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Latex is an emulsion (stable dispersion) of
polymer A polymer (; Greek ''poly-'', "many" + '' -mer'', "part") is a substance or material consisting of very large molecules called macromolecules, composed of many repeating subunits. Due to their broad spectrum of properties, both synthetic and ...
microparticle Microparticles are particles between 0.1 and 100 μm in size. Commercially available microparticles are available in a wide variety of materials, including ceramics, glass, polymers, and metals. Microparticles encountered in daily life includ ...
s in water. Latexes are found in
nature Nature, in the broadest sense, is the physical world or universe. "Nature" can refer to the phenomena of the physical world, and also to life in general. The study of nature is a large, if not the only, part of science. Although humans ar ...
, but synthetic latexes are common as well. In nature, latex is found as a
milky Milky is an Italian dance music production group consisting of producers Giordano Trivellato and Giuliano Sacchetto, with Italian singer Giuditta serving as their lead singer on their album ''Star''. is a Nordic country located on .... Gi ...
fluid found in 10% of all
flowering plant Flowering plants are plants that bear flowers and fruits, and form the clade Angiospermae (), commonly called angiosperms. They include all forbs (flowering plants without a woody stem), grasses and grass-like plants, a vast majority of ...
s (angiosperms). It is a complex emulsion that coagulates on exposure to air, consisting of
protein Proteins are large biomolecules and macromolecules that comprise one or more long chains of amino acid residues. Proteins perform a vast array of functions within organisms, including catalysing metabolic reactions, DNA replication, respon ...
s,
alkaloid Alkaloids are a class of basic BASIC (Beginners' All-purpose Symbolic Instruction Code) is a family of general-purpose, high-level programming languages designed for ease of use. The original version was created by John G. Kemeny and Th ...
s,
starch Starch or amylum is a polymeric carbohydrate consisting of numerous glucose units joined by glycosidic bonds. This polysaccharide is produced by most green plants for energy storage. Worldwide, it is the most common carbohydrate in human diets ...
es, sugars, oils,
tannin Tannins (or tannoids) are a class of astringent, polyphenolic biomolecules that bind to and precipitate proteins and various other organic compounds including amino acids and alkaloids. The term ''tannin'' (from Anglo-Norman ''tanner ...
s,
resin In polymer chemistry and materials science, resin is a solid or highly viscous substance of plant or synthetic origin that is typically convertible into polymers. Resins are usually mixtures of organic compounds. This article focuses on n ...
s, and
gum Gum may refer to: Types of gum * Adhesive * Bubble gum * Chewing gum * Gum (botany), sap or other resinous material associated with certain species of the plant kingdom ** Gum arabic, made from the sap of ''Acacia senegal'', an Old World tree s ...
s. It is usually exuded after tissue injury. In most plants, latex is white, but some have yellow, orange, or scarlet latex. Since the 17th century, latex has been used as a term for the fluid substance in plants, deriving from the
Latin Latin (, or , ) is a classical language belonging to the Italic branch of the Indo-European languages. Latin was originally a dialect spoken in the lower Tiber area (then known as Latium) around present-day Rome, but through the power ...
word for "liquid". It serves mainly as defense against herbivorous
insect Insects (from Latin ') are pancrustacean hexapod invertebrates of the class Insecta. They are the largest group within the arthropod phylum. Insects have a chitinous exoskeleton, a three-part body (head, thorax and abdomen), three pairs ...
s. Latex is not to be confused with plant sap; it is a distinct substance, separately produced, and with different functions. The word latex is also used to refer to natural latex
rubber Rubber, also called India rubber, latex, Amazonian rubber, ''caucho'', or ''caoutchouc'', as initially produced, consists of polymers of the organic compound isoprene, with minor impurities of other organic compounds. Thailand, Malaysia, a ...
, particularly non- vulcanized rubber. Such is the case in products like latex gloves, latex
condom A condom is a sheath-shaped barrier device used during sexual intercourse to reduce the probability of pregnancy or a sexually transmitted infection (STI). There are both male and female condoms. With proper use—and use at every act of inte ...
s and latex clothing.


Biology


Articulated laticifers

The cells ( laticifers) in which latex is found make up the laticiferous system, which can form in two very different ways. In many plants, the laticiferous system is formed from rows of cells laid down in the meristem of the stem or
root In vascular plants, the roots are the organs of a plant that are modified to provide anchorage for the plant and take in water and nutrients into the plant body, which allows plants to grow taller and faster. They are most often below the sur ...
. The
cell wall A cell wall is a structural layer surrounding some types of cells, just outside the cell membrane. It can be tough, flexible, and sometimes rigid. It provides the cell with both structural support and protection, and also acts as a filtering mec ...
s between these cells are dissolved so that continuous tubes, called latex vessels, are formed. Since these vessels are made of many cells, they are known as ''articulated laticifers''. This method of formation is found in the poppy family and in the
rubber Rubber, also called India rubber, latex, Amazonian rubber, ''caucho'', or ''caoutchouc'', as initially produced, consists of polymers of the organic compound isoprene, with minor impurities of other organic compounds. Thailand, Malaysia, a ...
trees ( Para rubber tree, members of the family
Euphorbiaceae Euphorbiaceae, the spurge family, is a large family of flowering plants. In English, they are also commonly called euphorbias, which is also the name of a genus in the family. Most spurges, such as '' Euphorbia paralias'', are herbs, but some, ...
, members of the mulberry and fig family, such as the Panama rubber tree '' Castilla elastica''), and members of the family
Asteraceae The family Asteraceae, alternatively Compositae, consists of over 32,000 known species of flowering plants in over 1,900 genera within the order Asterales. Commonly referred to as the aster, daisy, composite, or sunflower family, Compositae ...
. For instance, '' Parthenium argentatum'' the guayule plant, is in the tribe Heliantheae; other latex-bearing Asteraceae with articulated laticifers include members of the Cichorieae, a clade whose members produce latex, some of them in commercially interesting amounts. This includes ''
Taraxacum kok-saghyz ''Taraxacum kok-saghyz'', often abbreviated as ''TKS'' and commonly referred to as the Kazakh dandelion, rubber root, or Russian dandelion, is a species of dandelion native to Kazakhstan, Kyrgyzstan and Uzbekistan, that is notable for its product ...
'', a species cultivated for latex production.


Non-articulated laticifers

In the milkweed and spurge families, on the other hand, the laticiferous system is formed quite differently. Early in the development of the seedling, latex cells differentiate, and as the plant grows these latex cells grow into a branching system extending throughout the plant. In many euphorbs, the entire structure is made from a single cell – this type of system is known as a ''non-articulated laticifer'', to distinguish it from the multi-cellular structures discussed above. In the mature plant, the entire laticiferous system is descended from a single cell or group of cells present in the
embryo An embryo is an initial stage of development of a multicellular organism. In organisms that reproduce sexually, embryonic development is the part of the life cycle that begins just after fertilization of the female egg cell by the male sperm ...
. The laticiferous system is present in all parts of the mature plant, including roots, stems, leaves, and sometimes the
fruit In botany, a fruit is the seed-bearing structure in flowering plants that is formed from the ovary after flowering. Fruits are the means by which flowering plants (also known as angiosperms) disseminate their seeds. Edible fruits in partic ...
s. It is particularly noticeable in the cortical tissues. Latex is usually exuded as a white liquid, but is some cases it can be clear, yellow or red, as in
Cannabaceae Cannabaceae is a small family of flowering plants, known as the hemp family. As now circumscribed, the family includes about 170 species grouped in about 11 genera, including '' Cannabis'' (hemp), '' Humulus'' ( hops) and ''Celtis'' (hackberries ...
.


Productive species

Latex is produced by 20,000
flowering plant Flowering plants are plants that bear flowers and fruits, and form the clade Angiospermae (), commonly called angiosperms. They include all forbs (flowering plants without a woody stem), grasses and grass-like plants, a vast majority of ...
species from over 40 families. These include both dicots and monocots. Latex has been found in 14 percent of tropical plant species, as well as six percent of temperate plant species. Several members of the fungal kingdom also produce latex upon injury, such as '' Lactarius deliciosus'' and other
milk-caps Milk-cap (also milk cap, milkcap, or milky) is a common name that refers to mushroom-forming fungi of the genus, genera ''Lactarius (fungus), Lactarius'', ''Lactifluus'', and ''Multifurca'', all in the family Russulaceae. The common and eponymous ...
. This suggests it is the product of
convergent evolution Convergent evolution is the independent evolution of similar features in species of different periods or epochs in time. Convergent evolution creates analogous structures that have similar form or function but were not present in the last com ...
and has been selected for on many separate occasions.


Defense function

Latex functions to protect the plant from herbivores. The idea was first proposed in 1887 by Joseph F. James, who noted that latex
carries with it at the same time such disagreeable properties that it becomes a better protection to the plant from enemies than all the thorns, prickles, or hairs that could be provided. In this plant, so copious and so distasteful has the sap become that it serves a most important purpose in its economy.
Evidence showing this defense function include the finding that slugs will eat leaves drained of their latex but not intact ones, that many insects sever the veins carrying latex before they feed, and that the latex of '' Asclepias humistrata'' (sandhill milkweed) kills by trapping 30% of newly hatched monarch butterfly caterpillars. Other evidence is that latex contains 50–1000× higher concentrations of defense substances than other plant tissues. These toxins include ones that are also toxic to the plant and consist of a diverse range of chemicals that are either poisonous or " antinutritive." Latex is actively moved to the area of injury; in the case of '' Cryptostegia grandiflora'', latex more than 70 cm from the site of injury is mobilized. The large hydrostatic pressure in this vine enables an extremely high flow rate of latex. In a 1935 report the botanist Catherine M. Bangham observed that "piercing the fruit stalk of ''Cryptostegia grandiflora'' produced a jet of latex over a meter long, and maintained his jetfor several seconds." The clotting property of latex is functional in this defense since it limits wastage and its stickiness traps insects and their mouthparts. While there exist other explanations for the existence of latex including storage and movement of plant nutrients, waste, and maintenance of water balance that " sentially none of these functions remain credible and none have any empirical support".


Applications

The latex of many species can be processed to produce many materials. * Balatá and gutta percha latex contain an inelastic polymer related to rubber. *
Chicle Chicle () is a natural gum traditionally used in making chewing gum and other products. It is collected from several species of Mesoamerican trees in the genus ''Manilkara'', including '' M. zapota'', '' M. chicle'', '' M. staminodella'', and ...
and jelutong tree latex was used in chewing gum.


Personal and healthcare products

Natural rubber Rubber, also called India rubber, latex, Amazonian rubber, ''caucho'', or ''caoutchouc'', as initially produced, consists of polymers of the organic compound isoprene, with minor impurities of other organic compounds. Thailand, Malaysia, a ...
is the most important product obtained from latex; more than 12,000 plant species yield latex containing rubber, though in the vast majority of those species the rubber is not suitable for commercial use. This latex is used to make many other products including mattresses, gloves,
swim cap A swimming cap, swim cap or bathing cap, is a tightly fitted, skin-tight garment, commonly made from silicone, latex or lycra, worn on the head by recreational and competitive swimmers. Swim caps are worn for various reasons: they can be worn to ...
s,
condom A condom is a sheath-shaped barrier device used during sexual intercourse to reduce the probability of pregnancy or a sexually transmitted infection (STI). There are both male and female condoms. With proper use—and use at every act of inte ...
s, catheters and
balloon A balloon is a flexible bag that can be inflated with a gas, such as helium, hydrogen, nitrous oxide, oxygen, and air. For special tasks, balloons can be filled with smoke, liquid water, granular media (e.g. sand, flour or rice), or li ...
s.


Opium and opiates

Dried latex from the opium poppy is called
opium Opium (or poppy tears, scientific name: ''Lachryma papaveris'') is dried latex obtained from the seed capsules of the opium poppy '' Papaver somniferum''. Approximately 12 percent of opium is made up of the analgesic alkaloid morphine, which ...
, the source of several useful
analgesic An analgesic drug, also called simply an analgesic (American English), analgaesic (British English), pain reliever, or painkiller, is any member of the group of drugs used to achieve relief from pain (that is, analgesia or pain management). It ...
alkaloid Alkaloids are a class of basic BASIC (Beginners' All-purpose Symbolic Instruction Code) is a family of general-purpose, high-level programming languages designed for ease of use. The original version was created by John G. Kemeny and Th ...
s such as codeine,
thebaine Thebaine (paramorphine), also known as codeine methyl enol ether, is an opiate alkaloid, its name coming from the Greek Θῆβαι, '' Thēbai'' (Thebes), an ancient city in Upper Egypt. A minor constituent of opium, thebaine is chemically simil ...
, and
morphine Morphine is a strong opiate that is found naturally in opium, a dark brown resin in poppies ('' Papaver somniferum''). It is mainly used as a pain medication, and is also commonly used recreationally, or to make other illicit opioids. Ther ...
, the latter two of which can then further be used in the synthesis and manufacture of other (typically stronger)
opioids Opioids are substances that act on opioid receptors to produce morphine-like effects. Medically they are primarily used for pain relief, including anesthesia. Other medical uses include suppression of diarrhea, replacement therapy for opioid us ...
for medicinal use, and of heroin for the
illegal drug trade The illegal drug trade or drug trafficking is a global black market dedicated to the cultivation, manufacture, distribution and sale of prohibited drugs. Most jurisdictions prohibit trade, except under license, of many types of drugs through ...
. The opium poppy is also the source of medically useful non-analgesic alkaloids, such as papaverine and noscapine.


Clothing

Latex is used in many types of
clothing Clothing (also known as clothes, apparel, and attire) are items worn on the human body, body. Typically, clothing is made of fabrics or textiles, but over time it has included garments made from animal skin and other thin sheets of materials ...
. Worn on the body (or applied directly by painting), it tends to be skin-tight, producing a "second skin" effect.


Industrial and biological applications from synthetic latexes

Synthetic latexes are used in coatings (e.g., latex paint) and
glue Adhesive, also known as glue, cement, mucilage, or paste, is any non-metallic substance applied to one or both surfaces of two separate items that binds them together and resists their separation. The use of adhesives offers certain advant ...
s because they solidify by coalescence of the polymer particles as the water evaporates. These synthetic latexes therefore can form films without releasing potentially toxic organic solvents in the environment. Other uses include cement additives and to conceal information on scratchcards. Latex, usually styrene-based, is also used in immunoassays.


Allergic reactions

Some people only experience a mild allergy when exposed to latex, like eczema, contact dermatitis or developing a rash. Others have a serious latex allergy, and exposure to latex products such as
latex glove A rubber glove is a glove made out of natural rubber or Synthetic rubber. The term ‘rubber’ refers to durable, waterproof and elastic material made from natural or synthetic latex. Rubber gloves can be unsupported (rubber only) or supported ( ...
s can cause anaphylactic shock. Guayule latex has only 2% of the levels of protein found in ''
Hevea ''Hevea'' is a genus of flowering plants in the spurge family, Euphorbiaceae, with about ten members. It is also one of many names used commercially for the wood of the most economically important rubber tree, '' H. brasiliensis''. The genus ...
'' latexes, and is being researched as a lower-allergen substitute. Additionally, chemical processes may be employed to reduce the amount of antigenic protein in ''Hevea'' latex, yielding alternative materials such as Vytex Natural Rubber Latex which provide significantly reduced exposure to latex allergens. About half of people with spina bifida are also allergic to natural latex rubber, as well as people who have had multiple surgeries, and people who have had prolonged exposure to natural latex.


Microbial degradation

Several species of the microbe genera '' Actinomycetes'', '' Streptomyces'', '' Nocardia'', '' Micromonospora'', and '' Actinoplanes'' are capable of consuming rubber latex. However, the rate of biodegradation is slow, and the growth of bacteria utilizing rubber as a sole carbon source is also slow.


See also

* Latex clothing *
Natural rubber Rubber, also called India rubber, latex, Amazonian rubber, ''caucho'', or ''caoutchouc'', as initially produced, consists of polymers of the organic compound isoprene, with minor impurities of other organic compounds. Thailand, Malaysia, a ...
*


References


Footnotes


Notes


External links

* {{Authority control Materials Sculpture materials Rubber