Diphosphene is a compound having the formula . It exists as two
geometric isomers, ''E'' and ''Z''. Diphosphene is also the parent member of the entire class of
diphosphene compounds with the formula , where R is an
organyl group.
Visible radiation induces cis-trans isomerization, although further irradiation can excite the molecule to a triplet
diradical state. In triplet trans-HPPH, the P-P bond length is predicted to be 2.291 Å. It is not only longer than the P-P double bond in ground state trans-bis(2,4,6-tri-tert-butylphenyl)diphosphene, but also longer than that of P-P single bond in . Calculation of the dihedral angle of trans-HPPH suggests that it is almost 90 degree, which means the formation of
and
P-P bonds is forbidden and σ bond is enhanced.
References
{{Inorganic-compound-stub
Phosphorus hydrides