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Thermodynamic heat pump cycles or refrigeration cycles are the conceptual and
mathematical model A mathematical model is a description of a system using mathematical concepts and language. The process of developing a mathematical model is termed mathematical modeling. Mathematical models are used in the natural sciences (such as physics, ...
s for
heat pump A heat pump is a device that can heat a building (or part of a building) by transferring thermal energy from the outside using a refrigeration cycle. Many heat pumps can also operate in the opposite direction, cooling the building by removing ...
,
air conditioning Air conditioning, often abbreviated as A/C or AC, is the process of removing heat from an enclosed space to achieve a more comfortable interior environment (sometimes referred to as 'comfort cooling') and in some cases also strictly controlling ...
and
refrigeration The term refrigeration refers to the process of removing heat from an enclosed space or substance for the purpose of lowering the temperature.International Dictionary of Refrigeration, http://dictionary.iifiir.org/search.phpASHRAE Terminology, ht ...
systems. A heat pump is a mechanical system that allows for the transmission of
heat In thermodynamics, heat is defined as the form of energy crossing the boundary of a thermodynamic system by virtue of a temperature difference across the boundary. A thermodynamic system does not ''contain'' heat. Nevertheless, the term is ...
from one location (the "source") at a lower temperature to another location (the "sink" or "heat sink") at a higher temperature. Thus a heat pump may be thought of as a "heater" if the objective is to warm the heat sink (as when warming the inside of a home on a cold day), or a "refrigerator" or “cooler” if the objective is to cool the heat source (as in the normal operation of a freezer). In either case, the operating principles are similar. Heat is moved from a cold place to a warm place.


Thermodynamic cycles

According to the
second law of thermodynamics The second law of thermodynamics is a physical law based on universal experience concerning heat and energy interconversions. One simple statement of the law is that heat always moves from hotter objects to colder objects (or "downhill"), unle ...
, heat cannot spontaneously flow from a colder location to a hotter area;
work Work may refer to: * Work (human activity), intentional activity people perform to support themselves, others, or the community ** Manual labour, physical work done by humans ** House work, housework, or homemaking ** Working animal, an animal t ...
is required to achieve this. An air conditioner requires work to cool a living space, moving heat from the interior being cooled (the heat source) to the outdoors (the heat sink). Similarly, a refrigerator moves heat from inside the cold icebox (the heat source) to the warmer room-temperature air of the kitchen (the heat sink). The operating principle of an ideal
heat engine In thermodynamics and engineering, a heat engine is a system that converts heat to mechanical energy, which can then be used to do mechanical work. It does this by bringing a working substance from a higher state temperature to a lower stat ...
was described mathematically using the
Carnot cycle A Carnot cycle is an ideal thermodynamic cycle proposed by French physicist Sadi Carnot in 1824 and expanded upon by others in the 1830s and 1840s. By Carnot's theorem, it provides an upper limit on the efficiency of any classical thermodyna ...
by Sadi Carnot in 1824. An ideal refrigerator or heat pump can be thought of as an ideal
heat engine In thermodynamics and engineering, a heat engine is a system that converts heat to mechanical energy, which can then be used to do mechanical work. It does this by bringing a working substance from a higher state temperature to a lower stat ...
that is operating in a reverse Carnot cycle. Heat pump cycles and refrigeration cycles can be classified as ''vapor compression'', ''vapor absorption'', ''gas cycle'', or ''Stirling cycle'' types.


Vapor-compression cycle

The vapor-compression cycle is used by many refrigeration,
air conditioning Air conditioning, often abbreviated as A/C or AC, is the process of removing heat from an enclosed space to achieve a more comfortable interior environment (sometimes referred to as 'comfort cooling') and in some cases also strictly controlling ...
and other cooling applications and also within
heat pump A heat pump is a device that can heat a building (or part of a building) by transferring thermal energy from the outside using a refrigeration cycle. Many heat pumps can also operate in the opposite direction, cooling the building by removing ...
for heating applications. There are two heat exchangers, one being the condenser, which is hotter and releases heat, and the other being the evaporator, which is colder and accepts heat. For applications which need to operate in both heating and cooling mode, a
reversing valve A reversing valve is a type of valve and is a component in a heat pump, that changes the direction of refrigerant flow. By reversing the flow of refrigerant, the heat pump refrigeration cycle is changed from cooling to heating or vice versa. This ...
is used to switch the roles of these two heat exchangers. At the start of the thermodynamic cycle the
refrigerant A refrigerant is a working fluid used in the refrigeration cycle of air conditioning systems and heat pumps where in most cases they undergo a repeated phase transition from a liquid to a gas and back again. Refrigerants are heavily regulated ...
enters the
compressor A compressor is a mechanical device that increases the pressure of a gas by reducing its volume. An air compressor is a specific type of gas compressor. Compressors are similar to pumps: both increase the pressure on a fluid and both can tr ...
as a low pressure and low temperature vapor. Then the pressure is increased and the refrigerant leaves as a higher temperature and higher pressure superheated gas. This hot pressurised gas then passes through the condenser where it releases heat to the surroundings as it cools and condenses completely. The cooler high-pressure liquid next passes through the expansion valve (throttle valve) which reduces the pressure abruptly causing the temperature to drop dramatically. The cold low pressure mixture of liquid and vapor next travels through the evaporator where it vaporizes completely as it accepts heat from the surroundings before returning to the compressor as a low pressure low temperature gas to start the cycle again. Some simpler applications with fixed operating temperatures, such as a domestic
refrigerator A refrigerator, colloquially fridge, is a commercial and home appliance consisting of a thermally insulated compartment and a heat pump (mechanical, electronic or chemical) that transfers heat from its inside to its external environment so th ...
, may use a fixed speed compressor and fixed aperture expansion valve. Applications that need to operate at a high
coefficient of performance The coefficient of performance or COP (sometimes CP or CoP) of a heat pump, refrigerator or air conditioning system is a ratio of useful heating or cooling provided to work (energy) required. Higher COPs equate to higher efficiency, lower energy ( ...
in very varied conditions, as is the case with
heat pump A heat pump is a device that can heat a building (or part of a building) by transferring thermal energy from the outside using a refrigeration cycle. Many heat pumps can also operate in the opposite direction, cooling the building by removing ...
s where external temperatures and internal heat demand vary considerably through the seasons, typically use a variable speed inverter compressor and an adjustable expansion valve to control the pressures of the cycle more accurately. The above discussion is based on the ideal vapor-compression refrigeration cycle, and does not take into account real-world effects like frictional pressure drop in the system, slight thermodynamic irreversibility during the compression of the refrigerant vapor, or non-ideal gas behavior (if any).


Vapor absorption cycle

In the early years of the twentieth century, the vapor absorption cycle using water-ammonia systems was popular and widely used but, after the development of the vapor compression cycle, it lost much of its importance because of its low
coefficient of performance The coefficient of performance or COP (sometimes CP or CoP) of a heat pump, refrigerator or air conditioning system is a ratio of useful heating or cooling provided to work (energy) required. Higher COPs equate to higher efficiency, lower energy ( ...
(about one fifth of that of the vapor compression cycle). Nowadays, the vapor absorption cycle is used only where heat is more readily available than electricity, such as industrial
waste heat Waste heat is heat that is produced by a machine, or other process that uses energy, as a byproduct of doing work. All such processes give off some waste heat as a fundamental result of the laws of thermodynamics. Waste heat has lower utilit ...
,
solar thermal energy Solar thermal energy (STE) is a form of energy and a technology for harnessing solar energy to generate thermal energy for use in industry, and in the residential and commercial sectors. Solar thermal collectors are classified by the United St ...
by
solar collectors Solar collector may refer to: * Solar thermal collector, a solar collector that collects heat by absorbing sunlight * Solar Collector (sculpture), a 2008 interactive light art installation in Cambridge, Ontario, Canada See also *Concentrating s ...
, or off-the-grid refrigeration in
recreational vehicle A recreational vehicle, often abbreviated as RV, is a motor vehicle or trailer that includes living quarters designed for accommodation. Types of RVs include motorhomes, campervans, coaches, caravans (also known as travel trailers and campe ...
s. The absorption cycle is similar to the compression cycle, but depends on the partial pressure of the refrigerant vapor. In the absorption system, the compressor is replaced by an absorber and a generator. The absorber dissolves the refrigerant in a suitable liquid (dilute solution) and therefore the dilute solution becomes a strong solution. In the generator, on heat addition, the temperature increases and with it the partial pressure of the refrigerant vapor released from the strong solution. However, the generator requires a heat source, which would consumes energy unless waste heat is used. In an absorption refrigerator, a suitable combination of refrigerant and absorbent is used. The most common combinations are
ammonia Ammonia is an inorganic compound of nitrogen and hydrogen with the formula . A stable binary hydride, and the simplest pnictogen hydride, ammonia is a colourless gas with a distinct pungent smell. Biologically, it is a common nitrogenous ...
(refrigerant) and water (absorbent), and water (refrigerant) and
lithium bromide Lithium bromide (LiBr) is a chemical compound of lithium and bromine. Its extreme hygroscopic character makes LiBr useful as a desiccant in certain air conditioning systems.Wietelmann, Ulrich and Bauer, Richard J. (2005) "Lithium and Lithium Compo ...
(absorbent). Absorption refrigeration systems can be powered by
combustion Combustion, or burning, is a high-temperature exothermic redox chemical reaction between a fuel (the reductant) and an oxidant, usually atmospheric oxygen, that produces oxidized, often gaseous products, in a mixture termed as smoke. Combus ...
of
fossil fuels A fossil fuel is a hydrocarbon-containing material formed naturally in the Earth's crust from the remains of dead plants and animals that is extracted and burned as a fuel. The main fossil fuels are coal, oil, and natural gas. Fossil fuels ma ...
(e.g.,
coal Coal is a combustible black or brownish-black sedimentary rock, formed as rock strata called coal seams. Coal is mostly carbon with variable amounts of other elements, chiefly hydrogen, sulfur, oxygen, and nitrogen. Coal is formed when ...
,
oil An oil is any nonpolar chemical substance that is composed primarily of hydrocarbons and is hydrophobic (does not mix with water) & lipophilic (mixes with other oils). Oils are usually flammable and surface active. Most oils are unsaturated ...
,
natural gas Natural gas (also called fossil gas or simply gas) is a naturally occurring mixture of gaseous hydrocarbons consisting primarily of methane in addition to various smaller amounts of other higher alkanes. Low levels of trace gases like carbon d ...
, etc.) or
renewable energy Renewable energy is energy that is collected from renewable resources that are naturally replenished on a human timescale. It includes sources such as sunlight, wind, the movement of water, and geothermal heat. Although most renewable energy ...
(e.g., waste-heat recovery,
biomass Biomass is plant-based material used as a fuel for heat or electricity production. It can be in the form of wood, wood residues, energy crops, agricultural residues, and waste from industry, farms, and households. Some people use the terms bio ...
combustion, or
solar energy Solar energy is radiant light and heat from the Sun that is harnessed using a range of technologies such as solar power to generate electricity, solar thermal energy (including solar water heating), and solar architecture. It is an essen ...
).


Gas cycle

When the
working fluid For fluid power, a working fluid is a gas or liquid that primarily transfers force, motion, or mechanical energy. In hydraulics, water or hydraulic fluid transfers force between hydraulic components such as hydraulic pumps, hydraulic cylinders, a ...
is a gas that is compressed and expanded but does not change phase, the refrigeration cycle is called a ''gas cycle''.
Air The atmosphere of Earth is the layer of gases, known collectively as air, retained by Earth's gravity that surrounds the planet and forms its planetary atmosphere. The atmosphere of Earth protects life on Earth by creating pressure allowing f ...
is most often this working fluid. As there is no condensation and evaporation intended in a gas cycle, components corresponding to the condenser and evaporator in a vapor compression cycle are the hot and cold gas-to-gas
heat exchanger A heat exchanger is a system used to transfer heat between a source and a working fluid. Heat exchangers are used in both cooling and heating processes. The fluids may be separated by a solid wall to prevent mixing or they may be in direct conta ...
s. For given extreme temperatures, a gas cycle may be less efficient than a vapor compression cycle because the gas cycle works on the reverse
Brayton cycle The Brayton cycle is a thermodynamic cycle that describes the operation of certain heat engines that have air or some other gas as their working fluid. The original Brayton engines used a piston compressor and piston expander, but modern gas tu ...
instead of the reverse
Rankine cycle The Rankine cycle is an idealized thermodynamic cycle describing the process by which certain heat engines, such as steam turbines or reciprocating steam engines, allow mechanical work to be extracted from a fluid as it moves between a heat sourc ...
. As such, the working fluid never receives or rejects heat at constant temperature. In the gas cycle, the refrigeration effect is equal to the product of the specific heat of the gas and the rise in temperature of the gas in the low temperature side. Therefore, for the same cooling load, gas refrigeration cycle machines require a larger mass flow rate, which in turn increases their size. Because of their lower efficiency and larger bulk, ''air cycle'' coolers are not often applied in terrestrial refrigeration. The
air cycle machine An air cycle machine (ACM) is the refrigeration unit of the environmental control system (ECS) used in pressurized gas turbine-powered aircraft. Normally an aircraft has two or three of these ACM. Each ACM and its components are often referred as ...
is very common, however, on
gas turbine A gas turbine, also called a combustion turbine, is a type of continuous flow internal combustion engine. The main parts common to all gas turbine engines form the power-producing part (known as the gas generator or core) and are, in the directio ...
-powered
jet airliner A jet airliner or jetliner is an airliner powered by jet engines (passenger jet aircraft). Airliners usually have two or four jet engines; three-engined designs were popular in the 1970s but are less common today. Airliners are commonly clas ...
s since compressed air is readily available from the engines' compressor sections. These jet aircraft's cooling and ventilation units also serve the purpose of heating and pressurizing the
aircraft cabin An aircraft cabin is the section of an aircraft in which passengers travel. Most modern commercial aircraft are pressurized, as cruising altitudes are high enough such that the surrounding atmosphere is too thin for passengers and crew to breat ...
.


Stirling engine

The
Stirling cycle The Stirling cycle is a thermodynamic cycle that describes the general class of Stirling devices. This includes the original Stirling engine that was invented, developed and patented in 1816 by Robert Stirling with help from his brother, an e ...
heat engine can be driven in reverse, using a mechanical energy input to drive heat transfer in a reversed direction (i.e. a heat pump, or refrigerator). There are several design configurations for such devices that can be built. Several such setups require rotary or sliding seals, which can introduce difficult tradeoffs between frictional losses and refrigerant leakage.


Reversed Carnot cycle

The
Carnot cycle A Carnot cycle is an ideal thermodynamic cycle proposed by French physicist Sadi Carnot in 1824 and expanded upon by others in the 1830s and 1840s. By Carnot's theorem, it provides an upper limit on the efficiency of any classical thermodyna ...
is a reversible cycle so the four processes that comprise it, two isothermal and two isentropic, can also be reversed. When a Carnot cycle runs in reverse, it is called a ''reversed Carnot cycle''. A refrigerator or heat pump that acts according to the reversed Carnot cycle is called a Carnot refrigerator or Carnot heat pump, respectively. In the first stage of this cycle, the refrigerant absorbs heat isothermally from a low-temperature source, , in the amount . Next, the refrigerant is compressed isentropically (adiabatically, without heat transfer) and its temperature rises to that of the high-temperature source, . Then at this high temperature, the refrigerant isothermally rejects heat in the amount (negative according to the sign convention for heat lost by the system). Also during this stage, the refrigerant changes from a saturated vapor to a saturated liquid in the condenser. Lastly, the refrigerant expands isentropically until its temperature falls to that of the low-temperature source, .


Coefficient of performance

The merit of a refrigerator or heat pump is given by a parameter called the
coefficient of performance The coefficient of performance or COP (sometimes CP or CoP) of a heat pump, refrigerator or air conditioning system is a ratio of useful heating or cooling provided to work (energy) required. Higher COPs equate to higher efficiency, lower energy ( ...
(COP). The equation is: : = \frac where * Q is the useful
heat In thermodynamics, heat is defined as the form of energy crossing the boundary of a thermodynamic system by virtue of a temperature difference across the boundary. A thermodynamic system does not ''contain'' heat. Nevertheless, the term is ...
given off or taken up by the considered system. * W_ is the net
work Work may refer to: * Work (human activity), intentional activity people perform to support themselves, others, or the community ** Manual labour, physical work done by humans ** House work, housework, or homemaking ** Working animal, an animal t ...
done on the considered system in one cycle. The detailed COP of a refrigerator is given by the following equation: : = \frac = \frac = \frac The COP of a heat pump (sometimes referred to as coefficient of amplification COA) is given by the following equations, where the
first law of thermodynamics The first law of thermodynamics is a formulation of the law of conservation of energy, adapted for thermodynamic processes. It distinguishes in principle two forms of energy transfer, heat and thermodynamic work for a system of a constant am ...
: W_+Q_+Q_ = \Delta_U = 0 and , Q_, = -Q_ was used in one of the last steps: : = \frac = \frac = \frac = \frac =1 +\frac Both the COP of a refrigerator and a heat pump can be greater than one. Combining these two equations results in: : = 1+ for fixed values of and . This implies that will be greater than one because will be a positive quantity. In a worst-case scenario, the heat pump will supply as much energy as it consumes, making it act as a resistance heater. However, in reality, as in home heating, some of is lost to the outside air through piping, insulation, etc., thus making the drop below unity when the outside air temperature is too low. Therefore, the system used to heat houses uses fuel. For Carnot refrigerators and heat pumps, the COP can be expressed in terms of temperatures: : = \frac = \frac : = \frac = \frac :These are the upper limits for the COP of any system operating between and .


References

;Notes * * *


External links


"The Basic Refrigeration Cycle"
{{DEFAULTSORT:Heat Pump And Refrigeration Cycle Thermodynamic cycles Heat pumps Gas technologies