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John James Waterston (1811 – 18 June 1883) was a
Scottish Scottish usually refers to something of, from, or related to Scotland, including: *Scottish Gaelic, a Celtic Goidelic language of the Indo-European language family native to Scotland *Scottish English *Scottish national identity, the Scottish ide ...
physicist A physicist is a scientist who specializes in the field of physics, which encompasses the interactions of matter and energy at all length and time scales in the physical universe. Physicists generally are interested in the root or ultimate caus ...
and a neglected pioneer of the
kinetic theory of gases Kinetic (Ancient Greek: κίνησις “kinesis”, movement or to move) may refer to: * Kinetic theory, describing a gas as particles in random motion * Kinetic energy, the energy of an object that it possesses due to its motion Art and ente ...
.


Early life

Waterston's father, George, was an
Edinburgh Edinburgh ( ; gd, Dùn Èideann ) is the capital city of Scotland and one of its 32 council areas. Historically part of the county of Midlothian (interchangeably Edinburghshire before 1921), it is located in Lothian on the southern shore of t ...
sealing wax Sealing wax is a wax material of a seal which, after melting, hardens quickly (to paper, parchment, ribbons and wire, and other material) forming a bond that is difficult to separate without noticeable tampering. Wax is used to verify something s ...
manufacturer and stationer, a relative of the Sandeman family
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and his brother, George. John was born, the sixth of nine children, into a family alive with interests in literature, science and music. He was educated at Edinburgh High School before becoming apprenticed as a
civil engineer A civil engineer is a person who practices civil engineering – the application of planning, designing, constructing, maintaining, and operating infrastructure while protecting the public and environmental health, as well as improving existing ...
to Messrs. Grainger and Miller. His employers encouraged him to attend lectures at the
University of Edinburgh The University of Edinburgh ( sco, University o Edinburgh, gd, Oilthigh Dhùn Èideann; abbreviated as ''Edin.'' in post-nominals) is a public research university based in Edinburgh, Scotland. Granted a royal charter by King James VI in 158 ...
. He studied mathematics and
physics Physics is the natural science that studies matter, its fundamental constituents, its motion and behavior through space and time, and the related entities of energy and force. "Physical science is that department of knowledge which relat ...
under Sir John Leslie as well as attending lectures in chemistry,
anatomy Anatomy () is the branch of biology concerned with the study of the structure of organisms and their parts. Anatomy is a branch of natural science that deals with the structural organization of living things. It is an old science, having it ...
and surgery and becoming an active participant in the student literary society. At age nineteen, Waterston published a paper proposing a mechanical explanation of gravitation, accounting for ''
action at a distance In physics, action at a distance is the concept that an object can be affected without being physically touched (as in mechanical contact) by another object. That is, it is the non-local interaction of objects that are separated in space. Non- ...
'' in terms of colliding particles and discussing interactions between linear and rotational motion that would play a part in his later kinetic theory. Waterston moved to London at age twenty-one, where he worked as a railroad
surveyor Surveying or land surveying is the technique, profession, art, and science of determining the terrestrial two-dimensional or three-dimensional positions of points and the distances and angles between them. A land surveying professional is c ...
, becoming an associate of the
Institution of Civil Engineers The Institution of Civil Engineers (ICE) is an independent professional association for civil engineers and a charitable body in the United Kingdom. Based in London, ICE has over 92,000 members, of whom three-quarters are located in the UK, wh ...
and publishing a paper on a graphical method for planning earthworks. The travel and disruption associated with his surveying work left Waterston little time to pursue his studies so he joined the
hydrography Hydrography is the branch of applied sciences which deals with the measurement and description of the physical features of oceans, seas, coastal areas, lakes and rivers, as well as with the prediction of their change over time, for the primary p ...
department of the Admiralty under
Francis Beaufort Rear-Admiral Sir Francis Beaufort (; 27 May 1774 – 17 December 1857) was an Irish hydrographer, rear admiral of the Royal Navy, and creator of the Beaufort cipher and the Beaufort scale. Early life Francis Beaufort was descended ...
. It was Beaufort who, in 1839, supported Waterston for the post of naval instructor for cadets of the
East India Company The East India Company (EIC) was an English, and later British, joint-stock company founded in 1600 and dissolved in 1874. It was formed to trade in the Indian Ocean region, initially with the East Indies (the Indian subcontinent and Southea ...
in
Bombay Mumbai (, ; also known as Bombay — the official name until 1995) is the capital city of the Indian state of Maharashtra and the ''de facto'' financial centre of India. According to the United Nations, as of 2018, Mumbai is the second- ...
. The posting worked well for Waterston who was able to pursue his reading and research at the library of Grant College.


Kinetic theory

While in
India India, officially the Republic of India (Hindi: ), is a country in South Asia. It is the seventh-largest country by area, the second-most populous country, and the most populous democracy in the world. Bounded by the Indian Ocean on the so ...
, he first developed his kinetic theory, independently of earlier and equally neglected partial accounts by
Daniel Bernoulli Daniel Bernoulli FRS (; – 27 March 1782) was a Swiss mathematician and physicist and was one of the many prominent mathematicians in the Bernoulli family from Basel. He is particularly remembered for his applications of mathematics to mechan ...
and John Herapath. He published it, at his own expense, in his book ''Thoughts on the Mental Functions'' (1843). He correctly derived all the consequences of the premise that gas
pressure Pressure (symbol: ''p'' or ''P'') is the force applied perpendicular to the surface of an object per unit area over which that force is distributed. Gauge pressure (also spelled ''gage'' pressure)The preferred spelling varies by country and ...
is a
function Function or functionality may refer to: Computing * Function key, a type of key on computer keyboards * Function model, a structured representation of processes in a system * Function object or functor or functionoid, a concept of object-oriente ...
of the number of
molecule A molecule is a group of two or more atoms held together by attractive forces known as chemical bonds; depending on context, the term may or may not include ions which satisfy this criterion. In quantum physics, organic chemistry, and bioch ...
s per unit
volume Volume is a measure of occupied three-dimensional space. It is often quantified numerically using SI derived units (such as the cubic metre and litre) or by various imperial or US customary units (such as the gallon, quart, cubic inch). The def ...
, ''N''; molecular
mass Mass is an intrinsic property of a body. It was traditionally believed to be related to the quantity of matter in a physical body, until the discovery of the atom and particle physics. It was found that different atoms and different elementa ...
, ''M''; and molecular mean-squared
velocity Velocity is the directional speed of an object in motion as an indication of its rate of change in position as observed from a particular frame of reference and as measured by a particular standard of time (e.g. northbound). Velocity is a ...
, \bar. He established the relationship: :P=NM\bar. He had been motivated to think of a ''wave theory of heat'' by analogy with the
wave theory of light In physics, physical optics, or wave optics, is the branch of optics that studies interference, diffraction, polarization, and other phenomena for which the ray approximation of geometric optics is not valid. This usage tends not to include effect ...
and some experiments by James Forbes and
Macedonio Melloni Macedonio Melloni (11 April 1798 – 11 August 1854) was an Italian physicist, notable for demonstrating that radiant heat has similar physical properties to those of light. Life Born at Parma, in 1824 he was appointed professor at the local Uni ...
on
radiant heat Thermal radiation is electromagnetic radiation generated by the thermal motion of particles in matter. Thermal radiation is generated when heat from the movement of charges in the material (electrons and protons in common forms of matter) is ...
. His statement that ''... in mixed media the mean square molecular velocity is inversely proportional to the specific weight of the molecules'' has been seen as the first statement of the
equipartition theorem In classical statistical mechanics, the equipartition theorem relates the temperature of a system to its average energies. The equipartition theorem is also known as the law of equipartition, equipartition of energy, or simply equipartition. T ...
for translational motion. Waterston grasped that, while the
kinetic energy In physics, the kinetic energy of an object is the energy that it possesses due to its motion. It is defined as the work needed to accelerate a body of a given mass from rest to its stated velocity. Having gained this energy during its accel ...
of an individual molecule with velocity v is \fracmv^2, heat energy is proportional to temperature T. That insight led him to derive the
ideal gas law The ideal gas law, also called the general gas equation, is the equation of state of a hypothetical ideal gas. It is a good approximation of the behavior of many gases under many conditions, although it has several limitations. It was first stat ...
: :\frac = \mbox. The publication made little impact, perhaps because of the title. He submitted his theory, under Beaufort's sponsorship, to the
Royal Society The Royal Society, formally The Royal Society of London for Improving Natural Knowledge, is a learned society and the United Kingdom's national academy of sciences. The society fulfils a number of roles: promoting science and its benefits, re ...
in 1845 but was rejected. Referee Sir John William Lubbock wrote ''The paper is nothing but nonsense.'' Unable to retrieve a copy of his paper (he had failed to make a copy for himself before submitting the paper to the Royal Society), he rewrote the work and sought to advertise it elsewhere, attracting little attention other than from
William John Macquorn Rankine William John Macquorn Rankine (; 5 July 1820 – 24 December 1872) was a Scottish mechanical engineer who also contributed to civil engineering, physics and mathematics. He was a founding contributor, with Rudolf Clausius and William Thomson ...
and
Hermann von Helmholtz Hermann Ludwig Ferdinand von Helmholtz (31 August 1821 – 8 September 1894) was a German physicist and physician who made significant contributions in several scientific fields, particularly hydrodynamic stability. The Helmholtz Association, ...
through whom it may have influenced August Krönig. The theory gained acceptance only when it was proposed by
Rudolf Clausius Rudolf Julius Emanuel Clausius (; 2 January 1822 – 24 August 1888) was a German physicist and mathematician and is considered one of the central founding fathers of the science of thermodynamics. By his restatement of Sadi Carnot's principle ...
and
James Clerk Maxwell James Clerk Maxwell (13 June 1831 – 5 November 1879) was a Scottish mathematician and scientist responsible for the classical theory of electromagnetic radiation, which was the first theory to describe electricity, magnetism and light ...
in the 1850s by which time Waterston's contribution had been forgotten.


Later life

He returned to Edinburgh in 1857 to pursue his own novel physical ideas but met with unyielding neglect and discouragement from the scientific establishment. Neglect was exacerbated by his own increasing reclusiveness and hostility to the learned societies. He worked on
acoustics Acoustics is a branch of physics that deals with the study of mechanical waves in gases, liquids, and solids including topics such as vibration, sound, ultrasound and infrasound. A scientist who works in the field of acoustics is an acoustician ...
,
astronomy Astronomy () is a natural science that studies celestial objects and phenomena. It uses mathematics, physics, and chemistry in order to explain their origin and evolution. Objects of interest include planets, moons, stars, nebulae, galax ...
,
fluid mechanics Fluid mechanics is the branch of physics concerned with the mechanics of fluids (liquids, gases, and plasmas) and the forces on them. It has applications in a wide range of disciplines, including mechanical, aerospace, civil, chemical and bio ...
and
thermodynamics Thermodynamics is a branch of physics that deals with heat, work, and temperature, and their relation to energy, entropy, and the physical properties of matter and radiation. The behavior of these quantities is governed by the four laws of ther ...
. He left his Edinburgh home on 18 June and drowned in a nearby canal, possibly falling into the canal due to heat stress from his astronomical observation activities.


Recognition after death

As discussed above, Waterston's paper submitted to the Royal Society was rejected. Some years after Waterston's death,
Lord Rayleigh John William Strutt, 3rd Baron Rayleigh, (; 12 November 1842 – 30 June 1919) was an English mathematician and physicist who made extensive contributions to science. He spent all of his academic career at the University of Cambridge. Amo ...
(Secretary of Royal Society at that time) managed to dig it out from the archives of the Royal Society. Finally, Waterston's paper was published in the Philosophical Transactions of the Royal Society in 1892. (Please see below.) Rayleigh felt that Waterston's case was not an aberration, but the norm:
"The history of aterston'spaper suggests that highly speculative investigations, especially by an unknown author, are best brought before the world through some other channel than a scientific society, which naturally hesitates to admit into its printed records matter of uncertain value. Perhaps one may go further, and say that a young author who believes himself capable of great things would usually do well to secure favourable recognition of the scientific world by work whose scope is limited, and whose value is easily judged, before embarking upon higher flights."


See also

* John Herapath, another contemporaneous English physicist who also worked on the kinetic theory, and whose work was also neglected at the time


References


Bibliography

*J.J. Waterston, "On the physics of media that are composed of free and perfectly elastic molecules in a state of motion", Philosophical Transactions of the Royal Society of London A, vol. 183 (1892), pp. 1–79. (Note: Waterston died in 1883 and his paper was published some years after his death.) *Haldane, J. S. (ed.) (1928) ''The Collected Scientific Papers of John James Waterston'', including a biography by Haldane. *Brush, S. G. (1957) "The development of the kinetic theory of gases: II. Waterston", ''Annals of Science'', vol. 13, pp275–282 *- (1961) "John James Waterston and the kinetic theory of gases", ''American Scientist'', vol. 49, pp202–214 * Daub, E. E. (1970) "Waterston, Rankine and Clausius on the kinetic theory of gases", ''Isis'' vol. 61, pp105–106


External links

*
Neglected Pioneers: John Herapath
{{DEFAULTSORT:Waterston, John James 1811 births 1883 deaths Scottish physicists Alumni of the University of Edinburgh