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Cummingtonite ( ) is a metamorphic amphibole with the chemical composition , magnesium iron silicate hydroxide. Monoclinic cummingtonite is compositionally similar and polymorphic with orthorhombic anthophyllite, which is a much more common form of
magnesium Magnesium is a chemical element with the symbol Mg and atomic number 12. It is a shiny gray metal having a low density, low melting point and high chemical reactivity. Like the other alkaline earth metals (group 2 of the periodic ta ...
-rich amphibole, the latter being
metastable In chemistry and physics, metastability denotes an intermediate energetic state within a dynamical system other than the system's state of least energy. A ball resting in a hollow on a slope is a simple example of metastability. If the ball i ...
. Cummingtonite shares few compositional similarities with alkali amphiboles such as
arfvedsonite Arfvedsonite () is a sodium amphibole mineral with composition: aNa2] Fe2+)4Fe3+(OH)2, Si8O22]. It crystallizes in the monoclinic prismatic crystal system and typically occurs as greenish black to bluish grey fibrous to radiating or stellate pr ...
,
glaucophane Glaucophane is the name of a mineral and a mineral group belonging to the sodic amphibole supergroup of the double chain inosilicates, with the chemical formula ☐Na2(Mg3Al2)Si8O22(OH)2. Glaucophane crystallizes in the monoclinic system. Name G ...
-
riebeckite Riebeckite is a sodium-rich member of the amphibole group of silicate minerals, chemical formula Na2(Fe2+3Fe3+2)Si8O22(OH)2. It forms a solid solution series with magnesioriebeckite. It crystallizes in the monoclinic system, usually as long prisma ...
. There is little solubility between these minerals due to different crystal habit and inability of substitution between alkali elements and ferro-magnesian elements within the amphibole structure.


Name and discovery

Cummingtonite was named after the town of Cummington, Massachusetts, where it was discovered in 1824. Chester Dewey, "A Sketch of the Geology and Mineralogy of the Western Part of Massachusetts, and a Small Part of Adjoining States", in ''American Journal of Science'', first series, vol. 8, part 2, 1824, p. 1-60 It is also found in Sweden,
South Africa South Africa, officially the Republic of South Africa (RSA), is the Southern Africa, southernmost country in Africa. It is bounded to the south by of coastline that stretch along the Atlantic Ocean, South Atlantic and Indian Oceans; to the ...
,
Scotland Scotland (, ) is a Countries of the United Kingdom, country that is part of the United Kingdom. Covering the northern third of the island of Great Britain, mainland Scotland has a Anglo-Scottish border, border with England to the southeast ...
, and
New Zealand New Zealand ( mi, Aotearoa ) is an island country in the southwestern Pacific Ocean. It consists of two main landmasses—the North Island () and the South Island ()—and over 700 smaller islands. It is the sixth-largest island count ...
.


Chemistry

Cummingtonite is a member of the cummingtonite-
grunerite Grunerite is a mineral of the amphibole group of minerals with formula Fe7 Si8 O22( OH)2. It is the iron endmember of the grunerite-cummingtonite series. It forms as fibrous, columnar or massive aggregates of crystals. The crystals are monoclini ...
solid solution A solid solution, a term popularly used for metals, is a homogenous mixture of two different kinds of atoms in solid state and have a single crystal structure. Many examples can be found in metallurgy, geology, and solid-state chemistry. The wor ...
series which ranges from for magnesiocummingtonite to the iron rich grunerite endmember . Cummingtonite is used to describe minerals of this formula with between 30 and 70 per cent . Thus, cummingtonite is the series intermediate.
Manganese Manganese is a chemical element with the symbol Mn and atomic number 25. It is a hard, brittle, silvery metal, often found in minerals in combination with iron. Manganese is a transition metal with a multifaceted array of industrial alloy use ...
also substitutes for ) within cummingtonite amphibole, replacing B site atoms. These minerals are found in high-grade metamorphic
banded iron formation Banded iron formations (also known as banded ironstone formations or BIFs) are distinctive units of sedimentary rock consisting of alternating layers of iron oxides and iron-poor chert. They can be up to several hundred meters in thickness ...
and form a compositional series between (tirodite) and (dannemorite).
Calcium Calcium is a chemical element with the symbol Ca and atomic number 20. As an alkaline earth metal, calcium is a reactive metal that forms a dark oxide-nitride layer when exposed to air. Its physical and chemical properties are most similar t ...
,
sodium Sodium is a chemical element with the symbol Na (from Latin ''natrium'') and atomic number 11. It is a soft, silvery-white, highly reactive metal. Sodium is an alkali metal, being in group 1 of the periodic table. Its only stable ...
and
potassium Potassium is the chemical element with the symbol K (from Neo-Latin ''kalium'') and atomic number19. Potassium is a silvery-white metal that is soft enough to be cut with a knife with little force. Potassium metal reacts rapidly with atmosph ...
concentrations in cummingtonite are low. Cummingtonite tends toward more
calcium Calcium is a chemical element with the symbol Ca and atomic number 20. As an alkaline earth metal, calcium is a reactive metal that forms a dark oxide-nitride layer when exposed to air. Its physical and chemical properties are most similar t ...
substitution than related anthophyllite. Similarly, cummingtonite has lower
ferric In chemistry, iron(III) refers to the element iron in its +3 oxidation state. In ionic compounds (salts), such an atom may occur as a separate cation (positive ion) denoted by Fe3+. The adjective ferric or the prefix ferri- is often used to sp ...
iron and
aluminium Aluminium (aluminum in American and Canadian English) is a chemical element with the symbol Al and atomic number 13. Aluminium has a density lower than those of other common metals, at approximately one third that of steel. I ...
than anthophyllite. Amosite is a rare
asbestiform Asbestiform is a crystal habit. It describes a mineral that grows in a fibrous aggregate of high tensile strength, flexible, long, and thin crystals that readily separate.Committee on Asbestos: Selected Health Effects, 2006, ''Asbestos: Selected Can ...
variety of grunerite that was mined as asbestos only in the eastern part of the
Transvaal Province The Province of the Transvaal ( af, Provinsie van Transvaal), commonly referred to as the Transvaal (; ), was a province of South Africa from 1910 until 1994, when a new constitution subdivided it following the end of apartheid. The name "Trans ...
of
South Africa South Africa, officially the Republic of South Africa (RSA), is the Southern Africa, southernmost country in Africa. It is bounded to the south by of coastline that stretch along the Atlantic Ocean, South Atlantic and Indian Oceans; to the ...
. The origin of the name is ''Amosa'', the acronym for the mining company "Asbestos Mines of South Africa".


Occurrence

Cummingtonite is commonly found in metamorphosed magnesium-rich rocks and occurs in amphibolites. Usually it coexists with
hornblende Hornblende is a complex inosilicate series of minerals. It is not a recognized mineral in its own right, but the name is used as a general or field term, to refer to a dark amphibole. Hornblende minerals are common in igneous and metamorphic rock ...
or
actinolite Actinolite is an amphibole silicate mineral with the chemical formula . Etymology The name ''actinolite'' is derived from the Greek word ''aktis'' (), meaning "beam" or "ray", because of the mineral's fibrous nature. Mineralogy Actinolite is ...
, magnesium clinochlore chlorite,
talc Talc, or talcum, is a clay mineral, composed of hydrated magnesium silicate with the chemical formula Mg3Si4O10(OH)2. Talc in powdered form, often combined with corn starch, is used as baby powder. This mineral is used as a thickening agent a ...
, serpentine- antigorite minerals or metamorphic pyroxene. Magnesium-rich cummingtonite can also coexist with anthophyllite. Cummingtonite has also been found in some felsic volcanic rocks such as
dacite Dacite () is a volcanic rock formed by rapid solidification of lava that is high in silica and low in alkali metal oxides. It has a fine-grained (aphanitic) to porphyritic texture and is intermediate in composition between andesite and rhyolite ...
s.
Manganese Manganese is a chemical element with the symbol Mn and atomic number 25. It is a hard, brittle, silvery metal, often found in minerals in combination with iron. Manganese is a transition metal with a multifaceted array of industrial alloy use ...
rich species can be found in metamorphosed Mn-rich rock units. The
grunerite Grunerite is a mineral of the amphibole group of minerals with formula Fe7 Si8 O22( OH)2. It is the iron endmember of the grunerite-cummingtonite series. It forms as fibrous, columnar or massive aggregates of crystals. The crystals are monoclini ...
end member is characteristic of the metamorphosed iron formations of the
Lake Superior Lake Superior in central North America is the largest freshwater lake in the world by surface areaThe Caspian Sea is the largest lake, but is saline, not freshwater. and the third-largest by volume, holding 10% of the world's surface fresh wa ...
region and the
Labrador Trough The Labrador Trough or the New Quebec Orogen is a long and wide geologic belt in Canada, extending south-southeast from Ungava Bay through Quebec and Labrador. The trough is a linear belt of sedimentary and volcanic rocks which developed in an ...
. With prograde metamorphism cummingtonite and grunerite morph to members of the
olivine The mineral olivine () is a magnesium iron silicate with the chemical formula . It is a type of nesosilicate or orthosilicate. The primary component of the Earth's upper mantle, it is a common mineral in Earth's subsurface, but weathers quickl ...
and pyroxene series.


References


Further reading

* * * * {{refend Amphibole group Magnesium minerals Iron(II) minerals Asbestos