Heat deflection temperature or heat distortion temperature (DTUL, HDT, or HDTUL) is the
temperature
Temperature is a physical quantity that quantitatively expresses the attribute of hotness or coldness. Temperature is measurement, measured with a thermometer. It reflects the average kinetic energy of the vibrating and colliding atoms making ...
at which a
polymer
A polymer () is a chemical substance, substance or material that consists of very large molecules, or macromolecules, that are constituted by many repeat unit, repeating subunits derived from one or more species of monomers. Due to their br ...
or
plastic
Plastics are a wide range of synthetic polymers, synthetic or Semisynthesis, semisynthetic materials composed primarily of Polymer, polymers. Their defining characteristic, Plasticity (physics), plasticity, allows them to be Injection moulding ...
sample deforms under a specified load.
The HDT of a given plastic material is applied in many aspects to the design, engineering, and manufacturing of products which use
thermoplastic
A thermoplastic, or thermosoftening plastic, is any plastic polymer material that becomes pliable or moldable at a certain elevated temperature and solidifies upon cooling.
Most thermoplastics have a high molecular weight. The polymer chains as ...
components.
Determination
The heat distortion temperature is determined by the following test procedure outlined in ASTM D648. The test specimen is loaded in three-point bending in the edgewise direction. The outer fiber stress used for testing is either 0.455 MPa or 1.82 MPa, and the temperature is increased at 2 °C/min until the specimen deflects 0.25 mm. This is similar to the test procedure defined in the
ISO
The International Organization for Standardization (ISO ; ; ) is an independent, non-governmental, international standard development organization composed of representatives from the national standards organizations of member countries.
Me ...
75 standard.
Limitations that are associated with the determination of the HDT is that the sample is not thermally isotropic and, in thick samples in particular, will contain a temperature gradient. The HDT of a particular material can also be very sensitive to stress experienced by the component which is dependent on the component’s dimensions. The selected deflection of 0.25 mm (which is 0.2% additional strain) is selected arbitrarily and has no particular physical significance.
Application in injection molding
An injection molded plastic part is considered "safe" to remove from its mold once it is near or below the HDT. This means that part deformation will be held within acceptable limits after removal. The molding of plastics by necessity occurs at high temperatures (routinely 200 °C or higher) due to the low viscosity of plastics in fluid form (this issue can be addressed to some extent by the addition of
plasticizer
A plasticizer ( UK: plasticiser) is a substance that is added to a material to make it softer and more flexible, to increase its plasticity, to decrease its viscosity, and/or to decrease friction during its handling in manufacture.
Plasticizer ...
s to the melt, which is a secondary function of a plasticizer). Once plastic is in the mold, it must be cooled to a temperature to which little or no dimensional change will occur after removal. In general, plastics do not conduct heat well and so will take quite a while to cool to room temperature. One way to mitigate this is to use a cold mold (thereby increasing heat loss from the part). Even so, the cooling of the part to room temperature can limit the mass production of parts.
Choosing a resin with a higher heat deflection temperature (and therefore closer to melting temperature) can allow manufacturers to achieve a much faster molding process than they would otherwise while maintaining dimensional changes within certain limits.
See also
*
Vicat softening point
References
{{DEFAULTSORT:Heat Deflection Temperature
Polymer chemistry
Threshold temperatures