Manto Ore Deposit
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A polymetallic replacement deposit, also known as carbonate replacement deposit or high-temperature carbonate-hosted Ag-Pb-Zn deposit,Megaw, P.K.M., Ruiz, J., and Titley, S.R., 1988, High-Temperature, Carbonate-Hosted Ag-Pb-Zn(Cu) Deposits of Northern Mexico: Economic Geology, v. 83, pp.1856-1885 is an orebody of metallic minerals formed by the replacement of sedimentary, usually carbonate rock, by metal-bearing solutions in the vicinity of igneous intrusions. When the ore forms a blanketlike body along the bedding plane of the rock, it is commonly called a manto ore deposit. Other ore geometries are chimneys and veins. Polymetallic replacements/mantos are often stratiform wall-rock replacement orebodies distal to
porphyry copper Porphyry copper deposits are copper ore bodies that are formed from hydrothermal circulation, hydrothermal fluids that originate from a voluminous magma chamber several kilometers below the deposit itself. Predating or associated with those flui ...
deposits, or porphyry molybdenum deposits.Ray, G., Webster, I., Megaw, P., McGlasson, J., and Glover, K., 2001, The Lustdust Property in Central British Columbia: A Polymetallic Zoned Porphyry-Skarn-Manto-Vein System: British Columbia Geological Survey Geological Fieldwork 2001, p. 257-280 The term manto is derived from the Spanish word ''manto'', meaning "mantle" or "cloak". Although similar in orebody geometry, host-rock lithology, and the presence of lead and zinc, carbonate hosted lead zinc ore deposits, also known as Mississippi Valley type, are considered a different type of ore deposits. Mississippi valley type ore deposits lack silver and gold mineralization, are lower temperature, and are not associated with nearby igneous intrusions.


Mineralogy

Polymetallic replacement deposits are significant sources of
copper Copper is a chemical element; it has symbol Cu (from Latin ) and atomic number 29. It is a soft, malleable, and ductile metal with very high thermal and electrical conductivity. A freshly exposed surface of pure copper has a pinkish-orang ...
,
gold Gold is a chemical element; it has chemical symbol Au (from Latin ) and atomic number 79. In its pure form, it is a brightness, bright, slightly orange-yellow, dense, soft, malleable, and ductile metal. Chemically, gold is a transition metal ...
,
silver Silver is a chemical element; it has Symbol (chemistry), symbol Ag () and atomic number 47. A soft, whitish-gray, lustrous transition metal, it exhibits the highest electrical conductivity, thermal conductivity, and reflectivity of any metal. ...
,
lead Lead () is a chemical element; it has Chemical symbol, symbol Pb (from Latin ) and atomic number 82. It is a Heavy metal (elements), heavy metal that is density, denser than most common materials. Lead is Mohs scale, soft and Ductility, malleabl ...
, manganese, and
zinc Zinc is a chemical element; it has symbol Zn and atomic number 30. It is a slightly brittle metal at room temperature and has a shiny-greyish appearance when oxidation is removed. It is the first element in group 12 (IIB) of the periodic tabl ...
. The metallic ore minerals are mostly in sulfides, such as
galena Galena, also called lead glance, is the natural mineral form of lead(II) sulfide (PbS). It is the most important ore of lead and an important source of silver. Galena is one of the most abundant and widely distributed sulfide minerals. It crysta ...
,
sphalerite Sphalerite is a sulfide mineral with the chemical formula . It is the most important ore of zinc. Sphalerite is found in a variety of deposit types, but it is primarily in Sedimentary exhalative deposits, sedimentary exhalative, Carbonate-hoste ...
,
enargite Enargite is a copper arsenic sulfosalt mineral with formula Cu3AsS4. It takes its name from the Greek word , "distinct". Enargite is a steel gray, blackish gray, to violet black mineral with metallic luster. It forms slender orthorhombic prisms a ...
, and
argentite In mineralogy, argentite () is cubic silver sulfide (Ag2S), which can only exist at temperatures above , , or . When it cools to ordinary temperatures it turns into its monoclinic polymorph, acanthite. The International Mineralogical Associatio ...
. Gangue minerals include
quartz Quartz is a hard, crystalline mineral composed of silica (silicon dioxide). The Atom, atoms are linked in a continuous framework of SiO4 silicon–oxygen Tetrahedral molecular geometry, tetrahedra, with each oxygen being shared between two tet ...
,
pyrite The mineral pyrite ( ), or iron pyrite, also known as fool's gold, is an iron sulfide with the chemical formula Fe S2 (iron (II) disulfide). Pyrite is the most abundant sulfide mineral. Pyrite's metallic luster and pale brass-yellow hue ...
,
rhodochrosite Rhodochrosite is a manganese carbonate mineral with chemical composition Manganese(II) carbonate, MnCO3. In its pure form (rare), it is typically a rose-red colour, but it can also be shades of pink to pale brown. It Streak (mineralogy), streak ...
and
barite Baryte, barite or barytes ( or ) is a mineral consisting of barium sulfate (Ba S O4). Baryte is generally white or colorless, and is the main source of the element barium. The ''baryte group'' consists of baryte, celestine (strontium sulfate), ...
. The mineralogy changes with distance from the intrusive rock. Closest to the intrusion is the copper-gold zone; next is the lead-silver zone, then the zinc-manganese zone.


Classification

Manto ore deposits are defined by a strict stratigraphic control on their distribution, generally within a porous formation within a structural trap site. They are distinct from other copper ore bodies in that they are not associated with
shear zone In geology, a shear zone is a thin zone within the Earth's crust or upper mantle that has been strongly deformed, due to the walls of rock on either side of the zone slipping past each other. In the upper crust, where rock is brittle, the shear ...
s, and an intrusive link to manto deposit formation is not conclusively proven, but is often inferred.


Genetic model

The genetic model of manto formation is debated, but consists of the following broad principles; * The ''source'' of ore within manto deposits is considered to be interformational, from a sedimentary source within an adjacent sedimentary basin, or from ore fluids driven off from a granite intrusive. * The ''transport'' of copper into the manto deposit position was likely hydrothermal, either a metamorphic solution or copper-bearing hydrothermal solutions generated by intrusive granites. * The ''trap'' where the ore materials concentrated is typically a coarse-grained member of a carbonate formation, and the manto is usually sited in a stratigraphic or structural pinch-out of this formation although it is now thought that
hydrocarbon In organic chemistry, a hydrocarbon is an organic compound consisting entirely of hydrogen and carbon. Hydrocarbons are examples of group 14 hydrides. Hydrocarbons are generally colourless and Hydrophobe, hydrophobic; their odor is usually fain ...
s may have assisted in the migration of metals into favorable trap sites.


Morphology

Manto deposits were first described in great detail in Chile, where they sit within sedimentary strata overlying large granitic intrusions, in regions adjacent to
porphyry copper Porphyry copper deposits are copper ore bodies that are formed from hydrothermal circulation, hydrothermal fluids that originate from a voluminous magma chamber several kilometers below the deposit itself. Predating or associated with those flui ...
deposits. In Chile, the arid climate and deep regolith development, tended to favor preservation of
chalcocite Chalcocite (), copper(I) sulfide (Cu2S), is an important copper ore mineral. It is opaque and dark gray to black, with a metallic luster. It has a hardness of 2.5–3 on the Mohs scale. It is a sulfide with a monoclinic crystal system. T ...
-
malachite Malachite () is a copper Carbonate mineral, carbonate hydroxide mineral, with the chemical formula, formula Basic copper carbonate, Cu2CO3(OH)2. This opaque, green-banded mineral crystallizes in the monoclinic crystal system, and most often for ...
-
azurite Azurite or '' Azure spar'Krivovichev V. G.'' Mineralogical glossary. Scientific editor A. G. Bulakh. — St.Petersburg: St.Petersburg Univ. Publ. House. 2009. — 556 p. — ISBN 978-5-288-04863-0. ''(in Russian)'' is a soft, deep-blue copp ...
assemblages in the manto deposits, leading workers to believe that they were weathered equivalents of primary
chalcopyrite Chalcopyrite ( ) is a copper iron sulfide mineral and the most abundant copper ore mineral. It has the chemical formula CuFeS2 and crystallizes in the tetragonal system. It has a brassy to golden yellow color and a Mohs scale, hardness of 3.5 to 4 ...
deposits of porphyry-copper derivation. However, recent work suggests that there may be primary
chalcocite Chalcocite (), copper(I) sulfide (Cu2S), is an important copper ore mineral. It is opaque and dark gray to black, with a metallic luster. It has a hardness of 2.5–3 on the Mohs scale. It is a sulfide with a monoclinic crystal system. T ...
and
bornite Bornite, also known as peacock ore, is a sulfide mineral with chemical composition that crystallizes in the orthorhombic system (pseudo-cubic). It is an important copper ore. Appearance Bornite has a brown to copper-red color on fresh surfa ...
formed within degraded petroleum within trap sites, with copper precipitating from solution by reduction in contact with the reduced carbon. Thus, manto deposits need not be the weathered equivalents of primary
chalcopyrite Chalcopyrite ( ) is a copper iron sulfide mineral and the most abundant copper ore mineral. It has the chemical formula CuFeS2 and crystallizes in the tetragonal system. It has a brassy to golden yellow color and a Mohs scale, hardness of 3.5 to 4 ...
. Manto deposits may be formed in proximity to intrusives, for instance in the La Providencia mine,
Mexico Mexico, officially the United Mexican States, is a country in North America. It is the northernmost country in Latin America, and borders the United States to the north, and Guatemala and Belize to the southeast; while having maritime boundar ...
, a porphyry
stock Stocks (also capital stock, or sometimes interchangeably, shares) consist of all the Share (finance), shares by which ownership of a corporation or company is divided. A single share of the stock means fractional ownership of the corporatio ...
is the feeder for some twenty mantos as the pipe intersects favorable layers in the sedimentary sequence. However, these manto deposits are analogous to
skarn Skarns or tactites are coarse-grained metamorphic rocks that form by replacement of carbonate-bearing rocks during regional or contact metamorphism and metasomatism. Skarns may form by metamorphic recrystallization of impure carbonate protoliths, ...
deposits, and in some cases terminology may be misused. In many instances, manto/ polymetallic replacement/ carbonate replacement deposits can be considered as the distal part of a continuum with skarn deposits.


Example manto deposits

* Atacocha, PeruDan L. Mosier, Hal T. Morris, and Donald A. Singer, 1986, "Grade and tonnage models of polymetallic replacement deposits," in Dennis P. Cox and Donald A. Singer, ''Mineral Deposit Models'', US Geological Survey, Bulletin 1693, p.101-104. * Bingham Canyon, Utah (peripheral to the porphyry Copper) * El Boleo Mine,
Santa Rosalia, Baja California Sur Santa Claus (also known as Saint Nicholas, Saint Nick, Father Christmas, Kris Kringle or Santa) is a legendary figure originating in Western Christian culture who is said to bring gifts during the late evening and overnight hours on Christma ...
, Mexico * Charcas, San Luis Potosi, Mexico *
Gilman, Colorado Gilman is an ghost town, abandoned Mining community, mining town in southeastern Eagle County, Colorado, Eagle County, Colorado, United States. The Gilman post office operated from November 3, 1886, until April 22, 1986. The United States Postal ...
(zinc) *
Laurium Lavrio, Lavrion or Laurium (; (later ); from Middle Ages until 1908: Εργαστήρια ''Ergastiria'') is a town in southeastern part of Attica, Greece. It is part of Athens metropolitan area and the seat of the municipality of Lavreotik ...
, Greece * Leadville mining district, Colorado (silver, lead, zinc) * Magma Mine,
Superior, Arizona Superior (Western Apache language, Western Apache: Yooʼ Łigai) is a town in northern Pinal County, Arizona, United States, and is the oldest town in the county. According to the 2020 United States census, 2020 census, the population of the tow ...
(copper) * Naica, Chihuahua, Mexico *
Park City, Utah Park City is a city in Utah, United States. Most of the city is within Summit County, Utah, Summit County, with some portions extending into Wasatch County, Utah, Wasatch County. It is considered to be part of the Wasatch Back. The city is sou ...
(silver) *
Pioche, Nevada Pioche () is an Unincorporated towns in Nevada, unincorporated town in Lincoln County, Nevada, Lincoln County, Nevada, United States, approximately northeast of Las Vegas, Nevada, Las Vegas. U.S. Route 93 in Nevada, U.S. Route 93 is the main r ...
(silver) * Platosa, Mexico * Santa Eulalia, Mexico * Clark, Arizona * Tintic, Utah, (silver) *
Tombstone, Arizona Tombstone is a city in Cochise County, Arizona, Cochise County, Arizona, United States, founded in 1879 by Prospecting, prospector Ed Schieffelin in what was then Pima County, Arizona, Pima County, Arizona Territory. It became one of the last ...


See also

*
Ore genesis Various theories of ore genesis explain how the various types of mineral deposits form within Earth's crust. Ore-genesis theories vary depending on the mineral or commodity examined. Ore-genesis theories generally involve three components: sour ...
*
Polymetallic ore Polymetallic ores or multimetal ores are complex ores containing a number of chemical elements, among which the most important are lead and zinc. In addition, polymetallic ores can contain copper, gold, silver, cadmium, sometimes bismuth, tin, i ...


References


Literature

* Evans, Anthony, (1992) ''Ore Geology and Industrial Minerals: An Introduction'', Blackwell Science; 3rd edition * Guilbert, John M. and Charles F. Park, Jr (1986) ''The Geology of Ore Deposits'', W. H. Freeman {{ISBN, 0-7167-1456-6 Economic geology