Chromium(III) Perchlorate
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Chromium(III) perchlorate is an
inorganic compound An inorganic compound is typically a chemical compound that lacks carbon–hydrogen bonds⁠that is, a compound that is not an organic compound. The study of inorganic compounds is a subfield of chemistry known as ''inorganic chemistry''. Inorgan ...
, a salt with the chemical formula Cr(ClO4)3. It's hexahydrate Cr(ClO4)3·6H2O is a cyan solid that dissolves in water.


Preparation

Chromium perchlorate can prepared by reacting chromium(III) oxide or
chromium(III) hydroxide Chromium(III) hydroxide is a gelatinous green inorganic compound with the chemical formula . It is a polymer with an undefined structure and low solubility. It is amphoteric, dissolving in both strong alkalis and strong acids. :In alkali: :In ac ...
with
perchloric acid Perchloric acid is a mineral acid with the formula H Cl O4. It is an oxoacid of chlorine. Usually found as an aqueous solution, this colorless compound is a stronger acid than sulfuric acid, nitric acid and hydrochloric acid. It is a powerful oxid ...
: :Cr2O3 + 6HClO4 → 2Cr(ClO4)3 + 3H2O


Hydrates

Chromium perchlorate has many hydrates, such as the hexahydrate Cr(ClO4)3·6H2O and a nonahydrate Cr(ClO4)3·9H2O. All of them are cyan substances that are soluble in water.


Related compounds

*Cr(ClO4)3 will react with NH3 in suitable conditions to form an orange hexammine complex Cr(ClO4)3·6NH3. Other compounds with the general formula Cr(ClO4)3(NH3)x are also known. When x = 3, this compound is red, when x = 4 or 5, it is orange. The hexammine complex will explode. *Cr(ClO4)3 can also form complexes with N2H4, such as purple Cr(ClO4)3·2N2H4. *Cr(ClO4)3 can also form complexes with
urea Urea, also called carbamide (because it is a diamide of carbonic acid), is an organic compound with chemical formula . This amide has two Amine, amino groups (–) joined by a carbonyl functional group (–C(=O)–). It is thus the simplest am ...
(CO(NH2)2), such as Cr(ClO4)3·6CO(NH2)2 with a hexagonal structure.


References

{{Perchlorates Chromium(III) compounds Perchlorates