John James Waterston
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John James Waterston (1811 – 18 June 1883) was a Scottish
physicist A physicist is a scientist who specializes in the field of physics, which encompasses the interactions of matter and energy at all length and time scales in the physical universe. Physicists generally are interested in the root or ultimate cau ...
and a neglected pioneer of the kinetic theory of gases.


Early life

Waterston's father, George, was an
Edinburgh Edinburgh is the capital city of Scotland and one of its 32 Council areas of Scotland, council areas. The city is located in southeast Scotland and is bounded to the north by the Firth of Forth and to the south by the Pentland Hills. Edinburgh ...
sealing wax Sealing wax is a wax material of a seal (emblem), seal which, after melting, hardens quickly (to paper, parchment, ribbons and wire, and other material), forming a bond that is difficult to break without noticeable tampering. Wax is used to verify ...
manufacturer and stationer, a relative of the Sandeman family
Robert The name Robert is an ancient Germanic given name, from Proto-Germanic "fame" and "bright" (''Hrōþiberhtaz''). Compare Old Dutch ''Robrecht'' and Old High German ''Hrodebert'' (a compound of ''Hrōþ, Hruod'' () "fame, glory, honour, prais ...
and his brother, George. John was born, the sixth of nine children, into a family alive with interests in literature, science and music. He was educated at Edinburgh High School before becoming apprenticed as a
civil engineer A civil engineer is a person who practices civil engineering – the application of planning, designing, constructing, maintaining, and operating infrastructure while protecting the public and environmental health, as well as improving existing i ...
to Messrs. Grainger and Miller. His employers encouraged him to attend lectures at the
University of Edinburgh The University of Edinburgh (, ; abbreviated as ''Edin.'' in Post-nominal letters, post-nominals) is a Public university, public research university based in Edinburgh, Scotland. Founded by the City of Edinburgh Council, town council under th ...
. He studied mathematics and
physics Physics is the scientific study of matter, its Elementary particle, fundamental constituents, its motion and behavior through space and time, and the related entities of energy and force. "Physical science is that department of knowledge whi ...
under Sir John Leslie as well as attending lectures in
chemistry Chemistry is the scientific study of the properties and behavior of matter. It is a physical science within the natural sciences that studies the chemical elements that make up matter and chemical compound, compounds made of atoms, molecules a ...
,
anatomy Anatomy () is the branch of morphology concerned with the study of the internal structure of organisms and their parts. Anatomy is a branch of natural science that deals with the structural organization of living things. It is an old scien ...
and surgery and becoming an active participant in the student literary society. At age nineteen, Waterston published a paper proposing a mechanical explanation of gravitation, accounting for ''
action at a distance Action at a distance is the concept in physics that an object's motion (physics), motion can be affected by another object without the two being in Contact mechanics, physical contact; that is, it is the concept of the non-local interaction of ob ...
'' in terms of colliding particles and discussing interactions between linear and rotational motion that would play a part in his later kinetic theory. He proposed that ether is made of small cylindrical particles, and collisions with large matter particles would transfer rotational motion into linear motion, locally increasing the speed of the ether particles, which he claimed would lower the density of the ether and create an attractive force. Waterston moved to London at age twenty-one, where he worked as a railroad surveyor, becoming an associate of the
Institution of Civil Engineers The Institution of Civil Engineers (ICE) is an independent professional association for civil engineers and a Charitable organization, charitable body in the United Kingdom. Based in London, ICE has over 92,000 members, of whom three-quarters ar ...
and publishing a paper on a graphical method for planning earthworks. The travel and disruption associated with his surveying work left Waterston little time to pursue his studies so he joined the hydrography department of the Admiralty under
Francis Beaufort Sir Francis Beaufort ( ; 27 May 1774 – 17 December 1857) was an Irish hydrographer and naval officer who created the Beaufort cipher and the Beaufort scale. Early life Francis Beaufort was descended from French Protestant Hugu ...
. It was Beaufort who, in 1839, supported Waterston for the post of naval instructor for cadets of the
East India Company The East India Company (EIC) was an English, and later British, joint-stock company that was founded in 1600 and dissolved in 1874. It was formed to Indian Ocean trade, trade in the Indian Ocean region, initially with the East Indies (South A ...
in
Bombay Mumbai ( ; ), also known as Bombay ( ; its official name until 1995), is the capital city of the Indian States and union territories of India, state of Maharashtra. Mumbai is the financial centre, financial capital and the list of cities i ...
. The posting worked well for Waterston who was able to pursue his reading and research at the library of Grant College.


Kinetic theory

Building on his theory of the mechanical explanation of gravity, he was the first to develop the kinetic theory, independently of earlier and equally neglected partial accounts by
Daniel Bernoulli Daniel Bernoulli ( ; ; – 27 March 1782) was a Swiss people, Swiss-France, French mathematician and physicist and was one of the many prominent mathematicians in the Bernoulli family from Basel. He is particularly remembered for his applicati ...
and John Herapath. He published it, at his own expense, in his book ''Thoughts on the Mental Functions'' (1843). He correctly derived all the consequences of the premise that gas
pressure Pressure (symbol: ''p'' or ''P'') is the force applied perpendicular to the surface of an object per unit area over which that force is distributed. Gauge pressure (also spelled ''gage'' pressure)The preferred spelling varies by country and eve ...
is a function of the number of
molecule A molecule is a group of two or more atoms that are held together by Force, attractive forces known as chemical bonds; depending on context, the term may or may not include ions that satisfy this criterion. In quantum physics, organic chemi ...
s per unit
volume Volume is a measure of regions in three-dimensional space. It is often quantified numerically using SI derived units (such as the cubic metre and litre) or by various imperial or US customary units (such as the gallon, quart, cubic inch) ...
, ''N''; molecular
mass Mass is an Intrinsic and extrinsic properties, intrinsic property of a physical body, body. It was traditionally believed to be related to the physical quantity, quantity of matter in a body, until the discovery of the atom and particle physi ...
, ''M''; and molecular mean-squared
velocity Velocity is a measurement of speed in a certain direction of motion. It is a fundamental concept in kinematics, the branch of classical mechanics that describes the motion of physical objects. Velocity is a vector (geometry), vector Physical q ...
, \bar. He established the relationship: :P=NM\bar. He had been motivated to think of a ''wave theory of heat'' by analogy with the wave theory of light and some experiments by James Forbes and Macedonio Melloni on radiant heat. His statement that ''... in mixed media the mean square molecular velocity is inversely proportional to the specific weight of the molecules'' has been seen as the first statement of the
equipartition theorem In classical physics, classical statistical mechanics, the equipartition theorem relates the temperature of a system to its average energy, energies. The equipartition theorem is also known as the law of equipartition, equipartition of energy, ...
for translational motion. Waterston grasped that, while the
kinetic energy In physics, the kinetic energy of an object is the form of energy that it possesses due to its motion. In classical mechanics, the kinetic energy of a non-rotating object of mass ''m'' traveling at a speed ''v'' is \fracmv^2.Resnick, Rober ...
of an individual molecule with velocity v is \fracmv^2, heat energy is proportional to temperature T. That insight led him to derive the
ideal gas law The ideal gas law, also called the general gas equation, is the equation of state of a hypothetical ideal gas. It is a good approximation of the behavior of many gases under many conditions, although it has several limitations. It was first stat ...
: :\frac = \mbox. The publication made little impact, perhaps because of the title. He submitted his theory, under Beaufort's sponsorship, to the
Royal Society The Royal Society, formally The Royal Society of London for Improving Natural Knowledge, is a learned society and the United Kingdom's national academy of sciences. The society fulfils a number of roles: promoting science and its benefits, re ...
in 1845 but was rejected. Referee Sir John William Lubbock wrote ''The paper is nothing but nonsense.'' Unable to retrieve a copy of his paper (he had failed to make a copy for himself before submitting the paper to the Royal Society), he rewrote the work and sought to advertise it elsewhere, attracting little attention other than from
William John Macquorn Rankine William John Macquorn Rankine (; 5 July 1820 – 24 December 1872) was a Scottish mathematician and physicist. He was a founding contributor, with Rudolf Clausius and William Thomson (Lord Kelvin), to the science of thermodynamics, particularl ...
and
Hermann von Helmholtz Hermann Ludwig Ferdinand von Helmholtz (; ; 31 August 1821 – 8 September 1894; "von" since 1883) was a German physicist and physician who made significant contributions in several scientific fields, particularly hydrodynamic stability. The ...
through whom it may have influenced August Krönig. The theory gained acceptance only when it was proposed by
Rudolf Clausius Rudolf Julius Emanuel Clausius (; 2 January 1822 – 24 August 1888) was a German physicist and mathematician and is considered one of the central founding fathers of the science of thermodynamics. By his restatement of Sadi Carnot's principle ...
and
James Clerk Maxwell James Clerk Maxwell (13 June 1831 – 5 November 1879) was a Scottish physicist and mathematician who was responsible for the classical theory of electromagnetic radiation, which was the first theory to describe electricity, magnetism an ...
in the 1850s by which time Waterston's contribution had been forgotten.


Later life

He returned to Edinburgh in 1857 to pursue his own novel physical ideas but met with unyielding neglect and discouragement from the scientific establishment. Neglect was exacerbated by his own increasing reclusiveness and hostility to the learned societies. He worked on
acoustics Acoustics is a branch of physics that deals with the study of mechanical waves in gases, liquids, and solids including topics such as vibration, sound, ultrasound and infrasound. A scientist who works in the field of acoustics is an acoustician ...
,
astronomy Astronomy is a natural science that studies celestial objects and the phenomena that occur in the cosmos. It uses mathematics, physics, and chemistry in order to explain their origin and their overall evolution. Objects of interest includ ...
,
fluid mechanics Fluid mechanics is the branch of physics concerned with the mechanics of fluids (liquids, gases, and plasma (physics), plasmas) and the forces on them. Originally applied to water (hydromechanics), it found applications in a wide range of discipl ...
and
thermodynamics Thermodynamics is a branch of physics that deals with heat, Work (thermodynamics), work, and temperature, and their relation to energy, entropy, and the physical properties of matter and radiation. The behavior of these quantities is governed b ...
. In 1858, 27 years after he published his theory of the mechanical explanation of gravity and 15 years after publishing the kinetic theory, he continued to push for others to explore his ideas on gravity without much avail. He left his Edinburgh home on 18 June and drowned in a nearby canal, possibly falling into the canal due to heat stress from his astronomical observation activities.


Recognition after death

As discussed above, Waterston's paper submitted to the Royal Society was rejected. Some years after Waterston's death, Lord Rayleigh (Secretary of Royal Society at that time) managed to dig it out from the archives of the Royal Society. Finally, Waterston's paper was published in the Philosophical Transactions of the Royal Society in 1892. (Please see below.) Rayleigh felt that Waterston's case was not an aberration, but the norm:
"The history of aterston'spaper suggests that highly speculative investigations, especially by an unknown author, are best brought before the world through some other channel than a scientific society, which naturally hesitates to admit into its printed records matter of uncertain value. Perhaps one may go further, and say that a young author who believes himself capable of great things would usually do well to secure favourable recognition of the scientific world by work whose scope is limited, and whose value is easily judged, before embarking upon higher flights."


See also

* John Herapath, another contemporaneous English physicist who also worked on the kinetic theory, and whose work was also neglected at the time


References


Bibliography

*J.J. Waterston, "On the physics of media that are composed of free and perfectly elastic molecules in a state of motion", Philosophical Transactions of the Royal Society of London A, vol. 183 (1892), pp. 1–79. (Note: Waterston died in 1883 and his paper was published some years after his death.) *Haldane, J. S. (ed.) (1928) ''The Collected Scientific Papers of John James Waterston'', including a biography by Haldane. *Brush, S. G. (1957) "The development of the kinetic theory of gases: II. Waterston", ''Annals of Science'', vol. 13, pp275–282 *- (1961) "John James Waterston and the kinetic theory of gases", ''American Scientist'', vol. 49, pp202–214 * Daub, E. E. (1970) "Waterston, Rankine and Clausius on the kinetic theory of gases", ''Isis'' vol. 61, pp105–106


External links

*
Neglected Pioneers: John Herapath
{{DEFAULTSORT:Waterston, John James 1811 births 1883 deaths Scottish physicists Alumni of the University of Edinburgh