
Mu-metal is a
nickel
Nickel is a chemical element; it has symbol Ni and atomic number 28. It is a silvery-white lustrous metal with a slight golden tinge. Nickel is a hard and ductile transition metal. Pure nickel is chemically reactive, but large pieces are slo ...
–
iron
Iron is a chemical element; it has symbol Fe () and atomic number 26. It is a metal that belongs to the first transition series and group 8 of the periodic table. It is, by mass, the most common element on Earth, forming much of Earth's o ...
soft
ferromagnetic
Ferromagnetism is a property of certain materials (such as iron) that results in a significant, observable magnetic permeability, and in many cases, a significant magnetic coercivity, allowing the material to form a permanent magnet. Ferromagne ...
alloy
An alloy is a mixture of chemical elements of which in most cases at least one is a metal, metallic element, although it is also sometimes used for mixtures of elements; herein only metallic alloys are described. Metallic alloys often have prop ...
with very high
permeability, which is used for shielding sensitive electronic equipment against static or low-frequency
magnetic field
A magnetic field (sometimes called B-field) is a physical field that describes the magnetic influence on moving electric charges, electric currents, and magnetic materials. A moving charge in a magnetic field experiences a force perpendicular ...
s.
Properties
Mu-metal has several compositions. One such composition is approximately
: 77% nickel,
: 16% iron,
: 5%
copper
Copper is a chemical element; it has symbol Cu (from Latin ) and atomic number 29. It is a soft, malleable, and ductile metal with very high thermal and electrical conductivity. A freshly exposed surface of pure copper has a pinkish-orang ...
, and
: 2%
chromium
Chromium is a chemical element; it has Symbol (chemistry), symbol Cr and atomic number 24. It is the first element in Group 6 element, group 6. It is a steely-grey, Luster (mineralogy), lustrous, hard, and brittle transition metal.
Chromium ...
or
molybdenum
Molybdenum is a chemical element; it has Symbol (chemistry), symbol Mo (from Neo-Latin ''molybdaenum'') and atomic number 42. The name derived from Ancient Greek ', meaning lead, since its ores were confused with lead ores. Molybdenum minerals hav ...
.
More recently, mu-metal is considered to be ASTM A753 Alloy 4 and is composed of approximately
: 80% nickel,
: 12-15% iron,
: 5% molybdenum,
: and small amounts of various other elements such as
silicon
Silicon is a chemical element; it has symbol Si and atomic number 14. It is a hard, brittle crystalline solid with a blue-grey metallic lustre, and is a tetravalent metalloid (sometimes considered a non-metal) and semiconductor. It is a membe ...
.
The name came from the Greek letter mu (
μ) which represents permeability in physics and engineering formulas. A number of different proprietary formulations of the alloy are sold under trade names such as ''MuMETAL'', ''Mumetall'', and ''Mumetal2''.
Mu-metal typically has
relative permeability
In multiphase flow in porous media, the relative permeability of a Phase (matter), phase is a dimensionless measure of the effective Permeability (Earth sciences), permeability of that phase. It is the ratio of the effective permeability of that ...
values of 80,000–100,000 compared to several thousand for ordinary steel. It is a "soft" ferromagnetic material; it has low
magnetic anisotropy
In condensed matter physics, magnetic anisotropy describes how an object's magnetic properties can be anisotropy, different depending on direction. In the simplest case, there is no preferential direction for an object's magnetic moment. It will ...
and
magnetostriction
Magnetostriction is a property of magnetic materials that causes them to change their shape or dimensions during the process of magnetization. The variation of materials' magnetization due to the applied magnetic field changes the magnetostrictive ...
,
giving it a low
coercivity
Coercivity, also called the magnetic coercivity, coercive field or coercive force, is a measure of the ability of a ferromagnetic material to withstand an external magnetic field without becoming Magnetization, demagnetized. Coercivity is usual ...
so that it saturates at low magnetic fields. This gives it low
hysteresis losses when used in AC magnetic circuits. Other high-permeability nickel–iron alloys such as
permalloy
Permalloy () is a nickel–iron magnetic alloy, with about 80% nickel and 20% iron content. Invented in 1914 by physicist Gustav Elmen at Bell Telephone Laboratories, it is notable for its very high magnetic permeability, which makes it useful ...
have similar magnetic properties; mu-metal's advantage is that it is more
ductile
Ductility refers to the ability of a material to sustain significant plastic deformation before fracture. Plastic deformation is the permanent distortion of a material under applied stress, as opposed to elastic deformation, which is reversi ...
, malleable and workable, allowing it to be easily formed into the thin sheets needed for magnetic shields.
Mu-metal objects require
heat treatment
Heat treating (or heat treatment) is a group of industrial, thermal and metalworking processes used to alter the physical, and sometimes chemical, properties of a material. The most common application is metallurgical. Heat treatments are a ...
after they are in final form—
annealing in a magnetic field in
hydrogen
Hydrogen is a chemical element; it has chemical symbol, symbol H and atomic number 1. It is the lightest and abundance of the chemical elements, most abundant chemical element in the universe, constituting about 75% of all baryon, normal matter ...
atmosphere, which increases the
magnetic permeability
In electromagnetism, permeability is the measure of magnetization produced in a material in response to an applied magnetic field. Permeability is typically represented by the (italicized) Greek letter ''μ''. It is the ratio of the magnetic ...
about 40 times.
The annealing alters the material's
crystal structure
In crystallography, crystal structure is a description of ordered arrangement of atoms, ions, or molecules in a crystalline material. Ordered structures occur from intrinsic nature of constituent particles to form symmetric patterns that repeat ...
, aligning the
grains
A grain is a small, hard, dry fruit ( caryopsis) – with or without an attached hull layer – harvested for human or animal consumption. A grain crop is a grain-producing plant. The two main types of commercial grain crops are cereals and le ...
and removing some impurities, especially
carbon
Carbon () is a chemical element; it has chemical symbol, symbol C and atomic number 6. It is nonmetallic and tetravalence, tetravalent—meaning that its atoms are able to form up to four covalent bonds due to its valence shell exhibiting 4 ...
, which obstruct the free motion of the
magnetic domain
A magnetic domain is a region within a magnetic material in which the magnetization is in a uniform direction. This means that the individual magnetic moments of the atoms are aligned with one another and they point in the same direction. When c ...
boundaries. Bending or mechanical shock after annealing may disrupt the material's grain alignment, leading to a drop in the permeability of the affected areas, which can be restored by repeating the hydrogen annealing step.
Application

Mu-metal is a soft magnetic alloy with exceptionally high magnetic permeability. The high permeability of mu-metal provides a low
reluctance
Magnetic reluctance, or magnetic resistance, is a concept used in the analysis of magnetic circuits. It is defined as the ratio of magnetomotive force (mmf) to magnetic flux. It represents the opposition to magnetic flux, and depends on the ...
path for
magnetic flux
In physics, specifically electromagnetism, the magnetic flux through a surface is the surface integral of the normal component of the magnetic field B over that surface. It is usually denoted or . The SI unit of magnetic flux is the we ...
, leading to its use in
magnetic shields against static or slowly varying magnetic fields. Magnetic shielding made with high-permeability alloys like mu-metal works not by blocking magnetic fields but by providing a path for the
magnetic field line
A magnetic field (sometimes called B-field) is a physical field that describes the magnetic influence on moving electric charges, electric currents, and magnetic materials. A moving charge in a magnetic field experiences a force perpendicular ...
s around the shielded area. Thus, the best shape for shields is a closed container surrounding the shielded space.
The effectiveness of mu-metal shielding decreases with the alloy's permeability, which drops off at both low field strengths and, due to
saturation, at high field strengths. Thus, mu-metal shields are often made of several enclosures one inside the other, each of which successively reduces the field inside it. Because mu-metal saturates at relatively low fields, sometimes the outer layer in such multilayer shields is made of ordinary steel. Its higher saturation value allows it to handle stronger magnetic fields, reducing them to a lower level that can be shielded effectively by the inner mu-metal layers.
RF magnetic fields above about 100
kHz
The hertz (symbol: Hz) is the unit of frequency in the International System of Units (SI), often described as being equivalent to one event (or cycle) per second. The hertz is an SI derived unit whose formal expression in terms of SI base uni ...
can be shielded by
Faraday shields: ordinary conductive metal sheets or screens which are used to shield against
electric field
An electric field (sometimes called E-field) is a field (physics), physical field that surrounds electrically charged particles such as electrons. In classical electromagnetism, the electric field of a single charge (or group of charges) descri ...
s.
Superconducting
Superconductivity is a set of physical properties observed in superconductors: materials where electrical resistance vanishes and magnetic fields are expelled from the material. Unlike an ordinary metallic conductor, whose resistance decreases g ...
materials can also expel magnetic fields by the
Meissner effect
In condensed-matter physics, the Meissner effect (or Meißner–Ochsenfeld effect) is the expulsion of a magnetic field from a superconductor during its transition to the superconducting state when it is cooled below the critical temperature. Th ...
, but require
cryogenic
In physics, cryogenics is the production and behaviour of materials at very low temperatures.
The 13th International Institute of Refrigeration's (IIR) International Congress of Refrigeration (held in Washington, DC in 1971) endorsed a univers ...
temperatures.
The alloy has a low coercivity, near zero magnetostriction, and significant anisotropic magnetoresistance. The low magnetostriction is critical for industrial applications, where variable stresses in thin films would otherwise cause a ruinously large variation in magnetic properties.
Examples
Mu-metal is used to shield equipment from magnetic fields. For example:
*
Electric power
Electric power is the rate of transfer of electrical energy within a electric circuit, circuit. Its SI unit is the watt, the general unit of power (physics), power, defined as one joule per second. Standard prefixes apply to watts as with oth ...
transformer
In electrical engineering, a transformer is a passive component that transfers electrical energy from one electrical circuit to another circuit, or multiple Electrical network, circuits. A varying current in any coil of the transformer produces ...
s, which are built with mu-metal shells to prevent them from affecting nearby circuitry.
*
Hard disk
A hard disk drive (HDD), hard disk, hard drive, or fixed disk is an electro-mechanical data storage device that stores and retrieves digital data using magnetic storage with one or more rigid rapidly rotating hard disk drive platter, pla ...
s, which have mu-metal backings to the magnets found in the drive to keep the magnetic field away from the disk.
*
Cathode-ray tube
A cathode-ray tube (CRT) is a vacuum tube containing one or more electron guns, which emit electron beams that are manipulated to display images on a phosphorescent screen. The images may represent electrical waveforms on an oscilloscope, a ...
s used in analogue
oscilloscopes, which have mu-metal shields to prevent stray magnetic fields from deflecting the electron beam.
*
Magnetic phonograph cartridges, which have a mu-metal case to reduce interference when
LPs are played back.
*
Magnetic resonance imaging
Magnetic resonance imaging (MRI) is a medical imaging technique used in radiology to generate pictures of the anatomy and the physiological processes inside the body. MRI scanners use strong magnetic fields, magnetic field gradients, and ...
(MRI) equipment.
* The
magnetometer
A magnetometer is a device that measures magnetic field or magnetic dipole moment. Different types of magnetometers measure the direction, strength, or relative change of a magnetic field at a particular location. A compass is one such device, ...
s used in
magnetoencephalography
Magnetoencephalography (MEG) is a functional neuroimaging technique for mapping brain activity by recording magnetic fields produced by electric current, electrical currents occurring naturally in the human brain, brain, using very sensitive magn ...
and
magnetocardiography.
*
Photomultiplier tubes.
*
Vacuum chamber
A vacuum chamber is a rigid enclosure from which air and other gases are removed by a vacuum pump. This results in a low-pressure environment within the chamber, commonly referred to as a vacuum. A vacuum environment allows researchers to c ...
s for experiments with low-energy
electron
The electron (, or in nuclear reactions) is a subatomic particle with a negative one elementary charge, elementary electric charge. It is a fundamental particle that comprises the ordinary matter that makes up the universe, along with up qua ...
s, for example, photoelectron spectroscopy.
*
Superconducting
Superconductivity is a set of physical properties observed in superconductors: materials where electrical resistance vanishes and magnetic fields are expelled from the material. Unlike an ordinary metallic conductor, whose resistance decreases g ...
circuits and especially
Josephson junction
In physics, the Josephson effect is a phenomenon that occurs when two superconductors are placed in proximity, with some barrier or restriction between them. The effect is named after the British physicist Brian Josephson, who predicted in 1962 ...
circuits.
*
Fluxgate magnetometers and compasses as part of the sensor.
*
Proximity sensors (inductive type)
Similar materials
Other materials with similar magnetic properties include Co-Netic,
supermalloy, supermumetal, nilomag, sanbold, molybdenum
permalloy
Permalloy () is a nickel–iron magnetic alloy, with about 80% nickel and 20% iron content. Invented in 1914 by physicist Gustav Elmen at Bell Telephone Laboratories, it is notable for its very high magnetic permeability, which makes it useful ...
,
Sendust, M-1040, Hipernom, HyMu-80 and Amumetal.
Electrical steel
Electricity is the set of physical phenomena associated with the presence and motion of matter possessing an electric charge. Electricity is related to magnetism, both being part of the phenomenon of electromagnetism, as described by ...
is used similarly in some transformers as a cheaper, less permeable option.
Ceramic
ferrites Ferrite may refer to:
* Ferrite (iron), one of the allotropes of iron that is stable at room temperature and pressure, α-Fe
* Ferrite (magnet), a ferromagnetic ceramic material
See also
*
* Ferrite bead, a component placed on the end of a data c ...
are used for similar purposes, and have even higher permeability at high frequencies, but are brittle and nearly non-conductive, so can only replace mu-metals where conductivity and pliability aren't required.
History

Mu-metal was developed by British scientists Willoughby S. Smith and Henry J. Garnett
[US Patent 1582353]
Willoughby Statham Smith, Henry Joseph Garnett, ''Magnetic Alloy'', filed January 10, 1924, granted April 27, 1926[US Patent 1552769]
Willoughby Statham Smith, Henry Joseph Garnett, ''Magnetic Alloy'', filed January 10, 1924, granted September 8, 1925 and patented in 1923 for
inductive loading of
submarine telegraph cable
A submarine communications cable is a cable laid on the seabed between land-based stations to carry telecommunication signals across stretches of ocean and sea. The first submarine communications cables were laid beginning in the 1850s and car ...
s by The Telegraph Construction and Maintenance Co. Ltd. (now Telcon Metals Ltd.), a British firm that built the Atlantic undersea telegraph cables. The conductive seawater surrounding an undersea cable added a significant
capacitance
Capacitance is the ability of an object to store electric charge. It is measured by the change in charge in response to a difference in electric potential, expressed as the ratio of those quantities. Commonly recognized are two closely related ...
to the cable, causing distortion of the signal, which limited the
bandwidth
Bandwidth commonly refers to:
* Bandwidth (signal processing) or ''analog bandwidth'', ''frequency bandwidth'', or ''radio bandwidth'', a measure of the width of a frequency range
* Bandwidth (computing), the rate of data transfer, bit rate or thr ...
and slowed signaling speed to 10–12 words per minute. The bandwidth could be increased by adding
inductance
Inductance is the tendency of an electrical conductor to oppose a change in the electric current flowing through it. The electric current produces a magnetic field around the conductor. The magnetic field strength depends on the magnitude of the ...
to compensate. This was first done by wrapping the conductors with a helical wrapping of metal tape or wire of high magnetic permeability, which confined the magnetic field.
Telcon invented mu-metal to compete with
permalloy
Permalloy () is a nickel–iron magnetic alloy, with about 80% nickel and 20% iron content. Invented in 1914 by physicist Gustav Elmen at Bell Telephone Laboratories, it is notable for its very high magnetic permeability, which makes it useful ...
, the first high-permeability alloy used for cable compensation, whose patent rights were held by competitor
Western Electric
Western Electric Co., Inc. was an American electrical engineering and manufacturing company that operated from 1869 to 1996. A subsidiary of the AT&T Corporation for most of its lifespan, Western Electric was the primary manufacturer, supplier, ...
. Mu-metal was developed by adding copper to permalloy to improve
ductility
Ductility refers to the ability of a material to sustain significant plastic Deformation (engineering), deformation before fracture. Plastic deformation is the permanent distortion of a material under applied stress, as opposed to elastic def ...
. of fine mu-metal wire were needed for each 1.6 km of cable, creating a great demand for the alloy. The first year of production Telcon was making 30 tons per week. In the 1930s this use for mu-metal declined, but by World War II many other uses were found in the
electronics industry
The electronics industry is the industry (economics), industry that produces electronic devices. It emerged in the 20th century and is today one of the largest global industries. Contemporary society uses a vast array of electronic devices that ar ...
(particularly shielding for
transformer
In electrical engineering, a transformer is a passive component that transfers electrical energy from one electrical circuit to another circuit, or multiple Electrical network, circuits. A varying current in any coil of the transformer produces ...
s and
cathode-ray tube
A cathode-ray tube (CRT) is a vacuum tube containing one or more electron guns, which emit electron beams that are manipulated to display images on a phosphorescent screen. The images may represent electrical waveforms on an oscilloscope, a ...
s), as well as the
fuze
In military munitions, a fuze (sometimes fuse) is the part of the device that initiates its function. In some applications, such as torpedoes, a fuze may be identified by function as the exploder. The relative complexity of even the earliest fu ...
s inside
magnetic mines. Telcon Metals Ltd. abandoned the trademark "MUMETAL" in 1985. The last listed owner of the mark "MUMETAL" is Magnetic Shield Corporation, Illinois.
References
External links
Mu-Metal PropertiesZero gauss chambers{{Webarchive, url=https://web.archive.org/web/20130217134030/http://www.abschirmungen.eu/english/products/zero-gauss-chambers/ , date=2013-02-17
Info about using mu metal shields
Nickel alloys
Magnetic alloys
Ferromagnetic materials