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Headspace technology is a technique developed in the 1980s to elucidate the odor compounds present in the air surrounding various objects. Usually the objects of interest are odoriferous objects such as plants, flowers and foods. Similar techniques are also used to analyze the interesting scents of locations and environments such as tea shops and saw mills. After the data is analyzed, the scents can then be recreated by a perfumer. One of the early pioneers of this technology was Roman Kaiser who used it to measure and characterize the scents of tropical rainforests. Headspace techniques have since been used extensively to sample
in vivo Studies that are ''in vivo'' (Latin for "within the living"; often not italicized in English) are those in which the effects of various biological entities are tested on whole, living organisms or cells, usually animals, including humans, an ...
floral headspace of a large variety of numerous taxa and their aromatic compounds such as
fatty acid In chemistry, in particular in biochemistry, a fatty acid is a carboxylic acid with an aliphatic chain, which is either saturated and unsaturated compounds#Organic chemistry, saturated or unsaturated. Most naturally occurring fatty acids have an ...
derivatives (
aldehyde In organic chemistry, an aldehyde () (lat. ''al''cohol ''dehyd''rogenatum, dehydrogenated alcohol) is an organic compound containing a functional group with the structure . The functional group itself (without the "R" side chain) can be referred ...
s,
alcohol Alcohol may refer to: Common uses * Alcohol (chemistry), a class of compounds * Ethanol, one of several alcohols, commonly known as alcohol in everyday life ** Alcohol (drug), intoxicant found in alcoholic beverages ** Alcoholic beverage, an alco ...
s and
ketone In organic chemistry, a ketone is an organic compound with the structure , where R and R' can be a variety of carbon-containing substituents. Ketones contain a carbonyl group (a carbon-oxygen double bond C=O). The simplest ketone is acetone ( ...
s), benzenoids and
isoprenoids The terpenoids, also known as isoprenoids, are a class of naturally occurring organic chemicals derived from the 5-carbon compound isoprene and its derivatives called terpenes, diterpenes, etc. While sometimes used interchangeably with "terpenes" ...
.


Equipment

The headspace equipment involves a hollow dome or sphere-like objects which forms an airtight seal and surrounds the objects of interest. Inert gases are passed into the space containing the object or a vacuum is established such that the odor compounds are removed from the headspace. These compounds are in turn captured using a variety of techniques, among them cold surfaces, solvent traps, and adsorbent materials, with the latter techniques capable of longer periods of collection. The samples can then be analyzed using techniques such as
gas chromatography Gas chromatography (GC) is a common type of chromatography used in analytical chemistry for Separation process, separating and analyzing compounds that can be vaporized without Chemical decomposition, decomposition. Typical uses of GC include t ...
,
mass spectrometry Mass spectrometry (MS) is an analytical technique that is used to measure the mass-to-charge ratio of ions. The results are presented as a ''mass spectrum'', a plot of intensity as a function of the mass-to-charge ratio. Mass spectrometry is used ...
, or Carbon-13
NMR Nuclear magnetic resonance (NMR) is a physical phenomenon in which atomic nucleus, nuclei in a strong constant magnetic field are disturbed by a weak oscillating magnetic field (in the near and far field, near field) and respond by producing ...
. Several companies have patented similar headspace technologies: *Aromascope ( Takasago) *Jungle Essence ( Mane) *NaturePrint ( Firmenich) *ScentTrek (
Givaudan Givaudan S.A. () is a Swiss multinational manufacturer of flavours, fragrances and active cosmetic ingredients. As of 2008, it was the world's largest company in the flavour and fragrance industry. Overview The company's scents and flavours ...
) *Living Flower (
IFF In logic and related fields such as mathematics and philosophy, "if and only if" (often shortened as "iff") is paraphrased by the biconditional, a logical connective between statements. The biconditional is true in two cases, where either both ...
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References

{{Reflist, 2 Perfumery Flavor technology