
The Montreal Protocol on Substances That Deplete the Ozone Layer
is an international
treaty
A treaty is a formal, legally binding written agreement between sovereign states and/or international organizations that is governed by international law. A treaty may also be known as an international agreement, protocol, covenant, convention ...
designed to protect the
ozone layer
The ozone layer or ozone shield is a region of Earth's stratosphere that absorption (electromagnetic radiation), absorbs most of the Sun's ultraviolet radiation. It contains a high concentration of ozone (O3) in relation to other parts of the a ...
by phasing out the production of numerous substances that are responsible for
ozone depletion
Ozone depletion consists of two related events observed since the late 1970s: a lowered total amount of ozone in Earth, Earth's upper atmosphere, and a much larger springtime decrease in stratospheric ozone (the ozone layer) around Earth's polar ...
. It was agreed on 16 September 1987, and entered into force on 1 January 1989. Since then, it has undergone several amendments and adjustments, with revisions agreed to in 1990 (
London
London is the Capital city, capital and List of urban areas in the United Kingdom, largest city of both England and the United Kingdom, with a population of in . London metropolitan area, Its wider metropolitan area is the largest in Wester ...
), 1992 (
Copenhagen
Copenhagen ( ) is the capital and most populous city of Denmark, with a population of 1.4 million in the Urban area of Copenhagen, urban area. The city is situated on the islands of Zealand and Amager, separated from Malmö, Sweden, by the ...
), 1995 (
Vienna
Vienna ( ; ; ) is the capital city, capital, List of largest cities in Austria, most populous city, and one of Federal states of Austria, nine federal states of Austria. It is Austria's primate city, with just over two million inhabitants. ...
), 1997 (
Montreal
Montreal is the List of towns in Quebec, largest city in the Provinces and territories of Canada, province of Quebec, the List of the largest municipalities in Canada by population, second-largest in Canada, and the List of North American cit ...
), 1999 (
Beijing
Beijing, Chinese postal romanization, previously romanized as Peking, is the capital city of China. With more than 22 million residents, it is the world's List of national capitals by population, most populous national capital city as well as ...
), 2007 (Montreal), 2016 (
Kigali
Kigali () is the Capital (political), capital and largest city of Rwanda. It is near the nation's geographic centre in a region of rolling hills, with a series of valleys and ridges joined by steep slopes. As a primate city, Kigali is a relativ ...
) and 2018 (
Quito
Quito (; ), officially San Francisco de Quito, is the capital city, capital and second-largest city of Ecuador, with an estimated population of 2.8 million in its metropolitan area. It is also the capital of the province of Pichincha Province, P ...
). As a result of the international agreement, the ozone hole over
Antarctica
Antarctica () is Earth's southernmost and least-populated continent. Situated almost entirely south of the Antarctic Circle and surrounded by the Southern Ocean (also known as the Antarctic Ocean), it contains the geographic South Pole. ...
is slowly recovering. Climate projections indicate that the ozone layer will return to 1980 levels between 2040 (across much of the world) and 2066 (over Antarctica). Due to its widespread adoption and implementation, it has been hailed as an example of successful international co-operation. Former
United Nations
The United Nations (UN) is the Earth, global intergovernmental organization established by the signing of the Charter of the United Nations, UN Charter on 26 June 1945 with the stated purpose of maintaining international peace and internationa ...
(UN) Secretary-General
Kofi Annan
Kofi Atta Annan (8 April 193818 August 2018) was a Ghanaian diplomat who served as the seventh secretary-general of the United Nations from 1997 to 2006. Annan and the UN were the co-recipients of the 2001 Nobel Peace Prize. He was the founder a ...
stated that "perhaps the single most successful international agreement to date has been the Montreal Protocol". In comparison, effective burden-sharing and solution proposals mitigating regional conflicts of interest have been among the success factors for the ozone depletion challenge, where global regulation based on the
Kyoto Protocol
The was an international treaty which extended the 1992 United Nations Framework Convention on Climate Change (UNFCCC) that commits state parties to reduce greenhouse gas emissions, based on the scientific consensus that global warming is oc ...
has failed to do so.
[Of Montreal and Kyoto: A Tale of Two Protocols]
by Cass R. Sunstein 38 ELR 10566 8/2008 In this case of the ozone depletion challenge, there was global regulation already being installed before a scientific consensus was established. Also, overall public opinion was convinced of possible imminent risks.
[Environmental Politics Climate Change and Knowledge Politics](_blank)
Reiner Grundmann, Vol. 16, No. 3, 414–432, June 2007[Technische Problemlösung, Verhandeln und umfassende Problemlösung, (eng. technical trouble shooting, negotiating and generic problem solving capability)]
in Gesellschaftliche Komplexität und kollektive Handlungsfähigkeit (Societys complexity and collective ability to act), ed. Schimank, U. (2000). Frankfurt/Main: Campus, pp. 154–18
book summary at the Max Planck Gesellschaft
The ozone treaty has been ratified by 198 parties (197 states and the
European Union
The European Union (EU) is a supranational union, supranational political union, political and economic union of Member state of the European Union, member states that are Geography of the European Union, located primarily in Europe. The u ...
),
making it the
first universally ratified treaty in United Nations history.
This truly universal treaty has also been remarkable in the expedience of the policy-making process at the global scale, where only 14 years lapsed between a basic scientific research discovery (1973) and the international agreement signed (1985 and 1987).
Terms and purposes
The treaty
[The full terms of the Montreal Protocol are available from th]
United Nations Environment Programme (UNEP) Ozone Secretariat
is structured around several groups of
halogenated hydrocarbons that lead to the catalytic destruction of stratospheric ozone. All of the ozone depleting substances controlled by the Montreal Protocol contain either
chlorine
Chlorine is a chemical element; it has Symbol (chemistry), symbol Cl and atomic number 17. The second-lightest of the halogens, it appears between fluorine and bromine in the periodic table and its properties are mostly intermediate between ...
or
bromine
Bromine is a chemical element; it has chemical symbol, symbol Br and atomic number 35. It is a volatile red-brown liquid at room temperature that evaporates readily to form a similarly coloured vapour. Its properties are intermediate between th ...
(substances containing only
fluorine
Fluorine is a chemical element; it has Chemical symbol, symbol F and atomic number 9. It is the lightest halogen and exists at Standard temperature and pressure, standard conditions as pale yellow Diatomic molecule, diatomic gas. Fluorine is extre ...
do not harm the ozone layer, although they can be strong greenhouse gases). Some ozone-depleting substances (ODSs) are not yet controlled by the Montreal Protocol, including
nitrous oxide
Nitrous oxide (dinitrogen oxide or dinitrogen monoxide), commonly known as laughing gas, nitrous, or factitious air, among others, is a chemical compound, an Nitrogen oxide, oxide of nitrogen with the Chemical formula, formula . At room te ...
(N
2O). For a table of ozone-depleting substances controlled by the Montreal Protocol see:
For each group of ODSs, the treaty provides a timetable on which the production of those substances must be reduced and eventually eliminated. This includes a 10-year phase-out for developing countries identified in Article 5 of the treaty.
Chlorofluorocarbons (CFCs) Phase-out Management Plan
The purpose of the treaty is that each signatory states:
There was a faster phase-out of halon-1211, -2402, -1301, There was a slower phase-out (to zero by 2010) of other substances (halon 1211, 1301, 2402; CFCs 13, 111, 112, etc.) and some chemicals were given individual attention (
Carbon tetrachloride
Carbon tetrachloride, also known by many other names (such as carbon tet for short and tetrachloromethane, also IUPAC nomenclature of inorganic chemistry, recognised by the IUPAC), is a chemical compound with the chemical formula CCl4. It is a n ...
;
1,1,1-trichloroethane). The phasing-out of the less damaging
HCFC
Chlorofluorocarbons (CFCs) and hydrochlorofluorocarbons (HCFCs) are fully or partly halogenated hydrocarbons that contain carbon (C), hydrogen (H), chlorine (Cl), and fluorine (F). They are produced as volatile derivatives of methane, ethane, ...
s only began in 1996 and will go on until a complete phasing-out is achieved by 2030.
There were a few exceptions for "essential uses" where no acceptable substitutes were initially found (for example, metered dose inhalers commonly used to treat asthma and chronic obstructive pulmonary disease were previously exempt) or
Halon fire suppression systems used in submarines and aircraft (but not in general industry).
The substances in Group I of Annex A are:
* CFCl
3 (
CFC-11)
* CF
2Cl
2 (
CFC-12)
* C
2F
3Cl
3 (
CFC-113)
* C
2F
4Cl
2(
CFC-114)
* C
2F
5Cl (
CFC-115)
The provisions of the Protocol include the requirement that the Parties to the Protocol base their future decisions on the current scientific, environmental, technical, and economic information that is assessed through panels drawn from the worldwide expert communities. To provide that input to the decision-making process, advances in understanding on these topics were assessed in 1989, 1991, 1994, 1998 and 2002 in a series of reports entitled
Scientific assessment of ozone depletion, by the Scientific Assessment Panel (SAP).
In 1990 a Technology and Economic Assessment Panel was also established as the technology and economics advisory body to the Montreal Protocol Parties. The Technology and Economic Assessment Panel (TEAP) provides, at the request of Parties, technical information related to the alternative technologies that have been investigated and employed to make it possible to virtually eliminate use of Ozone Depleting Substances (such as CFCs and Halons), that harm the ozone layer. The TEAP is also tasked by the Parties every year to assess and evaluate various technical issues including evaluating nominations for essential use exemptions for CFCs and halons, and nominations for critical use exemptions for methyl bromide. TEAP's annual reports are a basis for the Parties' informed decision-making.
Numerous reports have been published by various inter-governmental, governmental and non-governmental organizations to catalogue and assess alternatives to the ozone depleting substances, since the substances have been used in various technical sectors, like in refrigeration, air conditioning, flexible and rigid foam, fire protection, aerospace, electronics, agriculture, and laboratory measurements.
Hydrochlorofluorocarbons (HCFCs) Phase-out Management Plan (HPMP)
Under the Montreal Protocol on Substances that Deplete the Ozone Layer, especially Executive Committee (ExCom) 53/37 and ExCom 54/39, Parties to this Protocol agreed to set year 2013 as the time to freeze the consumption and production of HCFCs for developing countries. For developed countries, reduction of HCFC consumption and production began in 2004 and 2010, respectively, with 100% reduction set for 2020. Developing countries agreed to start reducing its consumption and production of HCFCs by 2015, with 100% reduction set for 2030.
Hydrochlorofluorocarbons, commonly known as HCFCs, are a group of human-made compounds containing hydrogen, chlorine, fluorine and carbon. They are not found anywhere in nature. HCFC production began to take off after countries agreed to phase out the use of CFCs in the 1980s, which were found to be destroying the ozone layer. Like CFCs, HCFCs are used for refrigeration, aerosol propellants, foam manufacture and air conditioning. Unlike the CFCs, however, most HCFCs are broken down in the lowest part of the atmosphere and pose a much smaller risk to the ozone layer. Nevertheless, HCFCs are very potent
greenhouse gas
Greenhouse gases (GHGs) are the gases in the atmosphere that raise the surface temperature of planets such as the Earth. Unlike other gases, greenhouse gases absorb the radiations that a planet emits, resulting in the greenhouse effect. T ...
es, despite their very low atmospheric concentrations, measured in parts per trillion (million million).
The HCFCs are transitional CFCs replacements, used as
refrigerant
A refrigerant is a working fluid used in the cooling, heating, or reverse cooling/heating cycles of air conditioning systems and heat pumps, where they undergo a repeated phase transition from a liquid to a gas and back again. Refrigerants are ...
s, solvents, blowing agents for plastic foam manufacture, and fire extinguishers. In terms of
ozone depletion potential
The ozone depletion potential (ODP) of a chemical compound is the relative amount of degradation to the ozone layer it can cause, with trichlorofluoromethane (R-11 or CFC-11) being fixed at an ODP of 1.0. Chlorodifluoromethane (R-22), for examp ...
(ODP), in comparison to CFCs that have ODP 0.6–1.0, these HCFCs have lower ODPs (0.01–0.5). In terms of
global warming potential
Global warming potential (GWP) is a measure of how much heat a greenhouse gas traps in the atmosphere over a specific time period, relative to carbon dioxide (). It is expressed as a multiple of warming caused by the same mass of carbon dioxide ( ...
(GWP), in comparison to CFCs that have GWP 4,680–10,720, HCFCs have lower GWPs (76–2,270).
Hydrofluorocarbons (HFCs)
On 1 January 2019, the
Kigali Amendment
The Kigali Amendment to the Montreal Protocol is an international agreement to gradually reduce the consumption and production of hydrofluorocarbons (HFCs). It is a legally binding agreement designed to create rights and obligations in internati ...
to the Montreal Protocol came into force. Under the Kigali Amendment countries promised to reduce the use of hydrofluorocarbons (HFCs) by more than 80% over the next 30 years. By 27 December 2018, 65 countries had ratified the Amendment.
, 160 states
and the
European Union
The European Union (EU) is a supranational union, supranational political union, political and economic union of Member state of the European Union, member states that are Geography of the European Union, located primarily in Europe. The u ...
have ratified the Amendment.
Produced mostly in developed countries,
hydrofluorocarbons (HFCs) replaced CFCs and HCFCs. HFCs pose no harm to the ozone layer because, unlike CFCs and HCFCs, they do not contain chlorine. They are, however, greenhouse gases, with a high global warming potential (GWP), comparable to that of CFCs and HCFCs. In 2009, a study calculated that a fast phasedown of high-GWP HFCs could potentially prevent the equivalent of up to 8.8 Gt -eq per year in emissions by 2050. A proposed phasedown of HFCs was hence projected to avoid up to 0.5C of warming by 2100 under the high-HFC growth scenario, and up to 0.35C under the low-HFC growth scenario. Recognizing the opportunity presented for fast and effective phasing down of HFCs through the Montreal Protocol, starting in 2009 the
Federated States of Micronesia
The Federated States of Micronesia (, abbreviated FSM), or simply Micronesia, is an island country in Micronesia, a region of Oceania. The federation encompasses the majority of the Caroline Islands (excluding Palau) and consists of four Admin ...
proposed an amendment to phase down high-GWP HFCs, with the U.S., Canada, and Mexico following with a similar proposal in 2010.
After seven years of negotiations, in October 2016 at the 28th Meeting of the Parties to the Montreal Protocol in
Kigali
Kigali () is the Capital (political), capital and largest city of Rwanda. It is near the nation's geographic centre in a region of rolling hills, with a series of valleys and ridges joined by steep slopes. As a primate city, Kigali is a relativ ...
, the Parties to the Montreal Protocol adopted the Kigali Amendment whereby the Parties agreed to phase down HFCs under the Montreal Protocol. The amendment to the Montreal Protocol commits the signatory parties to reduce their HFC production and consumption by at least 85 per cent from the annual average value in the period from 2011 to 2013. A group of developing countries including China, Brazil and South Africa are mandated to reduce their HFC use by 85 per cent of their average value in 2020-22 by the year 2045. India and some other developing countries – Iran, Iraq, Pakistan, and some oil economies like Saudi Arabia and Kuwait – will cut down their HFCs by 85 per cent of their values in 2024-26 by the year 2047.
On 17 November 2017, ahead of the 29th Meeting of the Parties of the Montreal Protocol, Sweden became the 20th Party to ratify the Kigali Amendment, pushing the Amendment over its ratification threshold ensuring that the Amendment would enter into force 1 January 2019.
History
In the 1970s, the chemists
Frank Sherwood Rowland and
Mario Molina, who were then at the
University of California, Irvine
The University of California, Irvine (UCI or UC Irvine) is a Public university, public Land-grant university, land-grant research university in Irvine, California, United States. One of the ten campuses of the University of California system, U ...
, began studying the impacts of CFCs in the Earth's atmosphere. They discovered that CFC molecules were stable enough to remain in the atmosphere until they got up into the middle of the
stratosphere
The stratosphere () is the second-lowest layer of the atmosphere of Earth, located above the troposphere and below the mesosphere. The stratosphere is composed of stratified temperature zones, with the warmer layers of air located higher ...
where they would finally (after an average of 50–100 years for two common CFCs) be broken down by
ultraviolet radiation
Ultraviolet radiation, also known as simply UV, is electromagnetic radiation of wavelengths of 10–400 nanometers, shorter than that of visible light, but longer than X-rays. UV radiation is present in sunlight and constitutes about 10% of t ...
releasing a
chlorine
Chlorine is a chemical element; it has Symbol (chemistry), symbol Cl and atomic number 17. The second-lightest of the halogens, it appears between fluorine and bromine in the periodic table and its properties are mostly intermediate between ...
atom. Rowland and Molina then proposed that these chlorine atoms might be expected to cause the breakdown of large amounts of ozone (O
3) in the stratosphere. Their argument was based upon an analogy to contemporary work by
Paul J. Crutzen and Harold Johnston, which had shown that nitric oxide (NO) could catalyze the destruction of ozone. (Several other scientists, including
Ralph Cicerone,
Richard Stolarski, Michael McElroy, and Steven Wofsy had independently proposed that chlorine could catalyze ozone loss, but none had realized that CFCs were a potentially large source of chlorine.) Crutzen, Molina and Rowland were awarded the 1995
Nobel Prize for Chemistry
The Nobel Prize in Chemistry () is awarded annually by the Royal Swedish Academy of Sciences to scientists in the various fields of chemistry. It is one of the five Nobel Prizes established by the will of Alfred Nobel in 1895, awarded for outst ...
for their work on this problem.
The environmental consequence of this discovery was that, since stratospheric ozone absorbs most of the ultraviolet-B (UV-B) radiation reaching the surface of the planet, depletion of the ozone layer by CFCs would lead to an increase in UV-B radiation at the surface, resulting in an increase in skin cancer and other impacts such as damage to crops and to marine phytoplankton.
The Rowland-Molina hypothesis was strongly disputed by representatives of the aerosol and halocarbon industries. The chair of the board of
DuPont
Dupont, DuPont, Du Pont, duPont, or du Pont may refer to:
People
* Dupont (surname) Dupont, also spelled as DuPont, duPont, Du Pont, or du Pont is a French surname meaning "of the bridge", historically indicating that the holder of the surname re ...
was quoted as saying that ozone depletion theory is "a science fiction tale...a load of rubbish...utter nonsense".
Robert Abplanalp
Robert Henry Abplanalp, ( KHS) (April 4, 1922 – August 30, 2003) was an American inventor and engineer who invented the modern form of the aerosol spray valve, the founder of Precision Valve Corporation, a Republican political activist, and ...
, the president of Precision Valve Corporation (and inventor of the first practical aerosol spray can valve), wrote to the Chancellor of UC Irvine to complain about Rowland's public statements (Roan, p. 56.)
After publishing their pivotal paper in June 1974, Rowland and Molina testified at a
hearing before the U.S. House of Representatives in December 1974. As a result, significant funding was made available to study various aspects of the problem and to confirm the initial findings. In 1976, the U.S.
National Academy of Sciences
The National Academy of Sciences (NAS) is a United States nonprofit, NGO, non-governmental organization. NAS is part of the National Academies of Sciences, Engineering, and Medicine, along with the National Academy of Engineering (NAE) and the ...
(NAS) released a report that confirmed the scientific credibility of the ozone depletion hypothesis.
NAS continued to publish assessments of related science for the next decade.
In 1982, representatives from 24 countries met in Stockholm, Sweden to decide on a "Global Framework Convention for the Protection of the Ozone Layer." The following year, a group of countries, including the United States, Canada, the Nordic Countries, and Switzerland, proposed a worldwide ban on "nonessential" uses of CFCs in spray cans.
Then, in 1985,
British Antarctic Survey
The British Antarctic Survey (BAS) is the United Kingdom's national polar research institute. It has a dual purpose, to conduct polar science, enabling better understanding of list of global issues, global issues, and to provide an active prese ...
scientists
Joe Farman,
Brian Gardiner and
Jon Shanklin published results of abnormally low ozone concentrations above
Halley Bay near the
South Pole
The South Pole, also known as the Geographic South Pole or Terrestrial South Pole, is the point in the Southern Hemisphere where the Earth's rotation, Earth's axis of rotation meets its surface. It is called the True South Pole to distinguish ...
. They speculated that this was connected to increased levels of CFCs in the atmosphere. It took several other attempts to establish the Antarctic losses as real and significant, especially after NASA had retrieved matching data from its satellite recordings. This unforeseen phenomenon in the Antarctic, as well as NASA's scientific images of the ozone hole played an important role in the Montreal Protocol negotiations. The impact of these studies, the metaphor 'ozone hole', and the colorful visual representation in a time lapse animation proved shocking enough for negotiators in Montreal, Canada to take the issue seriously.

Also in 1985, 20 nations, including most of the major CFC producers, signed the
Vienna Convention, which established a framework for negotiating international regulations on ozone-depleting substances. After the discovery of the ozone hole
by SAGE 2 it only took 18 months to reach a binding agreement in Montreal, Canada.
Mostafa Kamal Tolba, the head of the
UNEP
The United Nations Environment Programme (UNEP) is responsible for coordinating responses to environmental issues within the United Nations system. It was established by Maurice Strong, its first director, after the Declaration of the United Nati ...
at the time, was considered the "father of the Montreal Protocol" for his role in bringing the nations together for an agreement.
In 1986, an assessment spearheaded by NASA and sponsored by the United Nationals Environment Program, the
World Meteorological Organization
The World Meteorological Organization (WMO) is a List of specialized agencies of the United Nations, specialized agency of the United Nations responsible for promoting international cooperation on atmospheric science, climatology, hydrology an ...
, and various other organizations concluded that continued CFC emissions at the 1980 rate would "reduce global average ozone by about 9 percent by the latter half of the century." Based on these figures, the U.S.
Environmental Protection Agency estimated that in the United States alone there could be "over 150 million new cases of skin cancer among people currently alive and born by the year 2075, resulting in over 3 million deaths."
The CFC industry continued pushing back against regulation as late as 1986, when the Alliance for Responsible CFC Policy (an association representing the CFC industry founded by
DuPont
Dupont, DuPont, Du Pont, duPont, or du Pont may refer to:
People
* Dupont (surname) Dupont, also spelled as DuPont, duPont, Du Pont, or du Pont is a French surname meaning "of the bridge", historically indicating that the holder of the surname re ...
) was still arguing that the science was too uncertain to justify any action. In 1987, DuPont testified before the US Congress that "We believe there is no imminent crisis that demands unilateral regulation."
And even in March 1988, Du Pont Chair Richard E. Heckert would write in a letter to the United States Senate, "we will not produce a product unless it can be made, used, handled and disposed of safely and consistent with appropriate safety, health and environmental quality criteria. At the moment, scientific evidence does not point to the need for dramatic CFC emission reductions. There is no available measure of the contribution of CFCs to any observed ozone change..."
In an unexpected policy change, however, the Alliance for Responsible CFC Policy issued a statement in 1986 declaring that "large future increases...in CFCs...would be unacceptable to future generations," and that it would be "inconsistent with
ndustrygoals...to ignore the potential for risk to future generations." Three months before the protocol negotiations began, U.S. industry announced its support for new international controls on CFCs.
Multilateral Fund
The main objective of the ''Multilateral Fund for the Implementation of the Montreal Protocol'' is to assist developing country parties to the Montreal Protocol whose annual per capita consumption and production of ozone depleting substances (ODS) is less than 0.3 kg to comply with the control measures of the Protocol. Currently, 147 of the 196 Parties to the Montreal Protocol meet these criteria (they are referred to as Article 5 countries).
It embodies the principle agreed at the
United Nations Conference on Environment and Development in 1992 that countries have a common but differentiated responsibility to protect and manage the global commons.
The Fund is managed by an executive committee with an equal representation of seven industrialized and seven Article 5 countries, which are elected annually by a Meeting of the Parties. The Committee reports annually to the Meeting of the Parties on its operations. The work of the Multilateral Fund on the ground in developing countries is carried out by four Implementing Agencies, which have contractual agreements with the executive committee:
*
United Nations Environment Programme
The United Nations Environment Programme (UNEP) is responsible for coordinating responses to environmental issues within the United Nations system. It was established by Maurice Strong, its first director, after the Declaration of the United Nati ...
(UNEP), through its
OzonAction Programme.
*
United Nations Development Programme
The United Nations Development Programme (UNDP) is a United Nations agency tasked with helping countries eliminate poverty and achieve sustainable economic growth and human development. The UNDP emphasizes on developing local capacity towar ...
(UNDP).
*
United Nations Industrial Development Organization
The United Nations Industrial Development Organization (UNIDO) (French: Organisation des Nations unies pour le développement industriel; French/Spanish acronym: ONUDI) is a specialized agency of the United Nations that assists countries in e ...
(UNIDO).
*
World Bank
The World Bank is an international financial institution that provides loans and Grant (money), grants to the governments of Least developed countries, low- and Developing country, middle-income countries for the purposes of economic development ...
.
Up to 20 percent of the contributions of contributing parties can also be delivered through their bilateral agencies in the form of eligible projects and activities.
The fund is replenished on a three-year basis by the donors. Pledges amount to US$3.1 billion over the period 1991 to 2005. Funds are used, for example, to finance the conversion of existing manufacturing processes, train personnel, pay royalties and patent rights on new technologies, and establish national ozone offices.
Parties
As of October 2022, all Member States of the United Nations, the
Cook Islands
The Cook Islands is an island country in Polynesia, part of Oceania in the South Pacific Ocean. It consists of 15 islands whose total land area is approximately . The Cook Islands' Exclusive Economic Zone (EEZ) covers of ocean. Avarua is its ...
,
Niue
Niue is a self-governing island country in free association with New Zealand. It is situated in the South Pacific Ocean and is part of Polynesia, and predominantly inhabited by Polynesians. One of the world's largest coral islands, Niue is c ...
, the
Holy See
The Holy See (, ; ), also called the See of Rome, the Petrine See or the Apostolic See, is the central governing body of the Catholic Church and Vatican City. It encompasses the office of the pope as the Bishops in the Catholic Church, bishop ...
, the
State of Palestine
Palestine, officially the State of Palestine, is a country in West Asia. Recognized by International recognition of Palestine, 147 of the UN's 193 member states, it encompasses the Israeli-occupied West Bank, including East Jerusalem, and th ...
as well as the
European Union
The European Union (EU) is a supranational union, supranational political union, political and economic union of Member state of the European Union, member states that are Geography of the European Union, located primarily in Europe. The u ...
have ratified the original Montreal Protocol (see external link below), with the State of Palestine being the last party to ratify the agreement, bringing the total to 198. 197 of those parties (with the exception of the State of Palestine) have also ratified the London, Copenhagen, Montreal, and Beijing amendments.
Effect

Since the Montreal Protocol came into effect, the atmospheric concentrations of the most important chlorofluorocarbons and related chlorinated hydrocarbons have either leveled off or decreased. Halon concentrations have continued to increase, as the halons presently stored in fire extinguishers are released, but their rate of increase has slowed and their abundances are expected to begin to decline by about 2020. Also, the concentration of the HCFCs increased drastically at least partly because of many uses (e.g. used as solvents or refrigerating agents) CFCs were substituted with HCFCs. While there have been reports of attempts by individuals to circumvent the ban, e.g. by smuggling CFCs from undeveloped to developed nations, the overall level of compliance has been high. Statistical analysis from 2010 show a clear positive signal from the Montreal Protocol to the stratospheric ozone. In consequence, the Montreal Protocol has often been called the most successful international environmental agreement to date. In a 2001 report, NASA found the ozone thinning over Antarctica had remained the same thickness for the previous three years, however in 2003 the ozone hole grew to its second largest size. The most recent (2006) scientific evaluation of the effects of the Montreal Protocol states, "The Montreal Protocol is working: There is clear evidence of a decrease in the atmospheric burden of ozone-depleting substances and some early signs of stratospheric ozone recovery." However, a more recent study seems to point to a relative increase in CFCs due to an unknown source.
Reported in 1997, significant production of CFCs occurred in Russia for sale on the black market to the EU throughout the 90s. Related US production and consumption was enabled by fraudulent reporting due to poor enforcement mechanisms. Similar illegal markets for CFCs were detected in Taiwan, Korea, and Hong Kong.
The Montreal Protocol is also expected to have effects on human health. A 2015 report by the U.S. Environmental Protection Agency estimates that the protection of the ozone layer under the treaty will prevent over 280 million cases of skin cancer, 1.5 million skin cancer deaths, and 45 million cataracts in the United States.
However, the hydrochlorofluorocarbons, or HCFCs, and hydrofluorocarbons, or HFCs, contribute to
anthropogenic global warming. On a molecule-for-molecule basis, these compounds are up to 10,000 times more potent greenhouse gases than carbon dioxide. The Montreal Protocol currently calls for a complete phase-out of HCFCs by 2030, but does not place any restriction on HFCs. Since the CFCs themselves are equally powerful greenhouse gases, the mere substitution of HFCs for CFCs does not significantly increase the rate of anthropogenic climate change, but over time a steady increase in their use could increase the danger that human activity will change the climate.
Policy experts have advocated for increased efforts to link ozone protection efforts to climate protection efforts. Policy decisions in one arena affect the costs and effectiveness of environmental improvements in the other.
Regional detections of non-compliance
In 2018, scientists monitoring the atmosphere following the 2010 phaseout date reported evidence of continuing industrial production of CFC-11, likely in eastern Asia, with detrimental global effects on the ozone layer. A monitoring study detected fresh atmospheric releases of carbon tetrachloride from China's
Shandong
Shandong is a coastal Provinces of China, province in East China. Shandong has played a major role in Chinese history since the beginning of Chinese civilization along the lower reaches of the Yellow River. It has served as a pivotal cultural ...
province, beginning sometime after 2012, and accounting for a large part of emissions exceeding global estimates under the Montreal Protocol.
25th anniversary celebrations
The year 2012 marked the 25th anniversary of the signing of the Montreal Protocol. Accordingly, the Montreal Protocol community organized a range of celebrations at the national, regional and international levels to publicize its considerable success to date and to consider the work ahead for the future.
Among its accomplishments are:
*The Montreal Protocol was the first international treaty to address a global environmental regulatory challenge;
*the first to embrace the "precautionary principle" in its design for science-based policymaking;
*the first treaty where independent experts on atmospheric science, environmental impacts, chemical technology, and economics, reported directly to parties, without edit or censorship, functioning under norms of professionalism, peer review, and respect;
*the first to provide for national differences in responsibility and financial capacity to respond by establishing a multilateral fund for technology transfer; the first MEA with stringent reporting, trade, and binding chemical phase-out obligations for both developed and developing countries; and,
*the first treaty with a financial mechanism managed democratically by an executive board with equal representation by developed and developing countries.
Within 25 years of signing, parties to the MP celebrate significant milestones. Significantly, the world has phased-out 98% of the Ozone-Depleting Substances (ODS) contained in nearly 100 hazardous chemicals worldwide; every country is in compliance with stringent obligations; and, the MP has achieved the status of the first global regime with universal ratification; even the newest member state, South Sudan, ratified in 2013. UNEP received accolades for achieving global consensus that "demonstrates the world’s commitment to ozone protection, and more broadly, to global environmental protection".
[ozone.unep.org]
See also
*
Action for Climate Empowerment
*
Carbon footprint
A carbon footprint (or greenhouse gas footprint) is a calculated value or index that makes it possible to compare the total amount of greenhouse gases that an activity, product, company or country Greenhouse gas emissions, adds to the atmospher ...
*
Copenhagen Accord
*
Net capacity factor
*
International Day for the Preservation of the Ozone Layer
*
Paris Agreement
The Paris Agreement (also called the Paris Accords or Paris Climate Accords) is an international treaty on climate change that was signed in 2016. The treaty covers climate change mitigation, adaptation, and finance. The Paris Agreement was ...
*
R-134a
*
Section 608
*
Vienna Conference (1985)
*
Fossil fuel phase-out
*
Phase-out of fossil fuel vehicles
*
Phase-out of gas boilers
*
Plastic bans
Notes
References
(referred to as Ozone Layer Protection)
Further reading
*
Andersen, S. O. and K. M. Sarma. (2002). ''Protecting the Ozone Layer: the United Nations History, Earthscan Press''. London.
*
Andersen, S. O., K. M. Sarma and K. N. Taddonio. (2007). ''Technology Transfer for the Ozone Layer: Lessons for Climate Change''. Earthscan Press, London.
* Benedick, Richard E. (1991). ''Ozone Diplomacy''. Harvard University Press. (Ambassador Benedick was the Chief U.S. Negotiator at the meetings that resulted in the Protocol.)
* Brodeur, Paul (1986). "Annals of Chemistry: In the Face of Doubt." ''The New Yorker'', 9 June 1986, pp. 70–87.
* Chasek, Pam, David Downie, and J.W. Brown (2013). G''lobal Environmental Politics'', 6th ed., Boulder: Westview Press.
* Dotto, Lydia and Harold Schiff (1978). ''The Ozone War''. New York:
Doubleday (publisher)
Doubleday is an American publishing company. It was founded as the Doubleday & McClure Company in 1897. By 1947, it was the largest book publisher in the United States. It published the work of mostly U.S. authors under a number of imprints and ...
.
* Downie, David (1993). "Comparative Public Policy of Ozone Layer Protection." ''Political Science'' (NZ) 45(2): (December): 186–197.
* Downie, David (1995). "Road Map or False Trail: Evaluating the Precedence of the Ozone Regime as Model and Strategy for Global Climate Change," ''International Environmental Affairs'', 7(4):321–345 (Fall 1995).
* Downie, David (1999). "The Power to Destroy: Understanding Stratospheric Ozone Politics as a Common Pool Resource Problem", in J. Barkin and G. Shambaugh (eds.) ''Anarchy and the Environment: The International Relations of Common Pool Resources''. Albany: State University of New York Press.
*
David L. Downie (2012). "The Vienna Convention, Montreal Protocol and Global Policy to Protect Stratospheric Ozone", in P. Wexler et al. (eds.) ''Chemicals, Environment, Health: A Global Management Perspective''. Oxford: Taylor & Francis.
* Downie, David (2013) "Stratospheric Ozone Depletion." ''The Routledge Handbook of Global Environmental Politics''. New York: Routledge.
* Farman, J.C., B.G. Gardiner, and J.D. Shanklin (1985). "Large Losses of Total Ozone in Antarctica Reveal Seasonal / Interaction." ''Nature'' 315: 207–210, 16 May 1985.
* Gareau, Brian J. (2013). ''From Precaution to Profit: Contemporary Challenges to Environmental Protection in the Montreal Protocol''. New Haven & London: Yale University Press.
* Grundmann, Reiner. (2001). ''Transnational Environmental Policy: Reconstructing Ozone'', London: Routledge.
* Litfin, Karen T. (1994). ''Ozone Discourses''. Columbia University Press.
* Molina, Mario and F. Sherwood Rowland (1974). "Stratospheric Sink for Chlorofluoromethanes: Chlorine Atomic Catalyzed Destruction of Ozone." ''Nature'' 249: 810–812, 28 June 1974.
* Morissette, P.M. (1989). "The evolution of policy responses to stratospheric ozone depletion." ''Natural Resources Journal'' 29: 793–820.
* Parson, Edward (2003). ''Protecting the Ozone Layer: Science and Strategy''. Oxford: Oxford University Press.
* Roan, Sharon (1989). ''Ozone Crisis: The 15-Year Evolution of a Sudden Global Emergency''. New York, John Wiley and Sons
* United Nations Environmental Programme. (2012).
The Montreal Protocol and The Green Economy'.
* Velders, G. J. M., S. O. Andersen, J. S. Daniel, D. W. Fahey, and M. McFarland. (2007).
The Importance of the Montreal Protocol in Protecting the Climate'. Proc. of the Natl. Acad. Of Sci., 104(12), 4814–4819, .
* Velders, G. J. M., D. W. Fahey, J. S Daniel, M. McFarland, and S. O. Andersen. (2009).
The Large Contribution of Projected HFC Emissions to Future Climate Forcing'. Proc. of the Natl. Acad. Of Sci., 106(27), .
* Velders, G. J. M., A. R. Ravishankara, M. K. Miller, M. J. Molina, J. Alcamo, J. S. Daniel, D. W. Fahey, S. A. Montzka, and S. Reimann. (2012).
Preserving Montreal Protocol Climate Benefits by Limiting HFCs'. Science, 335(6071), 922–923, .
External links
Multilateral Fund for the Implementation of the Montreal ProtocolThe Montreal ProtocolThe Vienna ConventionOzone-Depleting Substances (ODS) Controlled Under the Montreal ProtocolThe Montreal Protocol Who's Whoby F.Sherwood Rowland and Mario J.Molina
Has the Montreal Protocol been successful in reducing ozone-depleting gases in the atmosphere? NOAA Aeronomy Lab)
Doomsday Déjà vu: Ozone Depletion's Lessons for Global Warming b
Ben LiebermanEIA reports Reports on illegal trade and solutions.
on the ''Montreal Protocol on Substances that Deplete the Ozone Layer'' in th
*
ttp://www.green-cooling-initiative.org/ Green Cooling InitiativeGreen Cooling Initiative on alternative natural refrigerants cooling technologies
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