Frederick Guthrie (scientist)
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Frederick Guthrie FRS
FRSE Fellowship of the Royal Society of Edinburgh (FRSE) is an award granted to individuals that the Royal Society of Edinburgh, Scotland's national academy of science and Literature, letters, judged to be "eminently distinguished in their subject". ...
(15 October 1833 – 21 October 1886) was a
British British may refer to: Peoples, culture, and language * British people, nationals or natives of the United Kingdom, British Overseas Territories and Crown Dependencies. * British national identity, the characteristics of British people and culture ...
physicist, chemist, and academic author. He was the son of Alexander Guthrie, a London tradesman, and the younger brother of mathematician
Francis Guthrie Francis Guthrie (born 22 January 1831 in London; d. 19 October 1899 in Claremont, Cape Town) was a Cape Colony mathematician and botanist who first posed the Four Colour Problem in 1852. He studied mathematics under Augustus De Morgan, and bo ...
. Along with William Fletcher Barrett he founded the Physical Society of London (now the
Institute of Physics The Institute of Physics (IOP) is a UK-based not-for-profit learned society and professional body that works to advance physics education, physics research, research and applied physics, application. It was founded in 1874 and has a worldwide ...
) in 1874 and was president of the society from 1884 until 1886. He believed that science should be based on experimentation rather than discussion.


Academic career

His academic career started at
University College, London University College London (Trade name, branded as UCL) is a Public university, public research university in London, England. It is a Member institutions of the University of London, member institution of the Federal university, federal Uni ...
, where he studied for three years. He studied chemistry under Thomas Graham and
Alexander William Williamson Alexander William Williamson Fellow of the Royal Society, FRS FRSE Chemical Society, PCS MRIA (1 May 18246 May 1904) was an English chemist. He is best known today for the Williamson ether synthesis. Life Williamson was born in 1824 in Wands ...
and mathematics under
Augustus De Morgan Augustus De Morgan (27 June 1806 – 18 March 1871) was a British mathematician and logician. He is best known for De Morgan's laws, relating logical conjunction, disjunction, and negation, and for coining the term "mathematical induction", the ...
. In 1852, he submitted his brother Francis's observations to De Morgan. In 1854 Guthrie went to
Heidelberg Heidelberg (; ; ) is the List of cities in Baden-Württemberg by population, fifth-largest city in the States of Germany, German state of Baden-Württemberg, and with a population of about 163,000, of which roughly a quarter consists of studen ...
to study under
Robert Bunsen Robert Wilhelm Eberhard Bunsen (; 30 March 1811 – 16 August 1899) was a German chemist. He investigated emission spectra of heated elements, and discovered caesium (in 1860) and rubidium (in 1861) with the physicist Gustav Kirchhoff. The Bu ...
and then in 1855 obtained a PhD at the
University of Marburg The Philipps University of Marburg () is a public research university located in Marburg, Germany. It was founded in 1527 by Philip I, Landgrave of Hesse, which makes it one of Germany's oldest universities and the oldest still operating Prote ...
under Adolph Wilhelm Hermann Kolbe. In 1856 he joined Edward Frankland, professor of chemistry at Owens College, Manchester. In 1859 he went to the
University of Edinburgh The University of Edinburgh (, ; abbreviated as ''Edin.'' in Post-nominal letters, post-nominals) is a Public university, public research university based in Edinburgh, Scotland. Founded by the City of Edinburgh Council, town council under th ...
. Guthrie synthesized
mustard gas Mustard gas or sulfur mustard are names commonly used for the organosulfur compound, organosulfur chemical compound bis(2-chloroethyl) sulfide, which has the chemical structure S(CH2CH2Cl)2, as well as other Chemical species, species. In the wi ...
in 1860 from
ethylene Ethylene (IUPAC name: ethene) is a hydrocarbon which has the formula or . It is a colourless, flammable gas with a faint "sweet and musky" odour when pure. It is the simplest alkene (a hydrocarbon with carbon–carbon bond, carbon–carbon doub ...
and
sulfur dichloride Sulfur dichloride is the chemical compound with the formula . This cherry-red liquid is the simplest sulfur chloride and one of the most common, and it is used as a precursor to organosulfur compounds. It is a highly corrosive and toxic substance ...
. Guthrie was probably not the first to synthesize mustard gas, but he was among the first to document its toxic effects. Guthrie did his mustard gas synthesis at almost the same time as Albert Niemann, who also synthesized mustard gas and noted its toxic effects in his own experiments. Both Guthrie and Niemann published their findings on 1 January 1860. In 1860 Guthrie was elected a Fellow of the
Royal Society of Edinburgh The Royal Society of Edinburgh (RSE) is Scotland's national academy of science and letters. It is a registered charity that operates on a wholly independent and non-partisan basis and provides public benefit throughout Scotland. It was establis ...
, his proposer being Lyon Playfair. He was elected a Fellow of the
Royal Society of London The Royal Society, formally The Royal Society of London for Improving Natural Knowledge, is a learned society and the United Kingdom's national academy of sciences. The society fulfils a number of roles: promoting science and its benefits, r ...
in 1871. He served as professor of chemistry and physics at the Royal College of Mauritius between 1861 and 1867. Guthrie was later a professor at the Royal School of Mines in London, where he mentored the future experimental physicist
C. V. Boys Sir Charles Vernon Boys, Fellow of the Royal Society, FRS (15 March 1855 – 30 March 1944) was a British physicist, known for his careful and innovative experimental work in the fields of thermodynamics and high-speed photography, and as a pop ...
. He also mentored
John Ambrose Fleming Sir John Ambrose Fleming (29 November 1849 – 18 April 1945) was an English electrical engineer who invented the vacuum tube, designed the radio transmitter with which the first transatlantic radio transmission was made, and also established ...
and was instrumental in turning his interest from chemistry to electricity. He invented the thermionic diode 1873 (for which alternate credit was sometimes later given to Edison's assistant W. J. Hammer) and coined the term eutectic in 1884. Guthrie wrote ''Elements of Heat'' in 1868 and ''Magnetism and Electricity'' in 1873 (published in 1876). Guthrie was also a linguist, playwright, and poet. Under the name Frederick Cerny, he wrote the poems ''The Jew'' (1863) and ''Logrono'' (1877). Guthrie died in 1886 and is buried in
Kensal Green Cemetery Kensal Green Cemetery is a cemetery in the Kensal Green area of North Kensington in the Royal Borough of Kensington and Chelsea and the London Borough of Hammersmith and Fulham in London, England. Inspired by Père Lachaise Cemetery in P ...
in
London London is the Capital city, capital and List of urban areas in the United Kingdom, largest city of both England and the United Kingdom, with a population of in . London metropolitan area, Its wider metropolitan area is the largest in Wester ...
.


Family

He was married four times. His son Frederick Bickell Guthrie was an agricultural chemist.


References

1833 births 1886 deaths British physicists British chemists Presidents of the Physical Society Alumni of University College London University of Marburg alumni Academics of the University of Edinburgh Burials at Kensal Green Cemetery {{UK-physicist-stub