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Lanny D. Schmidt (May 6, 1938 – March 27, 2020) was an American
chemist A chemist (from Greek ''chēm(ía)'' alchemy; replacing ''chymist'' from Medieval Latin ''alchemist'') is a scientist trained in the study of chemistry. Chemists study the composition of matter and its properties. Chemists carefully describe t ...
, inventor, author, and Regents Professor of Chemical Engineering and Materials Science at the
University of Minnesota The University of Minnesota, formally the University of Minnesota, Twin Cities, (UMN Twin Cities, the U of M, or Minnesota) is a public land-grant research university in the Twin Cities of Minneapolis and Saint Paul, Minnesota, United States. ...
. He is well known for his extensive work in surface science, detailed chemistry (microkinetics),
chemical reaction engineering Chemical reaction engineering (reaction engineering or reactor engineering) is a specialty in chemical engineering or industrial chemistry dealing with chemical reactors. Frequently the term relates specifically to catalytic reaction systems wh ...
,
catalysis Catalysis () is the process of increasing the rate of a chemical reaction by adding a substance known as a catalyst (). Catalysts are not consumed in the reaction and remain unchanged after it. If the reaction is rapid and the catalyst recyc ...
, and renewable energy. He is also well known for mentoring over a hundred graduate students and his work on millisecond reactors and reactive flash volatilization.


Education and research

Born in Waukegan, Illinois, Schmidt received a Bachelor of Science degree in chemistry in 1960 from Wheaton College in
Wheaton, Illinois Wheaton is a suburban city in Milton and Winfield Townships and is the county seat of DuPage County, Illinois. It is located approximately west of Chicago. As of the 2010 census, the city had a total population of 52,894, which was estimated ...
. From 1960 to 1964, he attended the
University of Chicago The University of Chicago (UChicago, Chicago, U of C, or UChi) is a private university, private research university in Chicago, Illinois. Its main campus is located in Chicago's Hyde Park, Chicago, Hyde Park neighborhood. The University of Chic ...
, where he received a Ph.D. degree in
physical chemistry Physical chemistry is the study of macroscopic and microscopic phenomena in chemical systems in terms of the principles, practices, and concepts of physics such as motion, energy, force, time, thermodynamics, quantum chemistry, statistica ...
and was awarded a
National Science Foundation The National Science Foundation (NSF) is an independent agency of the United States government that supports fundamental research and education in all the non-medical fields of science and engineering. Its medical counterpart is the National ...
Graduate Fellowship. Among many research endeavors, his thesis on alkali metal adsorption was supervised by Robert Gomer. In 1965, he completed a postdoctoral year at the
University of Chicago The University of Chicago (UChicago, Chicago, U of C, or UChi) is a private university, private research university in Chicago, Illinois. Its main campus is located in Chicago's Hyde Park, Chicago, Hyde Park neighborhood. The University of Chic ...
.


Research at Minnesota

In 1965, he joined the
Chemical Engineering Chemical engineering is an engineering field which deals with the study of operation and design of chemical plants as well as methods of improving production. Chemical engineers develop economical commercial processes to convert raw materials int ...
Department at the
University of Minnesota The University of Minnesota, formally the University of Minnesota, Twin Cities, (UMN Twin Cities, the U of M, or Minnesota) is a public land-grant research university in the Twin Cities of Minneapolis and Saint Paul, Minnesota, United States. ...
as an assistant professor in the Department of Chemical Engineering and Materials Science. Schmidt's research focused on various aspects of the chemistry and engineering of chemical reactions on solid surfaces. Reaction systems of recent interest are
catalytic combustion Catalytic combustion is a chemical process which uses a catalyst to speed desired oxidation reactions of fuel and so reduce the formation of undesired products, especially pollutant nitrogen oxide gases (NOx) far below what can be achieved without ...
processes to produce products such as syngas, olefins, and
oxygenate Oxygenated chemical compounds contain oxygen as a part of their chemical structure. The term usually refers to oxygenated chemical compounds added to fuels. Oxygenates are usually employed as gasoline additives to reduce carbon monoxide and soot ...
s by partial
oxidation Redox (reduction–oxidation, , ) is a type of chemical reaction in which the oxidation states of substrate change. Oxidation is the loss of electrons or an increase in the oxidation state, while reduction is the gain of electrons or a ...
, NOx removal, and incineration by total oxidation. One topic of his research is the characterization of adsorption and reactions on well-defined single-crystal surfaces. A second research topic is steady-state and transient reaction kinetics under conditions from ultrahigh
vacuum A vacuum is a space devoid of matter. The word is derived from the Latin adjective ''vacuus'' for "vacant" or " void". An approximation to such vacuum is a region with a gaseous pressure much less than atmospheric pressure. Physicists often di ...
to atmospheric pressure. Schmidt also researched catalytic reaction engineering, in which detailed models of reactors are constructed to simulate industrial reactor performance, with particular emphasis on chemical synthesis and on catalytic combustion.


Millisecond Reactors

Schmidt's research since the early 1990s has focused on the catalytic partial oxidation of alkanes (particularly methane) and oxygenates in continuous flow fixed bed supported
catalyst Catalysis () is the process of increasing the rate of a chemical reaction by adding a substance known as a catalyst (). Catalysts are not consumed in the reaction and remain unchanged after it. If the reaction is rapid and the catalyst recyc ...
reactors. In 2004, Schmidt and his graduate students demonstrated that biomass-derived
ethanol Ethanol (abbr. EtOH; also called ethyl alcohol, grain alcohol, drinking alcohol, or simply alcohol) is an organic compound. It is an alcohol with the chemical formula . Its formula can be also written as or (an ethyl group linked to a ...
could be converted to molecular
hydrogen Hydrogen is the chemical element with the symbol H and atomic number 1. Hydrogen is the lightest element. At standard conditions hydrogen is a gas of diatomic molecules having the formula . It is colorless, odorless, tasteless, non-toxic ...
for fuel cell at greater than 100% selectivity. The significant potential of this discovery has been well-described:
There is, however, a better way of storing the hydrogen needed for fuel cells: in ethanol, each molecule of which bundles six hydrogen atoms, two carbon atoms, and one oxygen atom into a package far more compact than gaseous hydrogen. Until recently, no one could figure out how to unbundle the ethanol molecules in an energy-efficient way. But Lanny Schmidt, a chemical engineer at the University of Minnesota, may now have found a silver bullet. He has developed a glass tube containing a series of metal plates about the size of a Bic lighter. Made out of the exotic metals rhodium and cerium, these plates can suck the hydrogen out of ethanol and feed it into a fuel cell. (Ironically, Schmidt had been looking for a catalyst that would strip hydrogen from plain old gasoline, but the ethanol turned out to work even better.)" — Sam Jaffe, ''
Washington Monthly ''Washington Monthly'' is a bimonthly, nonprofit magazine of United States politics and government that is based in Washington, D.C. The magazine is known for its annual ranking of American colleges and universities, which serves as an alterna ...
''
The discovery has been referenced over 200 times, and it led to Schmidt being listed among the Scientific American top 50 researchers of 2004.


Academic accomplishments

Schmidt has published over 350 papers in refereed journals and was a member of the
National Academy of Engineering The National Academy of Engineering (NAE) is an American nonprofit, non-governmental organization. The National Academy of Engineering is part of the National Academies of Sciences, Engineering, and Medicine, along with the National Academy of ...
. He has supervised approximately 90 Ph.D. theses and 15 M.S. theses at Minnesota, and 14 of his former students hold university teaching positions including
Maria Flytzani-Stephanopoulos Maria Flytzani-Stephanopoulos (1950 - October 28, 2019) was an American chemical engineer and, at the time of her death, had been the Robert and Marcy Haber Endowed Professor in Energy Sustainability and a Distinguished Professor at Tufts Uni ...
, Raymond Gorte and Dionisios Vlachos. In 2013, he was awarded the Neal R. Amundson Award at the 3rd North American Symposium on Chemical Reaction Engineering. Schmidt has previously been awarded the Parravano Award (1997) by the Michigan Catalysis Society, the Alpha Xi Sigma Award (1993) by the American Institute of Chemical Engineers, and a Humboldt Prize (1994) from Germany. He has been honored by several institutions through supported lectures including the Reilly Lectures (1990) at Notre Dame, the Dodge Lectures (1992) at Yale University, the Mason Lectures (1996) at Stanford University, the Merck Lecture (1997) at Rutgers University, the Centennial Lecture (1997) at Purdue University, the Schiut Lecture (1997) at the University of Delaware and the Hottell Lecture (1999) at MIT. In 2000, he was a plenary speaker at the International Congress on Catalysis in Spain, and in 1998 he served as the Fairchild Scholar at the California Institute of Technology.


Policy and public service

Throughout his career, Schmidt has promoted the importance of reaction engineering to
chemical engineering Chemical engineering is an engineering field which deals with the study of operation and design of chemical plants as well as methods of improving production. Chemical engineers develop economical commercial processes to convert raw materials int ...
and chemistry as a separate discipline. In 2004, he published the second edition of his best-selling textbook, ''The Engineering of Chemical Reactions,'' which stressed the importance of the relationships between
thermodynamics Thermodynamics is a branch of physics that deals with heat, work, and temperature, and their relation to energy, entropy, and the physical properties of matter and radiation. The behavior of these quantities is governed by the four laws of th ...
, kinetics, and transport phenomena for a full understanding of reactor design. Since 2003, Schmidt has been a strong advocate of biomass-derived
energy In physics, energy (from Ancient Greek: ἐνέργεια, ''enérgeia'', “activity”) is the quantitative property that is transferred to a body or to a physical system, recognizable in the performance of work and in the form of hea ...
and a supporter of biomass processing research as a solution to the decreasing
petroleum Petroleum, also known as crude oil, or simply oil, is a naturally occurring yellowish-black liquid mixture of mainly hydrocarbons, and is found in geological formations. The name ''petroleum'' covers both naturally occurring unprocessed crud ...
supply. He frequently argued that thermochemical (non-biological) biomass conversion processes have significant advantages over biological processes that will eventually permit small-scale, highly efficient biomass-to-fuel chemical plants.


Achievements and key publications

Schmidt has authored the following journal articles describing significant advances in
chemical reaction engineering Chemical reaction engineering (reaction engineering or reactor engineering) is a specialty in chemical engineering or industrial chemistry dealing with chemical reactors. Frequently the term relates specifically to catalytic reaction systems wh ...
: * * * *


References


External links


Schmidt Research Group at the University of Minnesota
*Lanny D. Schmidt Biographical Documentary () ()
Scientific American: 50 scientific leaders of 2004
{{DEFAULTSORT:Schmidt, Lanny D. American physical chemists 1938 births 2020 deaths People from Waukegan, Illinois Wheaton College (Illinois) alumni Members of the United States National Academy of Engineering American chemical engineers Minnesota CEMS