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Yttrium aluminium garnet (YAG, Y3 Al5 O12) is a synthetic
crystal A crystal or crystalline solid is a solid material whose constituents (such as atoms, molecules, or ions) are arranged in a highly ordered microscopic structure, forming a crystal lattice that extends in all directions. In addition, macros ...
line material of the
garnet Garnets () are a group of silicate minerals that have been used since the Bronze Age as gemstones and abrasives. Garnet minerals, while sharing similar physical and crystallographic properties, exhibit a wide range of chemical compositions, de ...
group. It is a
cubic Cubic may refer to: Science and mathematics * Cube (algebra), "cubic" measurement * Cube, a three-dimensional solid object bounded by six square faces, facets or sides, with three meeting at each vertex ** Cubic crystal system, a crystal system w ...
yttrium Yttrium is a chemical element; it has Symbol (chemistry), symbol Y and atomic number 39. It is a silvery-metallic transition metal chemically similar to the lanthanides and has often been classified as a "rare-earth element". Yttrium is almost a ...
aluminium Aluminium (or aluminum in North American English) is a chemical element; it has chemical symbol, symbol Al and atomic number 13. It has a density lower than that of other common metals, about one-third that of steel. Aluminium has ...
oxide phase, with other examples being YAlO3 (YAP) in a
hexagonal In geometry, a hexagon (from Greek , , meaning "six", and , , meaning "corner, angle") is a six-sided polygon. The total of the internal angles of any simple (non-self-intersecting) hexagon is 720°. Regular hexagon A regular hexagon is d ...
or an orthorhombic,
perovskite Perovskite (pronunciation: ) is a calcium titanium oxide mineral composed of calcium titanate (chemical formula ). Its name is also applied to the class of compounds which have the same type of crystal structure as , known as the perovskite (stru ...
-like form, and the monoclinic Y4Al2O9 (YAM). Due to its broad optical transparency, low internal stress, high hardness, chemical and heat resistance, YAG is used for a variety of optics. Its lack of
birefringence Birefringence, also called double refraction, is the optical property of a material having a refractive index that depends on the polarization and propagation direction of light. These optically anisotropic materials are described as birefrin ...
(unlike sapphire) makes it an interesting material for high-energy/high-power laser systems. Laser damage levels of YAG ranged from 1.1 to 2.2 kJ/cm2 (1064 nm, 10 ns). YAG, like garnet and
sapphire Sapphire is a precious gemstone, a variety of the mineral corundum, consisting of aluminium oxide () with trace amounts of elements such as iron, titanium, cobalt, lead, chromium, vanadium, magnesium, boron, and silicon. The name ''sapphire ...
, has no uses as a laser medium when pure. However, after being doped with an appropriate ion, YAG is commonly used as a host material in various
solid-state laser A solid-state laser is a laser that uses a active laser medium, gain medium that is a solid, rather than a liquid as in dye lasers or a gas as in gas lasers. Semiconductor-based lasers are also in the solid state, but are generally considered as ...
s. Rare earth elements such as
neodymium Neodymium is a chemical element; it has Symbol (chemistry), symbol Nd and atomic number 60. It is the fourth member of the lanthanide series and is considered to be one of the rare-earth element, rare-earth metals. It is a hard (physics), hard, sli ...
and
erbium Erbium is a chemical element; it has Symbol (chemistry), symbol Er and atomic number 68. A silvery-white solid metal when artificially isolated, natural erbium is always found in chemical combination with other elements. It is a lanthanide, a rare- ...
can be doped into YAG as active laser ions, yielding Nd:YAG and Er:YAG lasers, respectively.
Cerium Cerium is a chemical element; it has Chemical symbol, symbol Ce and atomic number 58. It is a hardness, soft, ductile, and silvery-white metal that tarnishes when exposed to air. Cerium is the second element in the lanthanide series, and while it ...
-doped YAG (Ce:YAG) is used as a
phosphor A phosphor is a substance that exhibits the phenomenon of luminescence; it emits light when exposed to some type of radiant energy. The term is used both for fluorescent or phosphorescent substances which glow on exposure to ultraviolet or ...
in
cathode-ray tube A cathode-ray tube (CRT) is a vacuum tube containing one or more electron guns, which emit electron beams that are manipulated to display images on a phosphorescent screen. The images may represent electrical waveforms on an oscilloscope, a ...
s and white
light-emitting diode A light-emitting diode (LED) is a semiconductor device that emits light when current flows through it. Electrons in the semiconductor recombine with electron holes, releasing energy in the form of photons. The color of the light (corre ...
s, and as a
scintillator A scintillator ( ) is a material that exhibits scintillation, the property of luminescence, when excited by ionizing radiation. Luminescent materials, when struck by an incoming particle, absorb its energy and scintillate (i.e. re-emit the ab ...
.


Gemstone YAG

YAG for a period was used in
jewelry Jewellery (or jewelry in American English) consists of decorative items worn for personal adornment such as brooches, ring (jewellery), rings, necklaces, earrings, pendants, bracelets, and cufflinks. Jewellery may be attached to the body or the ...
as a
diamond Diamond is a Allotropes of carbon, solid form of the element carbon with its atoms arranged in a crystal structure called diamond cubic. Diamond is tasteless, odourless, strong, brittle solid, colourless in pure form, a poor conductor of e ...
and other
gemstone A gemstone (also called a fine gem, jewel, precious stone, semiprecious stone, or simply gem) is a piece of mineral crystal which, when cut or polished, is used to make jewellery, jewelry or other adornments. Certain Rock (geology), rocks (such ...
simulant. Colored variants and their doping elements include: green (
chromium Chromium is a chemical element; it has Symbol (chemistry), symbol Cr and atomic number 24. It is the first element in Group 6 element, group 6. It is a steely-grey, Luster (mineralogy), lustrous, hard, and brittle transition metal. Chromium ...
), blue (
cobalt Cobalt is a chemical element; it has Symbol (chemistry), symbol Co and atomic number 27. As with nickel, cobalt is found in the Earth's crust only in a chemically combined form, save for small deposits found in alloys of natural meteoric iron. ...
), red (
manganese Manganese is a chemical element; it has Symbol (chemistry), symbol Mn and atomic number 25. It is a hard, brittle, silvery metal, often found in minerals in combination with iron. Manganese was first isolated in the 1770s. It is a transition m ...
), yellow (
titanium Titanium is a chemical element; it has symbol Ti and atomic number 22. Found in nature only as an oxide, it can be reduced to produce a lustrous transition metal with a silver color, low density, and high strength, resistant to corrosion in ...
), blue/pink/purple (
neodymium Neodymium is a chemical element; it has Symbol (chemistry), symbol Nd and atomic number 60. It is the fourth member of the lanthanide series and is considered to be one of the rare-earth element, rare-earth metals. It is a hard (physics), hard, sli ...
, depending on light source), pink, and orange. As faceted gems they are valued (as synthetics) for their clarity, durability, high
refractive index In optics, the refractive index (or refraction index) of an optical medium is the ratio of the apparent speed of light in the air or vacuum to the speed in the medium. The refractive index determines how much the path of light is bent, or refrac ...
and
dispersion Dispersion may refer to: Economics and finance *Dispersion (finance), a measure for the statistical distribution of portfolio returns * Price dispersion, a variation in prices across sellers of the same item *Wage dispersion, the amount of variat ...
, and occasionally properties like simulating
alexandrite The mineral or gemstone chrysoberyl is an aluminate of beryllium with the formula Be Al2 O4. The name chrysoberyl is derived from the Greek words χρυσός ''chrysos'' and βήρυλλος ''beryllos'', meaning "a gold-white spar". Despite ...
's color-changing property. The critical angle of YAG is 33 degrees. YAG cuts like natural
garnet Garnets () are a group of silicate minerals that have been used since the Bronze Age as gemstones and abrasives. Garnet minerals, while sharing similar physical and crystallographic properties, exhibit a wide range of chemical compositions, de ...
, with polishing being performed with
alumina Aluminium oxide (or aluminium(III) oxide) is a chemical compound of aluminium and oxygen with the chemical formula . It is the most commonly occurring of several aluminium oxides, and specifically identified as aluminium oxide. It is commonly ...
or
diamond Diamond is a Allotropes of carbon, solid form of the element carbon with its atoms arranged in a crystal structure called diamond cubic. Diamond is tasteless, odourless, strong, brittle solid, colourless in pure form, a poor conductor of e ...
(50,000 or 100,000 grit) on common polishing laps. YAG has low heat sensitivity. As a synthetic gemstone YAG has numerous varietal and trade names, as well as a number of misnomers. Synonymous names include: ''alexite'', ''amamite'', ''circolite'', ''dia-bud'', ''diamite'', ''diamogem'', ''diamonair'', ''diamone'', ''diamonique'', ''diamonite'', ''diamonte'', ''di'yag'', ''geminair'', ''gemonair'', ''kimberly'', ''Linde simulated diamond'', ''nier-gem'', ''regalair'', ''replique'', ''somerset'', ''triamond'', ''YAIG'', and ''yttrium garnet''. Production for the gem trade decreased after the introduction of synthetic
cubic zirconia Cubic zirconia (CZ) is the cubic crystalline form of zirconium dioxide (ZrO2). The synthesized material is hard and usually colorless, but may be made in a variety of different colors. It should not be confused with zircon, which is a zirc ...
; there was little production. Some demand exists as synthetic garnet, and for designs where the very high refractive index of cubic zirconia is not desirable.


Technical-use varieties


Nd:YAG

Neodymium Neodymium is a chemical element; it has Symbol (chemistry), symbol Nd and atomic number 60. It is the fourth member of the lanthanide series and is considered to be one of the rare-earth element, rare-earth metals. It is a hard (physics), hard, sli ...
- doped YAG (Nd:YAG) was developed in the early 1960s, and the first working Nd:YAG laser was invented in 1964. Neodymium-YAG is the most widely used
active laser medium The active laser medium (also called a gain medium or lasing medium) is the source of optical gain within a laser. The gain results from the stimulated emission of photons through electronic or molecular transitions to a lower energy state from ...
in
solid-state laser A solid-state laser is a laser that uses a active laser medium, gain medium that is a solid, rather than a liquid as in dye lasers or a gas as in gas lasers. Semiconductor-based lasers are also in the solid state, but are generally considered as ...
s, being used for everything from low-power continuous-wave lasers to high-power Q-switched (pulsed) lasers with power levels measured in the kilowatts. The thermal conductivity of Nd:YAG is higher and its
fluorescence Fluorescence is one of two kinds of photoluminescence, the emission of light by a substance that has absorbed light or other electromagnetic radiation. When exposed to ultraviolet radiation, many substances will glow (fluoresce) with colore ...
lifetime is about twice as long as that of Nd:YVO4 crystals, however it is not as efficient and is less stable, requiring more precisely controlled temperatures. The best absorption band of Nd:YAG for pumping the laser is centered at 807.5 nm, and is 1 nm wide. Most Nd:YAG lasers produce infrared light at a wavelength of 1064 nm. Light at this wavelength is rather dangerous to vision, since it can be focused by the eye's
lens A lens is a transmissive optical device that focuses or disperses a light beam by means of refraction. A simple lens consists of a single piece of transparent material, while a compound lens consists of several simple lenses (''elements'') ...
onto the
retina The retina (; or retinas) is the innermost, photosensitivity, light-sensitive layer of tissue (biology), tissue of the eye of most vertebrates and some Mollusca, molluscs. The optics of the eye create a focus (optics), focused two-dimensional ...
, but the light is invisible and does not trigger the
blink reflex The corneal reflex, also known as the blink reflex or eyelid reflex, is an involuntary blinking of the eyelids elicited by stimulation of the cornea (such as by touching or by a foreign body), though it could result from any peripheral stimulus ...
. Nd:YAG lasers can also be used with
frequency doubling Second-harmonic generation (SHG), also known as frequency doubling, is the lowest-order wave-wave nonlinear interaction that occurs in various systems, including optical, radio, atmospheric, and magnetohydrodynamic systems. As a prototype behav ...
or frequency tripling
crystal A crystal or crystalline solid is a solid material whose constituents (such as atoms, molecules, or ions) are arranged in a highly ordered microscopic structure, forming a crystal lattice that extends in all directions. In addition, macros ...
s, to produce green light with a wavelength of 532 nm or ultraviolet light at 355 nm, respectively. The
dopant A dopant (also called a doping agent) is a small amount of a substance added to a material to alter its physical properties, such as electrical or optics, optical properties. The amount of dopant is typically very low compared to the material b ...
concentration in commonly used Nd:YAG crystals usually varies between 0.5 and 1.4 molar percent. Higher dopant concentration is used for pulsed lasers; lower concentration is suitable for continuous-wave lasers. Nd:YAG is pinkish-purple, with lighter-doped rods being less intensely colored than heavier-doped ones. Since its absorption spectrum is narrow, the hue depends on the light under which it is observed.


Nd:Cr:YAG

YAG doped with
neodymium Neodymium is a chemical element; it has Symbol (chemistry), symbol Nd and atomic number 60. It is the fourth member of the lanthanide series and is considered to be one of the rare-earth element, rare-earth metals. It is a hard (physics), hard, sli ...
and
chromium Chromium is a chemical element; it has Symbol (chemistry), symbol Cr and atomic number 24. It is the first element in Group 6 element, group 6. It is a steely-grey, Luster (mineralogy), lustrous, hard, and brittle transition metal. Chromium ...
(Nd:Cr:YAG or Nd/Cr:YAG) has absorption characteristics which are superior to Nd:YAG. This is because energy is absorbed by the broad absorption bands of the Cr3+ dopant and then transferred to Nd3+ by dipole-dipole interactions. This material has been suggested for use in solar-pumped lasers, which could form part of a solar power satellite system.


Er:YAG

Erbium Erbium is a chemical element; it has Symbol (chemistry), symbol Er and atomic number 68. A silvery-white solid metal when artificially isolated, natural erbium is always found in chemical combination with other elements. It is a lanthanide, a rare- ...
-doped YAG (Er:YAG) is an active laser medium lasing at 2940 nm. Its absorption bands suitable for pumping are wide and located between 600 and 800 nm, allowing for efficient flashlamp pumping. The dopant concentration used is high: about 50% of the yttrium atoms are replaced. The Er:YAG laser wavelength couples well into water and body fluids, making this laser especially useful for medicine and dentistry uses; it is used for treatment of
tooth enamel Tooth enamel is one of the four major Tissue (biology), tissues that make up the tooth in humans and many animals, including some species of fish. It makes up the normally visible part of the tooth, covering the Crown (tooth), crown. The other ...
and in cosmetic surgery. Er:YAG is used for noninvasive monitoring of
blood sugar The blood sugar level, blood sugar concentration, blood glucose level, or glycemia is the measure of glucose concentrated in the blood. The body tightly regulates blood glucose levels as a part of metabolic homeostasis. For a 70 kg (1 ...
. The mechanical properties of Er:YAG are essentially the same as Nd:YAG. Er:YAG operates at wavelengths where the threshold for eye damage is relatively high (since the light is absorbed before striking the
retina The retina (; or retinas) is the innermost, photosensitivity, light-sensitive layer of tissue (biology), tissue of the eye of most vertebrates and some Mollusca, molluscs. The optics of the eye create a focus (optics), focused two-dimensional ...
), works well at room temperature, and has high slope efficiency. Er:YAG is pink.


Yb:YAG

Ytterbium Ytterbium is a chemical element; it has symbol Yb and atomic number 70. It is a metal, the fourteenth and penultimate element in the lanthanide series, which is the basis of the relative stability of its +2 oxidation state. Like the other lanthani ...
-doped YAG (Yb:YAG) is an active laser medium lasing at 1030 nm, with a broad, 18 nm wide absorption band at 940 nm. It is one of the most useful media for high-power diode-pumped solid state lasers. The dopant levels used range between 0.2% and 30% of replaced yttrium atoms. Yb:YAG has very low fractional heating, very high slope efficiency, and no excited-state absorption or up-conversion, high mechanical strength and high thermal conductivity. Yb:YAG can be pumped by reliable
InGaAs Indium gallium arsenide (InGaAs) (alternatively gallium indium arsenide, GaInAs) is a ternary alloy (chemical compound) of indium arsenide (InAs) and gallium arsenide (GaAs). Indium and gallium are group III elements of the periodic table while ...
laser diode file:Laser diode chip.jpg, The laser diode chip removed and placed on the eye of a needle for scale A laser diode (LD, also injection laser diode or ILD or semiconductor laser or diode laser) is a semiconductor device similar to a light-emittin ...
s at 940 or 970 nm. Yb:YAG is a good substitute for 1064 nm Nd:YAG in high-power applications, and its frequency-doubled 515 nm version can replace the 514 nm
argon laser An ion laser is a gas laser that uses an ionized gas as its lasing medium. Like other gas lasers, ion lasers feature a sealed cavity containing the laser medium and mirrors forming a Fabry–Pérot resonator. Unlike helium–neon lasers, the ...
s.


Nd:Ce:YAG

Neodymium Neodymium is a chemical element; it has Symbol (chemistry), symbol Nd and atomic number 60. It is the fourth member of the lanthanide series and is considered to be one of the rare-earth element, rare-earth metals. It is a hard (physics), hard, sli ...
-
cerium Cerium is a chemical element; it has Chemical symbol, symbol Ce and atomic number 58. It is a hardness, soft, ductile, and silvery-white metal that tarnishes when exposed to air. Cerium is the second element in the lanthanide series, and while it ...
double-doped YAG (Nd:Ce:YAG, or Nd,Ce:YAG) is an active laser medium material very similar to Nd:YAG. The added cerium atoms strongly absorb in the
ultraviolet Ultraviolet radiation, also known as simply UV, is electromagnetic radiation of wavelengths of 10–400 nanometers, shorter than that of visible light, but longer than X-rays. UV radiation is present in sunlight and constitutes about 10% of ...
region and transfer their energy to the neodymium atoms, increasing the pumping efficiency; the result is lower thermal distortion and higher power output than Nd:YAG at the same pumping level. The lasing wavelength, 1064 nm, is the same as for Nd:YAG. The material has a good resistance to damage caused by UV from the pump source, and low
lasing threshold The lasing threshold is the lowest excitation level at which a laser's output is dominated by stimulated emission rather than by spontaneous emission. Below the threshold, the laser's output power rises slowly with increasing excitation. Above thr ...
. Usually 1.1–1.4% of Y atoms are replaced with Nd, and 0.05–0.1% with Ce.


Ho:Cr:Tm:YAG

Holmium Holmium is a chemical element; it has symbol Ho and atomic number 67. It is a rare-earth element and the eleventh member of the lanthanide series. It is a relatively soft, silvery, fairly corrosion-resistant and malleable metal. Like many other ...
-
chromium Chromium is a chemical element; it has Symbol (chemistry), symbol Cr and atomic number 24. It is the first element in Group 6 element, group 6. It is a steely-grey, Luster (mineralogy), lustrous, hard, and brittle transition metal. Chromium ...
-
thulium Thulium is a chemical element; it has symbol Tm and atomic number 69. It is the thirteenth element in the lanthanide series of metals. It is the second-least abundant lanthanide in the Earth's crust, after radioactively unstable promethium. It i ...
triple-doped YAG (Ho:Cr:Tm:YAG, or Ho,Cr,Tm:YAG) is an active laser medium material with high efficiency. It lases at 2080 nm and can be pumped by a flashlamp or a laser diode. It is widely used in military, medicine, and meteorology. It works well at room temperature, has high slope efficiency, and operates at a wavelength where the threshold for eye damage is relatively high. When pumped by a diode, the 785 nm band for Tm3+ ion can be used. Other major pump bands are located between 400 and 800 nm. The dopant levels used are 0.35 atom.% Ho, 5.8 atom.% Tm, and 1.5 at.% Cr. The rods have green color, imparted by chromium(III).


Tm:YAG

Thulium Thulium is a chemical element; it has symbol Tm and atomic number 69. It is the thirteenth element in the lanthanide series of metals. It is the second-least abundant lanthanide in the Earth's crust, after radioactively unstable promethium. It i ...
-doped YAG (Tm:YAG) is an active laser medium that operates between 1930 and 2040 nm. It is suitable for diode pumping. A dual-mode Tm:YAG laser emits two frequencies separated by 1 GHz.


Cr4+:YAG

Chromium Chromium is a chemical element; it has Symbol (chemistry), symbol Cr and atomic number 24. It is the first element in Group 6 element, group 6. It is a steely-grey, Luster (mineralogy), lustrous, hard, and brittle transition metal. Chromium ...
(IV)-doped YAG (Cr:YAG) provides a large absorption cross section in the 0.9-1.2 micrometer spectral region, which makes it an attractive choice as a passive Q-switch for Nd-doped lasers. The resulting devices are solid-state, compact and low-cost. Cr:YAG has high damage threshold, good thermal conductivity, good chemical stability, resists
ultraviolet Ultraviolet radiation, also known as simply UV, is electromagnetic radiation of wavelengths of 10–400 nanometers, shorter than that of visible light, but longer than X-rays. UV radiation is present in sunlight and constitutes about 10% of ...
radiation, and is easily machinable. It is replacing more traditional Q-switching materials like
lithium fluoride Lithium fluoride is an inorganic compound with the chemical formula LiF. It is a colorless solid that transitions to white with decreasing crystal size. Its structure is analogous to that of sodium chloride, but it is much less soluble in water. ...
and organic
dye Juan de Guillebon, better known by his stage name DyE, is a French musician. He is known for the music video of the single "Fantasy Fantasy is a genre of speculative fiction that involves supernatural or Magic (supernatural), magical ele ...
s. The dopant levels used range between 0.5 and 3 percent (molar). Cr:YAG can be used for passive Q-switching of lasers that operate at wavelengths between 1000 and 1200 nm, such as those based on Nd:YAG, Nd:YLF, Nd:YVO4, and Yb:YAG. Cr:YAG can be also used as a laser gain medium itself, producing
tunable laser A tunable laser is a laser whose wavelength of operation can be altered in a controlled manner. While all active laser medium, laser gain media allow small shifts in output wavelength, only a few types of lasers allow continuous tuning over a sign ...
s with outputs adjustable between 1350 and 1550 nm. The Cr:YAG laser can generate
ultrashort pulse In optics, an ultrashort pulse, also known as an ultrafast event, is an electromagnetic pulse whose time duration is of the order of a picosecond (10−12 second) or less. Such pulses have a broadband optical spectrum, and can be created by ...
s (in the femtoseconds range) when it is pumped at 1064 nm by a Nd:YAG laser. Cr:YAG has been demonstrated in an application of non-linear optics as a self-pumped phase-conjugate mirror in a Nd:YAG "loop resonator". Such a mirror provides compensation of both phase and polarization aberrations induced into the loop resonator.


Dy:YAG

Dysprosium Dysprosium is a chemical element; it has symbol Dy and atomic number 66. It is a rare-earth element in the lanthanide series with a metallic silver luster. Dysprosium is never found in nature as a free element, though, like other lanthanides, it ...
-doped YAG (Dy:YAG) is a temperature-sensitive
phosphor A phosphor is a substance that exhibits the phenomenon of luminescence; it emits light when exposed to some type of radiant energy. The term is used both for fluorescent or phosphorescent substances which glow on exposure to ultraviolet or ...
used in temperature measurements. The phosphor is excited by a laser pulse and its temperature-dependent fluorescence is observed. Dy:YAG is sensitive in ranges of 300–1700 K. The phosphor can be applied directly to the measured surface, or to an end of an
optical fiber An optical fiber, or optical fibre, is a flexible glass or plastic fiber that can transmit light from one end to the other. Such fibers find wide usage in fiber-optic communications, where they permit transmission over longer distances and at ...
. It has also been studied as a single-phase white emitting phosphor in phosphor-converted white light-emitting diodes.


Sm:YAG

Samarium Samarium is a chemical element; it has symbol Sm and atomic number 62. It is a moderately hard silvery metal that slowly oxidizes in air. Being a typical member of the lanthanide series, samarium usually has the oxidation state +3. Compounds of s ...
-doped YAG (Sm:YAG) is a temperature-sensitive phosphor similar to Dy:YAG.


Tb:YAG

Terbium Terbium is a chemical element; it has Symbol (chemistry), symbol Tb and atomic number 65. It is a silvery-white, rare earth element, rare earth metal that is malleable and ductile. The ninth member of the lanthanide series, terbium is a fairly ele ...
-doped YAG (Tb:YAG) is a phosphor used in
cathode-ray tube A cathode-ray tube (CRT) is a vacuum tube containing one or more electron guns, which emit electron beams that are manipulated to display images on a phosphorescent screen. The images may represent electrical waveforms on an oscilloscope, a ...
s. It emits at yellow-green color, at 544 nm.


Ce:YAG

Cerium Cerium is a chemical element; it has Chemical symbol, symbol Ce and atomic number 58. It is a hardness, soft, ductile, and silvery-white metal that tarnishes when exposed to air. Cerium is the second element in the lanthanide series, and while it ...
(III)-doped YAG (Ce:YAG or YAG:Ce) is a phosphor, or a
scintillator A scintillator ( ) is a material that exhibits scintillation, the property of luminescence, when excited by ionizing radiation. Luminescent materials, when struck by an incoming particle, absorb its energy and scintillate (i.e. re-emit the ab ...
when in pure
single-crystal In materials science, a single crystal (or single-crystal solid or monocrystalline solid) is a material in which the crystal lattice of the entire sample is continuous and unbroken to the edges of the sample, with no grain boundaries. The absen ...
form, with a wide range of uses. It emits yellow light when subjected to blue or ultraviolet light or to x-rays. G. Blasse and A. Bril, "A new phosphor for flying-spot cathode-ray tubes for color televisions", Appl. Phys. Lett., 11, 1967, 53-54 It is used in white
light-emitting diode A light-emitting diode (LED) is a semiconductor device that emits light when current flows through it. Electrons in the semiconductor recombine with electron holes, releasing energy in the form of photons. The color of the light (corre ...
s as a coating on a high-brightness blue InGaN diode, converting part of the blue light into yellow, which together then appear as white. Such an arrangement gives less than ideal
color rendering The color rendering of a light source refers to its ability to reveal the colors of various objects faithfully (i.e. to produce Metamerism (color), illuminant metamerism) in comparison with an ideal or natural light source. Light sources with good ...
. The output brightness decreases with increasing temperature, further altering device color output. Ce:YAG is also used in some
mercury-vapor lamp A mercury-vapor lamp is a gas-discharge lamp that uses an electric arc through vaporized mercury to produce light. The arc discharge is generally confined to a small fused quartz arc tube mounted within a larger soda lime or borosilicate gla ...
s as one of the phosphors, often together with Eu:Y(P,V)O4 (yttrium phosphate-vanadate). It is also used as a phosphor in cathode-ray tubes, where it emits green (530 nm) to yellow-green (550 nm) light. When excited by electrons, it has virtually no afterglow (70 ns decay time). It is suitable for use in
photomultiplier A photomultiplier is a device that converts incident photons into an electrical signal. Kinds of photomultiplier include: * Photomultiplier tube, a vacuum tube converting incident photons into an electric signal. Photomultiplier tubes (PMTs for sh ...
s. Ce:YAG is used in PET scanners, high-energy
gamma radiation A gamma ray, also known as gamma radiation (symbol ), is a penetrating form of electromagnetic radiation arising from high energy interactions like the radioactive decay of atomic nuclei or astronomical events like solar flares. It consists o ...
and
charged particle In physics, a charged particle is a particle with an electric charge. For example, some elementary particles, like the electron or quarks are charged. Some composite particles like protons are charged particles. An ion, such as a molecule or atom ...
detectors, and high-resolution imaging screens for gamma,
x-ray An X-ray (also known in many languages as Röntgen radiation) is a form of high-energy electromagnetic radiation with a wavelength shorter than those of ultraviolet rays and longer than those of gamma rays. Roughly, X-rays have a wavelength ran ...
s,
beta radiation A beta particle, also called beta ray or beta radiation (symbol β), is a high-energy, high-speed electron or positron emitted by the radioactive decay of an atomic nucleus, known as beta decay. There are two forms of beta decay, β− decay and ...
and
ultraviolet radiation Ultraviolet radiation, also known as simply UV, is electromagnetic radiation of wavelengths of 10–400 nanometers, shorter than that of visible light, but longer than X-rays. UV radiation is present in sunlight and constitutes about 10% of t ...
. Ce:YAG can be further doped with
gadolinium Gadolinium is a chemical element; it has Symbol (chemistry), symbol Gd and atomic number 64. It is a silvery-white metal when oxidation is removed. Gadolinium is a malleable and ductile rare-earth element. It reacts with atmospheric oxygen or moi ...
.


See also

* Er:YAG laser *
Micro-pulling-down The micro-pulling-down (μ-PD) method is a crystal growth technique based on continuous transport of the melted substance through micro-channel(s) made in a crucible bottom. Continuous solidification of the melt is progressed on a liquid/solid int ...
* Nd:YAG laser *
Yttrium iron garnet Yttrium iron garnet (YIG) is a kind of synthetic garnet, with chemical composition , or Y3Fe5O12. It is a ferrimagnetic material with a Curie temperature of 560  K. YIG may also be known as yttrium ferrite garnet, or as iron yttrium oxide or ...


References

{{DEFAULTSORT:Yttrium Aluminium Garnet Yttrium compounds Aluminium compounds Synthetic minerals Optical materials Laser gain media Phosphors and scintillators Diamond simulants Aluminates