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Free molecular flow describes the
fluid dynamics In physics and engineering, fluid dynamics is a subdiscipline of fluid mechanics that describes the flow of fluids— liquids and gases. It has several subdisciplines, including ''aerodynamics'' (the study of air and other gases in motion) a ...
of gas where the
mean free path In physics, mean free path is the average distance over which a moving particle (such as an atom, a molecule, or a photon) travels before substantially changing its direction or energy (or, in a specific context, other properties), typically as ...
of the molecules is larger than the size of the chamber or of the object under test. For tubes/objects of the size of several cm, this means pressures well below 10−3
mbar The bar is a metric unit of pressure, but not part of the International System of Units (SI). It is defined as exactly equal to 100,000  Pa (100 kPa), or slightly less than the current average atmospheric pressure on Earth at sea l ...
. This is also called the regime of high
vacuum A vacuum is a space devoid of matter. The word is derived from the Latin adjective ''vacuus'' for "vacant" or " void". An approximation to such vacuum is a region with a gaseous pressure much less than atmospheric pressure. Physicists often ...
, or even
ultra-high vacuum Ultra-high vacuum (UHV) is the vacuum regime characterised by pressures lower than about . UHV conditions are created by pumping the gas out of a UHV chamber. At these low pressures the mean free path of a gas molecule is greater than approximatel ...
. This is opposed to viscous flow encountered at higher pressures. The presence of free molecular flow can be calculated, at least in estimation, with the
Knudsen number The Knudsen number (Kn) is a dimensionless number defined as the ratio of the molecular mean free path length to a representative physical length scale. This length scale could be, for example, the radius of a body in a fluid. The number is name ...
(Kn). If Kn > 10, the system is in free molecular flow, also known as Knudsen flow. In free molecular flow, the pressure of the remaining gas can be considered as effectively zero. Thus, boiling points do not depend on the residual pressure. The flow can be considered to be individual particles moving in straight lines. Practically, the "vapor" cannot move around bends or into other spaces behind obstacles, as they simply hit the tube wall. This implies conventional pumps cannot be used, as they rely on viscous flow and fluid pressure. Instead, special sorption pumps, ion pumps and momentum transfer pumps i.e.
turbomolecular pump A turbomolecular pump is a type of vacuum pump, superficially similar to a turbopump, used to obtain and maintain high vacuum. These pumps work on the principle that gas molecules can be given momentum in a desired direction by repeated collisi ...
s are used. Free molecular flow occurs in various processes such as
molecular distillation Molecular distillation is a type of short-path vacuum distillation, characterized by an extremely low vacuum pressure, 0.01 torr or below, which is performed using a molecular still. It is a process of separation, purification and concentration of ...
,
ultra-high vacuum Ultra-high vacuum (UHV) is the vacuum regime characterised by pressures lower than about . UHV conditions are created by pumping the gas out of a UHV chamber. At these low pressures the mean free path of a gas molecule is greater than approximatel ...
equipment such as
particle accelerator A particle accelerator is a machine that uses electromagnetic fields to propel charged particles to very high speeds and energies, and to contain them in well-defined beams. Large accelerators are used for fundamental research in particle ...
s, and naturally in
outer space Outer space, commonly shortened to space, is the expanse that exists beyond Earth and its atmosphere and between celestial bodies. Outer space is not completely empty—it is a near-perfect vacuum containing a low density of particles, pred ...
. The definition of a free molecular flow depends on the distance scale under consideration. For example, in the
interplanetary medium The interplanetary medium (IPM) or interplanetary space consists of the mass and energy which fills the Solar System The Solar System Capitalization of the name varies. The International Astronomical Union, the authoritative body regarding ...
, the plasma is in a free molecular flow regime in scales less than 1 AU; thus, planets and moons are effectively under particle bombardment. However, on larger scales, fluid-like behavior is observed, because the probability of collisions between particles becomes significant.


See also

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References

Fluid dynamics {{fluiddynamics-stub