Crocoite is a mineral consisting of
lead chromate,
Pb Cr O4, and crystallizing in the
monoclinic crystal system
In crystallography, the monoclinic crystal system is one of the seven crystal systems. A crystal system is described by three vectors. In the monoclinic system, the crystal is described by vectors of unequal lengths, as in the orthorhombic sy ...
. It is identical in composition with the artificial product
chrome yellow used as a paint pigment.
Description
Crocoite is commonly found as large, well-developed prismatic adamantine crystals, although in many cases are poorly terminated. Crystals are of a bright hyacinth-red color, translucent, and have an
adamantine to
vitreous lustre. On exposure to UV light some of the translucency and brilliancy is lost. The streak is orange-yellow;
Mohs hardness
The Mohs scale ( ) of mineral hardness is a qualitative ordinal scale, from 1 to 10, characterizing scratch resistance of mineral
In geology and mineralogy, a mineral or mineral species is, broadly speaking, a solid substance with a fair ...
is 2.5–3; and the
specific gravity
Relative density, also called specific gravity, is a dimensionless quantity defined as the ratio of the density (mass of a unit volume) of a substance to the density of a given reference material. Specific gravity for solids and liquids is nea ...
is 6.0.

It was discovered at the Berezovskoe Au Deposit (Berezovsk Mines) near
Ekaterinburg
Yekaterinburg (, ; ), alternatively Romanization of Russian, romanized as Ekaterinburg and formerly known as Sverdlovsk ( ; 1924–1991), is a city and the administrative centre of Sverdlovsk Oblast and the Ural Federal District, Russia. The ci ...
in the
Urals
The Ural Mountains ( ),; , ; , or simply the Urals, are a mountain range in Eurasia that runs north–south mostly through Russia, from the coast of the Arctic Ocean to the river Ural (river), Ural and northwestern Kazakhstan. in 1766;
and named crocoise by
F. S. Beudant in 1832, from the Greek κρόκος (''krokos''),
saffron, in allusion to its color, a name first altered to crocoisite and afterwards to crocoite. In the type locality the crystals are found in gold-bearing
quartz
Quartz is a hard, crystalline mineral composed of silica (silicon dioxide). The Atom, atoms are linked in a continuous framework of SiO4 silicon–oxygen Tetrahedral molecular geometry, tetrahedra, with each oxygen being shared between two tet ...
-veins traversing
granite
Granite ( ) is a coarse-grained (phanerite, phaneritic) intrusive rock, intrusive igneous rock composed mostly of quartz, alkali feldspar, and plagioclase. It forms from magma with a high content of silica and alkali metal oxides that slowly coo ...
or
gneiss
Gneiss (pronounced ) is a common and widely distributed type of metamorphic rock. It is formed by high-temperature and high-pressure metamorphic processes acting on formations composed of igneous or sedimentary rocks. This rock is formed under p ...
and associated with crocoite are
quartz
Quartz is a hard, crystalline mineral composed of silica (silicon dioxide). The Atom, atoms are linked in a continuous framework of SiO4 silicon–oxygen Tetrahedral molecular geometry, tetrahedra, with each oxygen being shared between two tet ...
, embreyite,
phoenicochroite and
vauquelinite. Phoenicochroite is a basic lead chromate, Pb
2CrO
5 with dark red crystals, and vauquelinite a lead and copper phosphate-chromate, Pb
2CuCrO
4PO
4OH, with brown or green monoclinic crystals. Vauquelinite was named after
Louis Nicolas Vauquelin
Louis Nicolas Vauquelin FRS(For) HFRSE (; 16 May 1763 – 14 November 1829) was a French pharmacist and chemist. He was the discoverer of chromium and beryllium.
Early life
Vauquelin was born at Saint-André-d'Hébertot in Normandy, France, th ...
, who in 1797 discovered (simultaneously with and independently of M. H. Klaproth) the element chromium in crocoite.
Abundant masses with exceptional examples of crocoite crystals have been found at Extended Mine, Adelaide Mine, Red Lead, West Comet, Platt and a few other Mines at
Dundas, Tasmania
Dundas was a historical mining locality, mineral field and railway location on the western foothills of the West Coast Range in Western Tasmania. It is now part of the locality of Zeehan.
Location
The town was located 5 kilometres east o ...
.
The Adelaide Mine is described as "probably the prime source of crocoite in the world.".The Adelaide Mining Company Pty. Ltd. has been actively mining crocoite from the Adelaide Mine since 2004. The website provides detailed information about the mine's history, operations, and the exceptional crocoite specimens it produces.
Crocoite is usually found in long slender prisms, usually about 10–20 mm but rarely up to 100 mm (4 inches) in length, with a brilliant lustre and color. Crocoite is also the official Tasmanian mineral emblem. Other localities which have yielded good crystallized specimens are Congonhas do Campo near Ouro Preto in
Brazil
Brazil, officially the Federative Republic of Brazil, is the largest country in South America. It is the world's List of countries and dependencies by area, fifth-largest country by area and the List of countries and dependencies by population ...
,
Luzon
Luzon ( , ) is the largest and most populous List of islands in the Philippines, island in the Philippines. Located in the northern portion of the List of islands of the Philippines, Philippine archipelago, it is the economic and political ce ...
in the
Philippines
The Philippines, officially the Republic of the Philippines, is an Archipelagic state, archipelagic country in Southeast Asia. Located in the western Pacific Ocean, it consists of List of islands of the Philippines, 7,641 islands, with a tot ...
,
Mutare
Mutare, formerly known as Umtali until 1982, is the capital and largest city in the province of Manicaland. It is the third most populated in Zimbabwe. Having surpassed Gweru in the 2012 census, with an urban area, urban population of 224,802 ...
in
Mashonaland
Mashonaland is a region in northeastern Zimbabwe. It is home to nearly half of the population of Zimbabwe. The majority of the Mashonaland people are from the Shona tribe while the Zezuru and Korekore dialects are most common. Harare is the larg ...
, near Menzies in Western Australia, plus Brazil, Germany and South Africa.
The relative rarity of crocoite is connected with the specific conditions required for its formation: an oxidation zone of lead ore bed and presence of ultramafic rocks serving as the source of chromium (in
chromite
Chromite is a crystalline mineral composed primarily of iron(II) oxide and chromium(III) oxide compounds. It can be represented by the chemical formula of Iron, FeChromium, Cr2Oxygen, O4. It is an oxide mineral belonging to the spinel group. The ...
). Oxidation of Cr
3+ into CrO
42− (from chromite) and decomposition of
galena
Galena, also called lead glance, is the natural mineral form of lead(II) sulfide (PbS). It is the most important ore of lead and an important source of silver.
Galena is one of the most abundant and widely distributed sulfide minerals. It crysta ...
(or other primary lead minerals) are required for crocoite formation. These conditions are relatively unusual.
As crocoite is composed of
lead(II) chromate
Lead(II) chromate is an inorganic compound with the chemical formula . It is a bright yellow salt that is very poorly soluble in water. It occurs also as the mineral crocoite. It is used as a pigment.
Structure
Two polymorphs of lead chromat ...
, it is toxic, containing both lead and
hexavalent chromium
Hexavalent chromium (chromium(VI), Cr(VI), chromium 6) is any chemical compound that contains the element chromium in the +6 oxidation state (thus hexavalent). It has been identified as carcinogenic, which is of concern since approximately of ...
.
Mines
'
The Adelaide Mine
Dundas, Tasmania, is famous for its world’s best crocoite. Adam Wright and his partners have been operating it for mineral specimen removal for a number of years and have had significant finds in recent years. In particular, the 2010 Pocket, and more recently, the Red River Pocket.
The Mineralogical Record has documented major crocoite discoveries at the Adelaide Mine, including the significant "Red River Find" in 2012. This publication highlights the mine's ongoing importance in the mineral collecting community.
Of the mines in the Dundas field, the Adelaide mine is the most
prolific source of superb crocoite specimens, historically as well as currently. The mine is situated at the junction of Comet Creek and
Adelaide Creek, near the base of a spur of Stichtite Hill about 2 km
southeast of the original Dundas townsite.
Of the numerous mines in the Dundas region, one has recently come back to life more than any other - The Adelaide Mine. The video titled "The Adelaide Mine" features Mineralogist Ralph Bottrill from Mineral Resources Tasmania, who provides an in-depth exploration of the renowned Adelaide Mine located in the Dundas region of Tasmania. In the video, viewers are taken underground to uncover the remarkable Red River find.
'
Red Lead Mine'', The Red Lead Mine, located in the Dundas region near Zeehan on the west coast of Tasmania, Australia, is renowned for its stunning crocoite specimens. Shane Dohnt purchased the Red Lead Mine in 1986 and has been actively working it for crocoite ever since. Initially, he continued with open-cut mining, but more recently, he has reopened an 1890s collapsed adit to access the lodes below the surface. This approach reduces environmental impact and allows access to potentially rich areas too deep for open-cut mining.
The Red Lead Mine has produced many fine specimens of crocoite over the years, and operations continue with the hope of discovering more exceptional specimens. The mine's crocoite specimens are highly sought after by collectors and have even been displayed at the Smithsonian Museum of Natural History in Washington D.C.
'
''. Crocoite from Tasmania has also been mined from the Dundas Extended Mine by Mike and Eleanor Phelan since the mid-1980s, but the mine's origins date back to 1892 when it was used as a prospecting tunnel for silver lead. In April 2019, the mine was listed for sale,
[For $300,000, you could own a hobby mine in a Tasmanian ghost town](_blank)
Damian McIntyre, ABC News Online
ABC News, also known as ABC News and Current Affairs, is a public news service produced by the Australian Broadcasting Corporation. The service covers both local and world affairs, broadcasting both nationally as ABC News, and across the Asia- ...
, 26 April 2019 however, it was not sold.
Gallery
Examples of crocoite
Crocoite from Tasmania.jpg, Specimen from the Red Lead Mine, Tasmania
Tasmania (; palawa kani: ''Lutruwita'') is an island States and territories of Australia, state of Australia. It is located to the south of the Mainland Australia, Australian mainland, and is separated from it by the Bass Strait. The sta ...
, Australia
Australia, officially the Commonwealth of Australia, is a country comprising mainland Australia, the mainland of the Australia (continent), Australian continent, the island of Tasmania and list of islands of Australia, numerous smaller isl ...
Crocoite-360746.jpg, Crocoite from Adelaide Mine, Dundas mineral field, Zeehan District, Tasmania, Australia
crocoite09.jpg, Crystal intergrowth
Berezov-crocoite.jpg, On pyromorphite – Berezovsk – Deposit Topotype
See also
*
Bellite
References
*
* Bushmakin, A.F., 1996. Crocoite from the Berezovsk gold mines. World of Stones, 10, 28–31
* Bottrill, R.S., Williams, P., Dohnt, S., Sorrell, S. and Kemp, N.R. (2006). Crocoite and associated minerals from Dundas and other locations in Tasmania. Australian Journal of Mineralogy. 12, 59–90
External links
List of Tasmanian state emblems{{Webarchive, url=https://web.archive.org/web/20181225064058/http://www.parliament.tas.gov.au/tpl/InfoSheets/StateEmblems.htm , date=25 December 2018
Lead minerals
Chromate minerals
Monoclinic minerals
Minerals in space group 14
Luminescent minerals
Minerals described in 1832
Symbols of Tasmania