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Fugitive gas emissions are emissions of gas (typically
natural gas Natural gas (also called fossil gas or simply gas) is a naturally occurring mixture of gaseous hydrocarbons consisting primarily of methane in addition to various smaller amounts of other higher alkanes. Low levels of trace gases like carbon d ...
, which contains
methane Methane ( , ) is a chemical compound with the chemical formula (one carbon atom bonded to four hydrogen atoms). It is a group-14 hydride, the simplest alkane, and the main constituent of natural gas. The relative abundance of methane ...
) to
atmosphere An atmosphere () is a layer of gas or layers of gases that envelop a planet, and is held in place by the gravity of the planetary body. A planet retains an atmosphere when the gravity is great and the temperature of the atmosphere is low. A ...
or
groundwater Groundwater is the water present beneath Earth's surface in rock and Pore space in soil, soil pore spaces and in the fractures of stratum, rock formations. About 30 percent of all readily available freshwater in the world is groundwater. A unit ...
which result from
oil and gas A fossil fuel is a hydrocarbon-containing material formed naturally in the Earth's crust from the remains of dead plants and animals that is extracted and burned as a fuel. The main fossil fuels are coal, oil, and natural gas. Fossil fuels ...
or
coal mining Coal mining is the process of extracting coal from the ground. Coal is valued for its energy content and since the 1880s has been widely used to generate electricity. Steel and cement industries use coal as a fuel for extraction of iron from ...
activity. In 2016, these emissions, when converted to their equivalent impact of carbon dioxide, accounted for 5.8% of all global
greenhouse gas emissions Greenhouse gas emissions from human activities strengthen the greenhouse effect, contributing to climate change. Most is carbon dioxide from burning fossil fuels: coal, oil, and natural gas. The largest emitters include coal in China and ...
. Most fugitive emissions are the result of loss of well integrity through poorly sealed well casings due to geochemically unstable
cement A cement is a binder, a chemical substance used for construction that sets, hardens, and adheres to other materials to bind them together. Cement is seldom used on its own, but rather to bind sand and gravel (aggregate) together. Cement mixe ...
. This allows gas to escape through the well itself (known as surface casing vent flow) or via lateral migration along adjacent
geological formation A geological formation, or simply formation, is a body of rock having a consistent set of physical characteristics ( lithology) that distinguishes it from adjacent bodies of rock, and which occupies a particular position in the layers of rock exp ...
s (known as gas migration). Approximately 1-3% of methane leakage cases in unconventional oil and gas wells are caused by imperfect seals and deteriorating cement in wellbores. Some leaks are also the result of leaks in equipment, intentional pressure release practices, or accidental releases during normal transportation, storage, and distribution activities. Emissions can be measured using either ground-based or airborne techniques. In
Canada Canada is a country in North America. Its ten provinces and three territories extend from the Atlantic Ocean to the Pacific Ocean and northward into the Arctic Ocean, covering over , making it the world's second-largest country by to ...
, the oil and gas industry is thought to be the largest source of
greenhouse gas A greenhouse gas (GHG or GhG) is a gas that absorbs and emits radiant energy within the thermal infrared range, causing the greenhouse effect. The primary greenhouse gases in Earth's atmosphere are water vapor (), carbon dioxide (), methane ...
and methane emissions, and approximately 40% of Canada's emissions originate from
Alberta Alberta ( ) is one of the thirteen provinces and territories of Canada. It is part of Western Canada and is one of the three prairie provinces. Alberta is bordered by British Columbia to the west, Saskatchewan to the east, the Northwest T ...
. Emissions are largely self-reported by companies. The Alberta Energy Regulator keeps a database on wells releasing fugitive gas emissions in Alberta, and the British Columbia Oil and Gas Commission keeps a database of leaky wells in
British Columbia British Columbia (commonly abbreviated as BC) is the westernmost province of Canada, situated between the Pacific Ocean and the Rocky Mountains. It has a diverse geography, with rugged landscapes that include rocky coastlines, sandy beaches, for ...
. Testing wells at the time of drilling was not required in British Columbia until 2010, and since then 19% of new wells have reported leakage problems. This number may be a low estimate, as suggested by fieldwork completed by the
David Suzuki Foundation The David Suzuki Foundation is a science-based non-profit environmental organization headquartered in Vancouver, British Columbia, Canada, with offices in Montreal and Toronto. It was established as a federally registered Canadian charity on J ...
. Some studies have shown a range of 6-30% of wells suffer gas leakage.A. Ingraffea, R. Santoro, S. B. Shonkoff, Wellbore Integrity: Failure Mechanisms, Historical Record, and Rate Analysis.
EPA’s Study Hydraul. Fract. Its Potential Impact Drink. Water Resour
2013 Tech. Work. Present. Well Constr. Subsurf. Model.'' (2013) (available at http://www2.epa.gov/hfstudy/2013-technical-workshop-presentations-0)
Canada and Alberta have plans for policies to reduce emissions, which may help combat climate change. Costs related to reducing emissions are very location-dependent and can vary widely. Methane has a greater global warming impact than
carbon dioxide Carbon dioxide ( chemical formula ) is a chemical compound made up of molecules that each have one carbon atom covalently double bonded to two oxygen atoms. It is found in the gas state at room temperature. In the air, carbon dioxide is t ...
, as its radiative force is 120, 86 and 34 times that of carbon dioxide, when considering a 1, 20 and 100 year time frame (including Climate Carbon Feedback Additionally, it leads to increases in carbon dioxide concentration through its
oxidation Redox (reduction–oxidation, , ) is a type of chemical reaction in which the oxidation states of substrate change. Oxidation is the loss of electrons or an increase in the oxidation state, while reduction is the gain of electrons or ...
by
water vapor (99.9839 °C) , - , Boiling point , , - , specific gas constant , 461.5 J/( kg·K) , - , Heat of vaporization , 2.27 MJ/kg , - , Heat capacity , 1.864 kJ/(kg·K) Water vapor, water vapour or aqueous vapor is the gaseous p ...
.


Sources of emissions

Fugitive gas emissions can arise as a result of operations in
hydrocarbon exploration Hydrocarbon exploration (or oil and gas exploration) is the search by petroleum geologists and geophysicists for deposits of hydrocarbons, particularly petroleum and natural gas, in the Earth using petroleum geology. Exploration methods Visi ...
, such as for natural gas or
petroleum Petroleum, also known as crude oil, or simply oil, is a naturally occurring yellowish-black liquid mixture of mainly hydrocarbons, and is found in geological formations. The name ''petroleum'' covers both naturally occurring unprocessed crud ...
. Often, sources of methane are also sources of
ethane Ethane ( , ) is an organic chemical compound with chemical formula . At standard temperature and pressure, ethane is a colorless, odorless gas. Like many hydrocarbons, ethane is isolated on an industrial scale from natural gas and as a petroc ...
, allowing methane emissions to be derived based on ethane emissions and ethane/methane ratios in the atmosphere. This method has given an estimate of increased methane emission from 20 Tg per year in 2008 to 35 Tg per year in 2014. A large portion of methane emissions can be contributed by only a few "super-emitters". The annual ethane emission increase rate in
North America North America is a continent in the Northern Hemisphere and almost entirely within the Western Hemisphere. It is bordered to the north by the Arctic Ocean, to the east by the Atlantic Ocean, to the southeast by South America and th ...
between 2009 and 2014 was 3-5%. It has been suggested that 62% of atmospheric ethane originates from leaks associated with natural gas production and transportation operations. It has also been suggested that ethane emissions measured in
Europe Europe is a large peninsula conventionally considered a continent in its own right because of its great physical size and the weight of its history and traditions. Europe is also considered a Continent#Subcontinents, subcontinent of Eurasia ...
are affected by
hydraulic fracturing Fracking (also known as hydraulic fracturing, hydrofracturing, or hydrofracking) is a well stimulation technique involving the fracturing of bedrock formations by a pressurized liquid. The process involves the high-pressure injection of "fra ...
and shale gas production operations in North America. Some researchers postulate that leakage problems are more likely to happen in unconventional wells, which are hydraulically fractured, than in conventional wells. Approximately 40% of methane emissions in Canada occur within Alberta, according to the National Inventory Report. Of the anthropogenic methane emissions in Alberta, 71% are generated by the oil and gas sector. It is estimated that 5% of the wells in Alberta are associated with natural gas leaking or venting. It is also estimated that 11% of all wells drilled in British Columbia, or 2739 wells out of 24599, have reported leakage problems. Some studies have estimated that 6-30% of all wells suffer gas leakage.


Well-specific and processing sources

Sources can include broken or leaky well casings (either at
abandoned wells Orphan, orphaned or abandoned wells are oil or gas wells that have been abandoned by fossil fuel extraction industries. These wells may have been deactivated because of economic viability, failure to transfer ownerships (especially at bankruptcy o ...
or unused, but not properly abandoned, wells) or lateral migration through the geological formations in the subsurface before being emitted to groundwater or atmosphere. Broken or leaky well casings are often the result of geochemically unstable or brittle cement. One researcher proposes 7 main paths for gas migration and surface casing vent flow: (1) between the cement and adjacent rock formation, (2) between the casing and encompassing cement, (3) between the casing and the cement plug, (4) directly through the cement plug, (5) through the cement between casing and adjacent rock formation, (6) through the cement between linking cavities from the casing side of the cement to the annulus side of the cement, and (7) through shears in the casing or well bore. Leakage and migration can be caused by hydraulic fracturing, although in many cases the method of fracturing is such that gas is not able to migrate through the well casing. Some studies observe that hydraulic fracturing of horizontal wells does not affect the likelihood of the well suffering from gas migration. It is estimated that approximately 0.6-7.7% of methane emissions produced during the lifetime of a fossil fuel well occur during activities that take place either at the well site or during processing.


Pipeline and distribution sources

Distribution of
hydrocarbon In organic chemistry, a hydrocarbon is an organic compound consisting entirely of hydrogen and carbon. Hydrocarbons are examples of group 14 hydrides. Hydrocarbons are generally colourless and hydrophobic, and their odors are usually weak or ...
products can lead to fugitive emissions caused by leaks in seals of pipes or storage containers, improper storage practices, or transportation accidents. Some leaks may be intentional, in the case of pressure release safety valves. Some emissions may originate from unintentional equipment leaks, such as from flanges or valves. It is estimated that approximately 0.07-10% of methane emissions occur during transportation, storage, and distribution activities.


Detection methods

There are several methods used to detect fugitive gas emissions. Often, measurements are taken at or near the
wellhead A wellhead is the component at the surface of an oil or gas well that provides the structural and pressure-containing interface for the drilling and production equipment. The primary purpose of a wellhead is to provide the suspension point and ...
s (via the use of soil gas samples, eddy covariance towers, dynamic flux chambers connected to a greenhouse gas analyzer), but it is also possible to measure emissions using an
aircraft An aircraft is a vehicle that is able to flight, fly by gaining support from the Atmosphere of Earth, air. It counters the force of gravity by using either Buoyancy, static lift or by using the Lift (force), dynamic lift of an airfoil, or in ...
with specialized instruments on board. An aircraft survey in northeastern British Columbia indicated emissions emanating from approximately 47% of active wells in the area. The same study suggests that actual methane emissions may be much higher than what is being reported by industry or estimated by government. For small-scale measurement projects,
infrared camera Infrared (IR), sometimes called infrared light, is electromagnetic radiation (EMR) with wavelengths longer than those of visible light. It is therefore invisible to the human eye. IR is generally understood to encompass wavelengths from around ...
leak inspections, well injection tracers, and
soil gas Soil gases (soil atmosphere) are the gases found in the air space between soil components. The spaces between the solid soil particles, if they do not contain water, are filled with air. The primary soil gases are nitrogen, carbon dioxide and o ...
sampling may be used. These are typically too labour-intensive to be useful to large oil and gas companies, and often airborne surveys are used instead. Other source identification methods used by industry include
carbon Carbon () is a chemical element with the symbol C and atomic number 6. It is nonmetallic and tetravalent—its atom making four electrons available to form covalent chemical bonds. It belongs to group 14 of the periodic table. Carbon ma ...
isotope analysis Isotope analysis is the identification of isotopic signature, abundance of certain stable isotopes of chemical elements within organic and inorganic compounds. Isotopic analysis can be used to understand the flow of energy through a food w ...
of gas samples, noise logs of the production casing, and neutron logs of the cased borehole. Atmospheric measurements through both airborne or ground-based sampling are often limited in sample density due to spatial constraints or sampling duration limitations. One way of attributing methane to a particular source is taking continuous measurements of the stable carbon isotopic measurements of atmospheric methane13CH4) in the plume of
anthropogenic Anthropogenic ("human" + "generating") is an adjective that may refer to: * Anthropogeny, the study of the origins of humanity Counterintuitively, anthropogenic may also refer to things that have been generated by humans, as follows: * Human i ...
methane sources using a mobile analytical system. Since different types and maturity levels of natural gas have different δ13CH4 signatures, these measurements can be used to determine the origin of methane emissions. Activities related to natural gas emit methane plumes with a range of -41.7 to -49.7 ± 0.7‰ of δ13CH4 signatures. High rates of methane emissions measured in the atmosphere at a regional scale, often through airborne measurements, may not represent typical leakage rates from natural gas systems.


Reporting and regulating emissions

Policies regulating reporting of fugitive gas emissions vary, and there is often an emphasis on self-reporting by companies. A necessary condition to successfully regulate greenhouse gas (GHG) emissions is the capacity to monitor and quantify the emissions before and after the regulations are in place. Since 1993, there have been voluntary actions by the oil and gas industry in the
United States The United States of America (U.S.A. or USA), commonly known as the United States (U.S. or US) or America, is a country Continental United States, primarily located in North America. It consists of 50 U.S. state, states, a Washington, D.C., ...
to adopt new technologies that reduce methane emissions, as well as the commitment to employ best management practices to achieve methane reductions at the sector level. In Alberta, the Alberta Energy Regulator maintains a database of self-reported instances of gas migration and surface casing vent flows at wells in the province. Reporting of leakage in British Columbia did not start until 1995, when it was required to test wells for leakage upon abandonment. Testing upon drilling of the well was not required in British Columbia until 2010. Among the 4017 wells drilled since 2010 in British Columbia, 19%, or 761 wells, have reported leakage problems. Fieldwork conducted by the David Suzuki Foundation, however, has discovered leaky wells that were not included in the British Columbia Oil and Gas Commission's (BCOGC) database, meaning that the number of leaky wells could be higher than reported. According to the BCOGC, surface casing vent flow is the major cause of leakage in wells at 90.2%, followed by gas migration at 7.1%. Based on the methane leakage rate of the reported 1493 wells that are currently leaking in British Columbia, a total leakage rate of 7070 m3 daily (2.5 million m3 yearly) is estimated, although this number may be underestimated as demonstrated by the fieldwork done by the David Suzuki Foundation. Bottom-up inventories of leakage involve determining average leakage rates for various emission sources such as equipment, wells, or pipes, and extrapolating this to the leakage that is estimated to be the total contribution by a given company. These methods usually underestimate methane emission rates, regardless of the scale of the inventory.


Addressing issues stemming from fugitive gas emissions

There are some solutions for addressing these issues. Most of them require policy implementation or changes at the company, regulator, or government levels (or all three). Policies can include emission caps, feed-in-tariff programs, and market-based solutions such as taxes or tradeable permits. Canada has enacted policies which include plans to reduce emissions from the oil and gas sector by 40 to 45% below 2012 levels by 2025. The Alberta government also has plans to reduce methane emissions from oil and gas operations by 45% by 2025. Reducing fugitive gas emissions could help slow climate change, since methane has a radiative force 25 times that of carbon dioxide when considering a 100 year time frame. Once emitted, methane is also oxidized by water vapour and increases carbon dioxide concentration, leading to further climate effects.


Costs of reducing fugitive gas emissions

Costs related to implementation of policies designed to reduce fugitive gas emissions vary greatly depending on the
geography Geography (from Greek: , ''geographia''. Combination of Greek words ‘Geo’ (The Earth) and ‘Graphien’ (to describe), literally "earth description") is a field of science devoted to the study of the lands, features, inhabitants, an ...
,
geology Geology () is a branch of natural science concerned with Earth and other Astronomical object, astronomical objects, the features or rock (geology), rocks of which it is composed, and the processes by which they change over time. Modern geology ...
, and
hydrology Hydrology () is the scientific study of the movement, distribution, and management of water on Earth and other planets, including the water cycle, water resources, and environmental watershed sustainability. A practitioner of hydrology is call ...
of the production and distribution areas. Often, the cost of reducing fugitive gas emissions falls to individual companies in the form of technology upgrades. This means that there is often a discrepancy between companies of different sizes as to how drastically they can financially afford to reduce their methane emissions.


Addressing and remediating fugitive gas emissions

The process of intervention in the case of leaky wells affected by surface casing vent flows and gas migrations can involve perforating the intervention area, pumping fresh water and then
slurry A slurry is a mixture of denser solids suspended in liquid, usually water. The most common use of slurry is as a means of transporting solids or separating minerals, the liquid being a carrier that is pumped on a device such as a centrifugal p ...
into the well, and remedial cementing of the intervention interval using methods such as bradenhead squeeze, cement squeeze, or circulation squeeze.


See also

* Gas leak *
Gas venting Gas venting, more specifically known as natural-gas venting or methane venting, is the intentional and controlled release of gases containing alkane hydrocarbons - predominately methane - into earth's atmosphere. It is a widely used method for ...


References

{{Reflist Greenhouse gas emissions Environment of North America Methane Environmental impact of the energy industry