Forensic materials engineering
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Forensic materials engineering, a branch of
forensic engineering Forensic engineering has been defined as ''"the investigation of failures - ranging from serviceability to catastrophic - which may lead to legal activity, including both civil and criminal".'' It includes the investigation of materials, produc ...
, focuses on the material evidence from crime or accident scenes, seeking defects in those materials which might explain why an accident occurred, or the source of a specific material to identify a criminal. Many analytical methods used for material identification may be used in investigations, the exact set being determined by the nature of the material in question, be it
metal A metal (from Greek μέταλλον ''métallon'', "mine, quarry, metal") is a material that, when freshly prepared, polished, or fractured, shows a lustrous appearance, and conducts electricity and heat relatively well. Metals are typicall ...
,
glass Glass is a non-crystalline, often transparent, amorphous solid that has widespread practical, technological, and decorative use in, for example, window panes, tableware, and optics. Glass is most often formed by rapid cooling ( quenching ...
,
ceramic A ceramic is any of the various hard, brittle, heat-resistant and corrosion-resistant materials made by shaping and then firing an inorganic, nonmetallic material, such as clay, at a high temperature. Common examples are earthenware, porcelain ...
,
polymer A polymer (; Greek '' poly-'', "many" + ''-mer'', "part") is a substance or material consisting of very large molecules called macromolecules, composed of many repeating subunits. Due to their broad spectrum of properties, both synthetic a ...
or
composite Composite or compositing may refer to: Materials * Composite material, a material that is made from several different substances ** Metal matrix composite, composed of metal and other parts ** Cermet, a composite of ceramic and metallic materials ...
. An important aspect is the analysis of
trace evidence Trace evidence is created when objects make contact. The material is often transferred by heat or induced by contact friction. The importance of trace evidence in criminal investigations was shown by Dr. Edmond Locard in the early 20th century. ...
such as skid marks on exposed surfaces, where contact between dissimilar materials leaves material traces of one left on the other. Provided the traces can be analysed successfully, then an accident or crime can often be reconstructed. Another aim will be to determine the cause of a broken component using the technique of fractography.


Metals and alloys

Metal surfaces can be analyzed in a number of ways, including by spectroscopy and EDX used during scanning electron microscopy. The nature and composition of the metal can normally be established by sectioning and polishing the bulk, and examining the flat section using
optical microscopy Optics is the branch of physics that studies the behaviour and properties of light, including its interactions with matter and the construction of instruments that use or detect it. Optics usually describes the behaviour of visible, ultravio ...
after
etching Etching is traditionally the process of using strong acid or mordant to cut into the unprotected parts of a metal surface to create a design in intaglio (incised) in the metal. In modern manufacturing, other chemicals may be used on other types ...
solutions have been used to provide contrast in the section between alloy constituents. Such solutions (often an acid) attack the surface preferentially, so isolating features or inclusions of one composition, enabling them to be seen much more clearly than in the polished but untreated surface.
Metallography Metallography is the study of the physical structure and components of metals, by using microscopy. Ceramic and polymeric materials may also be prepared using metallographic techniques, hence the terms ceramography, plastography and, collecti ...
is a routine technique for examining the
microstructure Microstructure is the very small scale structure of a material, defined as the structure of a prepared surface of material as revealed by an optical microscope above 25× magnification. The microstructure of a material (such as metals, polymers ...
of metals, but can also be applied to ceramics, glasses and polymers. SEM can often be critical in determining failures modes by examining fracture surfaces. The origin of a crack can be found and the way it grew assessed, to distinguish, for example, overload failure from fatigue. Often however, fatigue fractures are easy to distinguish from overload failures by the lack of ductility, and the existence of a fast crack growth region and the slow crack growth area on the fracture surface. Crankshaft fatigue for example is a common failure mode for engine parts. The example shows just two such zones, the slow crack at the base, the fast at the top.


Ceramics and glasses

Hard products like
ceramic A ceramic is any of the various hard, brittle, heat-resistant and corrosion-resistant materials made by shaping and then firing an inorganic, nonmetallic material, such as clay, at a high temperature. Common examples are earthenware, porcelain ...
pottery and
glass Glass is a non-crystalline, often transparent, amorphous solid that has widespread practical, technological, and decorative use in, for example, window panes, tableware, and optics. Glass is most often formed by rapid cooling ( quenching ...
windscreen The windshield (North American English) or windscreen (Commonwealth English) of an aircraft, car, bus, motorbike, truck, train, boat or streetcar is the front window, which provides visibility while protecting occupants from the elements. Mo ...
s can be studied using the same SEM methods used for metals, especially ESEM conducted at low vacuum. Fracture surfaces are especially valuable sources of information because surface features like hachures can enable the origin or origins of the cracks to be found. Analysis of the surface features is carried out using fractography. The position of the origin can then be matched with likely loads on the product to show how an accident occurred, for example. Inspection of bullet holes can often show the direction of travel and energy of the impact, and the way common glass products like bottles can be analysed to show whether deliberately or accidentally broken in a crime or accident. Defects such as foreign particles will often occur near or at the origin of the critical crack, and can be readily identified by ESEM.


Polymers and composites

Thermoplastics, thermosets, and composites can be analyzed using FTIR and
UV spectroscopy Ultraviolet (UV) is a form of electromagnetic radiation with wavelength from 10 nm (with a corresponding frequency around 30  PHz) to 400 nm (750  THz), shorter than that of visible light, but longer than X-rays. UV radiation i ...
as well as
NMR Nuclear magnetic resonance (NMR) is a physical phenomenon in which nuclei in a strong constant magnetic field are perturbed by a weak oscillating magnetic field (in the near field) and respond by producing an electromagnetic signal with ...
and ESEM. Failed samples can either be dissolved in a suitable solvent and examined directly (UV, IR and NMR spectroscopy) or as a thin film cast from solvent or cut using microtomy from the solid product. The slicing method is preferable since there are no complications from solvent absorption, and the integrity of the sample is partly preserved. Fractured products can be examined using fractography, an especially useful method for all fractured components using
macrophotography Macro photography (or photomacrography or macrography, and sometimes macrophotography) is extreme close-up photography, usually of very small subjects and living organisms like insects, in which the size of the subject in the photograph is gre ...
and
optical microscopy Optics is the branch of physics that studies the behaviour and properties of light, including its interactions with matter and the construction of instruments that use or detect it. Optics usually describes the behaviour of visible, ultravio ...
. Although polymers usually possess quite different properties to metals and ceramics, they are just as susceptible to failure from mechanical overload, fatigue and stress corrosion cracking if products are poorly designed or manufactured. Many plastics are susceptible to attack by active chemicals like
chlorine Chlorine is a chemical element with the symbol Cl and atomic number 17. The second-lightest of the halogens, it appears between fluorine and bromine in the periodic table and its properties are mostly intermediate between them. Chlorine i ...
, present at low levels in potable water supplies, especially if the injection mouldings are faulty. ESEM is especially useful for providing
elemental analysis Elemental analysis is a process where a sample of some material (e.g., soil, waste or drinking water, bodily fluids, minerals, chemical compounds) is analyzed for its elemental and sometimes isotopic composition. Elemental analysis can be qualita ...
from viewed parts of the sample being investigated. It is effectively a technique of
microanalysis Microanalysis is the chemical identification and quantitative analysis of very small amounts of chemical substances (generally less than 10 mg or 1 ml) or very small surfaces of material (generally less than 1 cm2). One of the pioneer ...
and valuable for examination of
trace evidence Trace evidence is created when objects make contact. The material is often transferred by heat or induced by contact friction. The importance of trace evidence in criminal investigations was shown by Dr. Edmond Locard in the early 20th century. ...
. On the other hand, colour rendition is absent, and there is no information provided about the way in which those elements are bonded to one another. Specimens will be exposed to a vacuum, so any volatiles may be removed, and surfaces may be contaminated by substances used to attach the sample to the mount.


Elastomers

Rubber products are often safety-critical parts of machines, so that failure can often cause accidents or loss of function. Failed products can be examined with many of the generic polymer methods, although it is more difficult if the sample is
vulcanized Vulcanization (British: Vulcanisation) is a range of processes for hardening rubbers. The term originally referred exclusively to the treatment of natural rubber with sulfur, which remains the most common practice. It has also grown to inclu ...
or
cross-linked In chemistry and biology a cross-link is a bond or a short sequence of bonds that links one polymer chain to another. These links may take the form of covalent bonds or ionic bonds and the polymers can be either synthetic polymers or natural ...
.
Attenuated total reflectance Attenuated total reflection (ATR) is a sampling technique used in conjunction with infrared spectroscopy which enables samples to be examined directly in the solid or liquid state without further preparation. ATR uses a property of total inter ...
infra-red spectroscopy is useful because the product is usually flexible so can be pressed against the
selenium Selenium is a chemical element with the symbol Se and atomic number 34. It is a nonmetal (more rarely considered a metalloid) with properties that are intermediate between the elements above and below in the periodic table, sulfur and tellurium, ...
crystal used for analysis. Simple swelling tests can also help to identify the specific elastomer used in a product. Often the best technique is ESEM using the X-ray elemental analysis facility on the microscope. Although the method only provides
elemental analysis Elemental analysis is a process where a sample of some material (e.g., soil, waste or drinking water, bodily fluids, minerals, chemical compounds) is analyzed for its elemental and sometimes isotopic composition. Elemental analysis can be qualita ...
, it can provide clues as to the identity of the elastomer being examined. Thus the presence of substantial amounts of
chlorine Chlorine is a chemical element with the symbol Cl and atomic number 17. The second-lightest of the halogens, it appears between fluorine and bromine in the periodic table and its properties are mostly intermediate between them. Chlorine i ...
indicates polychloroprene while the presence of
nitrogen Nitrogen is the chemical element with the symbol N and atomic number 7. Nitrogen is a nonmetal and the lightest member of group 15 of the periodic table, often called the pnictogens. It is a common element in the universe, estimated at se ...
indicates
nitrile rubber Nitrile rubber, also known as nitrile butadiene rubber, NBR, Buna-N, and acrylonitrile butadiene rubber, is a synthetic rubber derived from acrylonitrile (ACN) and butadiene. Trade names include Perbunan, Nipol, Krynac and Europrene. This rubber i ...
. The method is also useful in confirming
ozone cracking Cracks can be formed in many different elastomers by ozone attack, and the characteristic form of attack of vulnerable rubbers is known as ozone cracking. The problem was formerly very common, especially in tires, but is now rarely seen in those ...
by the large amounts of
oxygen Oxygen is the chemical element with the symbol O and atomic number 8. It is a member of the chalcogen group in the periodic table, a highly reactive nonmetal, and an oxidizing agent that readily forms oxides with most elements as ...
present on cracked surfaces. Ozone attacks susceptible elastomers such as
natural rubber Rubber, also called India rubber, latex, Amazonian rubber, ''caucho'', or ''caoutchouc'', as initially produced, consists of polymers of the organic compound isoprene, with minor impurities of other organic compounds. Thailand, Malaysia, and ...
,
nitrile rubber Nitrile rubber, also known as nitrile butadiene rubber, NBR, Buna-N, and acrylonitrile butadiene rubber, is a synthetic rubber derived from acrylonitrile (ACN) and butadiene. Trade names include Perbunan, Nipol, Krynac and Europrene. This rubber i ...
and polybutadiene and associated
copolymer In polymer chemistry, a copolymer is a polymer derived from more than one species of monomer. The polymerization of monomers into copolymers is called copolymerization. Copolymers obtained from the copolymerization of two monomer species are some ...
s. Such elastomers possess double bonds in their main chains, the group which is attacked during
ozonolysis In organic chemistry, ozonolysis is an organic reaction where the unsaturated bonds of alkenes (), alkynes (), or azo compounds () are cleaved with ozone (). Alkenes and alkynes form organic compounds in which the multiple carbon–carbon b ...
. The problem occurs when small concentrations of
ozone Ozone (), or trioxygen, is an inorganic molecule with the chemical formula . It is a pale blue gas with a distinctively pungent smell. It is an allotrope of oxygen that is much less stable than the diatomic allotrope , breaking down in the lo ...
gas are present near to exposed elastomer surfaces, such as
O-ring An O-ring, also known as a packing or a toric joint, is a mechanical gasket in the shape of a torus; it is a loop of elastomer with a round cross-section, designed to be seated in a groove and compressed during assembly between two or more par ...
s and
diaphragm seal A diaphragm seal is a flexible membrane that seals and isolates an enclosure. The flexible nature of this seal allows pressure effects to cross the barrier but not the material being contained. Common uses for diaphragm seals are to protect pres ...
s. The product must be in tension, but only very low strains are sufficient to cause degradation.


See also

* Applied spectroscopy * Brittleness * Circumstantial evidence *
Forensic engineering Forensic engineering has been defined as ''"the investigation of failures - ranging from serviceability to catastrophic - which may lead to legal activity, including both civil and criminal".'' It includes the investigation of materials, produc ...
*
Forensic polymer engineering Forensic polymer engineering is the study of failure in polymeric products. The topic includes the fracture of plastic products, or any other reason why such a product fails in service, or fails to meet its specification. The subject focuses on t ...
* Forensic science * Fracture * Fractography * Fracture mechanics *
Ozone cracking Cracks can be formed in many different elastomers by ozone attack, and the characteristic form of attack of vulnerable rubbers is known as ozone cracking. The problem was formerly very common, especially in tires, but is now rarely seen in those ...
*
Polymer degradation Polymer degradation is the reduction in the physical properties of a polymer, such as strength, caused by changes in its chemical composition. Polymers and particularly plastics are subject to degradation at all stages of their product life cycl ...
* Skid mark * Stress corrosion cracking *
Trace evidence Trace evidence is created when objects make contact. The material is often transferred by heat or induced by contact friction. The importance of trace evidence in criminal investigations was shown by Dr. Edmond Locard in the early 20th century. ...
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References

*Lewis, Peter Rhys, Reynolds, K, Gagg, C, ''Forensic Materials Engineering: Case studies'', CRC Press (2004). *Lewis, Peter Rhys Forensic Polymer Engineering: Why polymer products fail in service, 2nd edition, Woodhead/Elsevier (2016). Engineering disciplines Materials science Materials engineering