Ironstone is a
sedimentary rock
Sedimentary rocks are types of rock (geology), rock formed by the cementation (geology), cementation of sediments—i.e. particles made of minerals (geological detritus) or organic matter (biological detritus)—that have been accumulated or de ...
, either deposited directly as a ferruginous
sediment
Sediment is a solid material that is transported to a new location where it is deposited. It occurs naturally and, through the processes of weathering and erosion, is broken down and subsequently sediment transport, transported by the action of ...
or created by chemical replacement, that contains a substantial proportion of an
iron ore
Iron ores are rocks and minerals from which metallic iron can be economically extracted. The ores are usually rich in iron oxides and vary in color from dark grey, bright yellow, or deep purple to rusty red. The iron is usually found in the f ...
compound from which
iron
Iron is a chemical element; it has symbol Fe () and atomic number 26. It is a metal that belongs to the first transition series and group 8 of the periodic table. It is, by mass, the most common element on Earth, forming much of Earth's o ...
(Fe) can be
smelted commercially.
Not to be confused with native or
telluric iron, which is very rare and found in metallic form, the term ''ironstone'' is customarily restricted to hard, coarsely banded, non-banded, and non-
chert
Chert () is a hard, fine-grained sedimentary rock composed of microcrystalline or cryptocrystalline quartz, the mineral form of silicon dioxide (SiO2). Chert is characteristically of biological origin, but may also occur inorganically as a prec ...
y sedimentary rocks of
post-Precambrian age. The
Precambrian
The Precambrian ( ; or pre-Cambrian, sometimes abbreviated pC, or Cryptozoic) is the earliest part of Earth's history, set before the current Phanerozoic Eon. The Precambrian is so named because it preceded the Cambrian, the first period of t ...
deposits, which have a different origin, are generally known as
banded iron formation
Banded iron formations (BIFs; also called banded ironstone formations) are distinctive units of sedimentary rock consisting of alternating layers of iron oxides and iron-poor chert. They can be up to several hundred meters in thickness and e ...
s. The iron minerals comprising ironstones can consist either of oxides, i.e.
limonite
Limonite () is an iron ore consisting of a mixture of hydrated iron(III) oxide-hydroxides in varying composition. The generic formula is frequently written as , although this is not entirely accurate as the ratio of oxide to hydroxide can vary qu ...
,
hematite
Hematite (), also spelled as haematite, is a common iron oxide compound with the formula, Fe2O3 and is widely found in rocks and soils. Hematite crystals belong to the rhombohedral lattice system which is designated the alpha polymorph of . ...
, and
magnetite
Magnetite is a mineral and one of the main iron ores, with the chemical formula . It is one of the iron oxide, oxides of iron, and is ferrimagnetism, ferrimagnetic; it is attracted to a magnet and can be magnetization, magnetized to become a ...
; carbonates, i.e.
siderite
Siderite is a mineral composed of iron(II) carbonate (FeCO3). Its name comes from the Ancient Greek word (), meaning "iron". A valuable iron ore, it consists of 48% iron and lacks sulfur and phosphorus. Zinc, magnesium, and manganese commonly ...
; silicates, i.e.
chamosite
Chamosite is the Fe2+end member of the chlorite group. A hydrous aluminium silicate of iron, which is produced in an environment of low-to-moderate-grade metamorphosed iron deposits, as gray or black crystals in oolitic iron ore. Like other chl ...
; or some combination of these minerals.
[U.S. Bureau of Mines Staff (1996) ''Dictionary of Mining, Mineral, & Related Terms.'' Report SP-96-1, U.S. Department of Interior, U.S. Bureau of Mines, Washington, D.C.][Neuendorf, K. K. E., J. P. Mehl Jr., and J. A. Jackson, J. A., eds. (2005) ''Glossary of Geology'' (5th ed.). Alexandria, Virginia, American Geological Institute. 779 pp. ]
Description
Freshly cleaved ironstone is usually grey. The brown external appearance is due to
oxidation
Redox ( , , reduction–oxidation or oxidation–reduction) is a type of chemical reaction in which the oxidation states of the reactants change. Oxidation is the loss of electrons or an increase in the oxidation state, while reduction is ...
of its surface.
Ironstone, being a sedimentary rock is not always
homogeneous
Homogeneity and heterogeneity are concepts relating to the uniformity of a substance, process or image. A homogeneous feature is uniform in composition or character (i.e., color, shape, size, weight, height, distribution, texture, language, i ...
, and can be found in a red-and-black banded form called
tiger iron, sometimes used for
jewelry
Jewellery (or jewelry in American English) consists of decorative items worn for personal adornment such as brooches, ring (jewellery), rings, necklaces, earrings, pendants, bracelets, and cufflinks. Jewellery may be attached to the body or the ...
purposes.
Sometimes ironstone hosts
concretion
A concretion is a hard and compact mass formed by the precipitation of mineral cement within the spaces between particles, and is found in sedimentary rock or soil. Concretions are often ovoid or spherical in shape, although irregular shapes a ...
s or
opal
Opal is a hydrated amorphous form of silicon dioxide, silica (SiO2·''n''H2O); its water content may range from 3% to 21% by weight, but is usually between 6% and 10%. Due to the amorphous (chemical) physical structure, it is classified as a ...
gems.
Occurrence
Ironstone occurs in a variety of forms. The various forms of ironstone include siderite nodules; deeply weathered
saprolite
Saprolite is a chemically weathered rock. Saprolites form in the lower zones of soil profiles and represent deep weathering of the bedrock surface. In most outcrops, its color comes from ferric compounds. Deeply weathered profiles are widespread ...
, i.e. (
laterite
Laterite is a soil type rich in iron and aluminium and is commonly considered to have formed in hot and wet tropical areas. Nearly all laterites are of rusty-red coloration, because of high iron oxide content. They develop by intensive and prolo ...
); and
ooidal ironstone.
Uses
Ironstone as a source of iron
Ironstone, although widespread, is a limited source of iron. Historically, most British iron originated from ironstone, but it is now rarely used for this purpose because it is far too limited in quantity to be an economic source of iron ore.
Ceramics
Ironstone's oxide impurities render it useless as a component in
ceramic
A ceramic is any of the various hard, brittle, heat-resistant, and corrosion-resistant materials made by shaping and then firing an inorganic, nonmetallic material, such as clay, at a high temperature. Common examples are earthenware, porcela ...
s: the "
ironstone china
Ironstone china, ironstone ware or most commonly just ironstone, is a type of vitreous pottery first made in the United Kingdom in the early 19th century. It is often classed as earthenware although in appearance and properties it is similar to ...
" of Staffordshire and American manufacture, a fine, white, high-fired vitreous