Gallium Triiodide
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Gallium(III) iodide is the
inorganic compound An inorganic compound is typically a chemical compound that lacks carbon–hydrogen bonds⁠that is, a compound that is not an organic compound. The study of inorganic compounds is a subfield of chemistry known as ''inorganic chemistry''. Inorgan ...
with the
formula In science, a formula is a concise way of expressing information symbolically, as in a mathematical formula or a ''chemical formula''. The informal use of the term ''formula'' in science refers to the general construct of a relationship betwe ...
Ga I3. A yellow hygroscopic solid, it is the most common iodide of gallium. In the
chemical vapor transport In chemistry, a chemical transport reaction describes a process for purification and crystallization of non-volatility (chemistry), volatile solids. The process is also responsible for certain aspects of mineral growth from the effluent of volca ...
method of growing crystals of
gallium arsenide Gallium arsenide (GaAs) is a III-V direct band gap semiconductor with a Zincblende (crystal structure), zinc blende crystal structure. Gallium arsenide is used in the manufacture of devices such as microwave frequency integrated circuits, monoli ...
uses iodine as the transport agent. In the solid state, it exists as the dimer Ga2I6, with a
diborane Diborane(6), commonly known as diborane, is the chemical compound with the formula . It is a highly toxic, colorless, and pyrophoric gas with a repulsively sweet odor. Given its simple formula, borane is a fundamental boron compound. It has att ...
structure. When vaporized, its forms GaI3 molecules of D3h symmetry where the Ga–I distance is 2.458
Angstroms The angstrom (; ) is a unit of length equal to m; that is, one ten-billionth of a metre, a hundred-millionth of a centimetre, 0.1 nanometre, or 100 picometres. The unit is named after the Swedish physicist Anders Jonas Ångström (1814–1874) ...
. Gallium triiodide can be reduced with gallium metal to give a green-colored
gallium(I) iodide Gallium monoiodide is an inorganic gallium compound with the formula GaI or Ga4I4. It is a pale green solid and mixed valent gallium compound, which can contain gallium in the 0, +1, +2, and +3 oxidation states. It is used as a pathway for many ga ...
. The nature of this species is unclear, but it is useful for the preparation of gallium(I) and gallium(II) compounds.


See also

*
Gallium halides There are three sets of gallium halides, the trihalides where gallium has oxidation state +3, the intermediate halides containing gallium in oxidation states +1, +2 and +3 and some unstable monohalides, where gallium has oxidation state +1. Trihali ...


References


Cited sources

* Iodides Gallium compounds Metal halides {{inorganic-compound-stub