformation. More precisely, an e ...
of a is one-dimensional), then the eigenvalue a is returned with probability , \langle \psi_a, \phi\rangle, ^2, by the Born rule.


Compatible and incompatible observables in quantum mechanics

A crucial difference between classical quantities and quantum mechanical observables is that some pairs of quantum observables may not be simultaneously measurable, a property referred to as complementarity. This is mathematically expressed by non- commutativity of their corresponding operators, to the effect that the
commutator In mathematics, the commutator gives an indication of the extent to which a certain binary operation fails to be commutative. There are different definitions used in group theory and ring theory. Group theory The commutator of two elements, ...
\left hat, \hat\right:= \hat\hat - \hat\hat \neq \hat. This inequality expresses a dependence of measurement results on the order in which measurements of observables \hat and \hat are performed. A measurement of \hat alters the quantum state in a way that is incompatible with the subsequent measurement of \hat and vice versa. Observables corresponding to commuting operators are called ''compatible observables''. For example, momentum along say the x and y axes are compatible. Observables corresponding to non-commuting operators are called ''incompatible observables'' or ''complementary variables''. For example, the position and momentum along the same axis are incompatible. Incompatible observables cannot have a complete set of common eigenfunctions. Note that there can be some simultaneous eigenvectors of \hat and \hat, but not enough in number to constitute a complete basis.


See also


References


Further reading

* * * * * * * * * {{Quantum mechanics topics Control theory Mathematical physics Measurement Physical quantities Quantum mechanics Statistics