Manufacturing
Indium phosphide can be prepared from the reaction of white phosphorus and indium iodide at 400 °C., also by direct combination of the purified elements at high temperature and pressure, or by thermal decomposition of a mixture of a trialkyl indium compound andUses
InP is used in high-power and high-frequency electronics because of its superior electron velocity with respect to the more common semiconductorsApplications
The application fields of InP splits up into three main areas. It is used as the basis for optoelectronic components, high-speed electronics, and photovoltaics There is still a vastly under-utilized, yet technically exciting zone in theOptoelectronic applications
InP based lasers and LEDs can emit light in the very broad range of 1200 nm up to 12 µm. This light is used for fibre based Telecom and Datacom applications in all areas of the digitalised world. Light is also used for sensing applications. On one hand there are spectroscopic applications, where a certain wavelength is needed to interact with matter to detect highly diluted gases for example. Optoelectronic terahertz is used in ultra-sensitive spectroscopic analysers, thickness measurements of polymers and for the detection of multilayer coatings in the automotive industry. On the other hand there is a huge benefit of specific InP lasers because they are eye safe. The radiation is absorbed in the vitreous body of the human eye and cannot harm the retina.Telecommunications/Data communications
Indium Phosphide (InP) is used to produce efficient lasers, sensitive photodetectors and modulators in the wavelength window typically used for telecommunications, i.e., 1550 nm wavelengths, as it is a direct bandgap III-V compound semiconductor material. The wavelength between about 1510 nm and 1600 nm has the lowest attenuation available on optical fibre (about 0.2 dB/km). InP is a commonly used material for the generation of laser signals and the detection and conversion of those signals back to electronic form. Wafer diameters range from 2-4 inches. Applications are: • Long-haul optical fibre connections over great distance up to 5000 km typically >10 Tbit/s • Metro ring access networks • Company networks and data center • Fibre to the home • Connections to wireless 3G, LTE and 5G base stations • Free space satellite communicationOptical sensing
Spectroscopic Sensing aiming environmental protection and identification of dangerous substances • A growing field is sensing based on the wavelength regime of InP. One example for Gas Spectroscopy is drive test equipment with real-time measurement of (CO, CO2, NOX r NO + NO2. • Another example is FT-IR-Spectrometer VERTEX with a terahertz source. The terahertz radiation is generated from the beating signal of 2 InP lasers and an InP antenna that transforms the optical signal to the terahertz regime. • Stand-Off detection of traces of explosive substances on surfaces, e.g. for safety applications on airports or crime scene investigation after assassination attempts. • Quick verification of traces of toxic substances in gases and liquids (including tap water) or surface contaminations down to the ppb level. • Spectroscopy for non-destructive product control of e.g. food (early detection of spoiled foodstuff). Researchers of Eindhoven University of Technology and MantiSpectra have already demonstrated the application of an integrated near-infrared spectral sensor for milk. In addition, it has been proven that this technology can also be applied to plastics and illicit drugs. • Spectroscopy for many novel applications, especially in air pollution control are being discussed today and implementations are on the way.LiDAR systems for the automotive sector and industry 4.0
Widely discussed in the LiDAR arena is the wavelength of the signal. While some players have opted for 830-to-940-nm wavelengths to take advantage of available optical components, companies (including Blackmore, Neptec, Aeye, and Luminar) are increasingly turning to longer wavelengths in the also-well-served 1550-nm wavelength band, as those wavelengths allow laser powers roughly 100 times higher to be employed without compromising public safety. Lasers with emission wavelengths longer than ≈ 1.4 μm are often called “eye-safe” because light in that wavelength range is strongly absorbed in the eye's cornea, lens and vitreous body and therefore cannot damage the sensitive retina). • LiDAR-based sensor technology can provide a high level of object identification and classification with three-dimensional (3D) imaging techniques. • The automotive industry will adopt a chip-based, low cost solid state LiDAR sensor technology instead of large, expensive, mechanical LiDAR systems in the future. • For the most advanced chip-based LiDAR systems, InP will play an important role and will enable autonomous driving. (Report: Blistering Growth for Automotive Lidar, Stewart Wills). The longer eye safe wavelength is also more appropriate dealing with real world conditions like dust, fog and rain.High-speed electronics
Today's semiconductor technology allows the creation and detection of very high frequencies of 100 GHz and higher. Such components find their applications in wireless high-speed data communication (directional radio), radars (compact, energy-efficient and highly resolving), and radiometric sensing e. g. for weather- or atmospheric observations. InP is also used to realize high-speed microelectronics and such semiconductor devices are the fastest devices available today. Typically, microelectronics on InP is based on High-electron-mobility transistors (HEMT) or on Heterojunction bipolar transistors (HBT). The sizes and volumes of both transistors based on InP material is very small: 0.1 µm x 10 µm x 1 µm. Typical substrate thicknesses are < 100 µm. These transistors are assembled into circuits and modules for the following applications: • Security scanning systems: Imaging systems for airport security imaging and scanners for civil security applications • Wireless communications: High-speed 5G wireless communications will explore InP technology due to its superior performance. Such systems operate at frequencies beyond 100 GHz in order to support high data rates • Biomedical applications: Millimeter-wave and THz spectrometers are employed for non-invasive diagnostics in medical applications from cancer tissue identification, diabetes detection, to medical diagnostics using human exhaled air. • Non-destructive testing: Industrial applications employ scanning systems for quality control in e.g. automotive paint thickness applications and defects in composite materials in aerospace • Robotics: Robotic vision is essentially based on high resolution imaging radar systems at millimetre-waves • Radiometric sensing: Almost all components and pollutions in the atmosphere show characteristic absorptions/emissions (fingerprints) in the microwave range. InP allows to fabricate small, lightweight and mobile systems to identify such substances.Photovoltaic applications
Photovoltaic cells with highest efficiencies of up to 46% (Press Release, Fraunhofer ISE, 1. December 2014) implement InP substrates to achieve an optimal bandgap combination to efficiently convert solar radiation into electrical energy. Today, only InP substrates achieve the lattice constant to grow the required low bandgap materials with high crystalline quality. Research groups all over the world are looking for replacements due to the high costs of these materials. However, up to now all other options yield lower material qualities and hence lower conversion efficiencies. Further research focusses on the re-use of the InP substrate as template for the production of further solar cells. Also today’s state-of-the-art high-efficiency solar cells for concentrator photovoltaics (CPV) and for space applications use (Ga)InP and other III-V compounds to achieve the required bandgap combinations. Other technologies, such as Si solar cells, provide only half the power than III-V cells and furthermore show much stronger degradation in the harsh space environment. Finally, Si-based solar cells are also much heavier than III-V solar cells and yield to a higher amount of space debris. One way to significantly increase conversion efficiency also in terrestrial PV systems is the use of similar III-V solar cells in CPV systems where only about one-tenth of a percent of the area is covered by high-efficiency III-V solar cells.Chemistry
Indium phosphide also has one of the longest-lived optical phonons of any compound with theQuaternary compounds
Indium phosphide is sometimes alloyed with indium antimonide and Indium arsenide to create a quaternary alloy with a range of band gaps that depend on the different concentration ratios of its components (InP, InAs and InSb), such quaternary alloys was under extensive theoretical studies to study the effect of pressure and temperature on its properties.References
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