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Donald Lee Klein (born December 19, 1930) is an American inventor and
chemist A chemist (from Greek ''chēm(ía)'' alchemy; replacing ''chymist'' from Medieval Latin ''alchemist'') is a scientist trained in the study of chemistry. Chemists study the composition of matter and its properties. Chemists carefully describe t ...
, most known for inventing the process to fabricate the
self-aligned gate In semiconductor electronics fabrication technology, a self-aligned gate is a transistor manufacturing approach whereby the gate electrode of a MOSFET (metal–oxide–semiconductor field-effect transistor) is used as a mask for the doping of ...
MOSFET
transistor upright=1.4, gate (G), body (B), source (S) and drain (D) terminals. The gate is separated from the body by an insulating layer (pink). A transistor is a semiconductor device used to Electronic amplifier, amplify or electronic switch, switch ...
along with Robert E. Kerwin and John C. Sarace in 1967 at
Bell Labs Nokia Bell Labs, originally named Bell Telephone Laboratories (1925–1984), then AT&T Bell Laboratories (1984–1996) and Bell Labs Innovations (1996–2007), is an American industrial Research and development, research and scientific developm ...
. In 1994, together with Kerwin and Sarace, Klein received the
IEEE The Institute of Electrical and Electronics Engineers (IEEE) is a 501(c)(3) professional association for electronic engineering and electrical engineering (and associated disciplines) with its corporate office in New York City and its operat ...
Jack A. Morton award (renamed in 2000 to the
IEEE Andrew S. Grove Award The IEEE Andrew S. Grove Award is a Technical Field Award presented by the IEEE for outstanding contributions to solid-state devices and technology. The award may be presented to an individual or a team of up to three people. It was established ...
) "For pioneering work and the basic
patent A patent is a type of intellectual property that gives its owner the legal right to exclude others from making, using, or selling an invention for a limited period of time in exchange for publishing an enabling disclosure of the invention."A ...
on the self-aligned silicon-gate process, a key element in fabrication of very large scale integrated circuits." That same year, Klein, Kerwin and Sarace were declared "Inventors of the Year" by the New Jersey Inventors Hall of Fame.


Early life

Klein was born in
Brooklyn, New York Brooklyn () is a borough of New York City, coextensive with Kings County, in the U.S. state of New York. Kings County is the most populous county in the State of New York, and the second-most densely populated county in the United States, be ...
to Kalman Klein, a Hungarian
Jew Jews ( he, יְהוּדִים, , ) or Jewish people are an ethnoreligious group and nation originating from the Israelites Israelite origins and kingdom: "The first act in the long drama of Jewish history is the age of the Israelites""T ...
who immigrated to the
United States The United States of America (U.S.A. or USA), commonly known as the United States (U.S. or US) or America, is a country primarily located in North America. It consists of 50 states, a federal district, five major unincorporated territori ...
at age 16, and Emily Vogel, an American born Austro-Hungarian Jew. Donald's brother Herbert, who was 7 years older, was a
radio amateur An amateur radio operator is someone who uses equipment at an amateur radio station to engage in two-way personal communications with other amateur operators on radio frequencies assigned to the amateur radio service. Amateur radio operators h ...
from a young age. He served in
WWII World War II or the Second World War, often abbreviated as WWII or WW2, was a world war that lasted from 1939 to 1945. It involved the vast majority of the world's countries—including all of the great powers—forming two opposin ...
as a
radio operator A radio operator (also, formerly, wireless operator in British and Commonwealth English) is a person who is responsible for the operations of a radio system. The profession of radio operator has become largely obsolete with the automation of ra ...
on a ship for the
Navy A navy, naval force, or maritime force is the branch of a nation's armed forces principally designated for naval and amphibious warfare; namely, lake-borne, riverine, littoral, or ocean-borne combat operations and related functions. It in ...
. For Donald's 13th birthday, Herbert gave him his first
chemistry set A chemistry set is an educational toy allowing the user (typically a teenager) to perform simple chemistry experiments. History Forerunners The forerunners of the chemistry set were 17th century books on "natural magick", "which all exce ...
(which he obtained through his Electrical Engineering studies). Klein began experimenting with the chemicals, while collecting more from family members and buying his own. Eventually he had built his own laboratory in his parents' basement. After high school, Donald followed in his brother's footsteps, becoming a licensed radio amateur.


Education

In 1945, Klein attended
Brooklyn Technical High School Brooklyn Technical High School, commonly called Brooklyn Tech and administratively designated High School 430, is an elite public high school in New York City that specializes in science, technology, engineering, and mathematics. It is one of t ...
where he took many chemistry courses including
inorganic In chemistry, an inorganic compound is typically a chemical compound that lacks carbon–hydrogen bonds, that is, a compound that is not an organic compound. The study of inorganic compounds is a subfield of chemistry known as ''inorganic chemist ...
, qualitative and quantitative analysis,
organic chemistry Organic chemistry is a subdiscipline within chemistry involving the scientific study of the structure, properties, and reactions of organic compounds and organic materials, i.e., matter in its various forms that contain carbon atoms.Clayden, ...
,
physical chemistry Physical chemistry is the study of macroscopic and microscopic phenomena in chemical systems in terms of the principles, practices, and concepts of physics such as motion, energy, force, time, thermodynamics, quantum chemistry, statistica ...
and
chemical engineering Chemical engineering is an engineering field which deals with the study of operation and design of chemical plants as well as methods of improving production. Chemical engineers develop economical commercial processes to convert raw materials int ...
. After high school, Klein attended Polytechnic Institute of Brooklyn (now
New York University Tandon School of Engineering The New York University Tandon School of Engineering (commonly referred to as Tandon) is the engineering and applied sciences school of New York University. Tandon is the second oldest private engineering and technology school in the United Sta ...
). After briefly debating between Metallurgy and inorganic chemistry, Klein decided to major in inorganic chemistry. Eager to combine his passions of chemistry and electronics, Klein decided to research
radio frequency Radio frequency (RF) is the oscillation rate of an alternating electric current or voltage or of a magnetic, electric or electromagnetic field or mechanical system in the frequency range from around to around . This is roughly between the ...
titrimetry Titration (also known as titrimetry and volumetric analysis) is a common laboratory method of quantitative chemical analysis to determine the concentration of an identified analyte (a substance to be analyzed). A reagent, termed the ''titrant'' ...
for his undergraduate thesis, a new field at the time. Upon graduation, Klein began working at Sylvania Electric Products Inc. in Boston, Massachusetts to support his new family (he got married one week after graduating). Klein enjoyed his time at Sylvania where he was able to combine his passions for electronics and chemistry, working on
solid-state electronics Solid-state electronics means semiconductor electronics: electronic equipment using semiconductor devices such as transistors, diodes and integrated circuits (ICs). The term is also used as an adjective for devices in which semiconductor electr ...
. During his time at Sylvania, Klein wrote numerous articles for
QST ''QST'' is a magazine for amateur radio enthusiasts, published by the American Radio Relay League (ARRL). It is a membership journal that is included with membership in the ARRL. The publisher claims that circulation of ''QST'' in the United St ...
about
semiconductor A semiconductor is a material which has an electrical conductivity value falling between that of a conductor, such as copper, and an insulator, such as glass. Its resistivity falls as its temperature rises; metals behave in the opposite way. ...
device applications. After 2 years at Sylvania (which Klein refers to as his "post-graduate education"), Klein decided to pursue a graduate degree at the
University of Connecticut The University of Connecticut (UConn) is a public land-grant research university in Storrs, Connecticut, a village in the town of Mansfield. The primary 4,400-acre (17.8 km2) campus is in Storrs, approximately a half hour's drive from H ...
working with Dr. Roland Ward who he'd met during his undergraduate studies. Ward, often considered the father of solid-state chemistry, had moved from the Polytechnic Institute of Brooklyn to the University of Connecticut. Klein's research with Ward, which focused on
photochemistry Photochemistry is the branch of chemistry concerned with the chemical effects of light. Generally, this term is used to describe a chemical reaction caused by absorption of ultraviolet (wavelength from 100 to 400  nm), visible light (400– ...
was published in the
Journal of the American Chemical Society The ''Journal of the American Chemical Society'' is a weekly peer-reviewed scientific journal that was established in 1879 by the American Chemical Society. The journal has absorbed two other publications in its history, the ''Journal of Analytic ...
. In 1958, Klein graduated from the University of Connecticut with a PhD in inorganic chemistry.


Career

In 1958, Dr. Ward introduced Klein to a headhunter from Bell Labs who was eager to recruit Klein. Klein Joined Bell Labs in November, 1958. Although he was originally recruited to join the chemistry research department, Klein began working in the chemistry development department where he worked on the development of semiconductors. Klein was thrilled to be working along some of the brightest chemists in the world. As Klein said during an interview with the Chemical Heritage Foundation, "There were more experts under that one roof at Murray Hill, than at any university that I had ever been to, or have been in since. You could always find an expert in every single field you could think of." Klein referred to his time at Bell Labs as "the greatest post graduate education I ever had." Along with his colleagues, Klein worked to develop
etching Etching is traditionally the process of using strong acid or mordant to cut into the unprotected parts of a metal surface to create a design in intaglio (incised) in the metal. In modern manufacturing, other chemicals may be used on other types ...
techniques and ways to prevent
contamination Contamination is the presence of a constituent, impurity, or some other undesirable element that spoils, corrupts, infects, makes unfit, or makes inferior a material, physical body, natural environment, workplace, etc. Types of contamination ...
in the process of semiconductor production. In February 1966, Willard Boyle, a high level manager at Bell Labs, posed a problem to Klein. At the time, the production process of integrated circuits required 6 or 7 steps, each with a yield rate of below 90%, resulting in unacceptably low yield rates. What was desired was a process that would be go/no-go, meaning a process in which an entire batch of
wafers A wafer is a crisp, often sweet, very thin, flat, light and dry biscuit, often used to decorate ice cream, and also used as a garnish on some sweet dishes. Wafers can also be made into cookies with cream flavoring sandwiched between them. They ...
can be eliminated early on in the production process. Following his discussion with Dr. Boyle, Klein led a brainstorming session with several other Bell scientists to design a better process for building FET devices. Out of that meeting came the idea of using a heavily doped
polycrystalline A crystallite is a small or even microscopic crystal which forms, for example, during the cooling of many materials. Crystallites are also referred to as grains. Bacillite is a type of crystallite. It is rodlike with parallel longulites. Stru ...
silicon Silicon is a chemical element with the symbol Si and atomic number 14. It is a hard, brittle crystalline solid with a blue-grey metallic luster, and is a tetravalent metalloid and semiconductor. It is a member of group 14 in the periodic ta ...
layer as the gate of an FET. The gate was to be supported on dual layers of a
silicon nitride Silicon nitride is a chemical compound of the elements silicon and nitrogen. is the most thermodynamically stable and commercially important of the silicon nitrides, and the term "silicon nitride" commonly refers to this specific composition. It ...
and
silicon dioxide Silicon dioxide, also known as silica, is an oxide of silicon with the chemical formula , most commonly found in nature as quartz and in various living organisms. In many parts of the world, silica is the major constituent of sand. Silica is one ...
serving as the gate insulator. Using the FET as a model for integrated circuits, they fabricated and characterized hundreds of FET devices at high yield that exhibited close electrical tolerances. Klein and his group published numerous papers on this new technology and also patented the process. Klein remained at Bell Labs until 1967, when he joined IBM. Before joining IBM, an agreement was made between Bell Labs and IBM that Klein would not be allowed to work intimately on the problems that he had been working on at Bell Labs, for at least a period of time. Unable to work directly on MOSFET technology, Klein was asked to set up a group to advance the technology of
lithography Lithography () is a planographic method of printing originally based on the immiscibility of oil and water. The printing is from a stone (lithographic limestone) or a metal plate with a smooth surface. It was invented in 1796 by the German a ...
. More specifically, Klein's group worked on developing new
photoresist A photoresist (also known simply as a resist) is a light-sensitive material used in several processes, such as photolithography and photoengraving, to form a patterned coating on a surface. This process is crucial in the electronic industry. ...
technologies. While at IBM, Klein worked as a senior engineer, manager, and technical staff consultant. In 1987, Klein retired from IBM and began teaching Chemistry at the Department of Physical Sciences at
Dutchess Community College Dutchess Community College (SUNY Dutchess, Dutchess, or DCC) is a public community college in Dutchess County, New York. It is one of 30 community colleges within the State University of New York system (SUNY). The main campus covers . DCC also ...
in his hometown
Poughkeepsie, New York Poughkeepsie ( ), officially the City of Poughkeepsie, separate from the Town of Poughkeepsie around it) is a city in the U.S. state of New York. It is the county seat of Dutchess County, with a 2020 census population of 31,577. Poughkeepsi ...
.


Patents

*Method of fabricating semiconductor contacts, (1965). *Semiconductor surface cleaning, (1965). *Method for the preparation of atomically clean silicon, (1969). *Silicon oxide tunnel diode structure and method of making same, (1969). *Method for making MIS structures, (1969). *Cyclic polyisoprene photoresist compositions, (1972). *Device for removing low level contaminants from a liquid, (1977).


Personal life

In 1952, Klein married Ruth Kintzburger (also a chemist and radio amateur), a childhood friend from Brooklyn. Together they had 6 children and 21 grandchildren.


References

{{DEFAULTSORT:Klein, Donald Lee 1930 births Living people American chemists American inventors