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Josef Mattauch (21 November 1895 – 10 August 1976) was a nuclear physicist and chemist. He was known for the development of the Mattauch-Herzog double-focusing mass spectrometer, for his work on the investigation of isotopic abundances using
mass spectrometry Mass spectrometry (MS) is an analytical technique that is used to measure the mass-to-charge ratio of ions. The results are presented as a '' mass spectrum'', a plot of intensity as a function of the mass-to-charge ratio. Mass spectrometry is us ...
, and the determination of atomic weights. Much of his career was spent at the
Kaiser Wilhelm Institute for Chemistry The Kaiser Wilhelm Society for the Advancement of Science ( German: ''Kaiser-Wilhelm-Gesellschaft zur Förderung der Wissenschaften'') was a German scientific institution established in the German Empire in 1911. Its functions were taken over b ...
(later the
Max Planck Institute Max or MAX may refer to: Animals * Max (dog) (1983–2013), at one time purported to be the world's oldest living dog * Max (English Springer Spaniel), the first pet dog to win the PDSA Order of Merit (animal equivalent of OBE) * Max (gorilla) ( ...
). He developed the Mattauch isobar rule ("Isobarenregel") in 1934. He correctly predicted that the last of the
rare earth elements The rare-earth elements (REE), also called the rare-earth metals or (in context) rare-earth oxides or sometimes the lanthanides (yttrium and scandium are usually included as rare earths), are a set of 17 nearly-indistinguishable lustrous silve ...
, element 61 (later named
promethium Promethium is a chemical element with the symbol Pm and atomic number 61. All of its isotopes are radioactive; it is extremely rare, with only about 500–600 grams naturally occurring in Earth's crust at any given time. Promethium is one of on ...
), would not have stable isotopes.


Early life

Josef Heinrich Elisabeth Mattauch was born 21 November 1895 in Ostrau,
Moravia Moravia ( , also , ; cs, Morava ; german: link=yes, Mähren ; pl, Morawy ; szl, Morawa; la, Moravia) is a historical region in the east of the Czech Republic and one of three historical Czech lands, with Bohemia and Czech Silesia. The me ...
. Mattauch was educated at the
University of Vienna The University of Vienna (german: Universität Wien) is a public university, public research university located in Vienna, Austria. It was founded by Rudolf IV, Duke of Austria, Duke Rudolph IV in 1365 and is the oldest university in the Geogra ...
, where he worked with Felix Ehrenhaft. Ehrenhaft believed he had discovered a "sub-electron", smaller than anything measured by
Robert Andrews Millikan Robert Andrews Millikan (March 22, 1868 – December 19, 1953) was an American experimental physicist honored with the Nobel Prize for Physics in 1923 for the measurement of the elementary electric charge and for his work on the photoelectric ...
. Mattauch's results, however, were in agreement with Millikan and not Ehrenhaft. Mattauch completed his PhD degree in Vienna as of 1920. Through the help of another professor, Mattauch spent 1927–1928 on a
Rockefeller Fellowship The Rockefeller Foundation is an American private foundation and philanthropic medical research and arts funding organization based at 420 Fifth Avenue, New York City. The second-oldest major philanthropic institution in America, after the Carn ...
at
Caltech The California Institute of Technology (branded as Caltech or CIT)The university itself only spells its short form as "Caltech"; the institution considers other spellings such a"Cal Tech" and "CalTech" incorrect. The institute is also occasional ...
. There he worked with William Smythe on the development of early mass spectrometers.


Career

Mattauch returned to Vienna in 1928 as an unpaid lecturer. There he worked with student Richard F. K. Herzog to develop the Mattauch-Herzog double-focusing mass spectrometer. The first of a new type, it was announced in 1934. His work significantly improved the sharpness and sensitivity of mass spectroscopes. The double-focusing mechanism allowed for the separation and measurement of
isotopes Isotopes are two or more types of atoms that have the same atomic number (number of protons in their nuclei) and position in the periodic table (and hence belong to the same chemical element), and that differ in nucleon numbers (mass numbe ...
that could not be isolated by chemical means, and as such was a major contribution to
nuclear physics Nuclear physics is the field of physics that studies atomic nuclei and their constituents and interactions, in addition to the study of other forms of nuclear matter. Nuclear physics should not be confused with atomic physics, which studies t ...
. Mattauch became an associate professor at the University of Vienna in 1937. In 1938 Lise Meitner fled Germany after the Nazi occupation of Austria changed her citizenship from Austrian to German, making her subject to the
antisemitic Antisemitism (also spelled anti-semitism or anti-Semitism) is hostility to, prejudice towards, or discrimination against Jews. A person who holds such positions is called an antisemite. Antisemitism is considered to be a form of racism. Antis ...
Nuremberg Laws The Nuremberg Laws (german: link=no, Nürnberger Gesetze, ) were antisemitic and racist laws that were enacted in Nazi Germany on 15 September 1935, at a special meeting of the Reichstag convened during the annual Nuremberg Rally of ...
of 1935. Otto Hahn invited Mattauch to join the Institute. In 1939, Mattauch succeeded
Lise Meitner Elise Meitner ( , ; 7 November 1878 – 27 October 1968) was an Austrian-Swedish physicist who was one of those responsible for the discovery of the element protactinium and nuclear fission. While working at the Kaiser Wilhelm Institute on rad ...
as head of the department for mass spectroscopy, within the physics department at
Kaiser Wilhelm Institute for Chemistry The Kaiser Wilhelm Society for the Advancement of Science ( German: ''Kaiser-Wilhelm-Gesellschaft zur Förderung der Wissenschaften'') was a German scientific institution established in the German Empire in 1911. Its functions were taken over b ...
(KWI). A new Mattauch-Herzog mass spectrograph was installed. On 31 July 1941, Mattauch succeeded
Lise Meitner Elise Meitner ( , ; 7 November 1878 – 27 October 1968) was an Austrian-Swedish physicist who was one of those responsible for the discovery of the element protactinium and nuclear fission. While working at the Kaiser Wilhelm Institute on rad ...
as head of the physics department. Josef Mattauch was appointed an associate professor of nuclear chemistry at the
University of Berlin Humboldt-Universität zu Berlin (german: Humboldt-Universität zu Berlin, abbreviated HU Berlin) is a German public research university in the central borough of Mitte in Berlin. It was established by Frederick William III on the initiative o ...
in 1940. Hahn and Mattauch successfully sought funds for a major expansion for fundamental research in atomic physics. In 1942, the Minerva Project was approved, involving construction of a new building and addition of a cascade generator and
particle accelerator A particle accelerator is a machine that uses electromagnetic fields to propel charged particles to very high speeds and energies, and to contain them in well-defined beams. Large accelerators are used for fundamental research in particle ...
. On 1 November 1943 Mattauch advanced to the position of deputy director of the Institute. On 15 February 1944 and again on 24 March 1944, as part of the Bombing of Berlin in World War II, the Institute suffered severe bombing damage. This included the director's house, one wing of the Institute, Mattauch's new mass spectrograph, and valuable research papers. The Institute was temporarily relocated to Tailfingen (now Albstadt) in the
Württemberg Württemberg ( ; ) is a historical German territory roughly corresponding to the cultural and linguistic region of Swabia. The main town of the region is Stuttgart. Together with Baden and Hohenzollern, two other historical territories, Württ ...
district, in a textile factory belonging to the Ludwig Haasis company. On 1 April 1946, in
Göttingen Göttingen (, , ; nds, Chöttingen) is a university city in Lower Saxony, central Germany, the capital of the eponymous district. The River Leine runs through it. At the end of 2019, the population was 118,911. General information The ori ...
in the British zone of occupation,
Otto Hahn Otto Hahn (; 8 March 1879 – 28 July 1968) was a German chemist who was a pioneer in the fields of radioactivity and radiochemistry. He is referred to as the father of nuclear chemistry and father of nuclear fission. Hahn and Lise Meitner ...
became president of the Kaiser Wilhelm Society (Kaiser-Wilhelm-Gesellschaft, KWG). As of 1 October 1946, Hahn resigned as director of the Kaiser Wilhelm Institute of Chemistry, leaving Mattauch to manage the Institute. Mattauch officially became director on 31 July 1947. However, Mattauch suffered from
tuberculosis Tuberculosis (TB) is an infectious disease usually caused by ''Mycobacterium tuberculosis'' (MTB) bacteria. Tuberculosis generally affects the lungs, but it can also affect other parts of the body. Most infections show no symptoms, in w ...
and spent much of his time seeking treatment, traveling and working abroad. In 1948, Mattauch was a guest professor at the
University of Berne The University of Bern (german: Universität Bern, french: Université de Berne, la, Universitas Bernensis) is a university in the Swiss capital of Bern and was founded in 1834. It is regulated and financed by the Canton of Bern. It is a compreh ...
,
Switzerland ). Swiss law does not designate a ''capital'' as such, but the federal parliament and government are installed in Bern, while other federal institutions, such as the federal courts, are in other cities (Bellinzona, Lausanne, Luzern, Neuchâtel ...
. In his absence, Strassman became acting director. Mattauch and
Fritz Strassmann Friedrich Wilhelm Strassmann (; 22 February 1902 – 22 April 1980) was a German chemist who, with Otto Hahn in December 1938, identified the element barium as a product of the bombardment of uranium with neutrons. Their observation was the k ...
actively supported the proposed appointment of
Lise Meitner Elise Meitner ( , ; 7 November 1878 – 27 October 1968) was an Austrian-Swedish physicist who was one of those responsible for the discovery of the element protactinium and nuclear fission. While working at the Kaiser Wilhelm Institute on rad ...
as head of the physics department of the
University of Mainz The Johannes Gutenberg University Mainz (german: Johannes Gutenberg-Universität Mainz) is a public research university in Mainz, Rhineland Palatinate, Germany, named after the printer Johannes Gutenberg since 1946. With approximately 32,000 stu ...
. Hahn and Strassman asked Meitner to return as director, but she declined their offer. As of 1949, the Kaiser-Wilhelm-Gesellschaft was renamed the Max-Planck-Gesellschaft (MPG). Also in 1949, the renamed
Max Planck Institute for Chemistry The Max Planck Institute for Chemistry (Otto Hahn Institute; german: Max Planck Institut für Chemie - Otto Hahn Institut) is a non-university research institute under the auspices of the Max Planck Society (German: Max-Planck-Gesellschaft) in Ma ...
moved from Tailfingen to
Mainz Mainz () is the capital and largest city of Rhineland-Palatinate, Germany. Mainz is on the left bank of the Rhine, opposite to the place that the Main joins the Rhine. Downstream of the confluence, the Rhine flows to the north-west, with M ...
, Germany. At this time it consisted of two departments: Mass Spectrometry and Nuclear Physics was Mattauch's department, while Nuclear Chemistry was Strassmann's department. Given Mattauch's continued absence, Strassman formally replaced Mattauch as director, becoming the second director of the Max Planck Institute for Chemistry on 28 April 1950. However, restructuring of the Institute by the Senate of the MPG occurred in 1952, changing its research focus. Strassman resigned on 31 March 1953, and moved to the
University of Mainz The Johannes Gutenberg University Mainz (german: Johannes Gutenberg-Universität Mainz) is a public research university in Mainz, Rhineland Palatinate, Germany, named after the printer Johannes Gutenberg since 1946. With approximately 32,000 stu ...
. Mattauch again became the director of the Max Planck Institute for Chemistry. The Institute officially opened new facilities in Mainz in 1956. In 1957, Mattauch was one of the Göttinger Achtzehn (Göttingen eighteen), a group of eighteen leading nuclear researchers of the
Federal Republic of Germany Germany,, officially the Federal Republic of Germany, is a country in Central Europe. It is the second most populous country in Europe after Russia, and the most populous member state of the European Union. Germany is situated betwee ...
who wrote a
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( Göttinger Manifest, Göttinger Erklärung) opposing
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Konrad Adenauer Konrad Hermann Joseph Adenauer (; 5 January 1876 – 19 April 1967) was a Germany, German statesman who served as the first Chancellor of Germany, chancellor of the Federal Republic of Germany from 1949 to 1963. From 1946 to 1966, he was the fir ...
and
defense secretary The United States secretary of defense (SecDef) is the head of the United States Department of Defense, the executive department of the U.S. Armed Forces, and is a high ranking member of the federal cabinet. DoDD 5100.1: Enclosure 2: a The s ...
Franz-Josef Strauß's move to arm the West German army with
tactical nuclear weapon A tactical nuclear weapon (TNW) or non-strategic nuclear weapon (NSNW) is a nuclear weapon that is designed to be used on a battlefield in military situations, mostly with friendly forces in proximity and perhaps even on contested friendly territo ...
s. Mattauch retired in 1965. Christian Junge (1912-1996) succeeded Josef Mattauch as director of the Institute on October 1, 1968. Josef Heinrich Elisabeth Mattauch died 10 August 1976 in
Klosterneuburg Klosterneuburg (; frequently abbreviated as Kloburg by locals) is a town in Tulln District in the Austrian state of Lower Austria. It has a population of about 27,500. The Klosterneuburg Monastery, which was established in 1114 and soon after g ...
,
Austria Austria, , bar, Östareich officially the Republic of Austria, is a country in the southern part of Central Europe, lying in the Eastern Alps. It is a federation of nine states, one of which is the capital, Vienna, the most populou ...
.


Research

Mattauch primarily focused on mass spectroscopy and research into the binding energy of atomic nuclei. In the early 1930s, at the University of Vienna, Mattauch worked with Richard F. K. Herzog on fundamental aspects of ion optics as they applied to mass spectroscopy. They developed the Mattauch-Herzog double-focusing mass spectrometer. The sector mass spectrometer that they presented in 1934 became known throughout the scientific world as the “Mattauch-Herzog-System”. The Mattauch–Herzog geometry consists of a \pi / 4\sqrt radian electric sector, a drift length which is followed by a
right angle In geometry and trigonometry, a right angle is an angle of exactly 90 degrees or radians corresponding to a quarter turn. If a ray is placed so that its endpoint is on a line and the adjacent angles are equal, then they are right angles. ...
(\pi / 2) magnetic sector of opposite curvature direction. The entry of the ions sorted primarily by charge into the magnetic field produces an energy focussing effect and much higher transmission than a standard energy filter. The advantage of this geometry is that the ions of different masses are all focused onto the same flat plane, which allows the use of a photographic plate or other flat detector array. He developed the Mattauch isobar rule ("Isobarenregel") in 1934, which was used to predict the radioactivity of the
elements Element or elements may refer to: Science * Chemical element, a pure substance of one type of atom * Heating element, a device that generates heat by electrical resistance * Orbital elements, parameters required to identify a specific orbit of o ...
technetium Technetium is a chemical element with the Symbol (chemistry), symbol Tc and atomic number 43. It is the lightest element whose isotopes are all radioactive. All available technetium is produced as a synthetic element. Naturally occurring techneti ...
and
promethium Promethium is a chemical element with the symbol Pm and atomic number 61. All of its isotopes are radioactive; it is extremely rare, with only about 500–600 grams naturally occurring in Earth's crust at any given time. Promethium is one of on ...
. According to the rule, "if two adjacent elements on the periodic table have isotopes with the same mass number (isobars), one of the isotopes must be radioactive." Although the rule does not, in fact, hold for all elements, Mattauch was able to correctly predict that the last of the rare earth elements, element 61 (later named promethium), would not have stable isotopes. This led researchers to the realization that element 61 was likely to be extremely rare, and was not likely to be found naturally. In the 1950s, a period of stability after the war, Mattauch was able to build a strong mass spectrometry program at the Max Planck Institute. Using mass spectrometry he and other researchers were able to determine precise measurements of isotope masses, work that had started in Berlin. Measuring nuclear masses, they were able to precisely determine the nuclear masses of neutrons, protons and chlorine. They also focused on the
noble gases The noble gases (historically also the inert gases; sometimes referred to as aerogens) make up a class of chemical elements with similar properties; under standard conditions, they are all odorless, colorless, monatomic gases with very low che ...
, measuring tiny amounts of noble gases from meteorites.


Decorations and awards

* 1957, Wilhelm Exner Medal * 1964,
Austrian Decoration for Science and Art The Austrian Decoration for Science and Art (german: Österreichisches Ehrenzeichen für Wissenschaft und Kunst) is a state decoration of the Republic of Austria and forms part of the Austrian national honours system. History The "Austrian D ...
(Österreichisches Ehrenzeichen für Wissenschaft und Kunst) * 1965, Honorary doctorate from the
Vienna University of Technology TU Wien (TUW; german: Technische Universität Wien; still known in English as the Vienna University of Technology from 1975–2014) is one of the major universities in Vienna, Austria. The university finds high international and domestic recogn ...


References


Further reading

* {{DEFAULTSORT:Mattauch, Josef 1895 births 1976 deaths 20th-century German physicists Mass spectrometrists Max Planck Society people People from Ostrava Recipients of the Austrian Decoration for Science and Art Rare earth scientists Max Planck Institute directors