HOME

TheInfoList



OR:

Kyanite is a typically blue aluminosilicate
mineral In geology and mineralogy, a mineral or mineral species is, broadly speaking, a solid chemical compound with a fairly well-defined chemical composition and a specific crystal structure that occurs naturally in pure form.John P. Rafferty, ed. (2 ...
, found in
aluminium Aluminium (aluminum in American and Canadian English) is a chemical element with the symbol Al and atomic number 13. Aluminium has a density lower than those of other common metals, at approximately one third that of steel. It ha ...
-rich metamorphic
pegmatite A pegmatite is an igneous rock showing a very coarse texture, with large interlocking crystals usually greater in size than and sometimes greater than . Most pegmatites are composed of quartz, feldspar, and mica, having a similar silici ...
s and
sedimentary rock Sedimentary rocks are types of rock that are formed by the accumulation or deposition of mineral or organic particles at Earth's surface, followed by cementation. Sedimentation is the collective name for processes that cause these particles ...
. It is the high pressure polymorph of andalusite and sillimanite, and the presence of kyanite in metamorphic rocks generally indicates metamorphism deep in the
Earth's crust Earth's crust is Earth's thin outer shell of rock, referring to less than 1% of Earth's radius and volume. It is the top component of the lithosphere, a division of Earth's layers that includes the crust and the upper part of the mantle. The ...
. Kyanite is also known as disthene or cyanite. Kyanite is strongly
anisotropic Anisotropy () is the property of a material which allows it to change or assume different properties in different directions, as opposed to isotropy. It can be defined as a difference, when measured along different axes, in a material's physic ...
, in that its
hardness In materials science, hardness (antonym: softness) is a measure of the resistance to localized plastic deformation induced by either mechanical indentation or abrasion. In general, different materials differ in their hardness; for example hard ...
varies depending on its crystallographic direction. In kyanite, this anisotropism can be considered an identifying characteristic, along with its characteristic blue color. Its name comes from the same origin as that of the color
cyan Cyan () is the color between green and blue on the visible spectrum of light. It is evoked by light with a predominant wavelength between 490 and 520 nm, between the wavelengths of green and blue. In the subtractive color system, or CMYK col ...
, being derived from the Ancient Greek word κύανος. This is generally rendered into English as ''kyanos'' or ''kuanos'' and means "dark blue". Kyanite is used as a raw material in the manufacture of ceramics and abrasives, and it is an important index mineral used by geologists to trace
metamorphic zone In geology, a metamorphic zone is an area where, as a result of metamorphism, the same combination of minerals occur in the bedrock. These zones occur because most metamorphic minerals are only stable in certain intervals of temperature and pressu ...
s.


Properties

Kyanite is an aluminum silicate mineral, with chemical formula . It is typically patchy blue in color, though it can range from pale to deep blue and can also be gray or white or, infrequently, light green. It typically forms sprays of bladed crystals, but is less commonly found as distinct
euhedral Euhedral crystals (also known as idiomorphic or automorphic crystals) are those that are well-formed, with sharp, easily recognised faces. The opposite is anhedral (also known as '' xenomorphic'' or ''allotriomorphic''): a rock with an anhedr ...
(well-shaped) crystals, which are particularly prized by collectors. It has a perfect cleavage plane, parallel to the long axis of the crystal, and a second good cleavage plane that is at an angle of 79 degrees to the clevage plane. Kyanite also shows a parting on at an angle of about 85 degrees to the long axis of the crystal. Cleavage surfaces typically display a pearly luster. Crystals are slightly flexible. Kyanite's elongated, columnar crystals are usually a good first indication of the mineral, as well as its color (when the specimen is blue). Associated minerals are useful as well, especially the presence of the polymorphs of
staurolite Staurolite is a reddish brown to black, mostly opaque, nesosilicate mineral with a white streak. It crystallizes in the monoclinic crystal system, has a Mohs hardness of 7 to 7.5 and the chemical formula: Fe2+2Al9O6(SiO4)4(O,OH)2. Magnesium, ...
, which occur frequently with kyanite. However, the most useful characteristic in identifying kyanite is its anisotropism. If one suspects a specimen to be kyanite, verifying that it has two distinctly different
hardness In materials science, hardness (antonym: softness) is a measure of the resistance to localized plastic deformation induced by either mechanical indentation or abrasion. In general, different materials differ in their hardness; for example hard ...
values on perpendicular axes is a key to identification; it has a hardness of 5.5 parallel to and 7 parallel to . Thus, a steel needle will easily scratch a kyanite crystal parallel to its long axis, but the crystal is impervious to being scratched by a steel needle perpendicular to the long axis.


Structure

The kyanite structure can be visualized as a distorted
face centered cubic In crystallography, the cubic (or isometric) crystal system is a crystal system where the unit cell is in the shape of a cube. This is one of the most common and simplest shapes found in crystals and minerals. There are three main varieties ...
lattice of oxygen ions, with aluminium ions occupying 40% of the octahedral sites and silicon occupying 10% of the tetrahedral sites. The aluminium octahedra form chains along the length of the crystal, half of which are straight and half of which are zigzag, with silica tetrahedra linking the chains together. There is no direct linkage between silica tetraheda, making kyanite a member of the nesosilicate class of
silicate minerals Silicate minerals are rock-forming minerals made up of silicate groups. They are the largest and most important class of minerals and make up approximately 90 percent of Earth's crust. In mineralogy, silica (silicon dioxide, ) is usually con ...
.


Occurrence

Kyanite occurs in
biotite Biotite is a common group of phyllosilicate minerals within the mica group, with the approximate chemical formula . It is primarily a solid-solution series between the iron- endmember annite, and the magnesium-endmember phlogopite; more ...
gneiss Gneiss ( ) is a common and widely distributed type of metamorphic rock. It is formed by high-temperature and high-pressure metamorphic processes acting on formations composed of igneous or sedimentary rocks. Gneiss forms at higher temperatures a ...
, mica
schist Schist ( ) is a medium-grained metamorphic rock showing pronounced schistosity. This means that the rock is composed of mineral grains easily seen with a low-power hand lens, oriented in such a way that the rock is easily split into thin flakes ...
, and hornfels, which are
metamorphic rock Metamorphic rocks arise from the transformation of existing rock to new types of rock in a process called metamorphism. The original rock (protolith) is subjected to temperatures greater than and, often, elevated pressure of or more, caus ...
s formed at high pressure during regional
metamorphism Metamorphism is the transformation of existing rock (the protolith) to rock with a different mineral composition or texture. Metamorphism takes place at temperatures in excess of , and often also at elevated pressure or in the presence of ch ...
of a
protolith A protolith () is the original, unmetamorphosed rock from which a given metamorphic rock is formed. For example, the protolith of a slate is a shale or mudstone. Metamorphic rocks can be derived from any other kind of non-metamorphic rock an ...
rich in
aluminium Aluminium (aluminum in American and Canadian English) is a chemical element with the symbol Al and atomic number 13. Aluminium has a density lower than those of other common metals, at approximately one third that of steel. It ha ...
(a ''
pelitic A pelite ( Greek: ''pelos'', "clay") or metapelite is a metamorphosed fine-grained sedimentary rock, i.e. mudstone or siltstone. The term was earlier used by geologists to describe a clay-rich, fine-grained clastic sediment or sedimentary roc ...
'' protolith). Kyanite is also occasionally found in
granite Granite () is a coarse-grained ( phaneritic) intrusive igneous rock composed mostly of quartz, alkali feldspar, and plagioclase. It forms from magma with a high content of silica and alkali metal oxides that slowly cools and solidifies un ...
and
pegmatite A pegmatite is an igneous rock showing a very coarse texture, with large interlocking crystals usually greater in size than and sometimes greater than . Most pegmatites are composed of quartz, feldspar, and mica, having a similar silici ...
and associated
quartz Quartz is a hard, crystalline mineral composed of silica ( silicon dioxide). The atoms are linked in a continuous framework of SiO4 silicon-oxygen tetrahedra, with each oxygen being shared between two tetrahedra, giving an overall chemical f ...
veins Veins are blood vessels in humans and most other animals that carry blood towards the heart. Most veins carry deoxygenated blood from the tissues back to the heart; exceptions are the pulmonary and umbilical veins, both of which carry oxygenated ...
and is infrequently found in eclogites. It occurs as detrital grains in sedimentary rocks, although it tends to weather rapidly. It occurs associated with
staurolite Staurolite is a reddish brown to black, mostly opaque, nesosilicate mineral with a white streak. It crystallizes in the monoclinic crystal system, has a Mohs hardness of 7 to 7.5 and the chemical formula: Fe2+2Al9O6(SiO4)4(O,OH)2. Magnesium, ...
, andalusite, sillimanite, talc, hornblende, gedrite, mullite and
corundum Corundum is a crystalline form of aluminium oxide () typically containing traces of iron, titanium, vanadium and chromium. It is a rock-forming mineral. It is a naturally transparent material, but can have different colors depending on the pr ...
. Kyanite is one of three common minerals having the composition . Minerals with identical compositions but distinct crystal structure are called '' polymorphs''. The other polymorphs with identical composition to kyanite are andalusite and sillimanite. Kyanite is the polymorph most stable at high pressure, while andalusite is the most stable at lower temperature and pressure and sillimanite is the most stable at higher temperature and lower pressure, with the three polymorphs equally stable at the ''triple point'' near 4.2 kbar and . This makes the presence of kyanite in a metamorphic rock an indication of metamorphism at high pressure. Kyanite is often used as an index mineral to define and trace a
metamorphic zone In geology, a metamorphic zone is an area where, as a result of metamorphism, the same combination of minerals occur in the bedrock. These zones occur because most metamorphic minerals are only stable in certain intervals of temperature and pressu ...
that was subject to a particular degree of metamorphism at great depth in the crust. For example, G. M. Barrow defined kyanite zones and sillimanite zones in his pioneering work on the mineralogy of metamorphic rocks. Barrow was characterizing a region of Scotland that had experienced
regional metamorphism Metamorphism is the transformation of existing rock (the protolith) to rock with a different mineral composition or texture. Metamorphism takes place at temperatures in excess of , and often also at elevated pressure or in the presence of ch ...
at depth. By contrast, the metamorphic zones surrounding the Fanad Pluton of Ireland, which formed by contact metamorphism at a shallower depth in the crust, include andalusite and sillimanite zones but no kyanite zone. Kyanite is potentially stable at low temperature and pressure. However, under these conditions, the reactions that produces kyanite, such as : never take place, and hydrous aluminosilicate minerals such as muscovite,
pyrophyllite Pyrophyllite is a phyllosilicate mineral composed of aluminium silicate hydroxide: Al2Si4O10(OH)2. It occurs in two forms (habits): crystalline folia and compact masses; distinct crystals are not known. The folia have a pronounced pearly ...
, or
kaolinite Kaolinite ( ) is a clay mineral, with the chemical composition Al2 Si2 O5( OH)4. It is an important industrial mineral. It is a layered silicate mineral, with one tetrahedral sheet of silica () linked through oxygen atoms to one octahed ...
are found instead of kyanite. Bladed crystals of kyanite are not uncommon, but individual euhedral crystals are prized by collectors. Kyanite occurs in Manhattan schist, formed under extreme pressure as a result of a
continental collision In geology, continental collision is a phenomenon of plate tectonics that occurs at convergent boundaries. Continental collision is a variation on the fundamental process of subduction, whereby the subduction zone is destroyed, mountains produ ...
during the assembly of the supercontinent of Pangaea. It is also found in pegmatites of the
Appalachian Mountains The Appalachian Mountains, often called the Appalachians, (french: Appalaches), are a system of mountains in eastern to northeastern North America. The Appalachians first formed roughly 480 million years ago during the Ordovician Period. The ...
and in Minas Gerais, Brazil. Splendid specimens are found at
Pizzo Forno Pizzo Forno is a mountain of the Swiss Lepontine Alps, overlooking Chironico in the canton of Ticino. It is to be found between Piumogna Valley, Chironico Valley and Leventina Valley. It is in pyramid form and is separate from Pizzo Campo Tencia ...
in Switzerland.


Uses

Kyanite is used primarily in
refractory In materials science, a refractory material or refractory is a material that is resistant to decomposition by heat, pressure, or chemical attack, and retains strength and form at high temperatures. Refractories are polycrystalline, polyphase, ...
and ceramic products, including
porcelain Porcelain () is a ceramic material made by heating substances, generally including materials such as kaolinite, in a kiln to temperatures between . The strength and translucence of porcelain, relative to other types of pottery, arises main ...
plumbing and
dishware Tableware is any dish or dishware used for setting a table, serving food, and dining. It includes cutlery, glassware, serving dishes, and other items for practical as well as decorative purposes. The quality, nature, variety and number of ob ...
. It is also used in electronics, electrical insulators and abrasives. At temperatures above 1100 °C kyanite decomposes into mullite and vitreous silica via the following reaction: 3(Al2O3·SiO2) → 3Al2O3·2SiO2 + SiO2. This transformation results in an expansion. Mullitized kyanite is used to manufacture
refractory material In materials science, a refractory material or refractory is a material that is resistant to decomposition by heat, pressure, or chemical attack, and retains strength and form at high temperatures. Refractories are polycrystalline, polyphase, ...
s. Kyanite has been used as a semiprecious
gemstone A gemstone (also called a fine gem, jewel, precious stone, or semiprecious stone) is a piece of mineral crystal which, in cut and polished form, is used to make jewelry or other adornments. However, certain rocks (such as lapis lazuli, opal, ...
, which may display cat's eye chatoyancy, though this use is limited by its anisotropism and perfect cleavage. Color varieties include recently discovered orange kyanite from Tanzania. The orange color is due to inclusion of small amounts of
manganese Manganese is a chemical element with the Symbol (chemistry), symbol Mn and atomic number 25. It is a hard, brittle, silvery metal, often found in minerals in combination with iron. Manganese is a transition metal with a multifaceted array of ...
(Mn3+) in the structure.


References

;Specific citations: ;General references:
Mineral Galleries
*


External links

* {{Jewellery Gemstones Aluminium minerals Nesosilicates Triclinic minerals Industrial minerals Minerals in space group 2