
Metal deactivators, or metal deactivating agents (MDA) are
fuel additives and
oil additives used to stabilize fluids by deactivating (usually by
sequestering) metal
ions, mostly introduced by the action of naturally occurring acids in the fuel and acids generated in
lubricant
A lubricant (sometimes shortened to lube) is a substance that helps to reduce friction between surfaces in mutual contact, which ultimately reduces the heat generated when the surfaces move. It may also have the function of transmitting forces, ...
s by oxidative processes with the metallic parts of the systems. Fuels desulfurized by
copper sweetening also contain a significant trace amounts of copper.
Metal deactivators inhibit the
catalytic
Catalysis () is the increase in reaction rate, rate of a chemical reaction due to an added substance known as a catalyst (). Catalysts are not consumed by the reaction and remain unchanged after it. If the reaction is rapid and the catalyst ...
effects of such ions, especially
copper
Copper is a chemical element; it has symbol Cu (from Latin ) and atomic number 29. It is a soft, malleable, and ductile metal with very high thermal and electrical conductivity. A freshly exposed surface of pure copper has a pinkish-orang ...
, retarding the formation of gummy residues (e.g.
gels containing copper
mercaptide). Even concentrations of copper as low as 0.1 ppm can have detrimental effects.
An example of a metal deactivator used for
gasoline
Gasoline ( North American English) or petrol ( Commonwealth English) is a petrochemical product characterized as a transparent, yellowish, and flammable liquid normally used as a fuel for spark-ignited internal combustion engines. When for ...
and
jet fuel
Jet fuel or aviation turbine fuel (ATF, also abbreviated avtur) is a type of aviation fuel designed for use in aircraft powered by Gas turbine, gas-turbine engines. It is colorless to straw-colored in appearance. The most commonly used fuels for ...
s is
salen. It is used in turbine and
jet fuel
Jet fuel or aviation turbine fuel (ATF, also abbreviated avtur) is a type of aviation fuel designed for use in aircraft powered by Gas turbine, gas-turbine engines. It is colorless to straw-colored in appearance. The most commonly used fuels for ...
s,
diesel,
heating oil, and
greases. It is approved for military and commercial
aviation fuels.
Benzotriazole and its various derivatives are also common in
lubricant
A lubricant (sometimes shortened to lube) is a substance that helps to reduce friction between surfaces in mutual contact, which ultimately reduces the heat generated when the surfaces move. It may also have the function of transmitting forces, ...
formulas.
References
See also
*
Oil additive
*
Sequestrant
*
Corrosion inhibitor
{{Motor fuel
Fuel additives
Lubricants
Material protection