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Spandex, Lycra, or elastane is a
synthetic fiber Synthetic fibers or synthetic fibres (in British English; see spelling differences) are fibers made by humans through chemical synthesis, as opposed to natural fibers that are directly derived from living organisms, such as plants (like cotton) ...
known for its exceptional elasticity. It is a
polyether In organic chemistry, ethers are a class of compounds that contain an ether group—an oxygen atom connected to two alkyl or aryl groups. They have the general formula , where R and R′ represent the alkyl or aryl groups. Ethers can again be ...
-
polyurea Polyurea is a type of elastomer that is derived from the reaction product of an isocyanate component and a synthetic resin blend component through step-growth polymerization. The isocyanate can be aromatic or aliphatic in nature. It can be m ...
copolymer In polymer chemistry, a copolymer is a polymer derived from more than one species of monomer. The polymerization of monomers into copolymers is called copolymerization. Copolymers obtained from the copolymerization of two monomer species are ...
that was invented in 1958 by chemist Joseph Shivers at
DuPont DuPont de Nemours, Inc., commonly shortened to DuPont, is an American multinational chemical company first formed in 1802 by French-American chemist and industrialist Éleuthère Irénée du Pont de Nemours. The company played a major role in ...
's Benger Laboratory in Waynesboro, Virginia, US. The generic name "spandex", which is an
anagram An anagram is a word or phrase formed by rearranging the letters of a different word or phrase, typically using all the original letters exactly once. For example, the word ''anagram'' itself can be rearranged into ''nag a ram'', also the word ...
of the word "expands", is the preferred name in
North America North America is a continent in the Northern Hemisphere and almost entirely within the Western Hemisphere. It is bordered to the north by the Arctic Ocean, to the east by the Atlantic Ocean, to the southeast by South America and th ...
. In
continental Europe Continental Europe or mainland Europe is the contiguous continent of Europe, excluding its surrounding islands. It can also be referred to ambiguously as the European continent, – which can conversely mean the whole of Europe – and, by ...
, it is referred to by variants of "elastane", including (France), (Germany, Sweden), (Spain), (Italy), and (Netherlands); and in the UK, Ireland, Portugal, Spain, Latin America, Australia, and New Zealand, it is primarily known as "Lycra". Brand names for spandex include Lycra (made by The Lycra Company, previously a division of DuPont Textiles and Interiors), Elaspan (The Lycra Company), Acepora (
Taekwang Group Taekwang Group is a large South Korean '' chaebol'' (conglomerate), producing clothing, apparel, chemical, industry, and financial services products. Subsidiaries * Taekwang Industry * Taekwang Synthetic Fiber (ChangShu, China) * Taekwang Swi ...
), Creora ( Hyosung), INVIYA ( Indorama Corporation), ROICA and Dorlastan ( Asahi Kasei), Linel (Fillattice), and ESPA ( Toyobo).


History

In the post-World War II era, DuPont Textiles Fibers Department, formed in 1952, became the most profitable division of DuPont, dominating the
synthetic fiber Synthetic fibers or synthetic fibres (in British English; see spelling differences) are fibers made by humans through chemical synthesis, as opposed to natural fibers that are directly derived from living organisms, such as plants (like cotton) ...
market worldwide. At this time, women began to emerge as a significant group of consumers because of their need for underwear and hosiery. After conducting
market research Market research is an organized effort to gather information about target markets and customers: know about them, starting with who they are. It is an important component of business strategy and a major factor in maintaining competitiveness. Ma ...
to find out what women wanted from textiles, DuPont began developing fibers to meet such needs—including a better fiber for women's
girdles A belt, especially if a cord or rope, is called a girdle if it is worn as part of Christian liturgical vestments, or in certain historical, literary or sports contexts. Girdles are used to close a cassock in Christian denominations, including t ...
, which were commonly made of rubber at the time. By the 1930s, DuPont became interested in developing a synthetic elastic fiber. DuPont made its first breakthrough in the early 1950s when chemist Joseph C. Shivers used an intermediate substance to modify
Dacron Polyethylene terephthalate (or poly(ethylene terephthalate), PET, PETE, or the obsolete PETP or PET-P), is the most common thermoplastic polymer resin of the polyester family and is used in fibres for clothing, containers for liquids and fo ...
polyester, producing a stretchy fiber that could withstand high temperatures. Determined to find a fiber to replace rubber in garments, after nearly a decade of research, Shivers perfected the fiber in 1958 at
DuPont DuPont de Nemours, Inc., commonly shortened to DuPont, is an American multinational chemical company first formed in 1802 by French-American chemist and industrialist Éleuthère Irénée du Pont de Nemours. The company played a major role in ...
's Benger Laboratory in Waynesboro, Virginia. Moreover, the nature of spandex allowed it to be incorporated into other garments besides girdles and undergarments.


Lycra brand

To distinguish its brand of spandex fiber, DuPont chose the
trade name A trade name, trading name, or business name, is a pseudonym used by companies that do not operate under their registered company name. The term for this type of alternative name is a "fictitious" business name. Registering the fictitious name w ...
''Lycra'' (originally called ''Fiber K''). DuPont launched an extensive publicity campaign for its Lycra brand, taking advertisements and full-page ads in top women's magazines such as ''
Vogue Vogue may refer to: Business * ''Vogue'' (magazine), a US fashion magazine ** British ''Vogue'', a British fashion magazine ** ''Vogue Arabia'', an Arab fashion magazine ** ''Vogue Australia'', an Australian fashion magazine ** ''Vogue China'', ...
'', '' Glamour'', ''
Harper's Bazaar ''Harper's Bazaar'' is an American monthly women's fashion magazine. It was first published in New York City on November 2, 1867, as the weekly ''Harper's Bazar''. ''Harper's Bazaar'' is published by Hearst and considers itself to be the ...
'', '' Mademoiselle'', ''
McCall's ''McCall's'' was a monthly American women's magazine, published by the McCall Corporation, that enjoyed great popularity through much of the 20th century, peaking at a readership of 8.4 million in the early 1960s. It was established as a small-f ...
'', ''
Ladies' Home Journal ''Ladies' Home Journal'' was an American magazine last published by the Meredith Corporation. It was first published on February 16, 1883, and eventually became one of the leading women's magazines of the 20th century in the United States. In ...
'', and '' Good Housekeeping''.
Audrey Hepburn Audrey Hepburn (born Audrey Kathleen Ruston; 4 May 1929 – 20 January 1993) was a British actress and humanitarian. Recognised as both a film and fashion icon, she was ranked by the American Film Institute as the third-greatest female screen ...
helped catapult the brand on and off-screen during this time; models and actresses like
Joan Collins Dame Joan Henrietta Collins (born 23 May 1933) is an English actress, author and columnist. Collins is the recipient of several accolades, including a Golden Globe Award, a People's Choice Award, two Soap Opera Digest Awards and a Primeti ...
and
Ann-Margret Ann-Margret Olsson (born April 28, 1941) is a Swedish–American actress, singer, and dancer. As an actress and singer, she is credited as Ann-Margret. She is known for her roles in '' Pocketful of Miracles'' (1961), ''State Fair'' (1962), '' ...
followed Hepburn's aesthetic by posing in Lycra clothing for photo shoots and magazine covers. By the mid-1970s, with the emergence of the women's liberation movement, girdle sales began to drop as they came to be associated with anti-independence and emblematic of an era that was quickly passing away. In response, DuPont reimagined Lycra as the aerobic fitness movement emerged in the 1970s. The association of Lycra with fitness had been established at the
1968 Winter Olympic Games The 1968 Winter Olympics, officially known as the X Olympic Winter Games (french: Les Xes Jeux olympiques d'hiver), were a winter multi-sport event held from 6 to 18 February 1968 in Grenoble, France. Thirty-seven countries participated. Frenchm ...
, when the French ski team wore Lycra garments to compete. This popularized the brand as essential athletic wear because of its flexible and lightweight material. The fiber came to be especially popular in mid-thigh-length shorts worn by cyclists. By the 1980s, the fitness trend had reached its height in popularity and fashionistas began wearing shorts on the street. Spandex proved such a popular fiber in the garment industry that, by 1987, DuPont had trouble meeting worldwide demand. In the 1990s a variety of other items made with spandex proved popular, including a successful line of body-shaping foundation garments sold under the trade name ''Bodyslimmers''. As the decade progressed, shirts, pants, dresses, and even shoes were being made with spandex blends, and mass-market retailers like Banana Republic were even using it for menswear.


Environmental impact

In 2014, it was noted that most clothes containing spandex end up as non-recyclable waste once they have been worn out, because fabric blends containing spandex are difficult to recycle. This contributes to the pollution of the environment.


Production

Spandex fibers are produced in four ways: melt extrusion, reaction spinning, solution dry spinning, and solution wet spinning. All of these methods include the initial step of reacting
monomer In chemistry, a monomer ( ; '' mono-'', "one" + '' -mer'', "part") is a molecule that can react together with other monomer molecules to form a larger polymer chain or three-dimensional network in a process called polymerization. Classification ...
s to produce a pre
polymer A polymer (; Greek '' poly-'', "many" + '' -mer'', "part") is a substance or material consisting of very large molecules called macromolecules, composed of many repeating subunits. Due to their broad spectrum of properties, both synthetic a ...
. Once the prepolymer is formed, it is reacted further in various ways and drawn out to make the fibers. The solution dry spinning method is used to produce over 94.5% of the world's spandex fibers."How spandex is made"
from How Products Are Made
The process has five steps: #The first step is to produce the prepolymer. This is done by mixing a macro glycol with a diisocyanate monomer. The two compounds are mixed in a reaction vessel to produce a prepolymer. A typical ratio of glycol to diisocyanate is 1:2. #The prepolymer is further reacted with an equal amount of
diamine A diamine is an amine with exactly two amino groups. Diamines are used as monomers to prepare polyamides, polyimides, and polyureas. The term ''diamine'' refers mostly to primary diamines, as those are the most reactive. In terms of quantities ...
. This reaction is known as '' chain extension reaction.'' The resulting solution is diluted with a solvent (
dimethylacetamide Dimethylacetamide (DMAc or DMA) is the organic compound with the formula CH3C(O)N(CH3)2. This colorless, water-miscible, high-boiling liquid is commonly used as a polar solvent in organic synthesis. DMA is miscible with most other solvents, altho ...
) to produce the spinning solution. The solvent helps make the solution thinner and more easily handled, and then it can be pumped into the fiber production cell. #The spinning solution is pumped into a cylindrical spinning cell. In this cell, the polymer solution is forced through a metal plate called a
spinneret A spinneret is a silk-spinning organ of a spider or the larva of an insect. Some adult insects also have spinnerets, such as those borne on the forelegs of Embioptera. Spinnerets are usually on the underside of a spider's opisthosoma, and are ...
. This causes the solution to be aligned in strands of liquid polymer. As the strands pass through the cell, they are heated in the presence of a
nitrogen Nitrogen is the chemical element with the symbol N and atomic number 7. Nitrogen is a nonmetal and the lightest member of group 15 of the periodic table, often called the pnictogens. It is a common element in the universe, estimated at se ...
and solvent gas. This process causes the liquid polymer to react chemically and form solid strands. #As the fibers exit the cell, an amount of solid strands are bundled together to produce the desired thickness. #The resulting fibers are then treated with a finishing agent which can be magnesium stearate or a polymer. This treatment prevents the fibers' sticking together and aids in textile manufacture. The fibers are then transferred through a series of rollers onto a spool.


Function

The exceptional elasticity of spandex fibers increases the clothing's pressure comfort, enhancing the ease of body movements. Pressure comfort is the response towards clothing by the human body's pressure receptors (
mechanoreceptor A mechanoreceptor, also called mechanoceptor, is a sensory receptor that responds to mechanical pressure or distortion. Mechanoreceptors are innervated by sensory neurons that convert mechanical pressure into electrical signals that, in animals, a ...
s present in skin sensory cells). The sensation response is affected mainly by the stretch, snug, loose, heavy, lightweight, soft, and stiff structure of the material. The elasticity and strength (stretching up to five times its length) of spandex has been incorporated into a wide range of garments, especially in skin-tight garments. A benefit of spandex is its significant strength and elasticity and its ability to return to the original shape after stretching and faster drying than ordinary fabrics. For clothing, spandex is usually mixed with
cotton Cotton is a soft, fluffy staple fiber that grows in a boll, or protective case, around the seeds of the cotton plants of the genus '' Gossypium'' in the mallow family Malvaceae. The fiber is almost pure cellulose, and can contain minor pe ...
or
polyester Polyester is a category of polymers that contain the ester functional group in every repeat unit of their main chain. As a specific material, it most commonly refers to a type called polyethylene terephthalate (PET). Polyesters include natura ...
, and accounts for a small percentage of the final fabric, which therefore retains most of the look and feel of the other fibers. An estimated 80% of clothing sold in the
United States The United States of America (U.S.A. or USA), commonly known as the United States (U.S. or US) or America, is a country Continental United States, primarily located in North America. It consists of 50 U.S. state, states, a Washington, D.C., ...
contained spandex in 2010.


Gallery

Athlete.png, A road cyclist wearing compression garments Hurdler.jpg, A hurdler in a uniform


References


External links


"What's That Stuff: Spandex"
''Chemical and Engineering News'' {{Clothing materials and parts Products introduced in 1958 1970s fashion 1980s fashion 2000s fashion 2010s fashion Copolymers Elastomers Synthetic fibers Technical fabrics Woven fabrics