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A fire brick, firebrick, or refractory is a block of ceramic material used in lining furnaces,
kiln A kiln is a thermally insulated chamber, a type of oven, that produces temperatures sufficient to complete some process, such as hardening, drying, or chemical changes. Kilns have been used for millennia to turn objects made from clay int ...
s, fireboxes, and
fireplace A fireplace or hearth is a structure made of brick, stone or metal designed to contain a fire. Fireplaces are used for the relaxing ambiance they create and for heating a room. Modern fireplaces vary in heat efficiency, depending on the design. ...
s. A refractory brick is built primarily to withstand high temperature, but will also usually have a low
thermal conductivity The thermal conductivity of a material is a measure of its ability to conduct heat. It is commonly denoted by k, \lambda, or \kappa. Heat transfer occurs at a lower rate in materials of low thermal conductivity than in materials of high thermal ...
for greater
energy efficiency Energy efficiency may refer to: * Energy efficiency (physics), the ratio between the useful output and input of an energy conversion process ** Electrical efficiency, useful power output per electrical power consumed ** Mechanical efficiency, a ...
. Usually dense firebricks are used in applications with extreme mechanical, chemical, or thermal stresses, such as the inside of a wood-fired kiln or a furnace, which is subject to abrasion from
wood Wood is a porous and fibrous structural tissue found in the stems and roots of trees and other woody plants. It is an organic materiala natural composite of cellulose fibers that are strong in tension and embedded in a matrix of lignin th ...
, fluxing from ash or
slag Slag is a by-product of smelting ( pyrometallurgical) ores and used metals. Broadly, it can be classified as ferrous (by-products of processing iron and steel), ferroalloy (by-product of ferroalloy production) or non-ferrous/base metals (by-pr ...
, and high temperatures. In other, less harsh situations, such as in an electric- or
natural gas Natural gas (also called fossil gas or simply gas) is a naturally occurring mixture of gaseous hydrocarbons consisting primarily of methane in addition to various smaller amounts of other higher alkanes. Low levels of trace gases like carbon di ...
-fired
kiln A kiln is a thermally insulated chamber, a type of oven, that produces temperatures sufficient to complete some process, such as hardening, drying, or chemical changes. Kilns have been used for millennia to turn objects made from clay int ...
, more porous bricks, commonly known as "kiln bricks", are a better choice. They are weaker, but they are much lighter and easier to form and insulate far better than dense bricks. In any case, firebricks should not
spall Spall are fragments of a material that are broken off a larger solid body. It can be produced by a variety of mechanisms, including as a result of projectile impact, corrosion, weathering, cavitation, or excessive rolling pressure (as in a ball ...
, and their strength should hold up well during rapid temperature changes.


Manufacture

In the making of firebrick,
fireclay Fire clay is a range of refractory clays used in the manufacture of ceramics, especially fire brick. The United States Environmental Protection Agency defines fire clay very generally as a "mineral aggregate composed of hydrous silicates of alumi ...
is fired in the kiln until it is partly
vitrified Vitrification (from Latin ''vitreum'', "glass" via French ''vitrifier'') is the full or partial transformation of a substance into a glass, that is to say, a non-crystalline amorphous solid. Glasses differ from liquids structurally and glasses po ...
. For special purposes, the brick may also be glazed. There are two standard sizes of fire brick: and . Also available are firebrick "splits" which are half the thickness and are often used to line wood stoves and fireplace inserts. The dimensions of a split are usually . Fire brick was first invented in 1822 by
William Weston Young William Weston Young (1776–1847) was a British Quaker entrepreneur, artist, botanist, wreck-raiser, surveyor, potter, and inventor of the firebrick. Biography William Weston Young was born on 20 April 1776 at Lewin's Mead, Bristol, England, ...
in the
Neath Valley The Vale of Neath (or Neath Valley, Welsh: ''Cwm Nedd''), one of the South Wales Valleys, encompasses the upper reaches of the River Neath in southwest Wales. In addition to the River Neath, it is traversed by the Neath Canal and the A465 dual ...
of
Wales Wales ( cy, Cymru ) is a country that is part of the United Kingdom. It is bordered by England to the east, the Irish Sea to the north and west, the Celtic Sea to the south west and the Bristol Channel to the south. It had a population in ...
.


High temperature applications

The
silica Silicon dioxide, also known as silica, is an oxide of silicon with the chemical formula , most commonly found in nature as quartz and in various living organisms. In many parts of the world, silica is the major constituent of sand. Silica is ...
fire bricks that line
steel Steel is an alloy made up of iron with added carbon to improve its strength and fracture resistance compared to other forms of iron. Many other elements may be present or added. Stainless steels that are corrosion- and oxidation-resistant t ...
-making furnaces are used at temperatures up to , which would melt many other types of ceramic, and in fact part of the silica firebrick liquefies. High-temperature Reusable Surface Insulation (HRSI), a material with the same composition, was used in the insulating tiles of the
Space Shuttle The Space Shuttle is a retired, partially reusable launch system, reusable low Earth orbital spacecraft system operated from 1981 to 2011 by the U.S. National Aeronautics and Space Administration (NASA) as part of the Space Shuttle program. I ...
. Non-ferrous metallurgical processes use ''basic'' refractory bricks because the slags used in these processes readily dissolve the "acidic" silica bricks. The most common basic refractory bricks used in smelting non-ferrous metal concentrates are "chrome-magnesite" or "magnesite-chrome" bricks (depending on the relative ratios of
magnesite Magnesite is a mineral with the chemical formula ( magnesium carbonate). Iron, manganese, cobalt, and nickel may occur as admixtures, but only in small amounts. Occurrence Magnesite occurs as veins in and an alteration product of ultramafic ...
and
chromite Chromite is a crystalline mineral composed primarily of iron(II) oxide and chromium(III) oxide compounds. It can be represented by the chemical formula of FeCr2O4. It is an oxide mineral belonging to the spinel group. The element magnesium can s ...
ores used in their manufacture).


Lower temperature applications

A range of other materials find use as firebricks for lower
temperature Temperature is a physical quantity that expresses quantitatively the perceptions of hotness and coldness. Temperature is measured with a thermometer. Thermometers are calibrated in various temperature scales that historically have relied o ...
applications.
Magnesium oxide Magnesium oxide ( Mg O), or magnesia, is a white hygroscopic solid mineral that occurs naturally as periclase and is a source of magnesium (see also oxide). It has an empirical formula of MgO and consists of a lattice of Mg2+ ions and O2− ions ...
is often used as a lining for furnaces. Silica bricks are the most common type of bricks used for the inner lining of furnaces and
incinerator Incineration is a waste treatment process that involves the combustion of substances contained in waste materials. Industrial plants for waste incineration are commonly referred to as waste-to-energy facilities. Incineration and other high ...
s. As the inner lining is usually of sacrificial nature, fire bricks of higher alumina content may be employed to lengthen the duration between re-linings. Very often cracks can be seen in this sacrificial inner lining shortly after being put into operation. They revealed more expansion joints should have been put in the first place, but these now become expansion joints themselves and are of no concern as long as structural integrity is not affected. Silicon carbide, with high abrasive strength, is a popular material for hearths of
incinerator Incineration is a waste treatment process that involves the combustion of substances contained in waste materials. Industrial plants for waste incineration are commonly referred to as waste-to-energy facilities. Incineration and other high ...
s and cremators. Common red clay brick may be used for chimneys and wood-fired ovens.


See also

*
Harbison-Walker Refractories Company Harbison-Walker Refractories Company originated as the Star Firebrick Company on March 7, 1865, with Articles of Association by a group of Pittsburgh and Allegheny residents. On January 30, 1875, Hay Walker Sr. and Samuel P. Harbison entered Articl ...
*
Equivalent VIII ''Equivalent VIII'', 1966, 120 Firebricks, 5 x 27 x 90 ¼ inches, occasionally referred to as ''The Bricks'', is the last of a series of minimalist sculptures by Carl Andre. The sculpture consists of 120 fire bricks, arranged in two layers, in ...
*
Niles Firebrick Niles Firebrick was manufactured by the Niles Fire brick Company since it was created in 1872 by John Rhys Thomas until the company was sold in 1953 and completely shutdown in 1960. Capital to establish the company was provided by Lizzie B. Ward to ...


References


Further reading

* {{DEFAULTSORT:Fire Brick Bricks Refractory materials Silicates