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"NFPA 704: Standard System for the Identification of the Hazards of Materials for Emergency Response" is a standard maintained by the
The four divisions are typically color-coded with red on top indicating
"NFPA 704: Standard System for the Identification of the Hazards of Materials for Emergency Response" is a standard maintained by the U.S.
The United States of America (U.S.A. or USA), commonly known as the United States (U.S. or US) or America, is a country primarily located in North America. It consists of 50 states, a federal district, five major unincorporated territo ...
-based National Fire Protection Association
The National Fire Protection Association (NFPA) is an international nonprofit organization devoted to eliminating death, injury, property and economic loss due to fire, electrical and related hazards. As of 2018, the NFPA claims to have 50,000 mem ...
. First "tentatively adopted as a guide" in 1960, and revised several times since then, it defines the colloquial "Safety Square" or "Fire Diamond" which is used by emergency personnel to quickly and easily identify the risks posed by hazardous materials. This helps determine what, if any, special equipment should be used, procedures followed, or precautions taken during the initial stages of an emergency response. It is an internationally accepted safety standard, and is crucial while transporting chemicals
A chemical substance is a form of matter having constant chemical composition and characteristic properties. Some references add that chemical substance cannot be separated into its constituent elements by physical separation methods, i.e., with ...
.
Codes
The four divisions are typically color-coded with red on top indicating flammability
A combustible material is something that can burn (i.e., ''combust'') in air. A combustible material is flammable if it ignites easily at ambient temperatures. In other words, a combustible material ignites with some effort and a flammable mat ...
, blue on the left indicating level of health hazard
A hazard is a potential source of harm. Substances, events, or circumstances can constitute hazards when their nature would allow them, even just theoretically, to cause damage to health, life, property, or any other interest of value. The probabi ...
, yellow on the right for chemical reactivity
In chemistry, reactivity is the impulse for which a chemical substance undergoes a chemical reaction, either by itself or with other materials, with an overall release of energy.
''Reactivity'' refers to:
* the chemical reactions of a single ...
, and white containing codes for special hazards. Each of health, flammability and reactivity is rated on a scale from 0 (no hazard) to 4 (severe hazard). The latest version of NFPA 704 sections 5, 6, 7 and 8 for the specifications of each classification are listed below. The numeric values in the first column are designated in the standard by "Degree of Hazard" using Arabic numerals
Arabic numerals are the ten numerical digits: , , , , , , , , and . They are the most commonly used symbols to write decimal numbers. They are also used for writing numbers in other systems such as octal, and for writing identifiers such as ...
(0, 1, 2, 3, 4), not to be confused with other classification systems, such as that in the NFPA 30 Flammable and Combustible Liquids Code, where flammable and combustible liquid categories are designated by "Class", using Roman numerals
Roman numerals are a numeral system that originated in ancient Rome and remained the usual way of writing numbers throughout Europe well into the Late Middle Ages. Numbers are written with combinations of letters from the Latin alphabet, eac ...
(I, II, III).
History
The development of NFPA 704 is credited to theCharlotte Fire Department
The Charlotte Fire Department provides fire suppression, emergency medical services, technical rescue services, hazardous materials mitigation, disaster response, code enforcement, fire investigations, and public education for the city of Charlo ...
after a fire at the Charlotte Chemical Company in 1959 led to severe injuries to many of the firefighters. Upon arrival, the fire crew found a fire burning inside a vat that firefighters assumed to be burning kerosene. The crew tried to suppress the fire, which resulted in the vat exploding due to metallic sodium being stored in the kerosene. Thirteen firefighters were injured, including several of whom had critical injuries and one who lost both ears and most of his face from the incident.
At the time, such vats were not labelled with the materials they contained, so firefighters didn't have the necessary information to recognize that hazardous materials were present, which required a specific response. In this case, sodium was able to react with water to release hydrogen gas and large amounts of heat, which has the potential to explode.
The Charlotte Fire Department developed training to respond to fires involving hazardous materials, ensured that protective clothing was available to those responding, and expanded the fire prevention inspection program. Fire Marshal J. F. Morris developed the diamond shaped placard as a marking system to indicate when a building contained hazardous materials, with their levels of flammability, reactivity and health effects.
See also
*Globally Harmonized System of Classification and Labeling of Chemicals
The Globally Harmonized System of Classification and Labelling of Chemicals (GHS) is an internationally agreed-upon standard managed by the United Nations that was set up to replace the assortment of hazardous material classification and labelli ...
* Hazard symbol
Hazard symbols or warning symbols are recognisable symbols designed to warn about hazardous or dangerous materials, locations, or objects, including electric currents, poisons, and radioactivity. The use of hazard symbols is often regulated by ...
* HMIS Color Bar
* Hazchem
* Hazmat
Dangerous goods, abbreviated DG, are substances that when transported are a risk to health, safety, property or the environment. Certain dangerous goods that pose risks even when not being transported are known as hazardous materials ( syllab ...
References
External links
* * * * {{Portal bar, United States NFPA Standards Safety codes