Lamproite
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Lamproite is an ultrapotassic mantle-derived volcanic or subvolcanic rock. It has low CaO, Al2O3, Na2O, high K2O/Al2O3, a relatively high MgO content and extreme enrichment in incompatible elements. Lamproites are geographically widespread yet are volumetrically insignificant. Unlike kimberlites, which are found exclusively in Archaean
craton A craton ( , , or ; from "strength") is an old and stable part of the continental lithosphere, which consists of Earth's two topmost layers, the crust and the uppermost mantle. Having often survived cycles of merging and rifting of contine ...
s, lamproites are found in terrains of varying age, ranging from Archaean in Western Australia, to Palaeozoic and Mesozoic in southern Spain. They also vary widely in age, from Proterozoic to
Pleistocene The Pleistocene ( ; referred to colloquially as the ''ice age, Ice Age'') is the geological epoch (geology), epoch that lasted from to 11,700 years ago, spanning the Earth's most recent period of repeated glaciations. Before a change was fin ...
, the youngest known example from
Gaussberg Gaussberg (or Schwarzen Berg, Mount Gauss) is an extinct, high volcanic cone in East Antarctica fronting on Davis Sea immediately west of Posadowsky Glacier (Antarctica), Posadowsky Glacier. It is ice-free and conical in nature, having formed s ...
in Antarctica being 56,000 ± 5,000 years old. Lamproite volcanology is varied, with both diatreme styles and
cinder cone A cinder cone or scoria cone is a steep, volcanic cone, conical landform of loose pyroclastic rock, pyroclastic fragments, such as volcanic ash, clinkers, or scoria that has been built around a volcanic vent. The pyroclastic fragments are forme ...
or cone edifices known.


Petrology

Lamproites form from partially melted mantle at depths exceeding 150 km. The molten material is forced to the surface in volcanic pipes, bringing with it xenoliths and
diamond Diamond is a Allotropes of carbon, solid form of the element carbon with its atoms arranged in a crystal structure called diamond cubic. Diamond is tasteless, odourless, strong, brittle solid, colourless in pure form, a poor conductor of e ...
s from the harzburgitic
peridotite Peridotite ( ) is a dense, coarse-grained igneous rock consisting mostly of the silicate minerals olivine and pyroxene. Peridotite is ultramafic, as the rock contains less than 45% silica. It is high in magnesium (Mg2+), reflecting the high pr ...
or eclogite mantle regions where diamond formation is stabilized. Recent research, for example on the lamproites at
Gaussberg Gaussberg (or Schwarzen Berg, Mount Gauss) is an extinct, high volcanic cone in East Antarctica fronting on Davis Sea immediately west of Posadowsky Glacier (Antarctica), Posadowsky Glacier. It is ice-free and conical in nature, having formed s ...
in
Antarctica Antarctica () is Earth's southernmost and least-populated continent. Situated almost entirely south of the Antarctic Circle and surrounded by the Southern Ocean (also known as the Antarctic Ocean), it contains the geographic South Pole. ...
, and lead-lead
isotope geochemistry Isotope geochemistry is an aspect of geology based upon the study of natural variations in the relative abundances of isotopes of various Chemical element, elements. Variations in isotopic abundance are measured by isotope-ratio mass spectrometry, ...
have revealed that the source of lamproites may be transition zone melts of subducted
lithosphere A lithosphere () is the rigid, outermost rocky shell of a terrestrial planet or natural satellite. On Earth, it is composed of the crust and the lithospheric mantle, the topmost portion of the upper mantle that behaves elastically on time ...
which has become trapped at the base of the lithospheric mantle. This observation also reconciles the depth of melting with the peculiar geochemistry, which is most easily explained by melting of already felsic material under deep mantle conditions.


Mineralogy

The mineralogy of lamproites is controlled by their peculiar
geochemistry Geochemistry is the science that uses the tools and principles of chemistry to explain the mechanisms behind major geological systems such as the Earth's crust and its oceans. The realm of geochemistry extends beyond the Earth, encompassing the e ...
, with a predominance of rare
silica Silicon dioxide, also known as silica, is an oxide of silicon with the chemical formula , commonly found in nature as quartz. In many parts of the world, silica is the major constituent of sand. Silica is one of the most complex and abundant f ...
-deficient mineral species and rare, mantle-derived minerals predominating. Minerals typical of lamproites include: forsteritic olivine; high
iron Iron is a chemical element; it has symbol Fe () and atomic number 26. It is a metal that belongs to the first transition series and group 8 of the periodic table. It is, by mass, the most common element on Earth, forming much of Earth's o ...
leucite;
titanium Titanium is a chemical element; it has symbol Ti and atomic number 22. Found in nature only as an oxide, it can be reduced to produce a lustrous transition metal with a silver color, low density, and high strength, resistant to corrosion in ...
-rich
aluminium Aluminium (or aluminum in North American English) is a chemical element; it has chemical symbol, symbol Al and atomic number 13. It has a density lower than that of other common metals, about one-third that of steel. Aluminium has ...
-poor phlogopite;
potassium Potassium is a chemical element; it has Symbol (chemistry), symbol K (from Neo-Latin ) and atomic number19. It is a silvery white metal that is soft enough to easily cut with a knife. Potassium metal reacts rapidly with atmospheric oxygen to ...
- and titanium-rich richterite; low aluminium diopside; and iron-rich
sanidine Sanidine is the high temperature form of potassium feldspar with a general formula K(AlSi3O8). Sanidine is found most typically in felsic volcanic rocks such as obsidian, rhyolite and trachyte. Sanidine crystallizes in the monoclinic crystal sys ...
. A variety of rare trace minerals occur. The rocks are high in potassium with 6 to 8% potassium oxide. High
chromium Chromium is a chemical element; it has Symbol (chemistry), symbol Cr and atomic number 24. It is the first element in Group 6 element, group 6. It is a steely-grey, Luster (mineralogy), lustrous, hard, and brittle transition metal. Chromium ...
and nickel content is typical. The rocks commonly are altered to talc with
carbonate A carbonate is a salt of carbonic acid, (), characterized by the presence of the carbonate ion, a polyatomic ion with the formula . The word "carbonate" may also refer to a carbonate ester, an organic compound containing the carbonate group ...
or serpentine,
chlorite The chlorite ion, or chlorine dioxide anion, is the halite (oxyanion), halite with the chemical formula of . A chlorite (compound) is a compound that contains this group, with chlorine in the oxidation state of +3. Chlorites are also known as s ...
, and
magnetite Magnetite is a mineral and one of the main iron ores, with the chemical formula . It is one of the iron oxide, oxides of iron, and is ferrimagnetism, ferrimagnetic; it is attracted to a magnet and can be magnetization, magnetized to become a ...
. Zeolites and
quartz Quartz is a hard, crystalline mineral composed of silica (silicon dioxide). The Atom, atoms are linked in a continuous framework of SiO4 silicon–oxygen Tetrahedral molecular geometry, tetrahedra, with each oxygen being shared between two tet ...
may also occur. Lamproites are characterized by the presence of widely varying amounts (5-90 vol.%) of the following primary phases (Mitchell & Bergman, 1991): * titanian (2-10 wt.% TiO2), aluminium-poor (5-12 wt.% Al2O3) phenocrystic phlogopite; * titanian (5-10 wt.% TiO2) groundmass poikilitic " tetraferriphlogopite"; * titanian (3-5 wt.% TiO2), potassium (4-6 wt.% K2O) richterite; * forsteritic (Mg)
olivine The mineral olivine () is a magnesium iron Silicate minerals, silicate with the chemical formula . It is a type of Nesosilicates, nesosilicate or orthosilicate. The primary component of the Earth's upper mantle (Earth), upper mantle, it is a com ...
; * aluminium-poor (<1 wt.% Al2O3), sodium-poor (<1 wt.% Na2O) diopside; * nonstoichiometric iron-rich (1-4 wt.% Fe2O3) leucite, and; * iron-rich
sanidine Sanidine is the high temperature form of potassium feldspar with a general formula K(AlSi3O8). Sanidine is found most typically in felsic volcanic rocks such as obsidian, rhyolite and trachyte. Sanidine crystallizes in the monoclinic crystal sys ...
(typically 1-5 wt.% Fe2O3). The presence of all the above phases is not required in order to classify a rock as a lamproite. Any one mineral may be dominant, and this, together with the two or three other major minerals present, suffices to determine the petrographic name. The presence of the following minerals precludes a rock from being classified as a lamproite: primary
plagioclase Plagioclase ( ) is a series of Silicate minerals#Tectosilicates, tectosilicate (framework silicate) minerals within the feldspar group. Rather than referring to a particular mineral with a specific chemical composition, plagioclase is a continu ...
, melilite, monticellite, kalsilite, nepheline, Na-rich alkali feldspar, sodalite, nosean, hauyne, melanite, schorlomite or kimzeyite.


Geochemistry

Lamproites conform to the following chemical characteristics: * molar K2O/Na2O > 3, i.e., ultrapotassic; * molar K2O/Al2O3 > 0.8 and commonly > 1; * molar (K2O + Na2O)/Al2O3 typically > 1, i.e., peralkaline; * typically < 10 wt.% each of FeO and CaO, TiO2 1-7 wt.%, > 2000 and commonly > 5000 ppm Ba, > 500 ppm Zr, > 1000 ppm Sr, and > 200 ppm La.


Economic importance

The economic significance of lamproite became known with the discovery of Ellendale E4 and E9 lamproite pipes and better known 1979 discovery of the Argyle diamond pipe in
Western Australia Western Australia (WA) is the westernmost state of Australia. It is bounded by the Indian Ocean to the north and west, the Southern Ocean to the south, the Northern Territory to the north-east, and South Australia to the south-east. Western Aust ...
. This discovery led to the intense study and re-evaluation of other known lamproite occurrences worldwide; previously only kimberlite pipes were considered economically viable sources of
diamond Diamond is a Allotropes of carbon, solid form of the element carbon with its atoms arranged in a crystal structure called diamond cubic. Diamond is tasteless, odourless, strong, brittle solid, colourless in pure form, a poor conductor of e ...
s. The Argyle diamond mine remains the only economically viable source of lamproite diamonds. This deposit differs markedly by having a high content of diamonds but low quality of most stones. Research at Argyle diamond have shown that most stones are of E-type; they originate from eclogite source rocks and were formed under high temperature ~. The Argyle diamond mine is the main source of rare pink diamonds.
Olivine The mineral olivine () is a magnesium iron Silicate minerals, silicate with the chemical formula . It is a type of Nesosilicates, nesosilicate or orthosilicate. The primary component of the Earth's upper mantle (Earth), upper mantle, it is a com ...
lamproite pyroclastic rocks and dikes are sometimes hosts for
diamond Diamond is a Allotropes of carbon, solid form of the element carbon with its atoms arranged in a crystal structure called diamond cubic. Diamond is tasteless, odourless, strong, brittle solid, colourless in pure form, a poor conductor of e ...
s. The diamonds occur as xenocrysts that have been carried to the surface or to shallow depths by the lamproite diapiric intrusions. The diamonds of Crater of Diamonds State Park near Murfreesboro, Arkansas are found in a lamproite host.


Nomenclature

Lamproites, as a group, were known by a variety of localised names because their mineralogy is quite variable, and because of their rarity often few examples of the following lamproite variants were known. Modern terminology classes all as lamproites but modifies this term with the mineral abundances as per the standard IUGS rules.


Related rock types

* * *


References


Further reading

* * * *


External links


Lamproite-hosted diamonds
retrieved June 7, 2005

retrieved June 7, 2005

retrieved June 7, 2005

{{Authority control Ultrapotassic rocks Economic geology Igneous petrology Volcanic rocks Subvolcanic rocks