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The Deep Earth Carbon Degassing (DECADE) project is an initiative to unite scientists around the world to make tangible advances towards quantifying the amount of
carbon Carbon () is a chemical element; it has chemical symbol, symbol C and atomic number 6. It is nonmetallic and tetravalence, tetravalent—meaning that its atoms are able to form up to four covalent bonds due to its valence shell exhibiting 4 ...
outgassed from the Earth's deep interior (core, mantle, crust) into the surface environment (e.g. biosphere, hydrosphere, cryosphere, atmosphere) through naturally occurring processes. DECADE is an initiative within the Deep Carbon Observatory (DCO). Volcanoes are the main pathway in which deeply sourced volatiles, including carbon, are transferred from the Earth's interior to the surface environment. An additional, though less well understood, pathway includes along faults and fractures within the Earth's crust, often referred to as tectonic degassing. When the DCO was first formed in 2009 estimates of global carbon flux from volcanic regions ranged from 65 to 540 Mt/yr, and constraints on global tectonic degassing were virtually unknown. The order of magnitude uncertainty in current volcanic/tectonic carbon outgassing makes answering fundamental questions about the global carbon budget virtually impossible. In particular, one fundamental unknown is if carbon transferred to the Earth's interior via subduction is efficiently recycled back to the Earth's mantle
lithosphere A lithosphere () is the rigid, outermost rocky shell of a terrestrial planet or natural satellite. On Earth, it is composed of the crust and the lithospheric mantle, the topmost portion of the upper mantle that behaves elastically on time ...
, crust and surface environment through volcanic and tectonic degassing, or if significant quantities of carbon are being subducted into the deep mantle. Because significant quantities of mantle carbon are also released through
mid-ocean ridge A mid-ocean ridge (MOR) is a undersea mountain range, seafloor mountain system formed by plate tectonics. It typically has a depth of about and rises about above the deepest portion of an ocean basin. This feature is where seafloor spreading ...
volcanism, if carbon inputs and outputs at subduction zone settings are in balance, then the net effect will be an imbalance in the global carbon budget, with carbon being preferentially removed from the Earth's deep interior and redistributed to more shallow reservoirs including the mantle
lithosphere A lithosphere () is the rigid, outermost rocky shell of a terrestrial planet or natural satellite. On Earth, it is composed of the crust and the lithospheric mantle, the topmost portion of the upper mantle that behaves elastically on time ...
, crust,
hydrosphere The hydrosphere () is the combined mass of water found on, under, and above the Planetary surface, surface of a planet, minor planet, or natural satellite. Although Earth's hydrosphere has been around for about 4 billion years, it continues to ch ...
and
atmosphere An atmosphere () is a layer of gases that envelop an astronomical object, held in place by the gravity of the object. A planet retains an atmosphere when the gravity is great and the temperature of the atmosphere is low. A stellar atmosph ...
. The implications of this may mean that carbon concentrations in the surface environment have increased over Earth's history, which has a significant impact on climate change. Findings from the DECADE project will increase our understanding of how carbon cycles through deep Earth, and patterns in volcanic emissions data could potentially alert scientists to an impending eruption.


Project goals

The main goal of the DECADE project is to refine estimates of global carbon outgassing using a multipronged approach. Specifically, the DECADE initiative unites scientists with expertise in
geochemistry Geochemistry is the science that uses the tools and principles of chemistry to explain the mechanisms behind major geological systems such as the Earth's crust and its oceans. The realm of geochemistry extends beyond the Earth, encompassing the e ...
,
petrology Petrology () is the branch of geology that studies rocks, their mineralogy, composition, texture, structure and the conditions under which they form. Petrology has three subdivisions: igneous, metamorphic, and sedimentary petrology. Igneous ...
and
volcanology Volcanology (also spelled vulcanology) is the study of volcanoes, lava, magma and related geology, geological, geophysical and geochemistry, geochemical phenomena (volcanism). The term ''volcanology'' is derived from the Latin language, Latin ...
to provide constraints on the global volcanic carbon flux by 1) establishing a database of volcanic and hydrothermal gas compositions and fluxes linked to EarthChem/PetDB and the Smithsonian Global Volcanism Program, 2) building a global monitoring network to measure the volcanic carbon flux of 20 active volcanoes continuously, 3) measure the carbon flux of remote volcanoes, for which no or only sparse data are currently available, 4) develop new field and analytical instrumentation for carbon measurements and flux monitoring, and 5) establish formal collaborations with volcano observatories around the world to support
volcanic gas Volcanic gases are gases given off by active (or, at times, by dormant) volcanoes. These include gases trapped in cavities (Vesicular texture, vesicles) in volcanic rocks, dissolved or dissociated gases in magma and lava, or gases emanating from ...
measurement and monitoring activities.


History

The DECADE initiative was conceived in September 2011 by the International Association of Volcanology and Chemistry of the Earth's Interior Commission on the Chemistry of Volcanic Gases during its 11th field workshop. Here the charge of the initiative was broadly defined and the governance structure established. The DECADE receives financial support from Deep Carbon Observatory to meet the project goals, with support distributed to DECADE members based on project proposal submission and external review and/or consensus by the board of directors. All projects are significantly matched by funding sources from the individual investigators or other funding agencies. The initiative is led by a board of directors that has nine members including one chair and two co-vice chairs. Currently, the DECADE initiative has around 80 members from 13 countries.


Achievements

, major achievements supported or partially supported by the DECADE initiative include: * Modification of the IEDA EarthChem database to include volcanic gas composition and gas flux data. * Instrumenting 9 volcanoes ( Masaya Volcano, Turrialba Volcano, Poás Volcano, Nevado del Ruiz, Galeras, Villarrica (instruments destroyed by eruption), Popocatépetl, Mount Merapi, Whakaari / White Island) with permanent multi-component gas analyzer system (Multi-GAS) stations for near continuous CO2 and SO2 measurements and near continuous SO2 flux measurements using miniDOAS. * Quantification of volcanic gas emissions and compositions from remote regions such as the Aleutian, Vanuatu and Papua New Guinea volcanic arcs. * First measurements of gas emissions from Mount Bromo and Anak Krakatau Volcanoes, Krakatoa Indonesia. * Establishing volcanic gas chemical changes as eruption precursors at Poás and Turrialba Volcanoes, Costa Rica. * Airborne sampling of volcanic plumes for carbon isotopes and analyses using Delta Ray Infrared Isotope Spectrometer. * Determination of diffuse CO2 degassing in the Azores. * Quantification of global CO2 emissions from volcanoes during eruptions, passive degassing and diffuse degassing


Volcanoes

The following volcanoes are currently monitored by the DECADE initiative:


Map of the DCO DECADE project volcano installations

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See also

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References

{{Reflist


External links


Deep Earth Carbon Degassing

Earthchem/petdb The Petrological Database

Global Volcanism Program
Volcanism Geophysics Carbon