Landfill gas is a mix of different gases created by the action of
microorganism
A microorganism, or microbe,, ''mikros'', "small") and ''organism'' from the el, ὀργανισμός, ''organismós'', "organism"). It is usually written as a single word but is sometimes hyphenated (''micro-organism''), especially in old ...
s within a
landfill as they decompose
organic waste
Biodegradable waste includes any organic matter in waste which can be broken down into carbon dioxide, water, methane or simple organic molecules by micro-organisms and other living things by composting, aerobic digestion, anaerobic digesti ...
, including for example,
food waste and
paper waste. Landfill gas is approximately forty to sixty percent
methane
Methane ( , ) is a chemical compound with the chemical formula (one carbon atom bonded to four hydrogen atoms). It is a group-14 hydride, the simplest alkane, and the main constituent of natural gas. The relative abundance of methane ...
, with the remainder being mostly
carbon dioxide
Carbon dioxide ( chemical formula ) is a chemical compound made up of molecules that each have one carbon atom covalently double bonded to two oxygen atoms. It is found in the gas state at room temperature. In the air, carbon dioxide is t ...
. Trace amounts of other
volatile organic compounds (VOCs) comprise the remainder (<1%). These trace gases include a large array of species, mainly simple
hydrocarbon
In organic chemistry, a hydrocarbon is an organic compound consisting entirely of hydrogen and carbon. Hydrocarbons are examples of group 14 hydrides. Hydrocarbons are generally colourless and hydrophobic, and their odors are usually weak or ...
s.
[Hans-Jürgen Ehrig, Hans-Joachim Schneider and Volkmar Gossow "Waste, 7. Deposition" in Ullmann's Encyclopedia of Industrial Chemistry, 2011, Wiley-VCH, Weinheim. ]
Landfill gases have an influence on
climate change
In common usage, climate change describes global warming—the ongoing increase in global average temperature—and its effects on Earth's climate system. Climate change in a broader sense also includes previous long-term changes to ...
. The major components are
CO2 and
methane
Methane ( , ) is a chemical compound with the chemical formula (one carbon atom bonded to four hydrogen atoms). It is a group-14 hydride, the simplest alkane, and the main constituent of natural gas. The relative abundance of methane ...
, both of which are
greenhouse gasses. Methane in the atmosphere is a far more potent greenhouse gas, with each molecule having twenty-five times the effect of a molecule of carbon dioxide. Methane itself however accounts for less composition of the atmosphere than does carbon dioxide. Landfills are the third-largest source of methane in the US.
Because of the significant negative effects of these gases, regulatory regimes have been set up to
monitor landfill gas, reduce the amount of
biodegradable content in
municipal waste, and to create
landfill gas utilization strategies, which include
gas flaring or capture for electricity generation.
Production
Landfill gases are the result of three processes:
[
# evaporation of volatile organic compounds (e.g., solvents)
# ]chemical reaction
A chemical reaction is a process that leads to the chemical transformation of one set of chemical substances to another. Classically, chemical reactions encompass changes that only involve the positions of electrons in the forming and breaking ...
s between waste components
# microbial action, especially methanogenesis.
The first two depend strongly on the nature of the waste. The dominant process in most landfills is the third process whereby anaerobic bacteria
An anaerobic organism or anaerobe is any organism that does not require molecular oxygen for growth. It may react negatively or even die if free oxygen is present. In contrast, an aerobic organism (aerobe) is an organism that requires an oxygenat ...
decompose organic waste to produce biogas, which consists of methane and carbon dioxide together with traces of other compounds. Despite the heterogeneity of waste, the evolution of gases follows well defined kinetic pattern. Formation of methane and CO2 commences about six months after depositing the landfill material. The evolution of gas reaches a maximum at about 20 years, then declines over the course of decades.[
When landfill gas permeates through a soil cover, a fraction of the ]methane
Methane ( , ) is a chemical compound with the chemical formula (one carbon atom bonded to four hydrogen atoms). It is a group-14 hydride, the simplest alkane, and the main constituent of natural gas. The relative abundance of methane ...
in the gas is oxidized microbially to CO2.
Monitoring
Because gases produced by landfills are both valuable and sometimes hazardous, monitoring techniques have been developed. Flame ionization detectors can be used to measure methane levels as well as total VOC levels. Surface monitoring and sub-surface monitoring as well as monitoring of the ambient air is carried out. In the U.S., under the Clean Air Act of 1990, it is required that many large landfills install gas collection and control systems, which means that at the very least the facilities must collect and flare the gas.
U.S. Federal regulations under Subtitle D of RCRA formed in October 1979 regulate the siting, design, construction, operation, monitoring, and closure of MSW landfills. Subtitle D now requires controls on the migration of methane in landfill gas. Monitoring requirements must be met at landfills during their operation, and for an additional 30 years after. The landfills affected by Subtitle D of RCRA are required to control gas by establishing a way to check for methane emissions periodically and therefore prevent off-site migration. Landfill owners and operators must make sure the concentration of methane gas does not exceed 25% of the LEL for methane in the facilities' structures and the LEL for methane at the facility boundary.
Use
The gases produced within a landfill can be collected and used in various ways. The landfill gas can be utilized directly on-site by a boiler or any type of combustion system, providing heat. Electricity can also be generated on-site through the use of microturbines, steam turbines, or fuel cells. The landfill gas can also be sold off-site and sent into natural gas pipelines. This approach requires the gas to be processed into pipeline quality, e.g., by removing various contaminants and components. Landfill gas can also be used to evaporate leachate, another byproduct of the landfill process. This application displaces another fuel that was previously used for the same thing.
The efficiency of gas collection at landfills directly impacts the amount of energy that can be recovered - closed landfills (those no longer accepting waste) collect gas more efficiently than open landfills (those that are still accepting waste). A comparison of collection efficiency at closed and open landfills found about a 17 percentage point difference between the two.
Opposition
Capture and use of landfill gas can be expensive. Some environmental groups claim that the projects do not produce "renewable power" because trash (their source) is not renewable. The Sierra Club opposes government subsidies for such projects. The Natural Resources Defense Council (NRDC) argues that government incentives should be directed more towards solar, wind, and energy-efficiency efforts.
Safety
Landfill gas emissions can lead to environmental
A biophysical environment is a biotic and abiotic surrounding of an organism or population, and consequently includes the factors that have an influence in their survival, development, and evolution. A biophysical environment can vary in scal ...
, hygiene and security problems in the landfill. Several accidents have occurred, for example at Loscoe
Loscoe is a village near Heanor in Derbyshire, England, lying within the civil parish of Heanor and Loscoe. It had prominent coalmines in the 19th and 20th centuries. Denby Common and Codnor Breach are hamlets on the western edge of the villa ...
, England in 1986, where migrating landfill gas accumulated and partially destroyed a property. An accident causing two deaths occurred from an explosion in a house adjacent to Skellingsted landfill in Denmark in 1991. Due to the risk presented by landfill gas, there is a clear need to monitor gas produced by landfills. In addition to the risk of fire and explosion, gas migration in the subsurface can result in contact with landfill gas with groundwater
Groundwater is the water present beneath Earth's surface in rock and Pore space in soil, soil pore spaces and in the fractures of stratum, rock formations. About 30 percent of all readily available freshwater in the world is groundwater. A unit ...
. This, in turn, can result in contamination of groundwater by organic compounds present in nearly all landfill gas.[Kerfoot, H.B., Chapter 3.5 In Christensen, T. H., Cossu, R. & Stegmann, R. (1999)Landfilling of waste: Biogas]
Although usually evolved only in trace amounts, landfills do release some aromatics and chlorocarbons.
Landfill gas migration
Landfill gas migration is a complex process in which gases produced by waste in a landfill move from the site of original deposition to other places via diffusion, usually from areas of high concentration to low. The process is also affected by th ...
, due to pressure differentials and diffusion, can occur. This can create an explosion hazard if the gas reaches sufficiently high concentrations in adjacent buildings.
By country
Brazil
United States
See also
*Anaerobic digestion
Anaerobic digestion is a sequence of processes by which microorganisms break down biodegradable material in the absence of oxygen. The process is used for industrial or domestic purposes to manage waste or to produce fuels. Much of the ferm ...
* Biodegradability
* Biogas
*Flue gas
Flue gas is the gas exiting to the atmosphere via a flue, which is a pipe or channel for conveying exhaust gases from a fireplace, oven, furnace, boiler or steam generator. Quite often, the flue gas refers to the combustion exhaust gas produc ...
* Landfill gas utilization
*Relative cost of electricity generated by different sources
Different methods of electricity generation can incur a variety of different costs, which can be divided into three general categories: 1) wholesale costs, or all costs paid by utilities associated with acquiring and distributing electricity to ...
* Underground coal gasification
References
External links
* GA Mansoori, N Enayati, LB Agyarko (2016)
Energy: Sources, Utilization, Legislation, Sustainability, Illinois as Model State
World Sci. Pub. Co.,
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Landfill
Anaerobic digestion
Industrial gases