Edward A. Guggenheim
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Edward Armand Guggenheim FRS (11 August 1901 – 9 August 1970) was an English
physical chemist Physical chemistry is the study of macroscopic and microscopic phenomena in chemical systems in terms of the principles, practices, and concepts of physics such as motion, energy, force, time, thermodynamics, quantum chemistry, statistical mecha ...
, noted for his contributions to
thermodynamics Thermodynamics is a branch of physics that deals with heat, Work (thermodynamics), work, and temperature, and their relation to energy, entropy, and the physical properties of matter and radiation. The behavior of these quantities is governed b ...
.


Life

Guggenheim was born in
Manchester Manchester () is a city and the metropolitan borough of Greater Manchester, England. It had an estimated population of in . Greater Manchester is the third-most populous metropolitan area in the United Kingdom, with a population of 2.92&nbs ...
11 August 1901, the son of Armand Guggenheim and Marguerite Bertha Simon. His father was
Swiss Swiss most commonly refers to: * the adjectival form of Switzerland * Swiss people Swiss may also refer to: Places * Swiss, Missouri * Swiss, North Carolina * Swiss, West Virginia * Swiss, Wisconsin Other uses * Swiss Café, an old café located ...
, a naturalised
British citizen The primary law governing nationality in the United Kingdom is the British Nationality Act 1981, which came into force on 1 January 1983. Regulations apply to the British Islands, which include the UK itself (England, Wales, Scotland, and Nor ...
. Guggenheim married Simone Ganzin (died 1954), in 1934 and Ruth Helen Aitkin, born Clarke, widow, in 1955. They had no children. He died in
Reading, Berkshire Reading ( ) is a town and borough in Berkshire, England, and the county town of Berkshire. It is the United Kingdom's largest town, with a combined population of 355,596. Most of Reading built-up area, its built-up area lies within the Borough ...
9 August 1970.


Education

Guggenheim was educated at Terra Nova School,
Southport Southport is a seaside resort, seaside town in the Metropolitan Borough of Sefton in Merseyside, England. It lies on the West Lancashire Coastal Plain, West Lancashire coastal plain and the east coast of the Irish Sea, approximately north of ...
,
Charterhouse School Charterhouse is a Public school (United Kingdom), public school (English independent boarding school for pupils aged 13–18) in Godalming, Surrey, England. Founded by Thomas Sutton in 1611 on the site of the old Carthusian monastery in Charter ...
and
Gonville and Caius College, Cambridge Gonville and Caius College, commonly known as Caius ( ), is a constituent college of the University of Cambridge in Cambridge, England. Founded in 1348 by Edmund Gonville, it is the fourth-oldest of the University of Cambridge's 31 colleges and ...
, where he obtained firsts in both the mathematics part 1 and chemistry part 2 triposes. Unable to gain a fellowship at the college, he went to
Denmark Denmark is a Nordic countries, Nordic country in Northern Europe. It is the metropole and most populous constituent of the Kingdom of Denmark,, . also known as the Danish Realm, a constitutionally unitary state that includes the Autonomous a ...
where he studied under J. N. Brønsted at the
University of Copenhagen The University of Copenhagen (, KU) is a public university, public research university in Copenhagen, Copenhagen, Denmark. Founded in 1479, the University of Copenhagen is the second-oldest university in Scandinavia, after Uppsala University. ...
.


Career

Returning to England, he found a place at
University College In a number of countries, a university college is a college institution that provides tertiary education but does not have full or independent university status. A university college is often part of a larger university. The precise usage varies f ...
, London where he wrote his first book, ''Modern Thermodynamics by the Methods of
Willard Gibbs Josiah Willard Gibbs (; February 11, 1839 – April 28, 1903) was an American mechanical engineer and scientist who made fundamental theoretical contributions to physics, chemistry, and mathematics. His work on the applications of thermodynami ...
'' (1933), which "established his reputation and revolutionized the teaching of the subject". He was also a visiting professor of chemistry at
Stanford University Leland Stanford Junior University, commonly referred to as Stanford University, is a Private university, private research university in Stanford, California, United States. It was founded in 1885 by railroad magnate Leland Stanford (the eighth ...
, and later became a reader in the
chemical engineering Chemical engineering is an engineering field which deals with the study of the operation and design of chemical plants as well as methods of improving production. Chemical engineers develop economical commercial processes to convert raw materials ...
department at
Imperial College London Imperial College London, also known as Imperial, is a Public university, public research university in London, England. Its history began with Prince Albert of Saxe-Coburg and Gotha, Prince Albert, husband of Queen Victoria, who envisioned a Al ...
. During
World War II World War II or the Second World War (1 September 1939 – 2 September 1945) was a World war, global conflict between two coalitions: the Allies of World War II, Allies and the Axis powers. World War II by country, Nearly all of the wo ...
he worked on defence matters for the
navy A navy, naval force, military maritime fleet, war navy, or maritime force is the military branch, branch of a nation's armed forces principally designated for naval warfare, naval and amphibious warfare; namely, lake-borne, riverine, littoral z ...
. In 1946 he was appointed professor of chemistry and head of department at
Reading University The University of Reading is a public research university in Reading, Berkshire, England. It was founded in 1892 as the University Extension College, Reading, an extension college of Christchurch College, Oxford, and became University College, ...
, where he stayed until his retirement in 1966.


Publications

Guggenheim produced eleven books and more than 100 papers. His first book,''Modern Thermodynamics by the Methods of Willard Gibbs'' (1933), was a 206-page, detailed study, with text, figures, index, and preface by F. G. Donnan, showing how the analytical thermodynamic methods developed by
Willard Gibbs Josiah Willard Gibbs (; February 11, 1839 – April 28, 1903) was an American mechanical engineer and scientist who made fundamental theoretical contributions to physics, chemistry, and mathematics. His work on the applications of thermodynami ...
leads in a straightforward manner to relations such as phases, constants, solution, systems, and laws, that are unambiguous and exact. This book, together with
Gilbert N. Lewis Gilbert Newton Lewis (October 23 or October 25, 1875 – March 23, 1946) was an American physical chemist and a dean of the college of chemistry at University of California, Berkeley. Lewis was best known for his discovery of the covalent bon ...
and Merle Randall's 1923 textbook ''Thermodynamics and the Free Energy of Chemical Substances'', are said to be responsible for the inception of the modern science of
chemical thermodynamics Chemical thermodynamics is the study of the interrelation of heat and work with chemical reactions or with physical changes of state within the confines of the laws of thermodynamics. Chemical thermodynamics involves not only laboratory measure ...
. Other books included ''Statistical Thermodynamics'' with Ralph Fowler (1939), and ''Thermodynamics – an Advanced Treatment for Chemists and Physicists'' . In the preface to this book, he states that no thermodynamics book written before 1929 even attempts an account of any of the following matters: # The modern definition of heat given by
Max Born Max Born (; 11 December 1882 – 5 January 1970) was a German-British theoretical physicist who was instrumental in the development of quantum mechanics. He also made contributions to solid-state physics and optics, and supervised the work of a ...
in 1921. # The quantal theory of the
entropy Entropy is a scientific concept, most commonly associated with states of disorder, randomness, or uncertainty. The term and the concept are used in diverse fields, from classical thermodynamics, where it was first recognized, to the micros ...
of gases and its experimental verification. #
Peter Debye Peter Joseph William Debye ( ; born Petrus Josephus Wilhelmus Debije, ; March 24, 1884 – November 2, 1966) was a Dutch-American physicist and physical chemist, and Nobel laureate in Chemistry. Biography Early life Born in Maastricht, Neth ...
's formulae for the
activity coefficient In thermodynamics, an activity coefficient is a factor used to account for deviation of a mixture of chemical substances from ideal behaviour. In an ideal mixture, the microscopic interactions between each pair of chemical species are the same ( ...
s of
electrolytes An electrolyte is a substance that conducts electricity through the movement of ions, but not through the movement of electrons. This includes most soluble salts, acids, and bases, dissolved in a polar solvent like water. Upon dissolving, t ...
. # The use of electrochemical potentials of ions # The application of thermodynamics to dielectrics and to paramagnetic substances.


Honours and awards

Guggenheim was elected a Fellow of the
Royal Society The Royal Society, formally The Royal Society of London for Improving Natural Knowledge, is a learned society and the United Kingdom's national academy of sciences. The society fulfils a number of roles: promoting science and its benefits, re ...
in 1946. His nomination reads In 1972, the E. A. Guggenheim Memorial Fund was established by friends and colleagues. The income from the fund is used to (a) award an annual prize and (b) to provide a biennial or triennial memorial lecture on some topic of chemistry or physics appropriate to the interests of Guggenheim.E. A. Guggenheim Memorial Fund
– established in 1972
The Guggenheim Medal was introduced in 2014 by the
Institution of Chemical Engineers The Institution of Chemical Engineers (IChemE) is a global professional engineering institution with 30,000 members in 114 countries. It was founded in 1922 and awarded a Royal Charter in 1957. The Institution has offices in Rugby, Warwickshire, ...
for significant contributions to research in thermodynamics and / or complex fluids. The first recipient (in 2015) was Professor George Jackson of
Imperial College London Imperial College London, also known as Imperial, is a Public university, public research university in London, England. Its history began with Prince Albert of Saxe-Coburg and Gotha, Prince Albert, husband of Queen Victoria, who envisioned a Al ...
.www.icheme.org
George Jackson receives first Guggenheim medal
''The Chemical Engineer'', March 2015 p 52 "Winners of 2014 medals announced"


See also

* Guggenheim scheme * Stavermann–Guggenheim equation *
Bromley equation The Bromley equation was developed in 1973 by Leroy A. Bromley with the objective of calculating activity coefficients for aqueous electrolyte solutions whose concentrations are above the range of validity of the Debye–Hückel equation. This eq ...
* Entropy (energy dispersal) *
Non-random two-liquid model The non-random two-liquid model (abbreviated NRTL model) is an activity coefficient model introduced by Renon and John Prausnitz, Prausnitz in 1968 that correlates the activity coefficients \gamma_i of a compound with its mole fractions x_i in th ...
* Specific ion interaction theory *
Thermodynamic activity In thermodynamics, activity (symbol ) is a measure of the "effective concentration" of a species in a mixture, in the sense that the species' chemical potential depends on the activity of a real solution in the same way that it would depend on conc ...


References

{{DEFAULTSORT:Guggenheim, Edward A 1901 births 1970 deaths People educated at Charterhouse School Alumni of Gonville and Caius College, Cambridge English chemists Thermodynamicists Academics of the University of Reading Fellows of the Royal Society