HOME

TheInfoList



OR:

John Tyndall FRS (; 2 August 1820 – 4 December 1893) was a prominent 19th-century Irish physicist. His scientific fame arose in the 1850s from his study of diamagnetism. Later he made discoveries in the realms of infrared radiation and the physical properties of air, proving the connection between atmospheric CO and what is now known as the
greenhouse effect The greenhouse effect is a process that occurs when energy from a planet's host star goes through the planet's atmosphere and heats the planet's surface, but greenhouse gases in the atmosphere prevent some of the heat from returning directly ...
in 1859. Tyndall also published more than a dozen science books which brought state-of-the-art 19th century experimental physics to a wide audience. From 1853 to 1887 he was professor of physics at the Royal Institution of Great Britain in London. He was elected as a member to the
American Philosophical Society The American Philosophical Society (APS), founded in 1743 in Philadelphia, is a scholarly organization that promotes knowledge in the sciences and humanities through research, professional meetings, publications, library resources, and communit ...
in 1868.


Early years and education

Tyndall was born in
Leighlinbridge Leighlinbridge (; ) is a small town on the River Barrow in County Carlow, Ireland. The N9 National primary route once passed through the village, which was by-passed in the 1980s. It now lies on the R705 regional road. It covers the to ...
, County Carlow, Ireland. His father was a local police constable, descended from
Gloucestershire Gloucestershire ( abbreviated Glos) is a county in South West England. The county comprises part of the Cotswold Hills, part of the flat fertile valley of the River Severn and the entire Forest of Dean. The county town is the city of ...
emigrants who settled in southeast Ireland around 1670. Tyndall attended the local schools (Ballinabranna Primary School) in County Carlow until his late teens, and was probably an assistant teacher near the end of his time there. Subjects learned at school notably included technical drawing and mathematics with some applications of those subjects to land surveying. He was hired as a draftsman by the
Ordnance Survey of Ireland Ordnance Survey Ireland (OSI; ga, Suirbhéireacht Ordanáis Éireann) is the national mapping agency of Ireland. It was established on 4 March 2002 as a body corporate. It is the successor to the former Ordnance Survey of Ireland. It and the ...
in his late teens in 1839, and moved to work for the
Ordnance Survey Ordnance Survey (OS) is the national mapping agency for Great Britain. The agency's name indicates its original military purpose (see ordnance and surveying), which was to map Scotland in the wake of the Jacobite rising of 1745. There was a ...
for Great Britain in 1842. In the decade of the 1840s, a railway-building boom was in progress, and Tyndall's land surveying experience was valuable and in demand by the railway companies. Between 1844 and 1847, he was lucratively employed in railway construction planning. In 1847, Tyndall opted to become a mathematics and surveying teacher at
Queenwood College Queenwood College was a British Public School, that is an independent fee-paying school, situated near Stockbridge, Hampshire, England. The school was in operation from 1847 to 1896. History of the site In 1335 Edward III gave the Manor of Ea ...
, a boarding school in
Hampshire Hampshire (, ; abbreviated to Hants) is a ceremonial and non-metropolitan county in western South East England on the coast of the English Channel. Home to two major English cities on its south coast, Southampton and Portsmouth, Hampshire ...
. Recalling this decision later, he wrote: "the desire to grow intellectually did not forsake me; and, when railway work slackened, I accepted in 1847 a post as master in Queenwood College." Another recently arrived young teacher at Queenwood was
Edward Frankland Sir Edward Frankland, (18 January 18259 August 1899) was an English chemist. He was one of the originators of organometallic chemistry and introduced the concept of combining power or valence. An expert in water quality and analysis, he was ...
, who had previously worked as a chemical laboratory assistant for the British Geological Survey. Frankland and Tyndall became good friends. On the strength of Frankland's prior knowledge, they decided to go to Germany to further their education in science. Among other things, Frankland knew that certain German universities were ahead of any in Britain in experimental chemistry and physics. (British universities were still focused on classics and mathematics and not laboratory science.) The pair moved to Germany in summer 1848 and enrolled at the University of Marburg, attracted by the reputation of Robert Bunsen as a teacher. Tyndall studied under Bunsen for two years. Perhaps more influential for Tyndall at Marburg was Professor
Hermann Knoblauch Karl Hermann Knoblauch (; 11 April 1820 – 30 June 1895) was a German physicist. He is most notable for his studies of radiant heat. He was one of the six founding members of the Deutsche Physikalische Gesellschaft at Berlin on 14 January 1845. ...
, with whom Tyndall maintained communications by letter for many years afterwards. Tyndall's Marburg dissertation was a mathematical analysis of screw surfaces in 1850 (under Friedrich Ludwig Stegmann). Tyndall stayed in Germany for a further year doing research on magnetism with Knoblauch, including some months' visit at the Berlin laboratory of Knoblauch's main teacher, Heinrich Gustav Magnus. It is clear today that Bunsen and Magnus were among the very best experimental science instructors of the era. Thus, when Tyndall returned to live in England in summer 1851, he probably had as good an education in experimental science as anyone in England.


Early scientific work

Tyndall's early original work in physics was his experiments on
magnetism Magnetism is the class of physical attributes that are mediated by a magnetic field, which refers to the capacity to induce attractive and repulsive phenomena in other entities. Electric currents and the magnetic moments of elementary particles ...
and diamagnetic polarity, on which he worked from 1850 to 1856. His two most influential reports were the first two, co-authored with Knoblauch. One of them was entitled "The magneto-optic properties of crystals, and the relation of magnetism and diamagnetism to molecular arrangement", dated May 1850. The two described an inspired experiment, with an inspired interpretation. These and other magnetic investigations very soon made Tyndall known among the leading scientists of the day. He was elected a
Fellow of the Royal Society Fellowship of the Royal Society (FRS, ForMemRS and HonFRS) is an award granted by the judges of the Royal Society of London to individuals who have made a "substantial contribution to the improvement of natural knowledge, including mathemati ...
in 1852. In his search for a suitable research appointment, he was able to ask the longtime editor of the leading German physics journal ( Poggendorff) and other prominent men to write testimonials on his behalf. In 1853, he attained the prestigious appointment of Professor of
Natural Philosophy Natural philosophy or philosophy of nature (from Latin ''philosophia naturalis'') is the philosophical study of physics, that is, nature and the physical universe. It was dominant before the development of modern science. From the ancien ...
(Physics) at the Royal Institution in London, due in no small part to the esteem his work had garnered from
Michael Faraday Michael Faraday (; 22 September 1791 – 25 August 1867) was an English scientist who contributed to the study of electromagnetism and electrochemistry. His main discoveries include the principles underlying electromagnetic inducti ...
, the leader of magnetic investigations at the Royal Institution. About a decade later Tyndall was appointed the successor to the positions held by Michael Faraday at the Royal Institution on Faraday's retirement.


Alpine mountaineering and glaciology

Tyndall visited the
Alps The Alps () ; german: Alpen ; it, Alpi ; rm, Alps ; sl, Alpe . are the highest and most extensive mountain range system that lies entirely in Europe, stretching approximately across seven Alpine countries (from west to east): France, Sw ...
mountains in 1856 for scientific reasons and ended up becoming a pioneering mountain climber. He visited the Alps almost every summer from 1856 onward, was a member of the very first mountain-climbing team to reach the top of the Weisshorn (1861), and led one of the early teams to reach the top of the Matterhorn (1868). His is one of the names associated with the "
Golden age of alpinism The golden age of alpinism was the decade in mountaineering between Alfred Wills's ascent of the Wetterhorn in 1854 and Edward Whymper's ascent of the Matterhorn in 1865, during which many major peaks in the Alps saw their first ascents. Promin ...
" — the mid-Victorian years when the more difficult of the Alpine peaks were summited for the first time. In the Alps, Tyndall studied
glacier A glacier (; ) is a persistent body of dense ice that is constantly moving under its own weight. A glacier forms where the accumulation of snow exceeds its ablation over many years, often centuries. It acquires distinguishing features, such a ...
s, and especially
glacier motion Glacial motion is the motion of glaciers, which can be likened to rivers of ice. It has played an important role in sculpting many landscapes. Most lakes in the world occupy basins scoured out by glaciers. Glacial motion can be fast (up to , o ...
. His explanation of glacial flow brought him into dispute with others, particularly
James David Forbes James David Forbes (1809–1868) was a Scottish physicist and glaciologist who worked extensively on the conduction of heat and seismology. Forbes was a resident of Edinburgh for most of his life, educated at its University and a professor ...
. Much of the early scientific work on glacier motion had been done by Forbes, but Forbes at that time did not know of the phenomenon of regelation, which was discovered a little later by Michael Faraday. Regelation played a key role in Tyndall's explanation. Forbes did not see regelation in the same way at all. Complicating their debate, a disagreement arose publicly over who deserved to get investigator credit for what. Articulate friends of Forbes, as well as Forbes himself, thought that Forbes should get the credit for most of the good science, whereas Tyndall thought the credit should be distributed more widely. Tyndall commented: "The idea of semi-fluid motion belongs entirely to Louis Rendu; the proof of the quicker central flow belongs in part to Rendu, but almost wholly to Louis Agassiz and Forbes; the proof of the retardation of the bed belongs to Forbes alone; while the discovery of the locus of the point of maximum motion belongs, I suppose, to me." When Forbes and Tyndall were in the grave, their disagreement was continued by their respective official biographers. Everyone tried to be reasonable, but agreement was not attained. More disappointingly, aspects of glacier motion remained not understood or not proved. Numerous landforms and geographical features are named for John Tyndall, including Tyndall Glacier in
Chile Chile, officially the Republic of Chile, is a country in the western part of South America. It is the southernmost country in the world, and the closest to Antarctica, occupying a long and narrow strip of land between the Andes to the eas ...
, Tyndall Glacier in
Colorado Colorado (, other variants) is a state in the Mountain West subregion of the Western United States. It encompasses most of the Southern Rocky Mountains, as well as the northeastern portion of the Colorado Plateau and the western edge of the ...
, Tyndall Glacier in
Alaska Alaska ( ; russian: Аляска, Alyaska; ale, Alax̂sxax̂; ; ems, Alas'kaaq; Yup'ik: ''Alaskaq''; tli, Anáaski) is a state located in the Western United States on the northwest extremity of North America. A semi-exclave of the U ...
,
Mount Tyndall Mount Tyndall is a peak in the Mount Whitney region of the Sierra Nevada in the U.S. state of California. At , it is the tenth highest peak in the state. The mountain was named in honor of the Irish scientist and mountaineer, John Tyndall. G ...
in
California California is a state in the Western United States, located along the Pacific Coast. With nearly 39.2million residents across a total area of approximately , it is the most populous U.S. state and the 3rd largest by area. It is also the m ...
, and
Mount Tyndall Mount Tyndall is a peak in the Mount Whitney region of the Sierra Nevada in the U.S. state of California. At , it is the tenth highest peak in the state. The mountain was named in honor of the Irish scientist and mountaineer, John Tyndall. G ...
in
Tasmania ) , nickname = , image_map = Tasmania in Australia.svg , map_caption = Location of Tasmania in AustraliaCoordinates: , subdivision_type = Country , subdi ...
.


Main scientific work

Work on glaciers alerted Tyndall to the research of de Saussure into the heating effect of sunlight, and the concept of Fourier, developed by Pouillet and
William Hopkins William Hopkins FRS (2 February 179313 October 1866) was an English mathematician and geologist. He is famous as a private tutor of aspiring undergraduate Cambridge mathematicians, earning him the ''sobriquet'' the " senior-wrangler maker." ...
; that heat from the sun penetrates the atmosphere more easily than "obscure heat" (
infrared Infrared (IR), sometimes called infrared light, is electromagnetic radiation (EMR) with wavelengths longer than those of Light, visible light. It is therefore invisible to the human eye. IR is generally understood to encompass wavelengths from ...
) "terrestrial radiation" from the warmed Earth, causing what we now call the
greenhouse effect The greenhouse effect is a process that occurs when energy from a planet's host star goes through the planet's atmosphere and heats the planet's surface, but greenhouse gases in the atmosphere prevent some of the heat from returning directly ...
. In the spring of 1859, Tyndall began research into how
thermal radiation Thermal radiation is electromagnetic radiation generated by the thermal motion of particles in matter. Thermal radiation is generated when heat from the movement of charges in the material (electrons and protons in common forms of matter) i ...
, both visible and obscure, affects different gases and aerosols. He developed differential absorption spectroscopy using the electro-magnetic thermopile devised by Melloni. Tyndall began intensive experiments on 9 May 1859, at first without significant results, then improved the sensitivity of the apparatus and on 18 May wrote in his journal "Experimented all day; the subject is completely in my hands!" On 26 May he gave the
Royal Society The Royal Society, formally The Royal Society of London for Improving Natural Knowledge, is a learned society and the United Kingdom's national academy of sciences. The society fulfils a number of roles: promoting science and its benefits, re ...
a note which described his methods, and stated "With the exception of the celebrated memoir of M. Pouillet on Solar Radiation through the atmosphere, nothing, so far as I am aware, has been published on the transmission of radiant heat through gaseous bodies. We know nothing of the effect even of air upon heat radiated from terrestrial sources." Note; it is now appreciated that in 1856 Eunice Foote had published experiments on how the sun's rays heated gases, giving evidence that and water vapour absorbed heat, and speculated that changes in their proportions could affect
climate Climate is the long-term weather pattern in an area, typically averaged over 30 years. More rigorously, it is the mean and variability of meteorological variables over a time spanning from months to millions of years. Some of the meteorologi ...
, but she did not differentiate the effects of
infrared Infrared (IR), sometimes called infrared light, is electromagnetic radiation (EMR) with wavelengths longer than those of Light, visible light. It is therefore invisible to the human eye. IR is generally understood to encompass wavelengths from ...
heat.
On 10 June, he demonstrated the research in a Royal Society lecture, noting that coal gas and
ether In organic chemistry, ethers are a class of compounds that contain an ether group—an oxygen atom connected to two alkyl or aryl groups. They have the general formula , where R and R′ represent the alkyl or aryl groups. Ethers can again ...
strongly absorbed (infrared) radiant heat, and his experimental confirmation of the (
greenhouse effect The greenhouse effect is a process that occurs when energy from a planet's host star goes through the planet's atmosphere and heats the planet's surface, but greenhouse gases in the atmosphere prevent some of the heat from returning directly ...
) concept; that solar heat crosses an atmosphere, but "when the heat is absorbed by the planet, it is so changed in quality that the rays emanating from the planet cannot get with the same freedom back into space. Thus the atmosphere admits of the entrance of solar heat; but checks its exit, and the result is a tendency to accumulate heat at the surface of the planet."Weekly Evening Meeting, Friday, June 10, 1859. The Prince Consort, Vice-Patron, in the Chair. John Tyndall, Esq. F.R.S. "On the Transmission of Heat of different qualities through Gases of different kinds", in Tyndall's studies of the action of
radiant energy Radiant may refer to: Computers, software, and video games * Radiant (software), a content management system * GtkRadiant, a level editor created by id Software for their games * Radiant AI, a technology developed by Bethesda Softworks for ''Th ...
on the constituents of air led him onto several lines of inquiry, and his original research results included the following: * Tyndall explained the heat in the Earth's atmosphere in terms of the capacities of the various gases in the air to absorb radiant heat, in the form of infrared radiation. His measuring device, which used thermopile technology, is an early landmark in the history of absorption spectroscopy of gases. He was the first to correctly measure the relative infrared absorptive powers of the gases
nitrogen Nitrogen is the chemical element with the symbol N and atomic number 7. Nitrogen is a nonmetal and the lightest member of group 15 of the periodic table, often called the pnictogens. It is a common element in the universe, estimated at se ...
,
oxygen Oxygen is the chemical element with the symbol O and atomic number 8. It is a member of the chalcogen group in the periodic table, a highly reactive nonmetal, and an oxidizing agent that readily forms oxides with most elements ...
, water vapour,
carbon dioxide Carbon dioxide ( chemical formula ) is a chemical compound made up of molecules that each have one carbon atom covalently double bonded to two oxygen atoms. It is found in the gas state at room temperature. In the air, carbon dioxide is t ...
,
ozone Ozone (), or trioxygen, is an inorganic molecule with the chemical formula . It is a pale blue gas with a distinctively pungent smell. It is an allotrope of oxygen that is much less stable than the diatomic allotrope , breaking down in the l ...
,
methane Methane ( , ) is a chemical compound with the chemical formula (one carbon atom bonded to four hydrogen atoms). It is a group-14 hydride, the simplest alkane, and the main constituent of natural gas. The relative abundance of methane ...
, and other trace gases and vapours. He concluded that water vapour is the strongest absorber of radiant heat in the atmosphere and is the principal gas controlling air temperature. Absorption by the other gases is not negligible but relatively small. Prior to Tyndall it was widely surmised that the Earth's atmosphere warms the surface in what was later called a
greenhouse effect The greenhouse effect is a process that occurs when energy from a planet's host star goes through the planet's atmosphere and heats the planet's surface, but greenhouse gases in the atmosphere prevent some of the heat from returning directly ...
, but he was the first to prove it. The proof was that water vapour strongly absorbed infrared radiation. Three years earlier, in 1856, the American scientist Eunice Newton Foote had announced experiments demonstrating that water vapour and carbon dioxide absorb heat from solar radiation, but she did not differentiate the effects of infrared. Relatedly, Tyndall in 1860 was first to demonstrate and quantify that visually transparent gases are infrared emitters. * He devised demonstrations that advanced the question of how radiant heat is absorbed and emitted at the molecular level. He appears to be the first person to have demonstrated experimentally that emission of heat in chemical reactions has its physical origination within the newly created molecules (1864). He produced instructive demonstrations involving the incandescent conversion of infrared into visible light at the molecular level, which he called
calorescence Calorescence is a term describing the process whereby matter absorbs infrared radiant energy and emits visible radiant energy in its place. For example, some kinds of flammable gas give off large amounts of radiant heat and very little visible lig ...
(1865), in which he used materials that are transparent to infrared and opaque to visible light or vice versa. He usually referred to infrared as "radiant heat", and sometimes as "ultra-red undulations", as the word "infrared" did not start coming into use until the 1880s. His main reports of the 1860s were republished as a 450-page collection in 1872 under the title ''Contributions to Molecular Physics in the Domain of Radiant Heat''. * In the investigations on radiant heat in air it had been necessary to use air from which all traces of floating dust and other
particulates Particulates – also known as atmospheric aerosol particles, atmospheric particulate matter, particulate matter (PM) or suspended particulate matter (SPM) – are microscopic particles of solid or liquid matter suspended in the air. Th ...
had been removed. A very sensitive way to detect particulates is to bathe the air with intense light. The scattering of light by particulate impurities in air and other gases, and in liquids, is known today as the Tyndall Effect or Tyndall Scattering. In studying this scattering during the late 1860s Tyndall was a beneficiary of recent improvements in electric-powered lights. He also had the use of good light concentrators. He developed the nephelometer and similar instruments that show properties of
aerosols An aerosol is a suspension of fine solid particles or liquid droplets in air or another gas. Aerosols can be natural or anthropogenic. Examples of natural aerosols are fog or mist, dust, forest exudates, and geyser steam. Examples of a ...
and colloids through concentrated light beams against a dark background and are based on exploiting the Tyndall Effect. (When combined with microscopes, the result is the
ultramicroscope An ultramicroscope is a microscope with a system that lights the object in a way that allows viewing of tiny particles via light scattering, and not light reflection or absorption. When the diameter of a particle is below or near the wavelength ...
, which was developed later by others). * He was the first to observe and report the phenomenon of thermophoresis in aerosols. He spotted it surrounding hot objects while investigating the Tyndall Effect with focused lightbeams in a dark room. He devised a better way to demonstrate it, and then simply reported it (1870), without investigating the physics of it in depth. * In radiant-heat experiments that called for much laboratory expertise in the early 1860s, he showed for a variety of readily vaporisable liquids that, molecule for molecule, the vapour form and the liquid form have essentially the same power to absorb radiant heat. (In modern experiments using narrow-band spectra, some small differences are found that Tyndall's equipment was unable to get at; see e.g. absorption spectrum of H2O). * He consolidated and enhanced the results of Desains,
Forbes ''Forbes'' () is an American business magazine owned by Integrated Whale Media Investments and the Forbes family. Published eight times a year, it features articles on finance, industry, investing, and marketing topics. ''Forbes'' also r ...
,
Knoblauch Knoblauch is a surname of German origin, a metonymic occupational name for a gardener or trader with garlic. It is also the German word for garlic. It may refer to: *Chuck Knoblauch (born 1968), American baseball player **Ray Knoblauch (1928–200 ...
and others demonstrating that the principal properties of visible light can be reproduced for radiant heat – namely reflection, refraction, diffraction, polarisation, depolarisation, double refraction, and rotation in a magnetic field. * Using his expertise about radiant heat absorption by gases, he invented a system for measuring the amount of carbon dioxide in a sample of exhaled human breath (1862, 1864). The basics of Tyndall's system is in daily use in hospitals today for monitoring patients under anaesthesia. (See capnometry.) * When studying the absorption of radiant heat by
ozone Ozone (), or trioxygen, is an inorganic molecule with the chemical formula . It is a pale blue gas with a distinctively pungent smell. It is an allotrope of oxygen that is much less stable than the diatomic allotrope , breaking down in the l ...
, he came up with a demonstration that helped confirm or reaffirm that ozone is an oxygen cluster (1862). * In the lab he came up with the following simple way to obtain "optically pure" air, i.e. air that has no visible signs of particulate matter. He built a square wooden box with a couple of glass windows on it. Before closing the box, he coated the inside walls and floor of the box with glycerin, which is a sticky syrup. He found that after a few days' wait the air inside the box was entirely particulate-free when examined with strong light beams through the glass windows. The various floating-matter particulates had all ended up getting stuck to the walls or settling on the sticky floor. Now, in the optically pure air there were no signs of any "germs", i.e. no signs of floating micro-organisms. Tyndall sterilised some meat-broths by simply boiling them, and then compared what happened when he let these meat-broths sit in the optically pure air, and in ordinary air. The broths sitting in the optically pure air remained "sweet" (as he said) to smell and taste after many months of sitting, while the ones in ordinary air started to become putrid after a few days. This demonstration extended Louis Pasteur's earlier demonstrations that the presence of micro-organisms is a precondition for biomass decomposition. However, the next year (1876) Tyndall failed to consistently reproduce the result. Some of his supposedly heat-sterilized broths rotted in the optically pure air. From this Tyndall was led to find viable bacterial spores (endospores) in supposedly heat-sterilized broths. He discovered the broths had been contaminated with dry bacterial spores from hay in the lab. All bacteria are killed by simple boiling, except that bacteria have a spore form that can survive boiling, he correctly contended, citing research by Ferdinand Cohn. Tyndall found a way to eradicate the bacterial spores that came to be known as "
Tyndallization Tyndallization is a process from the nineteenth century for sterilizing substances, usually food, named after its inventor John Tyndall, that can be used to kill heat-resistant endospores. Although now considered dated, it is still occasionally use ...
". Tyndallization historically was the earliest known effective way to destroy bacterial spores. At the time, it affirmed the " germ theory" against a number of critics whose experimental results had been defective from the same cause. During the mid-1870s Pasteur and Tyndall were in frequent communication. * Invented a better fireman's respirator, a hood that filtered smoke and noxious gas from air (1871, 1874). * In the late 1860s and early 1870s he wrote an introductory book about sound propagation in air, and was a participant in a large-scale British project to develop a better
foghorn A foghorn or fog signal is a device that uses sound to warn vehicles of navigational hazards such as rocky coastlines, or boats of the presence of other vessels, in foggy conditions. The term is most often used in relation to marine transport. Wh ...
. In laboratory demonstrations motivated by foghorn issues, Tyndall established that sound is partially ''reflected'' (i.e. partially bounced back like an echo) at the location where an air mass of one temperature meets another air mass of a different temperature; and more generally when a body of air contains two or more air masses of different densities or temperatures, the sound travels poorly because of reflections occurring at the interfaces between the air masses, and very poorly when many such interfaces are present. (He then argued, though inconclusively, that this is the usual main reason why the same distant sound, e.g. foghorn, can be heard stronger or fainter on different days or at different times of day.) An index of 19th-century scientific research journals has John Tyndall as the author of more than 147 papers in science research journals, with practically all of them dated between 1850 and 1884, which is an average of more than four papers a year over that 35-year period. In his lectures at the Royal Institution Tyndall put a great value on, and was talented at producing, lively, visible demonstrations of physics concepts. In one lecture, Tyndall demonstrated the propagation of light down through a stream of falling water via
total internal reflection Total internal reflection (TIR) is the optical phenomenon in which waves arriving at the interface (boundary) from one medium to another (e.g., from water to air) are not refracted into the second ("external") medium, but completely reflect ...
of the light. It was referred to as the "light fountain". It is historically significant today because it demonstrates the scientific foundation for modern fibre optic technology. During second half of the 20th century Tyndall was usually credited with being the first to make this demonstration. However, Jean-Daniel Colladon published a report of it in '' Comptes Rendus'' in 1842, and there's some suggestive evidence that Tyndall's knowledge of it came ultimately from Colladon and no evidence that Tyndall claimed to have originated it himself.


Molecular physics of radiant heat

Tyndall was an experimenter and laboratory apparatus builder, not an abstract model builder. But in his experiments on radiation and the heat-absorptive power of gases, he had an underlying agenda to understand the physics of molecules. Tyndall said in 1879: "During nine years of labour on the subject of radiation n the 1860s heat and light were handled throughout by me, not as ends, but as instruments by the aid of which the mind might perchance lay hold upon the ultimate particles of matter." This agenda is explicit in the title he picked for his 1872 book ''Contributions to Molecular Physics in the Domain of Radiant Heat''. It is present less explicitly in the spirit of his widely read 1863 book ''Heat Considered as a Mode of Motion''. Besides heat he also saw magnetism and sound propagation as reducible to molecular behaviours. Invisible molecular behaviours were the ultimate basis of all physical activity. With this mindset, and his experiments, he outlined an account whereby differing types of molecules have differing absorptions of infrared radiation because their molecular structures give them differing oscillating resonances. He'd gotten into the oscillating resonances idea because he'd seen that any one type of molecule has differing absorptions at differing radiant frequencies, and he was entirely persuaded that the only difference between one frequency and another is the frequency. He'd also seen that the absorption behaviour of molecules is quite different from that of the atoms composing the molecules. For example, the gas nitric oxide (NO) absorbed more than a thousand times more infrared radiation than either nitrogen (N2) or oxygen (O2). He'd also seen in several kinds of experiments that – no matter whether a gas is a weak absorber of broad-spectrum radiant heat – any gas will strongly absorb the radiant heat coming from a separate body of the same type of gas.In the late 1850s Balfour Stewart had showed that cold rock-salt was a very strong absorber of the radiations from hot rock-salt, even though rock-salt was a very weak absorber of the radiations from all other kinds of heat-sources tested. By the early 1860s this had been generalized in the scientific literature to the principle that any kind of chemical will very strongly absorb the radiations coming from a separate body of the same kind of chemical. In Tyndall's words this was a "principle which lies at the basis of spectrum analysis, ... namely, that a body which is competent to emit any ray, whether of heat or light, is competent in the same degree to absorb that ray
(1866)
Tyndall made several original observations around 1863 by beginning with the assumption that this principle is correct. The following is a summary of one of them. It was well-known at the time that in a flame of burning carbon monoxide, the carbon monoxide chemically combines with the oxygen of the air to form carbon dioxide plus heat. Tyndall observed that if a body of cold or room-temperature carbon dioxide is placed near the flame "the cold gas is intensely opaque to .e. it very strongly absorbsthe radiation from this particular flame, though it is highly transparent to .e. it very weakly absorbsheat of every other kind." Thus the great bulk of the heat in the carbon monoxide flame fits the emission spectrum of carbon dioxide, implying the heat is a radiant emission from the newly formed carbon dioxide molecules. Tyndall got the same type of result with a flame of burning hydrogen, another flame known to be chemically simple in the sense that very little intermediate or transitory molecules are produced in it. This appears to be the first demonstration that the heat given out in chemical reactions has its physical origination within the new molecules. Tyndall's report of the demonstration is in
Contributions to Molecular Physics in the Domain of Radiant Heat
', sections 11–17 of Chapter VI, dated 1864. A related demonstration is in sections 3–8 of Chapter V, dated 1863. It is also discussed in Tyndall's
Fragments of Science, Volume I
' Chapter III, dated 1866. For a modern analysis of where the heat is coming from in the carbon monoxide flame see Tyndall also interpreted the carbon monoxide flame as showing that carbon dioxide's spectral profile remains the same at room temperature and at a temperature of over 2000 °C, the temperature in the flame; and likewise for the product of the hydrogen flame. This was in contrast to the easily seen fact in solids such as carbon and platinum where the spectral profile moves towards the quicker frequencies when the temperature is increased.
That demonstrated a kinship between the molecular mechanisms of
absorption Absorption may refer to: Chemistry and biology *Absorption (biology), digestion **Absorption (small intestine) *Absorption (chemistry), diffusion of particles of gas or liquid into liquid or solid materials *Absorption (skin), a route by which s ...
and emission. Such a kinship was also in evidence in experiments by Balfour Stewart and others, cited and extended by Tyndall, that showed with respect to broad-spectrum radiant heat that molecules that are weak absorbers are weak emitters and strong absorbers are strong emitters.After his measurements of infrared absorption by gases in 1859, Tyndall measured infrared emission by gases in 1860, with respect to broad-spectrum infrared radiation. He did this for many different gases, and when the gases were ranked by their emissive powers the rank order was the same as it was for their absorptive powers. His February 1861 article
On the Absorption and Radiation of Heat by Gases and Vapours, and on the Physical Connexion of Radiation, Absorption, and Conduction
in ''Philosophical Transactions of the Royal Society of London'', Volume 151, pages 1–36, year 1861, was later republished in the book
Contributions to Molecular Physics in the Domain of Radiant Heat
', Chapter I; and in the same book there is more in Chapter II section 11 (year 1862), and chapter IX section 6 (year 1865). These laboratory experiments by Tyndall on "the reciprocity of absorption and radiation on the part of gases" were informed by experiments done on solids by Balfour Stewart in 1858 and 1859. The two relevant articles by Balfour Stewart are online as republished in 1901 in
The Laws of Radiation and Absorption: Memoirs by Prévost, Stewart, Kirchhoff and Bunsen
'.
(For example,
rock-salt Halite (), commonly known as rock salt, is a type of salt, the mineral (natural) form of sodium chloride ( Na Cl). Halite forms isometric crystals. The mineral is typically colorless or white, but may also be light blue, dark blue, purple, p ...
is an exceptionally poor absorber of heat via radiation, and a good absorber of heat via conduction. When a plate of rock-salt is heated via conduction and let stand on an insulator, it takes an exceptionally long time to cool down; i.e., it's a poor emitter of infrared.) The kinship between absorption and emission was also consistent with some generic or abstract features of resonators. The chemical decomposition of molecules by lightwaves ( photochemical effect) convinced Tyndall that the resonator could not be the molecule as a whole unit; it had to be some substructure, because otherwise the photochemical effect would be impossible. But he was without testable ideas as to the form of this substructure, and did not partake in speculation in print. His promotion of the molecular mindset, and his efforts to experimentally expose what molecules are, has been discussed by one historian under the title ''"John Tyndall, The Rhetorician of Molecularity"''.


Educator

Besides being a scientist, John Tyndall was a science teacher and evangelist for the cause of science. He spent a significant amount of his time disseminating science to the general public. He gave hundreds of public lectures to non-specialist audiences at the Royal Institution in London. When he went on a public lecture tour in the US in 1872, large crowds of non-scientists paid fees to hear him lecture about the nature of light. A typical statement of Tyndall's reputation at the time is this from a London publication in 1878: "Following the precedent set by Faraday, Professor Tyndall has succeeded not only in original investigation and in teaching science soundly and accurately, but in making it attractive.... When he lectures at the Royal Institution the theatre is crowded." Tyndall said of the occupation of teacher "I do not know a higher, nobler, and more blessed calling." His greatest audience was gained ultimately through his books, most of which were not written for experts or specialists. He published more than a dozen science books. From the mid-1860s on, he was one of the world's most famous living physicists, due firstly to his skill and industry as a tutorialist. Most of his books were translated into German and French with his main tutorials staying in print in those languages for decades. As an indicator of his teaching attitude, here are his concluding remarks to the reader at the end of a 200-page tutorial book for a "youthful audience", ''The Forms of Water'' (1872): "Here, my friend, our labours close. It has been a true pleasure to me to have you at my side so long. In the sweat of our brows we have often reached the heights where our work lay, but you have been steadfast and industrious throughout, using in all possible cases your own muscles instead of relying upon mine. Here and there I have stretched an arm and helped you to a ledge, but the work of climbing has been almost exclusively your own. It is thus that I should like to teach you all things; showing you the way to profitable exertion, but leaving the exertion to you.... Our task seems plain enough, but you and I know how often we have had to wrangle resolutely with the facts to bring out their meaning. The work, however, is now done, and you are master of a fragment of that sure and certain knowledge which is founded on the faithful study of nature.... Here then we part. And should we not meet again, the memory of these days will still unite us. Give me your hand. Good bye." As another indicator, here is the opening paragraph of his 350-page tutorial entitled ''Sound'' (1867): "In the following pages I have tried to render the science of acoustics interesting to all intelligent persons, including those who do not possess any special scientific culture. The subject is treated experimentally throughout, and I have endeavoured so to place each experiment before the reader that he should realise it as an actual operation." In the preface to the 3rd edition of this book, he reports that earlier editions were translated into Chinese at the expense of the Chinese government and translated into German under the supervision of
Hermann von Helmholtz Hermann Ludwig Ferdinand von Helmholtz (31 August 1821 – 8 September 1894) was a German physicist and physician who made significant contributions in several scientific fields, particularly hydrodynamic stability. The Helmholtz Associat ...
(a big name in the science of acoustics). His first published tutorial, which was about glaciers (1860), similarly states: "The work is written with a desire to interest intelligent persons who may not possess any special scientific culture." His most widely praised tutorial, and probably his biggest seller, was the 550-page ''"Heat: a Mode of Motion"'' (1863; updated editions until 1880). It was in print for at least 50 years, and is in print today. Its primary feature is, as James Clerk Maxwell said in 1871, "the doctrines of the science f heatare forcibly impressed on the mind by well-chosen illustrative experiments." Tyndall's three longest tutorials, namely ''Heat'' (1863), ''Sound'' (1867), and ''Light'' (1873), represented state-of-the-art experimental physics at the time they were written. Much of their contents were recent major innovations in the understanding of their respective subjects, which Tyndall was the first writer to present to a wider audience. One caveat is called for about the meaning of "state of the art". The books were devoted to laboratory science and they avoided mathematics. In particular, they contain absolutely no infinitesimal calculus. Mathematical modelling using infinitesimal calculus, especially differential equations, was a component of the state-of-the-art understanding of heat, light and sound at the time.


Demarcation of science from religion

The majority of the progressive and innovative British physicists of Tyndall's generation were conservative and orthodox on matters of religion. That includes for example James Joule, Balfour Stewart,
James Clerk Maxwell James Clerk Maxwell (13 June 1831 – 5 November 1879) was a Scottish mathematician and scientist responsible for the classical theory of electromagnetic radiation, which was the first theory to describe electricity, magnetism and ligh ...
, George Gabriel Stokes and William Thomson – all names investigating heat or light contemporaneously with Tyndall. These conservatives believed, and sought to strengthen the basis for believing, that religion and science were consistent and harmonious with each other. Tyndall, however, was a member of a club that vocally supported
Charles Darwin Charles Robert Darwin ( ; 12 February 1809 – 19 April 1882) was an English naturalist, geologist, and biologist, widely known for his contributions to evolutionary biology. His proposition that all species of life have descended ...
's theory of evolution and sought to strengthen the barrier, or separation, between religion and science. The most prominent member of this club was the anatomist Thomas Henry Huxley. Tyndall first met Huxley in 1851 and the two had a lifelong friendship. Chemist
Edward Frankland Sir Edward Frankland, (18 January 18259 August 1899) was an English chemist. He was one of the originators of organometallic chemistry and introduced the concept of combining power or valence. An expert in water quality and analysis, he was ...
and mathematician Thomas Archer Hirst, both of whom Tyndall had known since before going to university in Germany, were members too. Others included the social philosopher
Herbert Spencer Herbert Spencer (27 April 1820 – 8 December 1903) was an English philosopher, psychologist, biologist, anthropologist, and sociologist famous for his hypothesis of social Darwinism. Spencer originated the expression " survival of the f ...
. Though not nearly so prominent as Huxley in controversy over philosophical problems, Tyndall played his part in communicating to the educated public what he thought were the virtues of having a clear separation between science (knowledge & rationality) and religion (faith & spirituality). As the elected president of the British Association for the Advancement of Science in 1874, he gave a long keynote speech at the Association's annual meeting held that year in Belfast. The speech gave a favourable account of the history of evolutionary theories, mentioning Darwin's name favourably more than 20 times, and concluded by asserting that religious sentiment should not be permitted to "intrude on the region of ''knowledge'', over which it holds no command". This was a hot topic. The newspapers carried the report of it on their front pages – in Britain, Ireland & North America, even the European Continent – and many critiques of it appeared soon after. The attention and scrutiny increased the friends of the evolutionists' philosophical position, and brought it closer to mainstream ascendancy. In Rome in 1864,
Pope Pius IX Pope Pius IX ( it, Pio IX, ''Pio Nono''; born Giovanni Maria Mastai Ferretti; 13 May 1792 – 7 February 1878) was head of the Catholic Church from 1846 to 1878, the longest verified papal reign. He was notable for convoking the First Vatican ...
in his '' Syllabus of Errors'' decreed that it was an ''error'' that "reason is the ultimate standard by which man can and ought to arrive at knowledge" and an ''error'' that "divine revelation is imperfect" in the Bible – and anyone maintaining those errors was to be " anathematized" – and in 1888 decreed as follows: "The fundamental doctrine of rationalism is the supremacy of the human reason, which, refusing due submission to the divine and eternal reason, proclaims its own independence... A doctrine of such character is most hurtful both to individuals and to the State... It follows that it is quite unlawful to demand, to defend, or to grant, unconditional r promiscuousfreedom of thought, speech, writing, or religion." Those principles and Tyndall's principles were profound enemies. Luckily for Tyndall he didn't need to get into a contest with them in Britain. Even in Italy, Huxley and Darwin were awarded honorary medals and most of the Italian governing class was hostile to the papacy. But in Ireland during Tyndall's lifetime the majority of the population grew increasingly doctrinaire and vigorous in its Roman Catholicism and also grew stronger politically. Between 1886 and 1893, Tyndall was active in the debate in England about whether to give the Catholics of Ireland more freedom to go their own way. Like the great majority of Irish-born scientists of the 19th century he opposed the Irish Home Rule Movement. He had ardent views about it, which were published in newspapers and pamphlets. For example, in an opinion piece in ''
The Times ''The Times'' is a British daily national newspaper based in London. It began in 1785 under the title ''The Daily Universal Register'', adopting its current name on 1 January 1788. ''The Times'' and its sister paper '' The Sunday Times'' ( ...
'' on 27 December 1890 he saw priests and Catholicism as "the heart and soul of this movement" and wrote that placing the non-Catholic minority under the dominion of "the priestly horde" would be "an unspeakable crime". He tried unsuccessfully to get the UK's premier scientific society to denounce the Irish Home Rule proposal as contrary to the interests of science. In several essays included in his book ''Fragments of Science for Unscientific People'', Tyndall attempted to dissuade people from believing in the potential effectiveness of prayers. At the same time, though, he was not broadly anti-religious.The collection of Tyndall's essays where his views on religion are most clearly stated is ''Fragments of Science, Volume Two'' (also published under the title ''Fragments of Science for Unscientific People''). It is online in HTML text format a
Gutenberg.org
and in other text formats a
Archive.org
Reports that Tyndall's religious beliefs were "half-agnostic, half-deistic" (page 2) and "Tyndall viewed religion itself as both inescapable and emotionally necessary for humanity, though his conviction of religion's importance was often lost on his critics" (page 5). Many of his readers interpret Tyndall to be a confirmed agnostic, though he never explicitly declared himself to be so. The following statement from Tyndall is an example of Tyndall's agnostic mindset, made in 1867, and reiterated in 1878: "The phenomena of matter and force come within our intellectual range... but behind, and above, and around us the real mystery of the universe lies unsolved, and, as far as we are concerned, is incapable of solution.... Let us lower our heads, and acknowledge our ignorance, priest and philosopher, one and all."


Private life

Tyndall did not marry until age 55. His bride, Louisa Hamilton, was the 30-year-old daughter of a member of parliament ( Lord Claud Hamilton, M.P.). The following year, 1877, they built a summer chalet at
Belalp Belalp is a village and ski resort in the Swiss canton of Valais, situated at approximately above sea level in the municipality of Naters. Because of its altitude, Belalp is a vantage point offering views of the Dom and Fletschhorn mountains an ...
in the
Swiss Alps The Alpine region of Switzerland, conventionally referred to as the Swiss Alps (german: Schweizer Alpen, french: Alpes suisses, it, Alpi svizzere, rm, Alps svizras), represents a major natural feature of the country and is, along with the Swis ...
. Before getting married Tyndall had been living for many years in an upstairs apartment at the Royal Institution and continued living there after marriage until 1885 when a move was made to a house near Haslemere 45 miles southwest of London. The marriage was a happy one and without children. He retired from the Royal Institution at age 66 having complaints of ill health. Tyndall became financially well-off from sales of his popular books and fees from his lectures (but there is no evidence that he owned commercial patents). For many years he got non-trivial payments for being a part-time scientific advisor to a couple of quasi-governmental agencies and partly donated the payments to charity. His successful lecture tour of the United States in 1872 netted him a substantial amount of dollars, all of which he promptly donated to a trustee for fostering science in America. Late in life his money donations went most visibly to the Irish Unionist political cause. When he died, his wealth was £22,122. For comparison's sake, the income of a police constable in London was about £80 per year at the time.


Death

In his last years Tyndall often took chloral hydrate to treat his
insomnia Insomnia, also known as sleeplessness, is a sleep disorder in which people have trouble sleeping. They may have difficulty falling asleep, or staying asleep as long as desired. Insomnia is typically followed by daytime sleepiness, low energy, ...
. When bedridden and ailing, he died from an accidental overdose of this drug in 1893 at the age of 73, and was buried at Haslemere. The overdose was administered by his wife Louisa. “My darling,” said Tyndall when he realized what had happened, “you have killed your John.” Afterwards, Tyndall's wife took possession of his papers and assigned herself supervisor of an official biography of him. She procrastinated on the project, however, and it was still unfinished when she died in 1940 aged 95. The book eventually appeared in 1945, written by A. S. Eve and C. H. Creasey, whom Louisa Tyndall had authorised shortly before her death. John Tyndall is commemorated by a memorial (the ''Tyndalldenkmal'') erected at an elevation of on the mountain slopes above the village of
Belalp Belalp is a village and ski resort in the Swiss canton of Valais, situated at approximately above sea level in the municipality of Naters. Because of its altitude, Belalp is a vantage point offering views of the Dom and Fletschhorn mountains an ...
, where he had his holiday home, and in sight of the
Aletsch Glacier The Aletsch Glacier (german: Aletschgletscher, ) or Great Aletsch Glacier () is the largest glacier in the Alps. It has a length of about (2014), has about a volume of (2011), and covers about (2011) in the eastern Bernese Alps in the Swiss can ...
, which he had studied.


John Tyndall's books

* Tyndall, J. (1860)
The glaciers of the Alps, Being a narrative of excursions and ascents, an account of the origin and phenomena of glaciers and an exposition of the physical principles to which they are related
(1861 edition) Ticknor and Fields, Boston * Tyndall, J. (1862)
Mountaineering in 1861. A vacation tour
Longman, Green, Longman, and Roberts, London * Tyndall, J. (1865), '' On Radiation: One Lecture'' (40 pages) * Tyndall, J. (1868)
Heat : A mode of motion
(1869 edition) D. Appleton, New York * Tyndall, J. (1869), ''Natural Philosophy in Easy Lessons'' (180 pages) (a physics book intended for use in secondary schools) * Tyndall, J. (1870)
Faraday as a discoverer
Longmans, Green, London * Tyndall, J. (1870), ''Three Scientific Addresses by Prof. John Tyndall'' (75 pages) The short book ''Scientific Addresses'' was published in America only. It consisted of three speeches delivered in Britain in 1868–1870. Partly published in Britain in the short book entitled ''Essays on the Use and Limit of the Imagination in Science''. Some of this material was republished in the ''Fragments of Science'' collection. * Tyndall, J. (1870), ''Notes of a Course of Nine Lectures on Light'' (80 pages) * Tyndall, J. (1870), ''Notes of a Course of Seven Lectures on Electrical Phenomena and Theories'' (50 pages) * Tyndall, J. (1870)
''Researches on diamagnetism and magne-crystallic action: including the question of diamagnetic polarity''
(a compilation of 1850s research reports), Longmans, Green, London * Tyndall, J. (1871)
Hours of exercise in the Alps
Longmans, Green, and Co., London * Tyndall, J. (1871)
''Fragments of Science: A Series of Detached Essays, Lectures, and Reviews''
(1872 edition), Longmans, Green, London * Tyndall, J. (1872)
''Contributions to Molecular Physics in the Domain of Radiant Heat''
(a compilation of 1860s research reports), (1873 edition), D. Appleton and Company, New York * Tyndall, J. (1873)
The forms of water in clouds & rivers, ice & glaciers
H. S. King & Co., London * Tyndall, J. (1873), ''Six Lectures on Light'' (290 pages) * Tyndall, J. (1876), ''Lessons in Electricity at the Royal Institution'' (100 pages), (intended for secondary school students) * Tyndall, J. (1878)
Sound; delivered in eight lectures
(1969 edition), Greenwood Press, New York * Tyndall, J. (1882)
Essays on the floating matter of the air, in relation to putrefaction and infection
D. Appleton, New York * Tyndall, J. (1887)
Light and electricity: notes of two courses of lectures before the Royal institution of Great Britain
D. Appleton and Company, New York * Tyndall, J. (1892)
''New Fragments''
(miscellaneous essays for a broad audience), D. Appleton, New York


See also

* Ice sheet dynamics * Spontaneous generation * Greenhouse gas * John Tyndall's system for measuring radiant heat absorption in gases *
Tyndall's bar breaker Tyndall's bar breaker is a physical demonstration experiment to demonstrate the forces created by thermal expansion and shrinkage. It was demonstrated 1867 by the Irish scientist John Tyndall in his Christmas lectures for a "juvenile auditory". ...


Notes


Sources


Biographies of John Tyndall

* 430 pages. This is the "official" biography. *
William Tulloch Jeans William Tulloch Jeans (1848–1907) was a British parliamentary journalist and author. Career Jeans was parliamentary correspondent for ''The Globe'', and was widely known for and consulted on his knowledge of parliamentary principle. In their 1 ...
wrote a 100-page biography of Professor Tyndall in 1887 (the year Tyndall retired from the Royal Institution)
Downloadable
* Louisa Charlotte Tyndall, his wife, wrote an 8-page biography of John Tyndall that was published in 1899 in ''Dictionary of National Biography'' (volume 57). It is readable online (and a 1903 republication of the same biography is als
readable online
. *
Edward Frankland Sir Edward Frankland, (18 January 18259 August 1899) was an English chemist. He was one of the originators of organometallic chemistry and introduced the concept of combining power or valence. An expert in water quality and analysis, he was ...
, a longtime friend, wrote a 16-page biography of John Tyndall as an obituary in 1894 in a scientific journal. It i
readable online
* Gives an account of Tyndall's vocational development prior to 1853. * 220 pages. * Arthur Whitmore Smith, a professor of physics, wrote a 10-page biography of John Tyndall in 1920 in a scientific monthly
Readable online
* * John Walter Gregory, a naturalist, wrote a 9-page obituary of John Tyndall in 1894 in a natural science journal. Readable online. * An early, 8-page profile of John Tyndall appeared in 1864 i
''Portraits of Men of Eminence in Literature, Science and Art'', Volume II, pages 25–32
* A brief profile of Tyndall based on information supplied by Tyndall himself appeared in 1874 in . *
Claud Schuster Claud Schuster, 1st Baron Schuster, (22 August 1869 – 28 June 1956) was a British barrister and civil servant noted for his long tenure as Permanent Secretary to the Lord Chancellor's Office. Born to a Mancunian business family, Schuster w ...
, ''John Tyndall as a Mountaineer'', 56-page essay included in Schuster's book ''Postscript to Adventure'', year 1950 (New Alpine Library: Eyre & Spottiswoode, London). *. * The first major biography of Tyndall since 1945.


Further reading

* *


External links

* * * *
A blog maintained by a historian who is involved in transcribing Tyndall's letters
*Th

website {{DEFAULTSORT:Tyndall, John 1820 births 1893 deaths Atmospheric physicists Experimental physicists University of Marburg alumni Irish physicists Optical physicists Glaciologists Irish mountain climbers People from County Carlow Royal Medal winners Fellows of the Royal Society Drug-related deaths in England