Cornubian Batholith
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The Cornubian batholith is a large mass of
granite Granite ( ) is a coarse-grained (phanerite, phaneritic) intrusive rock, intrusive igneous rock composed mostly of quartz, alkali feldspar, and plagioclase. It forms from magma with a high content of silica and alkali metal oxides that slowly coo ...
rock, formed about 280 million years ago, which lies beneath much of
Cornwall Cornwall (; or ) is a Ceremonial counties of England, ceremonial county in South West England. It is also one of the Celtic nations and the homeland of the Cornish people. The county is bordered by the Atlantic Ocean to the north and west, ...
and
Devon Devon ( ; historically also known as Devonshire , ) is a ceremonial county in South West England. It is bordered by the Bristol Channel to the north, Somerset and Dorset to the east, the English Channel to the south, and Cornwall to the west ...
in the South West Peninsula of
England England is a Countries of the United Kingdom, country that is part of the United Kingdom. It is located on the island of Great Britain, of which it covers about 62%, and List of islands of England, more than 100 smaller adjacent islands. It ...
. The main exposed masses of granite are seen at
Dartmoor Dartmoor is an upland area in southern Devon, South West England. The moorland and surrounding land has been protected by National Park status since 1951. Dartmoor National Park covers . The granite that forms the uplands dates from the Carb ...
,
Bodmin Moor Bodmin Moor () is a granite moorland in north-eastern Cornwall, England, United Kingdom. It is in size, and dates from the Carboniferous period of geology, geological history. It includes Brown Willy, the highest point in Cornwall, and Rough To ...
,
St Austell Saint Austell (, ; ) is a town in Cornwall, England, United Kingdom, south of Bodmin and west of the border with Devon. At the 2021 Census in the United Kingdom, census it had a population of 20,900. History St Austell was a village centred ...
,
Carnmenellis Carnmenellis Hill (or just Carnmenellis) gives its name to the area of west Cornwall in England, between Redruth, Helston and Penryn. The hill itself is situated approximately three miles (5 km) south of Redruth.Ordnance Survey: Landra ...
,
Land's End Land's End ( or ''Pedn an Wlas'') is a headland and tourist and holiday complex in western Cornwall, England, United Kingdom, on the Penwith peninsula about west-south-west of Penzance at the western end of the A30 road. To the east of it is ...
and the
Isles of Scilly The Isles of Scilly ( ; ) are a small archipelago off the southwestern tip of Cornwall, England. One of the islands, St Agnes, Isles of Scilly, St Agnes, is over farther south than the most southerly point of the Great Britain, British mainla ...
. The intrusion is associated with significant quantities of
minerals In geology and mineralogy, a mineral or mineral species is, broadly speaking, a solid substance with a fairly well-defined chemical composition and a specific crystal structure that occurs naturally in pure form.John P. Rafferty, ed. (2011): M ...
, particularly
cassiterite Cassiterite is a tin oxide mineral, SnO2. It is generally opaque, but it is translucent in thin crystals. Its luster and multiple crystal faces produce a desirable gem. Cassiterite was the chief tin ore throughout ancient history and remains ...
, an ore of
tin Tin is a chemical element; it has symbol Sn () and atomic number 50. A silvery-colored metal, tin is soft enough to be cut with little force, and a bar of tin can be bent by hand with little effort. When bent, a bar of tin makes a sound, the ...
which has been mined since about 2000 BC. Other minerals include
china clay Kaolinite ( ; also called kaolin) is a clay mineral, with the chemical composition aluminium, Al2Silicon, Si2Oxygen, O5(hydroxide, OH)4. It is a layered silicate mineral, with one tetrahedron, tetrahedral sheet of silica () linked through oxygen ...
and ores of
copper Copper is a chemical element; it has symbol Cu (from Latin ) and atomic number 29. It is a soft, malleable, and ductile metal with very high thermal and electrical conductivity. A freshly exposed surface of pure copper has a pinkish-orang ...
,
lead Lead () is a chemical element; it has Chemical symbol, symbol Pb (from Latin ) and atomic number 82. It is a Heavy metal (elements), heavy metal that is density, denser than most common materials. Lead is Mohs scale, soft and Ductility, malleabl ...
,
zinc Zinc is a chemical element; it has symbol Zn and atomic number 30. It is a slightly brittle metal at room temperature and has a shiny-greyish appearance when oxidation is removed. It is the first element in group 12 (IIB) of the periodic tabl ...
and
tungsten Tungsten (also called wolfram) is a chemical element; it has symbol W and atomic number 74. It is a metal found naturally on Earth almost exclusively in compounds with other elements. It was identified as a distinct element in 1781 and first ...
. It takes its name from ''Cornubia'', the
Medieval Latin Medieval Latin was the form of Literary Latin used in Roman Catholic Church, Roman Catholic Western Europe during the Middle Ages. It was also the administrative language in the former Western Roman Empire, Roman Provinces of Mauretania, Numidi ...
name for Cornwall.


Extent and geometry

A
batholith A batholith () is a large mass of intrusive rock, intrusive igneous rock (also called plutonic rock), larger than in area, that forms from cooled magma deep in the Earth's crust. Batholiths are almost always made mostly of felsic or intermediate ...
is a large mass of
intrusive rock Intrusive rock is formed when magma penetrates existing rock, crystallizes, and solidifies underground to form ''Igneous intrusion, intrusions'', such as batholiths, dike (geology), dikes, Sill (geology), sills, laccoliths, and volcanic necks.I ...
formed from the crystallization of molten rock beneath the Earth's surface (
magma Magma () is the molten or semi-molten natural material from which all igneous rocks are formed. Magma (sometimes colloquially but incorrectly referred to as ''lava'') is found beneath the surface of the Earth, and evidence of magmatism has also ...
). From
gravity In physics, gravity (), also known as gravitation or a gravitational interaction, is a fundamental interaction, a mutual attraction between all massive particles. On Earth, gravity takes a slightly different meaning: the observed force b ...
and
magnetic Magnetism is the class of physical attributes that occur through a magnetic field, which allows objects to attract or repel each other. Because both electric currents and magnetic moments of elementary particles give rise to a magnetic field, m ...
geophysical data, the batholith is interpreted to extend from about 8°W, more than 100 km southwest of the Isles of Scilly, to the eastern edge of Dartmoor. The negative gravity anomaly, caused by the relatively low density of the granites compared to average
continental crust Continental crust is the layer of igneous, metamorphic, and sedimentary rocks that forms the geological continents and the areas of shallow seabed close to their shores, known as '' continental shelves''. This layer is sometimes called '' si ...
, is linear and trends WSW-ENE, parallel with that associated with the Haig Fras granite. The shape of the
batholith A batholith () is a large mass of intrusive rock, intrusive igneous rock (also called plutonic rock), larger than in area, that forms from cooled magma deep in the Earth's crust. Batholiths are almost always made mostly of felsic or intermediate ...
and the relationship between the individual
pluton In geology, an igneous intrusion (or intrusive body or simply intrusion) is a body of intrusive igneous rock that forms by crystallization of magma slowly cooling below the surface of the Earth. Intrusions have a wide variety of forms and com ...
s and the main mass of the granite remained entirely speculative until gravity data began to be used to constrain the thickness and shape of the batholith by modelling. The initial work by Martin Bott suggested that the batholith had an overall trapezoidal shape with a base to the batholith at about 10–12 km. However, current understanding of granite pluton shape suggest that most are either
laccolith A laccolith is a body of intrusive rock with a dome-shaped upper surface and a level base, fed by a conduit from below. A laccolith forms when magma (molten rock) rising through the Earth's crust begins to spread out horizontally, prying apart ...
ic or
lopolith A lopolith is a large igneous intrusion which is lenticular in shape with a depressed central region. Lopoliths are generally concordant with the intruded strata with dike or funnel-shaped feeder bodies below the body. The term was first defined ...
ic. Comparisons with other examples would suggest that the thicknesses of the individual plutons would be in the range 3–5 km, based on their outcrop widths. The volume of the batholith was estimated in 1989 to be around 68,000 cubic kilometres.


Formation

The Cornubian batholith formed during the
Early Permian 01 or 01 may refer to: * The year 2001, or any year ending with 01 * The month of January * 1 (number) Music * '01 (Richard Müller album), ''01'' (Richard Müller album), 2001 * 01 (Urban Zakapa album), ''01'' (Urban Zakapa album), 2011 * ''01011 ...
period, from about 300 to 275 Ma (million years ago) at a late stage in the mountain-building event known as the
Variscan orogeny The Variscan orogeny, or Hercynian orogeny, was a geologic mountain-building event caused by Late Paleozoic continental collision between Euramerica (Laurussia) and Gondwana to form the supercontinent of Pangaea. Nomenclature The name ''Varis ...
as a suite of late orogenic granites. It has been suggested that stretching of the Earth's crust ( crustal extension) allowed the granitic magmas to move to higher levels in the crust. Evidence from
neodymium Neodymium is a chemical element; it has Symbol (chemistry), symbol Nd and atomic number 60. It is the fourth member of the lanthanide series and is considered to be one of the rare-earth element, rare-earth metals. It is a hard (physics), hard, sli ...
and
strontium Strontium is a chemical element; it has symbol Sr and atomic number 38. An alkaline earth metal, it is a soft silver-white yellowish metallic element that is highly chemically reactive. The metal forms a dark oxide layer when it is exposed to ...
isotopes suggests that the magmas that formed the batholith were mainly the result of
partial melting Partial melting is the phenomenon that occurs when a rock is subjected to temperatures high enough to cause certain minerals to melt, but not all of them. Partial melting is an important part of the formation of all igneous rocks and some metamorp ...
of the lower crust with a minor component of basaltic magma from a mantle source. This lower crustal source is likely to have consisted of both
metasedimentary In geology, metasedimentary rock is a type of metamorphic rock. Such a rock was first formed through the deposition and solidification of sediment Sediment is a solid material that is transported to a new location where it is deposited. It occu ...
and metavolcanic rocks, of
Proterozoic The Proterozoic ( ) is the third of the four geologic eons of Earth's history, spanning the time interval from 2500 to 538.8 Mya, and is the longest eon of Earth's geologic time scale. It is preceded by the Archean and followed by the Phanerozo ...
age (2500 million to 539 million years old). As the molten rock cooled to around 1000
Celsius The degree Celsius is the unit of temperature on the Celsius temperature scale "Celsius temperature scale, also called centigrade temperature scale, scale based on 0 ° for the melting point of water and 100 ° for the boiling point ...
it solidified and crystallised and fractures along vertical joints formed. Over time the slate and sandstone rocks covering the granite were eroded exposing the granite in areas such as Dartmoor and Bodmin Moor. The granite also expanded and horizontal joints were formed. These joints are most clearly seen on exposed pieces of rock such as the Tors of Dartmoor and Bodmin Moor. As the granite erodes further, blocks of eroded granite known as clitter are left.


Timing

An approximate age of emplacement for the Cornubian batholith was known before
radiometric dating Radiometric dating, radioactive dating or radioisotope dating is a technique which is used to Chronological dating, date materials such as Rock (geology), rocks or carbon, in which trace radioactive impurity, impurities were selectively incorporat ...
methods became commonplace, from the observed relationships with the
sedimentary Sedimentary rocks are types of rock formed by the cementation of sediments—i.e. particles made of minerals (geological detritus) or organic matter (biological detritus)—that have been accumulated or deposited at Earth's surface. Sedime ...
rocks – both those which formed before the intrusion and those which were laid down after it. The youngest rocks into which the granites intrude are the
Carboniferous The Carboniferous ( ) is a Geologic time scale, geologic period and System (stratigraphy), system of the Paleozoic era (geology), era that spans 60 million years, from the end of the Devonian Period Ma (million years ago) to the beginning of the ...
Crackington and Bealsmill formations of
Namurian The Namurian is a stage in the regional stratigraphy of northwest Europe, with an age between roughly 331 and 319 Ma (million years ago). It is a subdivision of the Carboniferous system or period, as well as the regional Silesian series. The Na ...
to lower Westphalian age. This provides a lower bound for the timing of granite emplacement of about 310 Ma. The earliest instance of granitic clasts (fragments of the granite which have weathered away and become part of a new sedimentary rock) in younger sedimentary sequences is from the Late Permian St. Cyres beds. This gives an upper bound of about 250 Ma. The inferred age of emplacement from this evidence of Late Carboniferous to Early Permian has been confirmed by radiometric dating, although it has shown that the individual intrusions were emplaced over a significant time interval. The earliest dated major intrusion is the Carnmenellis pluton at 293.1±3 Ma. The youngest dated granite is the southern lobe of the Land's End pluton, intruded at 274.5±1.4 Ma. The earliest recorded magmatic activity is the intrusion of the small Hemerdon pluton on the southwestern flank of the Dartmoor pluton at 298.3±2.3 Ma. There is no apparent systematic variation in age of plutons compared to their position within the batholith. This suggests that the batholith grew by the coalescence of a series of separate intrusions over a period of about 25 Ma.


Mechanism of emplacement

As with all large intrusive bodies, the method by which the batholith's plutons were emplaced is a matter of debate, due to the space problem of adding such large masses to the upper crust. Four main mechanisms have been proposed;
stoping Stoping is the process of extracting the desired ore or other mineral from an underground mine, leaving behind an open space known as a stope. Stoping is used when the country rock is sufficiently strong not to collapse into the stope, althou ...
,
diapirism A diapir (; , ) is a type of intrusion in which a more mobile and ductilely deformable material is forced into brittle overlying rocks. Depending on the tectonic environment, diapirs can range from idealized mushroom-shaped Rayleigh–Taylor ...
, extensional faulting and uplift of the overlying
country rock Country rock is a music genre that fuses rock and country. It was developed by rock musicians who began to record country-flavored records in the late 1960s and early 1970s. These musicians recorded rock records using country themes, vocal sty ...
over a laccolithic sill with a relatively small vertical dyke feeder. Evidence for a stoping mechanism has been described locally from the margin of the Tregonning intrusion, where a series of intrusive sheets extend out from the roof zone of the intrusion into the country-rock. Although the Land's End pluton was once thought to have a diapiric origin, its emplacement is now interpreted to have been accommodated by fault movements during regional extension.


Plutons

The individual
pluton In geology, an igneous intrusion (or intrusive body or simply intrusion) is a body of intrusive igneous rock that forms by crystallization of magma slowly cooling below the surface of the Earth. Intrusions have a wide variety of forms and com ...
s that comprise the Cornubian Batholith can be broadly subdivided into five main lithologies: Two mica, Muscovite, Biotite, Tourmaline and Topaz granites, each named for their distinguishing mineral(s). The two-mica and muscovite granites are older, and can be found in the Carnmenellis, Bodmin and Isles of Scilly, whereas the younger biotite and tourmaline granites are found within the Land's End, St. Austell and Dartmoor plutons. Topaz granites outcrop within the Tregonning, Land's End and St Austell plutons.


Dartmoor

This is the largest exposed area of granite which also forms the easternmost development of the batholith. The granite consists of two main types, coarse-grained granite with abundant large
alkali feldspar Feldspar ( ; sometimes spelled felspar) is a group of rock-forming aluminium tectosilicate minerals, also containing other cations such as sodium, calcium, potassium, or barium. The most common members of the feldspar group are the ''plagiocla ...
megacrysts and coarse-grained granite with few megacrysts. To the southwest there is an area of coarse-grained granite with small megacrysts and several small exposures of fine-grained granite, particularly in the southeastern part of the outcrop. Interpretation of the gravity field over this pluton suggests that it is sheet-like with a thickness of nearly 10 km, and a root at its southern end extending down to about 17 km depth, which may represent the conduit that carried the magma to shallow crustal levels. It appears to have been intruded along the interface between Devonian and Carboniferous rocks. Uranium-lead dating of
Monazite Monazite is a primarily reddish-brown phosphate mineral that contains rare-earth elements. Due to variability in composition, monazite is considered a group of minerals. The most common species of the group is monazite-(Ce), that is, the cerium ...
from this intrusion gives emplacement ages of 278.2±0.8 Ma and 280.4±1.2 Ma.


Bodmin Moor

The Bodmin Moor pluton consists mainly of coarse-grained granite with abundant small megacrysts. Towards the centre and the western margin of the outcrop there are smaller bodies of fine-grained granite. Gravity data suggest that this pluton is in the form of a south-southeastward thickening wedge, reaching a maximum of about 7 km. Monazite from this pluton gives an emplacement age of 291.4±0.8 Ma.


St Austell

The St Austell pluton consists of coarse-grained megacrystic granite with large megacrysts at the western and eastern ends of the outcrop. The central part of the pluton is also coarse-grained but lacks the megacrysts. Between the central megacryst poor and the large megacryst rich coarse-grained granites at the western end, a medium-grained granite is developed with lithium-mica. Smaller bodies of fine-grained granite are found in the central part of the outcrop and at the western end. Gravity data indicate that this pluton is wedge-shaped similar to that at Bodmin. Monazite gives an emplacement age of 281.8±0.4 Ma for this pluton.


Carnmenellis

The Carnmenellis pluton and the smaller intrusion of Carn Brea appear to be part of a single intrusive body. The central part of the Carnmenellis outcrop is a medium-grained granite with few megacrysts. The bulk of the main outcrop and the Carn Brea and Carn Marth masses consist of coarse-grained megacrystic granite with small megacrysts. Small bodies of fine-grained granite are found towards the west of the Carnemellis outcrop. The shape of this pluton is interpreted to be a sheet about 3 km thick with a near central root extending down to about 7 km depth. Boreholes at Rosemanowes that extend to over 2.5 km deep have shown very little variation in the petrographic composition of the granite with depth in this pluton. Monazite gives an emplacement age of 293.7±0.6 Ma for this pluton.


Tregonning-Godolphin

The Tregonning Granite and Godolphin Granite are two distinct granite bodies on the southern coast of Cornwall. The Tregonning Granite is mainly a medium-grained lithium-mica granite with a body of fine-grained granite developed towards the northwest of the outcrop. It has a unique chemistry and differs from the granite found within the Carnmenellis and Land's End granites, likely forming in a different manner. The Godolphin Granite is mineralogically and chemically similar to the nearby Carnmenellis Granite, although is finer grained.


Land's End

The Land's End pluton is mainly a coarse-grained granite with abundant large megacrysts. There is an area in the centre which is poor in megacrysts and there are several small and medium-sized masses of fine-grained granite throughout the outcrop. Dating has been carried out on xenotime and monazite samples, from a fine-grained granite and the main coarse-grained granite respectively. These give emplacement ages of 279.3±0.4 Ma for the fine-grained granite and 274.8±0.5 Ma for the main phase granite. This difference is consistent with fine-grained granite being a roof-pendant to the coarse-grained main phase granite intrusion.


Isles of Scilly

The Isles of Scilly all have granite bedrock. The dominant rock type is a megacrystic biotite granite, although the megacrysts are relatively small. In the centre of the pluton a medium-grained granite is developed with few megacrysts, more tourmaline and less biotite than the main variety. Monazite from this pluton suggest an emplacement age of 290.3±0.6 Ma.


Haig Fras

This submarine outcrop, 45 km in length, lies 95 km northwest of the Scilly Isles, rising at one point to 38 m below sea level. In contrast to most granites of the Cornubian batholith the granites here are fine to medium-grained and generally lack megacrysts. It was intruded at 277 Ma and is considered most likely to be a separate but related intrusive body that runs parallel to the Cornubian batholith.


Other intrusions

Minor granitic intrusions are present throughout the peninsula. In some cases granitic bodies have been recognised from the mineralization above them, even if the intrusion itself has not been encountered. A series of minor intrusions are found within the country rock and the granites themselves. Common types are
pegmatite A pegmatite is an igneous rock showing a very coarse texture, with large interlocking crystals usually greater in size than and sometimes greater than . Most pegmatites are composed of quartz, feldspar, and mica, having a similar silicic c ...
s,
aplite Aplite () is an intrusive igneous rock that has a granitic composition. Aplites are fine-grained to aphanitic Aphanites (adj. ''aphanitic''; ) are igneous rocks that are so fine-grained that their component mineral crystals are not vi ...
s and
elvan Elvan is a name used in Cornwall and Devon for the native varieties of quartz-porphyry. They are dispersed irregularly in the Devonian series of rocks and some of them make very fine building stones (e.g. Pentewan stone, Polyphant stone and Cat ...
s.


Mineralogy and chemistry of the granite and other rocks


Granite

The main rock forming the batholith is
granite Granite ( ) is a coarse-grained (phanerite, phaneritic) intrusive rock, intrusive igneous rock composed mostly of quartz, alkali feldspar, and plagioclase. It forms from magma with a high content of silica and alkali metal oxides that slowly coo ...
, which formed when
magma Magma () is the molten or semi-molten natural material from which all igneous rocks are formed. Magma (sometimes colloquially but incorrectly referred to as ''lava'') is found beneath the surface of the Earth, and evidence of magmatism has also ...
cooled slowly, covered by 2–3,000 metres of slate and sandstone. The slow cooling gave time for crystals to form in the granite which are large enough to see with the naked eye, giving it a granular appearance. These grains are mainly of
quartz Quartz is a hard, crystalline mineral composed of silica (silicon dioxide). The Atom, atoms are linked in a continuous framework of SiO4 silicon–oxygen Tetrahedral molecular geometry, tetrahedra, with each oxygen being shared between two tet ...
,
feldspar Feldspar ( ; sometimes spelled felspar) is a group of rock-forming aluminium tectosilicate minerals, also containing other cations such as sodium, calcium, potassium, or barium. The most common members of the feldspar group are the ''plagiocl ...
and
biotite Biotite is a common group of phyllosilicate minerals within the mica group, with the approximate chemical formula . It is primarily a solid-solution series between the iron- endmember annite, and the magnesium-endmember phlogopite; more al ...
. The granite is generally coarse grained and in some places very coarse-grained, or pegmatitic (grains larger than 3 cm). Large
phenocrysts 300px, Swiss side of the Mont Blanc massif, has large white phenocrysts of plagioclase (that have trapezoid shapes when cut through). 1 euro coin (diameter 2.3 cm) for scale. A phenocryst is an early forming, relatively large and usually conspic ...
, several centimetres long, of K-feldspar, are a distinctive feature. The chemistry and mineralogy of the granites vary from one location to another, but they are all classified on the Chappell & White classification as being ''S-type'', which means that they are ultimately derived from
sedimentary rock Sedimentary rocks are types of rock (geology), rock formed by the cementation (geology), cementation of sediments—i.e. particles made of minerals (geological detritus) or organic matter (biological detritus)—that have been accumulated or de ...
protolith A protolith () is the original, unmetamorphosed rock from which a given metamorphic rock is formed. For example, the protolith of a slate is a shale or mudstone. Metamorphic rocks can be derived from any other kind of non-metamorphic rock and ...
.


Mineralogy

The Cornubian intrusions are mostly made up of two-
mica Micas ( ) are a group of silicate minerals whose outstanding physical characteristic is that individual mica crystals can easily be split into fragile elastic plates. This characteristic is described as ''perfect basal cleavage''. Mica is co ...
granite (containing both
muscovite Muscovite (also known as common mica, isinglass, or potash mica) is a hydrated phyllosilicate mineral of aluminium and potassium with formula KAl2(Al Si3 O10)( F,O H)2, or ( KF)2( Al2O3)3( SiO2)6( H2O). It has a highly perfect basal cleavage y ...
and
biotite Biotite is a common group of phyllosilicate minerals within the mica group, with the approximate chemical formula . It is primarily a solid-solution series between the iron- endmember annite, and the magnesium-endmember phlogopite; more al ...
). Li-mica granite forms a less common type found only in the St. Austell pluton and some smaller intrusions. Many of the granites contain large alkali feldspar phenocrysts. In some locations the original granite has been modified to form a
tourmaline Tourmaline ( ) is a crystalline silicate mineral, silicate mineral group in which boron is chemical compound, compounded with chemical element, elements such as aluminium, iron, magnesium, sodium, lithium, or potassium. This gemstone comes in a ...
-bearing granite called luxullianite. This tourmalinisation occurred during the late stages of cooling of the granite, as feldspar and mica were partly replaced by tourmaline.


Chemistry

The two-mica granites are strongly peraluminous – they have a high ratio of aluminium oxide to sodium and potassium oxides. They also have a low ratio of sodium to potassium and overall high level of alkalis. The granites are highly enriched in
lithium Lithium (from , , ) is a chemical element; it has chemical symbol, symbol Li and atomic number 3. It is a soft, silvery-white alkali metal. Under standard temperature and pressure, standard conditions, it is the least dense metal and the ...
,
boron Boron is a chemical element; it has symbol B and atomic number 5. In its crystalline form it is a brittle, dark, lustrous metalloid; in its amorphous form it is a brown powder. As the lightest element of the boron group it has three ...
,
caesium Caesium (IUPAC spelling; also spelled cesium in American English) is a chemical element; it has Symbol (chemistry), symbol Cs and atomic number 55. It is a soft, silvery-golden alkali metal with a melting point of , which makes it one of only f ...
and
uranium Uranium is a chemical element; it has chemical symbol, symbol U and atomic number 92. It is a silvery-grey metal in the actinide series of the periodic table. A uranium atom has 92 protons and 92 electrons, of which 6 are valence electrons. Ura ...
and moderately so in
fluorine Fluorine is a chemical element; it has Chemical symbol, symbol F and atomic number 9. It is the lightest halogen and exists at Standard temperature and pressure, standard conditions as pale yellow Diatomic molecule, diatomic gas. Fluorine is extre ...
,
gallium Gallium is a chemical element; it has Chemical symbol, symbol Ga and atomic number 31. Discovered by the French chemist Paul-Émile Lecoq de Boisbaudran in 1875, elemental gallium is a soft, silvery metal at standard temperature and pressure. ...
,
germanium Germanium is a chemical element; it has Symbol (chemistry), symbol Ge and atomic number 32. It is lustrous, hard-brittle, grayish-white and similar in appearance to silicon. It is a metalloid or a nonmetal in the carbon group that is chemically ...
,
rubidium Rubidium is a chemical element; it has Symbol (chemistry), symbol Rb and atomic number 37. It is a very soft, whitish-grey solid in the alkali metal group, similar to potassium and caesium. Rubidium is the first alkali metal in the group to have ...
, tin,
tantalum Tantalum is a chemical element; it has Symbol (chemistry), symbol Ta and atomic number 73. It is named after Tantalus, a figure in Greek mythology. Tantalum is a very hard, ductility, ductile, lustre (mineralogy), lustrous, blue-gray transition ...
,
tungsten Tungsten (also called wolfram) is a chemical element; it has symbol W and atomic number 74. It is a metal found naturally on Earth almost exclusively in compounds with other elements. It was identified as a distinct element in 1781 and first ...
and
thallium Thallium is a chemical element; it has Symbol (chemistry), symbol Tl and atomic number 81. It is a silvery-white post-transition metal that is not found free in nature. When isolated, thallium resembles tin, but discolors when exposed to air. Che ...
. Given the overall chemistry, the levels of
phosphorus Phosphorus is a chemical element; it has Chemical symbol, symbol P and atomic number 15. All elemental forms of phosphorus are highly Reactivity (chemistry), reactive and are therefore never found in nature. They can nevertheless be prepared ar ...
are also high. Strontium,
barium Barium is a chemical element; it has symbol Ba and atomic number 56. It is the fifth element in group 2 and is a soft, silvery alkaline earth metal. Because of its high chemical reactivity, barium is never found in nature as a free element. Th ...
and the elements from
scandium Scandium is a chemical element; it has Symbol (chemistry), symbol Sc and atomic number 21. It is a silvery-white metallic d-block, d-block element. Historically, it has been classified as a rare-earth element, together with yttrium and the lantha ...
to
zinc Zinc is a chemical element; it has symbol Zn and atomic number 30. It is a slightly brittle metal at room temperature and has a shiny-greyish appearance when oxidation is removed. It is the first element in group 12 (IIB) of the periodic tabl ...
are relatively depleted. This chemistry is consistent with partial melting of a source consisting of
greywacke Greywacke or graywacke ( ) is a variety of sandstone generally characterized by its hardness (6–7 on Mohs scale), dark color, and Sorting (sediment), poorly sorted angular grains of quartz, feldspar, and small rock fragments or sand-size Lith ...
s (a variety of sandstone). The conditions under which the melts formed is modelled to be temperature of 770 °C and a confining pressure of 50
MPa MPA or mPa may refer to: Academia Academic degrees * Master of Performing Arts * Master of Professional Accountancy * Master of Public Administration * Master of Public Affairs Schools * Mesa Preparatory Academy * Morgan Park Academy * M ...
. Differences in chemistry have been identified between an earlier group of plutons (Isles of Scilly, Carnmenellis & Bodmin Moor) and a later group (Land's End, St Austell & Dartmoor). The early group of granites contain more aluminium than the later set and have steeper slopes on plots of
cerium Cerium is a chemical element; it has Chemical symbol, symbol Ce and atomic number 58. It is a hardness, soft, ductile, and silvery-white metal that tarnishes when exposed to air. Cerium is the second element in the lanthanide series, and while it ...
against
yttrium Yttrium is a chemical element; it has Symbol (chemistry), symbol Y and atomic number 39. It is a silvery-metallic transition metal chemically similar to the lanthanides and has often been classified as a "rare-earth element". Yttrium is almost a ...
. The later group contain more common basic microgranite
xenolith A xenolith ("foreign rock") is a rock (geology), rock fragment (Country rock (geology), country rock) that becomes enveloped in a larger rock during the latter's development and solidification. In geology, the term ''xenolith'' is almost exclusi ...
s. The granites are generally rich in ammonium compared to average granites worldwide. There is also considerable variation between the individual plutons, with an average of 11 ppm for Dartmoor compared to 94 ppm for Bodmin Moor. The concentration of ammonium in these granites correlates well with both their initial / ratios and their peraluminosity. The relatively high ammonium content is interpreted to indicate that the granites were derived from a sedimentary protolith, or have been contaminated from such a source after emplacement to high crustal levels.


Associated metamorphic and metasomatic rocks

Around the edges of many of the plutons the country rocks have been transformed by heat in a process known as
contact metamorphism Metamorphism is the transformation of existing rock (the protolith) to rock with a different mineral composition or texture. Metamorphism takes place at temperatures in excess of , and often also at elevated pressure or in the presence of c ...
. The effects of this can be seen up to a distance of 4 miles from the granite in an area called the metamorphic aureole. The effect of this process depends on the type of rocks which were heated and their distance from the intrusion. Fine grained sedimentary rocks were transformed into
hornfels Hornfels is the group name for a set of Metamorphism#Contact .28thermal.29, contact metamorphic rocks that have been baked and hardened by the heat of Intrusive rock, intrusive igneous masses and have been rendered massive, hard, splintery, and in ...
and minerals such as
amphibole Amphibole ( ) is a group of inosilicate minerals, forming prism or needlelike crystals, composed of double chain tetrahedra, linked at the vertices and generally containing ions of iron and/or magnesium in their structures. Its IMA symbol is ...
,
pyroxene The pyroxenes (commonly abbreviated Px) are a group of important rock-forming inosilicate minerals found in many igneous and metamorphic rocks. Pyroxenes have the general formula , where X represents ions of calcium (Ca), sodium (Na), iron ( ...
. At greater distances from the plutons, the only evidence of metamorphism is spotting in these rocks.
Garnet Garnets () are a group of silicate minerals that have been used since the Bronze Age as gemstones and abrasives. Garnet minerals, while sharing similar physical and crystallographic properties, exhibit a wide range of chemical compositions, de ...
developed in
calcareous Calcareous () is an adjective meaning "mostly or partly composed of calcium carbonate", in other words, containing lime (mineral), lime or being chalky. The term is used in a wide variety of Science, scientific disciplines. In zoology ''Calcare ...
rocks as well as
amphibole Amphibole ( ) is a group of inosilicate minerals, forming prism or needlelike crystals, composed of double chain tetrahedra, linked at the vertices and generally containing ions of iron and/or magnesium in their structures. Its IMA symbol is ...
and
pyroxene The pyroxenes (commonly abbreviated Px) are a group of important rock-forming inosilicate minerals found in many igneous and metamorphic rocks. Pyroxenes have the general formula , where X represents ions of calcium (Ca), sodium (Na), iron ( ...
. The metamorphism of greenstones has generally led to the formation of
hornblende Hornblende is a complex silicate minerals#Inosilicates, inosilicate series of minerals. It is not a recognized mineral in its own right, but the name is used as a general or field term, to refer to a dark amphibole. Hornblende minerals are common ...
-
plagioclase Plagioclase ( ) is a series of Silicate minerals#Tectosilicates, tectosilicate (framework silicate) minerals within the feldspar group. Rather than referring to a particular mineral with a specific chemical composition, plagioclase is a continu ...
rocks. A feature of the granites of the batholith is the high concentrations of volatile components. Fluids rich in these have strongly affected the country rock and locally the granites themselves in a process called metasomatism. The first phase recognised is alkali metasomatism (where alkaline components are enhanced), which occurred within and at the margins of the granite.
Potassium Potassium is a chemical element; it has Symbol (chemistry), symbol K (from Neo-Latin ) and atomic number19. It is a silvery white metal that is soft enough to easily cut with a knife. Potassium metal reacts rapidly with atmospheric oxygen to ...
metasomatism Metasomatism (from the Greek μετά ''metá'' "change" and σῶμα ''sôma'' "body") is the chemical alteration of a rock by hydrothermal and other fluids. It is traditionally defined as metamorphism which involves a change in the chemical com ...
was followed by
sodium Sodium is a chemical element; it has Symbol (chemistry), symbol Na (from Neo-Latin ) and atomic number 11. It is a soft, silvery-white, highly reactive metal. Sodium is an alkali metal, being in group 1 element, group 1 of the peri ...
–metasomatism. Finally acid metasomatism (enrichment of acid components and depletion of alkalis) took place leading to the formation of greisen and tourmalines.


Mineral formation

Large
mineral In geology and mineralogy, a mineral or mineral species is, broadly speaking, a solid substance with a fairly well-defined chemical composition and a specific crystal structure that occurs naturally in pure form.John P. Rafferty, ed. (2011): Mi ...
deposits are found in the vicinity of the batholith and these have been mined for thousands of years. The area has been famous for its tin since about 2000 BC. The minerals formed when fluids escaped along fractures in the hot granite as it cooled and are typically found in
veins Veins () are blood vessels in the circulatory system of humans and most other animals that carry blood towards the heart. Most veins carry deoxygenated blood from the tissues back to the heart; exceptions are those of the pulmonary and fetal c ...
or washed into streams to form
alluvium Alluvium (, ) is loose clay, silt, sand, or gravel that has been deposited by running water in a stream bed, on a floodplain, in an alluvial fan or beach, or in similar settings. Alluvium is also sometimes called alluvial deposit. Alluvium is ...
. The mineral deposits are associated with multiple
lode In geology, a lode is a deposit of metalliferous ore that fills or is embedded in a fracture (or crack) in a rock formation or a vein of ore that is deposited or embedded between layers of rock. The current meaning (ore vein) dates from th ...
s and fractures that dip steeply and cut across both the granites and the country rocks. The ore-bearing lodes are up to several kilometres long and are 0.5 to 3m wide on average.


Stages of mineralization

There are four recognised stages of mineralization associated with different conditions as the granite slowly cooled. Each stage is associated with different temperatures, economic deposits of different metals and different
gangue Gangue () is the commercially worthless material that surrounds, or is closely mixed with, a wanted mineral in an ore deposit. It is thus distinct from overburden, which is the waste rock or materials overlying an ore or mineral body that are di ...
minerals. The first three stages have been connected to the intrusion and cooling of the batholith, while the fourth stage may have been driven by the heat production associated with
radioactive Radioactive decay (also known as nuclear decay, radioactivity, radioactive disintegration, or nuclear disintegration) is the process by which an unstable atomic nucleus loses energy by radiation. A material containing unstable nuclei is conside ...
materials in the granite. ;Stage 1 – exoskarns : The earliest phase of mineralization occurred during the intrusion of the granite. Hot water from the magma which was rich in silica, iron, aluminium, and magnesium mixed and dissolved
shale Shale is a fine-grained, clastic sedimentary rock formed from mud that is a mix of flakes of Clay mineral, clay minerals (hydrous aluminium phyllosilicates, e.g., Kaolinite, kaolin, aluminium, Al2Silicon, Si2Oxygen, O5(hydroxide, OH)4) and tiny f ...
s and metabasalts, and converted them into exoskarns in a process called
metasomatism Metasomatism (from the Greek μετά ''metá'' "change" and σῶμα ''sôma'' "body") is the chemical alteration of a rock by hydrothermal and other fluids. It is traditionally defined as metamorphism which involves a change in the chemical com ...
, where the chemical composition of rocks is changed by hot water or other fluids. Typical minerals formed at this time include
garnet Garnets () are a group of silicate minerals that have been used since the Bronze Age as gemstones and abrasives. Garnet minerals, while sharing similar physical and crystallographic properties, exhibit a wide range of chemical compositions, de ...
,
pyroxene The pyroxenes (commonly abbreviated Px) are a group of important rock-forming inosilicate minerals found in many igneous and metamorphic rocks. Pyroxenes have the general formula , where X represents ions of calcium (Ca), sodium (Na), iron ( ...
,
epidote Epidote is a calcium aluminium iron sorosilicate mineral. Description Well developed crystals of epidote, Ca2Al2(Fe3+;Al)(SiO4)(Si2O7)O(OH), crystallizing in the monoclinic system, are of frequent occurrence: they are commonly prismatic in ha ...
, chlorine-rich amphiboles, malayaite,
vesuvianite Vesuvianite, also known as idocrase, is a green, brown, yellow, or blue silicate mineral. Vesuvianite occurs as tetragonal crystals in skarn deposits and limestones that have been subjected to contact metamorphism. It was first discovered withi ...
,
siderite Siderite is a mineral composed of iron(II) carbonate (FeCO3). Its name comes from the Ancient Greek word (), meaning "iron". A valuable iron ore, it consists of 48% iron and lacks sulfur and phosphorus. Zinc, magnesium, and manganese commonly ...
and axinite. The skarns may contain economic amounts of
tin Tin is a chemical element; it has symbol Sn () and atomic number 50. A silvery-colored metal, tin is soft enough to be cut with little force, and a bar of tin can be bent by hand with little effort. When bent, a bar of tin makes a sound, the ...
,
copper Copper is a chemical element; it has symbol Cu (from Latin ) and atomic number 29. It is a soft, malleable, and ductile metal with very high thermal and electrical conductivity. A freshly exposed surface of pure copper has a pinkish-orang ...
,
iron Iron is a chemical element; it has symbol Fe () and atomic number 26. It is a metal that belongs to the first transition series and group 8 of the periodic table. It is, by mass, the most common element on Earth, forming much of Earth's o ...
and
arsenic Arsenic is a chemical element; it has Symbol (chemistry), symbol As and atomic number 33. It is a metalloid and one of the pnictogens, and therefore shares many properties with its group 15 neighbors phosphorus and antimony. Arsenic is not ...
. These minerals were formed at about the same time as the crystallisation of the pluton they are associated with. Temperatures associated with this stage were 375 – 450 °C. ;Stage 2 – greisen bordered veins and tourmaline veins and breccias : The second recognised phase of mineralization involved the granite being transformed by high-temperature late magmatic fluids rich in volatiles to form greisen and
tourmaline Tourmaline ( ) is a crystalline silicate mineral, silicate mineral group in which boron is chemical compound, compounded with chemical element, elements such as aluminium, iron, magnesium, sodium, lithium, or potassium. This gemstone comes in a ...
. Veins of
cassiterite Cassiterite is a tin oxide mineral, SnO2. It is generally opaque, but it is translucent in thin crystals. Its luster and multiple crystal faces produce a desirable gem. Cassiterite was the chief tin ore throughout ancient history and remains ...
(tin oxide) and
wolframite Wolframite is an iron, manganese, and tungstate mineral with a chemical formula of that is the intermediate mineral between ferberite ( rich) and hübnerite ( rich). Along with scheelite, the wolframite series are the most important tungsten ...
(a mineral containing iron, manganese and tungsten) are found associated with the greisens, the former deposited by high salinity, low , fluids and the latter by low salinity, high fluids.
Muscovite Muscovite (also known as common mica, isinglass, or potash mica) is a hydrated phyllosilicate mineral of aluminium and potassium with formula KAl2(Al Si3 O10)( F,O H)2, or ( KF)2( Al2O3)3( SiO2)6( H2O). It has a highly perfect basal cleavage y ...
s within the greisens give cooling ages similar to magmatic muscovites in the relevant granite. ;Stage 3 – the main phase of mineralization : The third and main phase of mineralization occurred at a later stage, and at lower temperatures (200 – 400 °C) as the granite intrusion cooled. Fluids circulating within the country rock leached out tin, copper and arsenic and deposited them in veins which generally lie on an east–west axis. The typical fill of these veins is
quartz Quartz is a hard, crystalline mineral composed of silica (silicon dioxide). The Atom, atoms are linked in a continuous framework of SiO4 silicon–oxygen Tetrahedral molecular geometry, tetrahedra, with each oxygen being shared between two tet ...
-tourmaline-
chlorite The chlorite ion, or chlorine dioxide anion, is the halite (oxyanion), halite with the chemical formula of . A chlorite (compound) is a compound that contains this group, with chlorine in the oxidation state of +3. Chlorites are also known as s ...
-sulfide-
fluorite Fluorite (also called fluorspar) is the mineral form of calcium fluoride, CaF2. It belongs to the halide minerals. It crystallizes in isometric cubic habit, although octahedral and more complex isometric forms are not uncommon. The Mohs scal ...
, with tin, copper, lead, zinc, iron and arsenic sulfides. This mineralization is 25–40 Ma later than the intrusion age for the Carnmenellis pluton. These veins are the main economically useful source of minerals. ;Stage 4 – crosscourses :The fourth and final stage of mineralization was the lowest temperature phase (100 – 170 °C) and is associated with veins containing multiple metallic elements (lead, zinc,
silver Silver is a chemical element; it has Symbol (chemistry), symbol Ag () and atomic number 47. A soft, whitish-gray, lustrous transition metal, it exhibits the highest electrical conductivity, thermal conductivity, and reflectivity of any metal. ...
and
uranium Uranium is a chemical element; it has chemical symbol, symbol U and atomic number 92. It is a silvery-grey metal in the actinide series of the periodic table. A uranium atom has 92 protons and 92 electrons, of which 6 are valence electrons. Ura ...
). The veins lie on a north–south or northwest–southeast axis and are known as 'crosscourses' because they cross-cut the earlier E-W trending veins. Gangue minerals include quartz,
barite Baryte, barite or barytes ( or ) is a mineral consisting of barium sulfate (Ba S O4). Baryte is generally white or colorless, and is the main source of the element barium. The ''baryte group'' consists of baryte, celestine (strontium sulfate), ...
and fluorite. Studies on quartz
fluid inclusions image:Inclumed.gif, 250px, Trapped in a time capsule the same size as the diameter of a human hair, the ore-forming liquid in this inclusion was so hot and contained so much dissolved solids that when it cooled, crystals of halite, sylvite, gypsum, ...
have shown that the fluids causing this stage are similar in composition to deep sedimentary
brine Brine (or briny water) is a high-concentration solution of salt (typically sodium chloride or calcium chloride) in water. In diverse contexts, ''brine'' may refer to the salt solutions ranging from about 3.5% (a typical concentration of seawat ...
s which are rich in sodium, calcium and chlorine. This brine came from Permo-Triassic sedimentary rocks that once covered the entire area. These rocks are still preserved in the
Southwest Approaches The Southwest Approaches is the name given to the offshore waters to the southwest of Great Britain and Ireland. The area includes the Celtic Sea, the Bristol Channel and sea areas off southwest Ireland. The area is bordered on the north by the ...
to the
English Channel The English Channel, also known as the Channel, is an arm of the Atlantic Ocean that separates Southern England from northern France. It links to the southern part of the North Sea by the Strait of Dover at its northeastern end. It is the busi ...
. Evidence of seawater influence suggests that the mineralization did not start until the Late
Triassic The Triassic ( ; sometimes symbolized 🝈) is a geologic period and system which spans 50.5 million years from the end of the Permian Period 251.902 million years ago ( Mya), to the beginning of the Jurassic Period 201.4 Mya. The Triassic is t ...
marine incursion at the earliest. The high heat flow from the granites helped drive fluid circulation.


China clay

Large economic deposits of
china clay Kaolinite ( ; also called kaolin) is a clay mineral, with the chemical composition aluminium, Al2Silicon, Si2Oxygen, O5(hydroxide, OH)4. It is a layered silicate mineral, with one tetrahedron, tetrahedral sheet of silica () linked through oxygen ...
are found in places across the south-west peninsula, in particular Lee Moor on the western edge of Dartmoor and the St Austell district. The china clay was formed by the alteration of feldspars in a process known as kaolinization. There is still debate about the origin and age of these deposits but they are commonly thought to arise from the circulation of
meteoric water Meteoric water, derived from precipitation such as snow and rain, includes water from lakes, rivers, and ice melts, all of which indirectly originate from precipitation. The journey of meteoric water from the atmosphere to the Earth's surface is a ...
(water from rain or snow) at a late stage during cooling of the batholith. One theory is that the kaolinization resulted from intense supergene
weathering Weathering is the deterioration of rocks, soils and minerals (as well as wood and artificial materials) through contact with water, atmospheric gases, sunlight, and biological organisms. It occurs '' in situ'' (on-site, with little or no move ...
in a tropical to warm climate during the
Cretaceous The Cretaceous ( ) is a geological period that lasted from about 143.1 to 66 mya (unit), million years ago (Mya). It is the third and final period of the Mesozoic Era (geology), Era, as well as the longest. At around 77.1 million years, it is the ...
to
Cenozoic The Cenozoic Era ( ; ) is Earth's current geological era, representing the last 66million years of Earth's history. It is characterized by the dominance of mammals, insects, birds and angiosperms (flowering plants). It is the latest of three g ...
, based on studies of D/ H and / ratios.


References


Sources

*


External links


Nick LeBoutillier's website on Cornish Geology
* Nick LeBoutillier's D.Phil. thesis: ''The Tectonics of Variscan Magmatism and Mineralisation in South West England'' (2002)
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Vol 2
{{coord, 50.2, -5.2, display=title Geology of Cornwall Geology of Devon Batholiths of Europe Permian England Granite Permian magmatism