Lechatelierite is
silica
Silicon dioxide, also known as silica, is an oxide of silicon with the chemical formula , commonly found in nature as quartz. In many parts of the world, silica is the major constituent of sand. Silica is one of the most complex and abundant f ...
glass,
amorphous
In condensed matter physics and materials science, an amorphous solid (or non-crystalline solid) is a solid that lacks the long-range order that is a characteristic of a crystal. The terms "glass" and "glassy solid" are sometimes used synonymousl ...
SiO
2, non-crystalline
mineraloid
A mineraloid is a naturally occurring substance that resembles a mineral, but does not demonstrate the crystallinity of a mineral. Mineraloid substances possess chemical compositions that vary beyond the generally accepted ranges for specific mi ...
. It is named for
Henry Louis Le Chatelier.
Structure
Lechatelierite is a
mineraloid
A mineraloid is a naturally occurring substance that resembles a mineral, but does not demonstrate the crystallinity of a mineral. Mineraloid substances possess chemical compositions that vary beyond the generally accepted ranges for specific mi ...
as it does not have a
crystal structure
In crystallography, crystal structure is a description of ordered arrangement of atoms, ions, or molecules in a crystalline material. Ordered structures occur from intrinsic nature of constituent particles to form symmetric patterns that repeat ...
. Although not a true mineral, it is often classified in the
quartz
Quartz is a hard, crystalline mineral composed of silica (silicon dioxide). The Atom, atoms are linked in a continuous framework of SiO4 silicon–oxygen Tetrahedral molecular geometry, tetrahedra, with each oxygen being shared between two tet ...
mineral group.
Formation
One common way in which lechatelierite forms naturally is by very-high-temperature melting of
quartz
Quartz is a hard, crystalline mineral composed of silica (silicon dioxide). The Atom, atoms are linked in a continuous framework of SiO4 silicon–oxygen Tetrahedral molecular geometry, tetrahedra, with each oxygen being shared between two tet ...
sand during a
lightning
Lightning is a natural phenomenon consisting of electrostatic discharges occurring through the atmosphere between two electrically charged regions. One or both regions are within the atmosphere, with the second region sometimes occurring on ...
strike. The result is an irregular, branching, often foamy hollow tube of silica glass called a
fulgurite.
[Lechatelierite on Mindat.org]
/ref> Not all fulgurites are lechatelierite; the original sand must be nearly pure silica.
Lechatelierite also forms as the result of high pressure shock metamorphism during meteorite
A meteorite is a rock (geology), rock that originated in outer space and has fallen to the surface of a planet or Natural satellite, moon. When the original object enters the atmosphere, various factors such as friction, pressure, and chemical ...
impact crater
An impact crater is a depression (geology), depression in the surface of a solid astronomical body formed by the hypervelocity impact event, impact of a smaller object. In contrast to volcanic craters, which result from explosion or internal c ...
ing and is a common component of a type of glassy ejecta
Ejecta (; ) are particles ejected from an area. In volcanology, in particular, the term refers to particles including pyroclastic rock, pyroclastic materials (tephra) that came out of a explosive eruption, volcanic explosion and magma eruption v ...
called tektites. Most tektites are blobs of impure glassy material, but tektites from the Sahara Desert
The Sahara (, ) is a desert spanning across North Africa. With an area of , it is the largest hot desert in the world and the list of deserts by area, third-largest desert overall, smaller only than the deserts of Antarctica and the northern Ar ...
in Libya
Libya, officially the State of Libya, is a country in the Maghreb region of North Africa. It borders the Mediterranean Sea to the north, Egypt to Egypt–Libya border, the east, Sudan to Libya–Sudan border, the southeast, Chad to Chad–L ...
and Egypt
Egypt ( , ), officially the Arab Republic of Egypt, is a country spanning the Northeast Africa, northeast corner of Africa and Western Asia, southwest corner of Asia via the Sinai Peninsula. It is bordered by the Mediterranean Sea to northe ...
, known as '' Libyan desert glass'', are composed of almost pure silica that is almost pure lechatelierite. High pressure experiments have shown that shock pressures of 85 GPa are needed to produce lechatelierite in quartz grains embedded in granite
Granite ( ) is a coarse-grained (phanerite, phaneritic) intrusive rock, intrusive igneous rock composed mostly of quartz, alkali feldspar, and plagioclase. It forms from magma with a high content of silica and alkali metal oxides that slowly coo ...
.
Lechatelierite was formed during the impact of a meteorite
A meteorite is a rock (geology), rock that originated in outer space and has fallen to the surface of a planet or Natural satellite, moon. When the original object enters the atmosphere, various factors such as friction, pressure, and chemical ...
into a layer of Coconino Sandstone at Meteor Crater in Arizona
Arizona is a U.S. state, state in the Southwestern United States, Southwestern region of the United States, sharing the Four Corners region of the western United States with Colorado, New Mexico, and Utah. It also borders Nevada to the nort ...
. During the rapid pressure reduction following the impact, steam expanded the newly formed lechatelierite. The shattered and expanded glass has a density less than that of water.
Lechatelierite may also form artificially, a unique example being the '' trinitite'' produced by melting of quartz sand at the first nuclear bomb explosion at Trinity Flats, White Sands, New Mexico."Lechatelierite Mineral Data" on Mineralogy Database
References
Impact event minerals
Glass in nature
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