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Lazurite is a
tectosilicate Silicate minerals are rock-forming minerals made up of silicate groups. They are the largest and most important class of minerals and make up approximately 90 percent of Earth's crust. In mineralogy, silica (silicon dioxide, ) is usually consid ...
mineral with
sulfate The sulfate or sulphate ion is a polyatomic anion with the empirical formula . Salts, acid derivatives, and peroxides of sulfate are widely used in industry. Sulfates occur widely in everyday life. Sulfates are salts of sulfuric acid and many ...
, sulfur and
chloride The chloride ion is the anion (negatively charged ion) Cl−. It is formed when the element chlorine (a halogen) gains an electron or when a compound such as hydrogen chloride is dissolved in water or other polar solvents. Chloride sa ...
with formula . It is a
feldspathoid The feldspathoids are a group of tectosilicate minerals which resemble feldspars but have a different structure and much lower silica content. They occur in rare and unusual types of igneous rocks, and are usually not found in rocks containing prim ...
and a member of the
sodalite Sodalite ( ) is a tectosilicate mineral with the formula , with royal blue varieties widely used as an ornamental gemstone. Although massive sodalite samples are opaque, crystals are usually transparent to translucent. Sodalite is a member of t ...
group. Lazurite crystallizes in the isometric system although well‐formed crystals are rare. It is usually massive and forms the bulk of the gemstone lapis lazuli. Lazurite is a deep‐blue to greenish‐blue. The colour is due to the presence of anions. It has a
Mohs hardness The Mohs scale of mineral hardness () is a qualitative ordinal scale, from 1 to 10, characterizing scratch resistance of various minerals through the ability of harder material to scratch softer material. The scale was introduced in 1812 by t ...
of 5.0 to 5.5 and a
specific gravity Relative density, or specific gravity, is the ratio of the density (mass of a unit volume) of a substance to the density of a given reference material. Specific gravity for liquids is nearly always measured with respect to water at its densest ...
of 2.4. It is translucent with a
refractive index In optics, the refractive index (or refraction index) of an optical medium is a dimensionless number that gives the indication of the light bending ability of that medium. The refractive index determines how much the path of light is bent, or ...
of 1.50. It is fusible at 3.5 on Wolfgang Franz von Kobell's fusibility scale, and soluble in HCl. It commonly contains or is associated with grains of
pyrite The mineral pyrite (), or iron pyrite, also known as fool's gold, is an iron sulfide with the chemical formula Fe S2 (iron (II) disulfide). Pyrite is the most abundant sulfide mineral. Pyrite's metallic luster and pale brass-yellow hue giv ...
. Lazurite is a product of
contact metamorphism Metamorphism is the transformation of existing rock (the protolith) to rock with a different mineral composition or texture. Metamorphism takes place at temperatures in excess of , and often also at elevated pressure or in the presence of che ...
of
limestone Limestone ( calcium carbonate ) is a type of carbonate sedimentary rock which is the main source of the material lime. It is composed mostly of the minerals calcite and aragonite, which are different crystal forms of . Limestone forms whe ...
and is typically associated with calcite, pyrite,
diopside Diopside is a monoclinic pyroxene mineral with composition . It forms complete solid solution series with hedenbergite () and augite, and partial solid solutions with orthopyroxene and pigeonite. It forms variably colored, but typically dull ...
,
humite Humite is a mineral found in the volcanically ejected masses of Vesuvius Mount Vesuvius ( ; it, Vesuvio ; nap, 'O Vesuvio , also or ; la, Vesuvius , also , or ) is a somma-stratovolcano located on the Gulf of Naples in Campania, Ital ...
, forsterite,
hauyne Hauyne or haüyne, also called hauynite or haüynite ( ), is a tectosilicate sulfate mineral with endmember formula . As much as 5 wt % may be present, and also and Cl. It is a feldspathoid and a member of the sodalite group. Hauyne was fir ...
and
muscovite Muscovite (also known as common mica, isinglass, or potash mica) is a hydrated phyllosilicate mineral of aluminium and potassium with formula K Al2(Al Si3 O10)( F,O H)2, or ( KF)2( Al2O3)3( SiO2)6( H2O). It has a highly perfect basal cleavag ...
. Other blue minerals, such as the
carbonate A carbonate is a salt of carbonic acid (H2CO3), characterized by the presence of the carbonate ion, a polyatomic ion with the formula . The word ''carbonate'' may also refer to a carbonate ester, an organic compound containing the carbonate ...
azurite Azurite is a soft, deep-blue copper mineral produced by weathering of copper ore deposits. During the early 19th century, it was also known as chessylite, after the type locality at Chessy-les-Mines near Lyon, France. The mineral, a basic carb ...
and the
phosphate In chemistry, a phosphate is an anion, salt, functional group or ester derived from a phosphoric acid. It most commonly means orthophosphate, a derivative of orthophosphoric acid . The phosphate or orthophosphate ion is derived from phosph ...
lazulite Lazulite () is a blue, phosphate mineral containing magnesium, iron, and aluminium phosphate. Lazulite forms one endmember of a solid solution series with the darker iron rich scorzalite. Lazulite crystallizes in the monoclinic system. Crystal ...
, may be confused with lazurite, but are easily distinguished with careful examination. At one time, lazurite was a synonym for
azurite Azurite is a soft, deep-blue copper mineral produced by weathering of copper ore deposits. During the early 19th century, it was also known as chessylite, after the type locality at Chessy-les-Mines near Lyon, France. The mineral, a basic carb ...
. Lazurite was first described in 1890 for an occurrence in the Sar-e-Sang District,
Koksha Kokshin (russian: Кокшин) is a Russian masculine surname, its feminine counterpart is Kokshina. It derives from the Russian given name Koksha, a derivative of Nikolai, and is sometimes misspelled as Kakshin or Kakshina. The surname may refer ...
Valley,
Badakhshan Badakhshan is a historical region comprising parts of modern-day north-eastern Afghanistan, eastern Tajikistan, and Taxkorgan Tajik Autonomous County in China. Badakhshan Province is one of the 34 provinces of Afghanistan. Much of historic Ba ...
Province,
Afghanistan Afghanistan, officially the Islamic Emirate of Afghanistan,; prs, امارت اسلامی افغانستان is a landlocked country located at the crossroads of Central Asia and South Asia. Referred to as the Heart of Asia, it is bordere ...
. It has been mined for more than 6,000 years in the lapis lazuli district of Badakhshan. It has been used as a pigment in painting and cloth
dyeing Dyeing is the application of dyes or pigments on textile materials such as fibers, yarns, and fabrics with the goal of achieving color with desired color fastness. Dyeing is normally done in a special solution containing dyes and particular c ...
since at least the 6th or 7th century. It is also mined at Lake Baikal in Siberia;
Mount Vesuvius Mount Vesuvius ( ; it, Vesuvio ; nap, 'O Vesuvio , also or ; la, Vesuvius , also , or ) is a somma-stratovolcano located on the Gulf of Naples in Campania, Italy, about east of Naples and a short distance from the shore. It is one of ...
;
Burma Myanmar, ; UK pronunciations: US pronunciations incl. . Note: Wikipedia's IPA conventions require indicating /r/ even in British English although only some British English speakers pronounce r at the end of syllables. As John Wells explai ...
;
Canada Canada is a country in North America. Its ten provinces and three territories extend from the Atlantic Ocean to the Pacific Ocean and northward into the Arctic Ocean, covering over , making it the world's second-largest country by tot ...
; and the
United States The United States of America (U.S.A. or USA), commonly known as the United States (U.S. or US) or America, is a country primarily located in North America. It consists of 50 states, a federal district, five major unincorporated territori ...
. The name is from the
Persian Persian may refer to: * People and things from Iran, historically called ''Persia'' in the English language ** Persians, the majority ethnic group in Iran, not to be conflated with the Iranic peoples ** Persian language, an Iranian language of the ...
for blue.


Structure

Lazurite and
hauyne Hauyne or haüyne, also called hauynite or haüynite ( ), is a tectosilicate sulfate mineral with endmember formula . As much as 5 wt % may be present, and also and Cl. It is a feldspathoid and a member of the sodalite group. Hauyne was fir ...
seem to have the same structure and both are sulfate-dominant minerals. Lazurite is a
pigment A pigment is a colored material that is completely or nearly insoluble in water. In contrast, dyes are typically soluble, at least at some stage in their use. Generally dyes are often organic compounds whereas pigments are often inorganic compou ...
(opalescent) and has a bright blue streak (especially as a component of the semiprecious stone lapis lazuli). Many hauynes have a white or pale blue streak and are translucent. The difference might be a consequence of the redox state (sulfate to sulfide ratio).


See also

* Lapis lazuli *
Ultramarine Ultramarine is a deep blue color pigment which was originally made by grinding lapis lazuli into a powder. The name comes from the Latin ''ultramarinus'', literally 'beyond the sea', because the pigment was imported into Europe from mines in Afg ...


References


External links

* {{Authority control Feldspathoid Sodalite group Sodium minerals Calcium minerals Aluminium minerals Pigments Cubic minerals Minerals in space group 218