
Fritware, also known as stone-paste, is a type of
pottery
Pottery is the process and the products of forming vessels and other objects with clay and other raw materials, which are fired at high temperatures to give them a hard and durable form. The place where such wares are made by a ''potter'' is al ...
in which ground glass (
frit
A frit is a ceramic composition that has been fused, quenched, and granulated. Frits form an important part of the batches used in compounding enamels and ceramic glazes; the purpose of this pre-fusion is to render any soluble and/or toxic com ...
) is added to
clay
Clay is a type of fine-grained natural soil material containing clay minerals (hydrous aluminium phyllosilicates, e.g. kaolinite, ). Most pure clay minerals are white or light-coloured, but natural clays show a variety of colours from impuriti ...
to reduce its fusion temperature. The mixture may include
quartz
Quartz is a hard, crystalline mineral composed of silica (silicon dioxide). The Atom, atoms are linked in a continuous framework of SiO4 silicon–oxygen Tetrahedral molecular geometry, tetrahedra, with each oxygen being shared between two tet ...
or other siliceous material. An organic compound such as
gum or
glue
Adhesive, also known as glue, cement, mucilage, or paste, is any non-metallic substance applied to one or both surfaces of two separate items that binds them together and resists their separation.
The use of adhesives offers certain advantage ...
may be added for binding. The resulting mixture can be fired at a lower temperature than clay alone. A
glaze is then applied on the surface.
Fritware was invented to give a strong white body, which, combined with
tin-glazing
Tin-glazing is the process of giving tin-glazed pottery items a ceramic glaze that is white, glossy and opaque, which is normally applied to red or buff earthenware. Tin-glaze is plain lead glaze with a small amount of tin oxide added.Caiger-S ...
of the surface, allowed it to approximate the result of
Chinese porcelain
Chinese ceramics are one of the most significant forms of Chinese art and ceramics globally. They range from construction materials such as bricks and tiles, to hand-built pottery vessels fired in bonfires or kilns, to the sophisticated Chinese ...
.
Porcelain
Porcelain (), also called china, is a ceramic material made by heating Industrial mineral, raw materials, generally including kaolinite, in a kiln to temperatures between . The greater strength and translucence of porcelain, relative to oth ...
was not manufactured in the Islamic world until modern times, and most fine
Islamic pottery
Islamic pottery occupied a geographical position between Chinese ceramics, and the pottery of the Byzantine Empire and Europe. For most of the period, it made great aesthetic achievements and influence as well, influencing Byzantium and Europe ...
was made of fritware. Frit was also a significant component in some early European porcelains.
Composition and techniques
Fritware was invented in the Medieval Islamic world to give a strong white body, which, combined with
tin-glazing
Tin-glazing is the process of giving tin-glazed pottery items a ceramic glaze that is white, glossy and opaque, which is normally applied to red or buff earthenware. Tin-glaze is plain lead glaze with a small amount of tin oxide added.Caiger-S ...
of the surface, allowed it to approximate the white colour, translucency, and thin walls of
Chinese porcelain
Chinese ceramics are one of the most significant forms of Chinese art and ceramics globally. They range from construction materials such as bricks and tiles, to hand-built pottery vessels fired in bonfires or kilns, to the sophisticated Chinese ...
. True
porcelain
Porcelain (), also called china, is a ceramic material made by heating Industrial mineral, raw materials, generally including kaolinite, in a kiln to temperatures between . The greater strength and translucence of porcelain, relative to oth ...
was not manufactured in the Islamic world until modern times, and most fine
Islamic pottery
Islamic pottery occupied a geographical position between Chinese ceramics, and the pottery of the Byzantine Empire and Europe. For most of the period, it made great aesthetic achievements and influence as well, influencing Byzantium and Europe ...
was made of fritware.
Frit
A frit is a ceramic composition that has been fused, quenched, and granulated. Frits form an important part of the batches used in compounding enamels and ceramic glazes; the purpose of this pre-fusion is to render any soluble and/or toxic com ...
was also a significant component in some early European porcelains.
Although its production centres may have shifted with time and imperial power, fritware remained in continued use throughout the Islamic world with little significant innovation. The technique was used to create many other significant artistic traditions such as
lustreware
Lustreware or lusterware (the respective spellings for British English and American English) is a type of pottery or porcelain with a metallic glaze that gives the effect of iridescence. It is produced by metallic oxides in an Ceramic glaze, over ...
,
Raqqa ware, and
Iznik pottery
Iznik pottery, or Iznik ware, named after the town of İznik in Anatolia where it was made, is a decorated ceramic that was produced from the last quarter of the 15th century until the end of the 17th century. Turkish stylization is a reflectio ...
.
Raw materials in one contemporary recipe used in Jaipur are quartz powder, glass power,
fuller's earth
Fuller's earth is a term for various clays used as an absorbent, filter, or bleaching agent. Products labeled fuller's earth typically consist of palygorskite (also known as attapulgite) or bentonite. Primary modern uses include as absorbents ...
,
borax
The BORAX Experiments were a series of safety experiments on boiling water nuclear reactors conducted by Argonne National Laboratory in the 1950s and 1960s at the National Reactor Testing Station in eastern Idaho. and
tragacanth
Tragacanth is a natural gum obtained from the dried sap of several species of Middle Eastern Fabaceae, legumes of the genus ''Astragalus (plant), Astragalus'', including ''Astragalus adscendens, A. adscendens'', ''Astragalus gummifer, A. gummifer ...
gum. Raw materials for a glaze are reported to be glass powder,
lead oxide
Lead oxides are a group of inorganic compounds with formulas including lead (Pb) and oxygen
Oxygen is a chemical element; it has chemical symbol, symbol O and atomic number 8. It is a member of the chalcogen group (periodic table), gr ...
, borax,
potassium nitrate
Potassium nitrate is a chemical compound with a sharp, salty, bitter taste and the chemical formula . It is a potassium salt of nitric acid. This salt consists of potassium cations and nitrate anions , and is therefore an alkali metal nit ...
,
zinc oxide
Zinc oxide is an inorganic compound with the Chemical formula, formula . It is a white powder which is insoluble in water. ZnO is used as an additive in numerous materials and products including cosmetics, Zinc metabolism, food supplements, rubbe ...
and
boric acid
Boric acid, more specifically orthoboric acid, is a compound of boron, oxygen, and hydrogen with formula . It may also be called hydrogen orthoborate, trihydroxidoboron or boracic acid. It is usually encountered as colorless crystals or a white ...
. The blue decoration is
cobalt oxide Cobalt oxide is a family of chemical compounds consisting of cobalt and oxygen atoms.
Compounds in the cobalt oxide family include:
* Cobalt(II) oxide (cobaltous oxide), CoO
* Cobalt(III) oxide (cobaltic oxide), Co2O3
*Cobalt(II,III) oxide
Co ...
.
History
Frit
A frit is a ceramic composition that has been fused, quenched, and granulated. Frits form an important part of the batches used in compounding enamels and ceramic glazes; the purpose of this pre-fusion is to render any soluble and/or toxic com ...
is crushed glass that is used in ceramics. The pottery produced from the manufacture of frit is often called 'fritware' but has also been referred to as "stonepaste" and "
faience
Faience or faïence (; ) is the general English language term for fine tin-glazed pottery. The invention of a white Ceramic glaze, pottery glaze suitable for painted decoration, by the addition of an stannous oxide, oxide of tin to the Slip (c ...
" among other names.
Fritware was innovative because the glaze and the body of the ceramic piece were made of nearly the same materials, allowing them to fuse better, be less likely to flake, and could also be fired at a lower temperature.
The manufacture of proto-fritware began in Iraq in the 9th century AD under the
Abbasid Caliphate
The Abbasid Caliphate or Abbasid Empire (; ) was the third caliphate to succeed the Islamic prophet Muhammad. It was founded by a dynasty descended from Muhammad's uncle, Abbas ibn Abd al-Muttalib (566–653 CE), from whom the dynasty takes ...
,
[''Archaeological chemistry'' by Zvi Goffer p.254](_blank)
/ref> and with the establishment of Samarra
Samarra (, ') is a city in Iraq. It stands on the east bank of the Tigris in the Saladin Governorate, north of Baghdad. The modern city of Samarra was founded in 836 by the Abbasid caliph al-Mu'tasim as a new administrative capital and mi ...
as its capital in 836, there is extensive evidence of ceramics in the court of the Abbasids both in Samarra and Baghdad. A ninth-century corpus of 'proto-stonepaste' from Baghdad
Baghdad ( or ; , ) is the capital and List of largest cities of Iraq, largest city of Iraq, located along the Tigris in the central part of the country. With a population exceeding 7 million, it ranks among the List of largest cities in the A ...
has "relict glass fragments" in its fabric. The glass is alkali-lime-lead-silica and, when the paste was fired or cooled, wollastonite
Wollastonite is a calcium Silicate minerals, inosilicate mineral (calcium, Casilicon, Sioxygen, O3) that may contain small amounts of iron, magnesium, and manganese substituting for calcium. It is usually white. It forms when impure limestone or D ...
and diopside crystals formed within the glass fragments. The lack of "inclusions of crushed pottery" suggests these fragments did not come from a glaze. The reason for their addition would have been to release alkali into the matrix on firing, which would "accelerate vitrification at a relatively low firing temperature, and thus increase the hardness and density of the eramicbody."
Following the fall of the Abbasid Caliphate, the main centres of manufacture moved to Egypt
Egypt ( , ), officially the Arab Republic of Egypt, is a country spanning the Northeast Africa, northeast corner of Africa and Western Asia, southwest corner of Asia via the Sinai Peninsula. It is bordered by the Mediterranean Sea to northe ...
where true fritware was invented between the 10th and the 12th centuries under the Fatimids
The Fatimid Caliphate (; ), also known as the Fatimid Empire, was a caliphate extant from the tenth to the twelfth centuries CE under the rule of the Fatimid dynasty, Fatimids, an Isma'ili Shi'a dynasty. Spanning a large area of North Africa ...
, but the technique then spread throughout the Middle East
The Middle East (term originally coined in English language) is a geopolitical region encompassing the Arabian Peninsula, the Levant, Turkey, Egypt, Iran, and Iraq.
The term came into widespread usage by the United Kingdom and western Eur ...
.
There are many variations on designs, colour, and composition, the last often attributed to the differences in mineral compositions of soil and rock used in the production of fritware. The bodies of the fritware ceramics were always made quite thin to imitate their porcelain counterparts in China, a practice not common before the discovery of the frit technique which produced stronger ceramics.[ In the 13th century the town of ]Kashan
Kashan (; ) is a city in the Central District (Kashan County), Central District of Kashan County, in the northern part of Isfahan province, Isfahan province, Iran, serving as capital of both the county and the district.
History
Earlies ...
in Iran was an important centre for the production of fritware. Abū'l-Qāsim, who came from a family of tilemakers in the city, wrote a treatise in 1301 on precious stones that included a chapter on the manufacture of fritware.[ His recipe specified a fritware body containing a mixture of 10 parts ]silica
Silicon dioxide, also known as silica, is an oxide of silicon with the chemical formula , commonly found in nature as quartz. In many parts of the world, silica is the major constituent of sand. Silica is one of the most complex and abundant f ...
to 1 part glass frit and 1 part clay. The frit was prepared by mixing powdered quartz with soda which acted as a flux
Flux describes any effect that appears to pass or travel (whether it actually moves or not) through a surface or substance. Flux is a concept in applied mathematics and vector calculus which has many applications in physics. For transport phe ...
. The mixture was then heated in a kiln.[ The internal circulation of pottery within the Islamic world from its earliest days was quite common, with the movement of ideas regarding pottery without their physical presence in certain areas being readily apparent.][ The movement of fritware into ]China
China, officially the People's Republic of China (PRC), is a country in East Asia. With population of China, a population exceeding 1.4 billion, it is the list of countries by population (United Nations), second-most populous country after ...
- whose monopoly on porcelain production had prompted the Islamic world to produce fritware to begin with - impacted Chinese porcelain
Chinese ceramics are one of the most significant forms of Chinese art and ceramics globally. They range from construction materials such as bricks and tiles, to hand-built pottery vessels fired in bonfires or kilns, to the sophisticated Chinese ...
decoration, deriving the signature cobalt blue
Cobalt blue is a blue pigment made by sintering cobalt(II) oxide with aluminium(III) oxide (alumina) at 1200 °C. Chemically, cobalt blue pigment is cobalt(II) oxide-aluminium oxide, or cobalt(II) aluminate, CoAl2O4. Cobalt blue is lighte ...
colour from Islamic traditions of fritware decoration. The transfer of this artistic idea was likely a consequence of the enhanced connection and trade relations between the Middle and Near East and Far East Asia under the Mongols beginning in the 13th century. The Middle and Near East had an initial monopoly on the cobalt colour due to its own richness in cobalt ore, which was especially abundant in Qamsar and Anarak in Persia.
Iznik pottery
Iznik pottery, or Iznik ware, named after the town of İznik in Anatolia where it was made, is a decorated ceramic that was produced from the last quarter of the 15th century until the end of the 17th century. Turkish stylization is a reflectio ...
was produced in Ottoman Turkey
The Ottoman Empire (), also called the Turkish Empire, was an imperial realm that controlled much of Southeast Europe, West Asia, and North Africa from the 14th to early 20th centuries; it also controlled parts of southeastern Central Euro ...
beginning in the last quarter of 15th century AD. It consists of a body, slip, and glaze, where the body and glaze are 'quartz-frit'. The 'frits' in both cases "are unusual in that they contain lead oxide as well as soda"; the lead oxide would help reduce the thermal expansion coefficient
Thermal expansion is the tendency of matter to increase in length, area, or volume, changing its size and density, in response to an increase in temperature (usually excluding phase transitions).
Substances usually contract with decreasing temp ...
of the ceramic. Microscopic analysis reveals that the material that has been labeled 'frit' is 'interstitial glass' which serves to connect the quartz particles. The glass was added as frit and the interstitial glass formed on firing.
In 2011, 29 potteries, employing a total of 300 persons, making fritware were identified in Jaipur.
Applications
Fritware served a wide variety of purposes in the medieval Islamic world. As a porcelain substitute, the fritware technique was used to craft bowls, vases, and pots, not only as symbols of luxury but also to practical ends. It was similarly used by medieval tilemakers to craft strong tiles with a colourless body that provided a suitable base for underglaze and decoration. Fritware was also known to be used to craft objects beyond pottery and tiling, and has been found to be used in the twelfth century to make objects like chess sets. There is also a tradition of using fritware to create intricate figurines, with surviving examples from the Seljuk Empire
The Seljuk Empire, or the Great Seljuk Empire, was a High Middle Ages, high medieval, culturally Turco-Persian tradition, Turco-Persian, Sunni Islam, Sunni Muslim empire, established and ruled by the Qiniq (tribe), Qïnïq branch of Oghuz Turks. ...
.
It was also used as the ceramic body for Islamic lustreware
Lustreware or lusterware (the respective spellings for British English and American English) is a type of pottery or porcelain with a metallic glaze that gives the effect of iridescence. It is produced by metallic oxides in an Ceramic glaze, over ...
, a technique that puts a lustred ceramic glaze
Ceramic glaze, or simply glaze, is a glassy coating on ceramics. It is used for decoration, to ensure the item is impermeable to liquids and to minimize the adherence of pollutants.
Glazing renders earthenware impermeable to water, sealing th ...
onto pottery.
Blue pottery
A small manufacturing cluster of fritware exists around Jaipur
Jaipur (; , ) is the List of state and union territory capitals in India, capital and the List of cities and towns in Rajasthan, largest city of the north-western States and union territories of India, Indian state of Rajasthan. , the city had ...
, Rajasthan
Rajasthan (; Literal translation, lit. 'Land of Kings') is a States and union territories of India, state in northwestern India. It covers or 10.4 per cent of India's total geographical area. It is the List of states and union territories of ...
in India, where it is known as 'Blue Pottery' due its most popular glaze. The Blue Pottery of Jaipur technique may have arrived in India with the Mughals
The Mughal Empire was an early modern empire in South Asia. At its peak, the empire stretched from the outer fringes of the Indus River Basin in the west, northern Afghanistan in the northwest, and Kashmir in the north, to the highlands of pre ...
, with production in Jaipur dating to at least as early as the 17th century.['Tryst with Tradition - Exploring Rajasthan Through the Alankar Museum' Jawahar Kala Kendra. Alankar Museum. 2011. Pg. 6]
References
Further reading
*
*
* "Technology of Frit Making in Iznik." Okyar F. Euro Ceramics VIII, Part 3. Trans Tech Publications. 2004, p. 2391-2394. Published for The European Ceramic Society.
* Pancaroğlu, O. (2007). ''Perpetual glory: Medieval Islamic ceramics from the Harvey B. Plotnick Collection'' (1055933707 805629715 M. Bayani, Trans.). Chicago, IL: Art Institute of Chicago.
* Watson, O. (2004). ''Ceramics from Islamic lands''. New York, NY: Thames & Hudson.
{{Islamic art
Pottery
Arabic pottery
Iranian pottery
Ceramic materials
Islamic pottery
Arab inventions