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Greenschists are metamorphic rocks that formed under the lowest temperatures and pressures usually produced by
regional metamorphism Metamorphism is the transformation of existing rock (the protolith) to rock with a different mineral composition or texture. Metamorphism takes place at temperatures in excess of , and often also at elevated pressure or in the presence of ch ...
, typically and 2–10 kilobars (). Greenschists commonly have an abundance of green minerals such as
chlorite The chlorite ion, or chlorine dioxide anion, is the halite with the chemical formula of . A chlorite (compound) is a compound that contains this group, with chlorine in the oxidation state of +3. Chlorites are also known as salts of chlorou ...
, serpentine, and
epidote Epidote is a calcium aluminium iron sorosilicate mineral. Description Well developed crystals of epidote, Ca2Al2(Fe3+;Al)(SiO4)(Si2O7)O(OH), crystallizing in the monoclinic system, are of frequent occurrence: they are commonly prismatic in ...
, and platy minerals such as muscovite and platy serpentine. The platiness gives the rock
schistosity Schist ( ) is a medium-grained metamorphic rock showing pronounced schistosity. This means that the rock is composed of mineral grains easily seen with a low-power hand lens, oriented in such a way that the rock is easily split into thin flakes o ...
(a tendency to split into layers.) Other common minerals include
quartz Quartz is a hard, crystalline mineral composed of silica ( silicon dioxide). The atoms are linked in a continuous framework of SiO4 silicon-oxygen tetrahedra, with each oxygen being shared between two tetrahedra, giving an overall chemical f ...
, orthoclase, talc,
carbonate mineral Carbonate minerals are those minerals containing the carbonate ion, . Carbonate divisions Anhydrous carbonates *Calcite group: trigonal ** Calcite CaCO3 ** Gaspéite (Ni,Mg,Fe2+)CO3 ** Magnesite MgCO3 **Otavite CdCO3 ** Rhodochrosite MnCO3 ...
s and
amphibole Amphibole () is a group of inosilicate minerals, forming prism or needlelike crystals, composed of double chain tetrahedra, linked at the vertices and generally containing ions of iron and/or magnesium in their structures. Its IMA symbol is ...
( actinolite). Greenschist is a general field petrologic term for metamorphic or altered
mafic A mafic mineral or rock is a silicate mineral or igneous rock rich in magnesium and iron. Most mafic minerals are dark in color, and common rock-forming mafic minerals include olivine, pyroxene, amphibole, and biotite. Common mafic rocks in ...
volcanic rock. In Europe, the term ''prasinite'' is sometimes used. A ''greenstone'' is sometimes a greenschist but can also be rock types without any schistosity, especially metabasalt ( spilite). However, basalts may remain quite black if primary pyroxene does not revert to chlorite or actinolite. To qualify for the name a rock must also exhibit schistosity or some foliation or layering. The rock is derived from
basalt Basalt (; ) is an aphanitic (fine-grained) extrusive igneous rock formed from the rapid cooling of low-viscosity lava rich in magnesium and iron (mafic lava) exposed at or very near the surface of a rocky planet or moon. More than 90 ...
,
gabbro Gabbro () is a phaneritic (coarse-grained), mafic intrusive igneous rock formed from the slow cooling of magnesium-rich and iron-rich magma into a holocrystalline mass deep beneath the Earth's surface. Slow-cooling, coarse-grained gabbro is ...
or similar rocks containing
sodium Sodium is a chemical element with the symbol Na (from Latin ''natrium'') and atomic number 11. It is a soft, silvery-white, highly reactive metal. Sodium is an alkali metal, being in group 1 of the periodic table. Its only stable ...
-rich
plagioclase Plagioclase is a series of tectosilicate (framework silicate) minerals within the feldspar group. Rather than referring to a particular mineral with a specific chemical composition, plagioclase is a continuous solid solution series, more p ...
feldspar Feldspars are a group of rock-forming aluminium tectosilicate minerals, also containing other cations such as sodium, calcium, potassium, or barium. The most common members of the feldspar group are the ''plagioclase'' (sodium-calcium) felds ...
, chlorite, epidote and quartz.


Petrology

''Greenschist'' is defined by the presence of the minerals
chlorite The chlorite ion, or chlorine dioxide anion, is the halite with the chemical formula of . A chlorite (compound) is a compound that contains this group, with chlorine in the oxidation state of +3. Chlorites are also known as salts of chlorou ...
,
epidote Epidote is a calcium aluminium iron sorosilicate mineral. Description Well developed crystals of epidote, Ca2Al2(Fe3+;Al)(SiO4)(Si2O7)O(OH), crystallizing in the monoclinic system, are of frequent occurrence: they are commonly prismatic in ...
, or actinolite, which give the rock its green color. Greenschists also have pronounced
schistosity Schist ( ) is a medium-grained metamorphic rock showing pronounced schistosity. This means that the rock is composed of mineral grains easily seen with a low-power hand lens, oriented in such a way that the rock is easily split into thin flakes o ...
. Schistosity is a thin layering of the rock produced by
metamorphism Metamorphism is the transformation of existing rock (the protolith) to rock with a different mineral composition or texture. Metamorphism takes place at temperatures in excess of , and often also at elevated pressure or in the presence of ch ...
(a '' foliation'') that permits the rock to easily be split into flakes or slabs less than thick. This arises from the presence of chlorite or other platy minerals that become aligned in layers during metamorphism. Greenschist may also contain
albite Albite is a plagioclase feldspar mineral. It is the sodium endmember of the plagioclase solid solution series. It represents a plagioclase with less than 10% anorthite content. The pure albite endmember has the formula . It is a tectosilicate ...
and often has a lepidoblastic, nematoblastic or schistose texture defined primarily by chlorite and actinolite. Grain size is rarely coarse, due primarily to the mineral assemblage. Chlorite and to a lesser extent actinolite typically exhibit small, flat or acicular crystal habits. ''Greenstone'' is a field term for any massive
mafic A mafic mineral or rock is a silicate mineral or igneous rock rich in magnesium and iron. Most mafic minerals are dark in color, and common rock-forming mafic minerals include olivine, pyroxene, amphibole, and biotite. Common mafic rocks in ...
volcanic rock that has been altered to a greenish color by the formation of the same minerals that give the green color to greenschist, whether or not the rock displays schistosity. The term has also been used to describe any igneous intrusions into the
Coal Measures Group The Coal Measures Group is a lithostratigraphical term coined to refer to the coal-bearing succession of rock strata which occur in the United Kingdom within the Westphalian Stage of the Carboniferous Period. Other than in Northern Ireland th ...
of Scotland, to describe
chamosite Chamosite is the Fe2+end member of the chlorite group. A hydrous aluminium silicate of iron, which is produced in an environment of low to moderate grade of metamorphosed iron deposits, as gray or black crystals in oolitic iron ore. Like other ...
-rich
mudstone Mudstone, a type of mudrock, is a fine-grained sedimentary rock whose original constituents were clays or muds. Mudstone is distinguished from '' shale'' by its lack of fissility (parallel layering).Blatt, H., and R.J. Tracy, 1996, ''Petrology.' ...
of Lower Jurassic age in Great Britain, or for nephrite or other greenish gemstones.


Greenschist facies

Greenschist facies is determined by the particular temperature and pressure conditions required to metamorphose basalt to form the typical greenschist facies minerals chlorite, actinolite, and albite. Greenschist facies results from low temperature, moderate pressure metamorphism. Metamorphic conditions which create typical greenschist facies assemblages are called the ''Barrovian Facies Sequence'', and the lower-pressure ''Abukuma Facies Series''. Temperatures of approximately and depths of about are the typical envelope of greenschist facies rocks. The equilibrium mineral assemblage of rocks subjected to greenschist facies conditions depends on primary rock composition. * Basalt: ''chlorite + actinolite + albite +/- epidote'' * Ultramafic: ''chlorite + serpentine +/- talc +/-
tremolite Tremolite is a member of the amphibole group of silicate minerals with composition: Ca2(Mg5.0-4.5Fe2+0.0-0.5)Si8O22(OH)2. Tremolite forms by metamorphism of sediments rich in dolomite and quartz. Tremolite forms a series with actinolite and fe ...
+/- diopside +/-
brucite Brucite is the mineral form of magnesium hydroxide, with the chemical formula Mg( OH)2. It is a common alteration product of periclase in marble; a low-temperature hydrothermal vein mineral in metamorphosed limestones and chlorite schists ...
'' * Pelites: ''
quartz Quartz is a hard, crystalline mineral composed of silica ( silicon dioxide). The atoms are linked in a continuous framework of SiO4 silicon-oxygen tetrahedra, with each oxygen being shared between two tetrahedra, giving an overall chemical f ...
+/-
albite Albite is a plagioclase feldspar mineral. It is the sodium endmember of the plagioclase solid solution series. It represents a plagioclase with less than 10% anorthite content. The pure albite endmember has the formula . It is a tectosilicate ...
+/- k-feldspar +/- chlorite, muscovite,
garnet Garnets () are a group of silicate minerals that have been used since the Bronze Age as gemstones and abrasives. All species of garnets possess similar physical properties and crystal forms, but differ in chemical composition. The different ...
,
pyrophyllite Pyrophyllite is a phyllosilicate mineral composed of aluminium silicate hydroxide: Al2Si4O10(OH)2. It occurs in two forms (habits): crystalline folia and compact masses; distinct crystals are not known. The folia have a pronounced pearly ...
+/-
graphite Graphite () is a crystalline form of the element carbon. It consists of stacked layers of graphene. Graphite occurs naturally and is the most stable form of carbon under standard conditions. Synthetic and natural graphite are consumed on la ...
'' * Calc-silicates: ''
calcite Calcite is a carbonate mineral and the most stable polymorph of calcium carbonate (CaCO3). It is a very common mineral, particularly as a component of limestone. Calcite defines hardness 3 on the Mohs scale of mineral hardness, based on scratc ...
+/-
dolomite Dolomite may refer to: *Dolomite (mineral), a carbonate mineral *Dolomite (rock), also known as dolostone, a sedimentary carbonate rock *Dolomite, Alabama, United States, an unincorporated community *Dolomite, California, United States, an unincor ...
+/- quartz +/- micas, scapolite, wollastonite, etc. In greater detail the greenschist facies is subdivided into subgreenschist, lower and upper greenschist. Lower temperatures are transitional with and overlap the
prehnite-pumpellyite facies The prehnite-pumpellyite facies is a metamorphic facies typical of subseafloor alteration of the oceanic crust around mid-ocean ridge spreading centres. It is a metamorphic grade transitional between zeolite facies and greenschist facies repres ...
and higher temperatures overlap with and include sub-
amphibolite Amphibolite () is a metamorphic rock that contains amphibole, especially hornblende and actinolite, as well as plagioclase feldspar, but with little or no quartz. It is typically dark-colored and dense, with a weakly foliated or schistose (flak ...
facies. If burial continues along Barrovian Sequence metamorphic trajectories, greenschist facies gives rise to
amphibolite facies Amphibolite () is a metamorphic rock that contains amphibole, especially hornblende and actinolite, as well as plagioclase feldspar, but with little or no quartz. It is typically dark-colored and dense, with a weakly foliated or schistose ...
assemblages, dominated by amphibole and eventually to granulite facies. Lower pressure, normally contact metamorphism produces
albite Albite is a plagioclase feldspar mineral. It is the sodium endmember of the plagioclase solid solution series. It represents a plagioclase with less than 10% anorthite content. The pure albite endmember has the formula . It is a tectosilicate ...
-epidote hornfels while higher pressures at great depth produces eclogite. Oceanic basalts in the vicinity of
mid-ocean ridge A mid-ocean ridge (MOR) is a seafloor mountain system formed by plate tectonics. It typically has a depth of about and rises about above the deepest portion of an ocean basin. This feature is where seafloor spreading takes place along a div ...
s typically exhibit sub-greenschist alteration. The
greenstone belt Greenstone belts are zones of variably metamorphosed mafic to ultramafic volcanic sequences with associated sedimentary rocks that occur within Archaean and Proterozoic cratons between granite and gneiss bodies. The name comes from the gree ...
s of the various
archean The Archean Eon ( , also spelled Archaean or Archæan) is the second of four geologic eons of Earth's history, representing the time from . The Archean was preceded by the Hadean Eon and followed by the Proterozoic. The Earth during the Arc ...
craton A craton (, , or ; from grc-gre, κράτος "strength") is an old and stable part of the continental lithosphere, which consists of Earth's two topmost layers, the crust and the uppermost mantle. Having often survived cycles of merging and ...
s are commonly altered to the greenschist facies. These ancient rocks are noted as host rocks for a variety of ore deposits in
Australia Australia, officially the Commonwealth of Australia, is a sovereign country comprising the mainland of the Australian continent, the island of Tasmania, and numerous smaller islands. With an area of , Australia is the largest country by ...
,
Namibia Namibia (, ), officially the Republic of Namibia, is a country in Southern Africa. Its western border is the Atlantic Ocean. It shares land borders with Zambia and Angola to the north, Botswana to the east and South Africa to the south and ea ...
and
Canada Canada is a country in North America. Its ten provinces and three territories extend from the Atlantic Ocean to the Pacific Ocean and northward into the Arctic Ocean, covering over , making it the world's second-largest country by to ...
. Greenschist-like rocks can also be formed under blueschist facies conditions if the original rock (
protolith A protolith () is the original, unmetamorphosed rock from which a given metamorphic rock is formed. For example, the protolith of a slate is a shale or mudstone. Metamorphic rocks can be derived from any other kind of non-metamorphic rock an ...
) contains enough
magnesium Magnesium is a chemical element with the symbol Mg and atomic number 12. It is a shiny gray metal having a low density, low melting point and high chemical reactivity. Like the other alkaline earth metals (group 2 of the periodic ...
. This explains the scarcity of blueschist preserved from before the
Neoproterozoic Era The Neoproterozoic Era is the unit of geologic time from 1 billion to 538.8 million years ago. It is the last era of the Precambrian Supereon and the Proterozoic Eon; it is subdivided into the Tonian, Cryogenian, and Ediacaran periods. It is p ...
1000 Ma ago when the Earth's
oceanic crust Oceanic crust is the uppermost layer of the oceanic portion of the tectonic plates. It is composed of the upper oceanic crust, with pillow lavas and a dike complex, and the lower oceanic crust, composed of troctolite, gabbro and ultramafic ...
contained more magnesium than today's oceanic crust.


Use


Europe

In Minoan Crete, greenschist and blueschist were used to pave streets and
courtyard A courtyard or court is a circumscribed area, often surrounded by a building or complex, that is open to the sky. Courtyards are common elements in both Western and Eastern building patterns and have been used by both ancient and contemporary ...
s between 1650 and 1600 BC. These rocks were likely quarried in Agia Pelagia on the north coast of central Crete. Across Europe, greenschist rocks have been used to make axes. Several sites, including Great Langdale in England, have been identified.


Eastern North America

A form of chlorite schist was popular in prehistoric Native American communities for the production of axes and
celts The Celts (, see pronunciation for different usages) or Celtic peoples () are. "CELTS location: Greater Europe time period: Second millennium B.C.E. to present ancestry: Celtic a collection of Indo-European peoples. "The Celts, an ancient ...
, as well as ornamental items. In the Middle
Woodland period In the classification of archaeological cultures of North America, the Woodland period of North American pre-Columbian cultures spanned a period from roughly 1000 BCE to European contact in the eastern part of North America, with some archaeo ...
, greenschist was one of the many trade items that were part of the Hopewell culture exchange network, sometimes transported over thousands of kilometers. During the time of the
Mississippian culture The Mississippian culture was a Native American civilization that flourished in what is now the Midwestern, Eastern, and Southeastern United States from approximately 800 CE to 1600 CE, varying regionally. It was known for building large, eart ...
, the
polity A polity is an identifiable political entity – a group of people with a collective identity, who are organized by some form of institutionalized social relations, and have a capacity to mobilize resources. A polity can be any other group of ...
of Moundville apparently had some control over the production and distribution of greenschist. The Moundville source has been shown to be from two localities in the Hillabee Formation of central and eastern Alabama.


See also

*
Metamorphism Metamorphism is the transformation of existing rock (the protolith) to rock with a different mineral composition or texture. Metamorphism takes place at temperatures in excess of , and often also at elevated pressure or in the presence of ch ...
*
List of rock types The following is a list of rock types recognized by geologists. There is no agreed number of specific types of rocks. Any unique combination of chemical composition, mineralogy, grain size, texture, or other distinguishing characteristics can des ...
*
List of minerals This is a list of minerals for which there are articles on Wikipedia. Minerals are distinguished by various chemical and physical properties. Differences in chemical composition and crystal structure distinguish the various ''species''. Within a m ...
* Pounamu, another type of rock frequently called greenstone


References

* Blatt, Harvey and Robert J. Tracy (1996). Petrology; Igneous, Sedimentary, and Metamorphic, 2nd Ed., W. H. Freeman. . *Gall, Daniel G. and Vincas P. Steponaitis, "Composition and Provenance of Greenstone Artifacts from Moundville," Southeastern Archaeology 20(2):99–117 001. *Steponaitis, Vincas P. Prehistoric Archaeology in the Southeastern United States, 1970–1985. Annual Review of Anthropology, Vol. 15. (1986), pp. 363–404. {{Metamorphic Facies Schist Metamorphic petrology he:צפחה#צפחות ירוקות