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Hemimorphite is the
chemical compound A chemical compound is a chemical substance composed of many identical molecules (or molecular entities) containing atoms from more than one chemical element held together by chemical bonds. A molecule consisting of atoms of only one element ...
Zn4( Si2O7)( OH)2 ·H2O, a component of
mineral In geology and mineralogy, a mineral or mineral species is, broadly speaking, a solid chemical compound with a fairly well-defined chemical composition and a specific crystal structure that occurs naturally in pure form.John P. Rafferty, ed. (2 ...
calamine Calamine, also known as calamine lotion, is a medication used to treat mild itchiness. This includes from sunburn, insect bites, poison ivy, poison oak, and other mild skin conditions. It may also help dry out skin irritation. It is applie ...
. It is a
silicate mineral Silicate minerals are rock-forming minerals made up of silicate groups. They are the largest and most important class of minerals and make up approximately 90 percent of Earth's crust. In mineralogy, silica (silicon dioxide, ) is usually consid ...
which, together with
smithsonite Smithsonite, also known as zinc spar, is the mineral form of zinc carbonate ( Zn CO3). Historically, smithsonite was identified with hemimorphite before it was realized that they were two different minerals. The two minerals are very similar in a ...
(ZnCO3), has been historically mined from the upper parts of
zinc Zinc is a chemical element with the symbol Zn and atomic number 30. Zinc is a slightly brittle metal at room temperature and has a shiny-greyish appearance when oxidation is removed. It is the first element in group 12 (IIB) of the periodi ...
and
lead Lead is a chemical element with the symbol Pb (from the Latin ) and atomic number 82. It is a heavy metal that is denser than most common materials. Lead is soft and malleable, and also has a relatively low melting point. When freshly cu ...
ore Ore is natural rock or sediment that contains one or more valuable minerals, typically containing metals, that can be mined, treated and sold at a profit.Encyclopædia Britannica. "Ore". Encyclopædia Britannica Online. Retrieved 7 Apr ...
s. Both compounds were originally believed to be the same mineral and classified as
calamine Calamine, also known as calamine lotion, is a medication used to treat mild itchiness. This includes from sunburn, insect bites, poison ivy, poison oak, and other mild skin conditions. It may also help dry out skin irritation. It is applie ...
. In the second half of the 18th century, it was discovered that these two different compounds were both present in calamine. They closely resemble one another. The silicate was the rarer of the two and was named ''hemimorphite'' because of the hemimorph development of its
crystal A crystal or crystalline solid is a solid material whose constituents (such as atoms, molecules, or ions) are arranged in a highly ordered microscopic structure, forming a crystal lattice that extends in all directions. In addition, macro ...
s. This unusual form, which is typical of only a few minerals, means that the crystals are terminated by dissimilar faces. Hemimorphite most commonly forms crystalline crusts and layers, also massive, granular, rounded and reniform aggregates, concentrically striated, or finely needle-shaped, fibrous or stalactitic, and rarely fan-shaped clusters of crystals. Some specimens show strong green
fluorescence Fluorescence is the emission of light by a substance that has absorbed light or other electromagnetic radiation. It is a form of luminescence. In most cases, the emitted light has a longer wavelength, and therefore a lower photon energy, tha ...
in shortwave
ultraviolet Ultraviolet (UV) is a form of electromagnetic radiation with wavelength from 10 nm (with a corresponding frequency around 30  PHz) to 400 nm (750  THz), shorter than that of visible light, but longer than X-rays. UV radiation ...
light (253.7 nm) and weak light pink fluorescence in longwave UV.


Occurrence

Hemimorphite most frequently occurs as the product of the
oxidation Redox (reduction–oxidation, , ) is a type of chemical reaction in which the oxidation states of substrate change. Oxidation is the loss of electrons or an increase in the oxidation state, while reduction is the gain of electrons or a ...
of the upper parts of sphalerite bearing ore bodies, accompanied by other secondary minerals which form the so-called ''iron cap'' or ''
gossan Gossan (eiserner hut or eisenhut) is intensely oxidized, weathered or decomposed rock, usually the upper and exposed part of an ore deposit or mineral vein. In the ''classic'' gossan or iron cap all that remains is iron oxides and quartz, often ...
''. Hemimorphite is an important
ore Ore is natural rock or sediment that contains one or more valuable minerals, typically containing metals, that can be mined, treated and sold at a profit.Encyclopædia Britannica. "Ore". Encyclopædia Britannica Online. Retrieved 7 Apr ...
of zinc and contains up to 54.2% of the metal, together with silicon, oxygen and hydrogen. The crystals are blunt at one end and sharp at the other. The regions on the
Belgian Belgian may refer to: * Something of, or related to, Belgium * Belgians, people from Belgium or of Belgian descent * Languages of Belgium, languages spoken in Belgium, such as Dutch, French, and German *Ancient Belgian language, an extinct languag ...
- German border are well known for their deposits of hemimorphite of metasomatic origin, especially
Vieille Montagne Vieille Montagne was a zinc mine in Kelmis (La Calamine), a town in Belgium between Liège and Aachen. The mine's name is French for "old mountain", and this is also reflected in its German name, (earlier, ). The mine was once a bone of contenti ...
in
Belgium Belgium, ; french: Belgique ; german: Belgien officially the Kingdom of Belgium, is a country in Northwestern Europe. The country is bordered by the Netherlands to the north, Germany to the east, Luxembourg to the southeast, France to th ...
and Aachen in Germany. Other deposits are in
Tarnowskie Góry Tarnowskie Góry (German: ''Tarnowitz''; szl, Tarnowske Gōry) is a town in Silesia, southern Poland, located in the Silesian Highlands near Katowice. On the south it borders the Upper Silesian Metropolitan Union, a megalopolis, the greater Si ...
area in
Upper Silesia Upper Silesia ( pl, Górny Śląsk; szl, Gůrny Ślůnsk, Gōrny Ślōnsk; cs, Horní Slezsko; german: Oberschlesien; Silesian German: ; la, Silesia Superior) is the southeastern part of the historical and geographical region of Silesia, locate ...
,
Poland Poland, officially the Republic of Poland, is a country in Central Europe. It is divided into 16 administrative provinces called voivodeships, covering an area of . Poland has a population of over 38 million and is the fifth-most populou ...
; near
Phoenixville Phoenixville is a borough in Chester County, Pennsylvania, United States. It is located northwest of Philadelphia at the junction of French Creek and the Schuylkill River. It is in the Philadelphia metropolitan area. The population is 18,616 ...
,
Pennsylvania Pennsylvania (; ( Pennsylvania Dutch: )), officially the Commonwealth of Pennsylvania, is a state spanning the Mid-Atlantic, Northeastern, Appalachian, and Great Lakes regions of the United States. It borders Delaware to its southeast, ...
; the
Missouri Missouri is a state in the Midwestern region of the United States. Ranking 21st in land area, it is bordered by eight states (tied for the most with Tennessee): Iowa to the north, Illinois, Kentucky and Tennessee to the east, Arkansas t ...
lead-zinc district; Elkhorn,
Montana Montana () is a state in the Mountain West division of the Western United States. It is bordered by Idaho to the west, North Dakota and South Dakota to the east, Wyoming to the south, and the Canadian provinces of Alberta, British Columb ...
;
Leadville The City of Leadville is a statutory city that is the county seat, the most populous community, and the only incorporated municipality in Lake County, Colorado, United States. The city population was 2,602 at the 2010 census and an estimated ...
,
Colorado Colorado (, other variants) is a state in the Mountain states, Mountain West subregion of the Western United States. It encompasses most of the Southern Rocky Mountains, as well as the northeastern portion of the Colorado Plateau and the wes ...
; and
Organ Mountains The Organ Mountains (also known as La Sierra de los Órganos) are a rugged mountain range in southern New Mexico in the Southwestern United States. Organ Mountains–Desert Peaks National Monument was declared a national monument on May 21, 2 ...
,
New Mexico ) , population_demonym = New Mexican ( es, Neomexicano, Neomejicano, Nuevo Mexicano) , seat = Santa Fe , LargestCity = Albuquerque , LargestMetro = Tiguex , OfficialLang = None , Languages = English, Spanish ( New Mexican), Navajo, Ke ...
in the United States; and in several localities in
North Africa North Africa, or Northern Africa is a region encompassing the northern portion of the African continent. There is no singularly accepted scope for the region, and it is sometimes defined as stretching from the Atlantic shores of Mauritania in ...
. Further hemimorphite occurrences are the Padaeng deposit near Mae Sod in western
Thailand Thailand ( ), historically known as Siam () and officially the Kingdom of Thailand, is a country in Southeast Asia, located at the centre of the Indochinese Peninsula, spanning , with a population of almost 70 million. The country is b ...
;
Sardinia Sardinia ( ; it, Sardegna, label=Italian, Corsican and Tabarchino ; sc, Sardigna , sdc, Sardhigna; french: Sardaigne; sdn, Saldigna; ca, Sardenya, label=Algherese and Catalan) is the second-largest island in the Mediterranean Sea, after ...
;
Nerchinsk Nerchinsk ( rus, Не́рчинск; bua, Нэршүү, ''Nershüü''; mn, Нэрчүү, ''Nerchüü''; mnc, m=, v=Nibcu, a=Nibqu; zh, t=涅尔琴斯克(尼布楚), p=Niè'ěrqínsīkè (Níbùchǔ)) is a town and the administrative ce ...
,
Siberia Siberia ( ; rus, Сибирь, r=Sibir', p=sʲɪˈbʲirʲ, a=Ru-Сибирь.ogg) is an extensive region, geographical region, constituting all of North Asia, from the Ural Mountains in the west to the Pacific Ocean in the east. It has been a ...
; Cave del Predil,
Italy Italy ( it, Italia ), officially the Italian Republic, ) or the Republic of Italy, is a country in Southern Europe. It is located in the middle of the Mediterranean Sea, and its territory largely coincides with the homonymous geographical ...
; Bleiberg, Carinthia,
Austria Austria, , bar, Östareich officially the Republic of Austria, is a country in the southern part of Central Europe, lying in the Eastern Alps. It is a federation of nine states, one of which is the capital, Vienna, the most populous ...
; Matlock,
Derbyshire Derbyshire ( ) is a ceremonial county in the East Midlands, England. It includes much of the Peak District National Park, the southern end of the Pennine range of hills and part of the National Forest. It borders Greater Manchester to the nor ...
, England.


References


Further reading

*Hurlbut, Cornelius S.; Klein, Cornelis, 1985, Manual of Mineralogy, 20th ed., *Boni, M., Gilg, H.A., Aversa, G., and Balassone, G., 2003, The "Calamine" of southwest Sardinia: Geology, mineralogy, and stable isotope geochemistry of supergene Zn mineralization: Economic Geology, v. 98, p. 731-748. *Reynolds, N.A., Chisnall, T.W., Kaewsang, K., Keesaneyabutr, C., and Taksavasu, T., 2003, The Padaeng supergene nonsulfide zinc deposit, Mae Sod, Thailand: Economic Geology, v. 98, p. 773-785.
Mineral galleries
{{Authority control Sorosilicates Zinc minerals Orthorhombic minerals Minerals in space group 44 Minerals described in 1853