Carbonyl Selenide
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Carbonyl selenide is a
chemical compound A chemical compound is a chemical substance composed of many identical molecules (or molecular entities) containing atoms from more than one chemical element held together by chemical bonds. A molecule consisting of atoms of only one element ...
with the
chemical formula A chemical formula is a way of presenting information about the chemical proportions of atoms that constitute a particular chemical compound or molecule, using chemical element symbols, numbers, and sometimes also other symbols, such as pare ...
. It is a linear molecule that is primarily of interest for research purposes.


Properties

Carbonyl selenide is a colorless gas with an unpleasant odor. Although the compound is quite stable, its solutions gradually revert to elemental
selenium Selenium is a chemical element; it has symbol (chemistry), symbol Se and atomic number 34. It has various physical appearances, including a brick-red powder, a vitreous black solid, and a grey metallic-looking form. It seldom occurs in this elem ...
and
carbon monoxide Carbon monoxide (chemical formula CO) is a poisonous, flammable gas that is colorless, odorless, tasteless, and slightly less dense than air. Carbon monoxide consists of one carbon atom and one oxygen atom connected by a triple bond. It is the si ...
.


Synthesis and reactions

Carbonyl selenide can be produced by treating selenium with carbon monoxide in the presence of amines. It is used in organoselenium chemistry as a means of incorporating
selenium Selenium is a chemical element; it has symbol (chemistry), symbol Se and atomic number 34. It has various physical appearances, including a brick-red powder, a vitreous black solid, and a grey metallic-looking form. It seldom occurs in this elem ...
into
organic compounds Some chemical authorities define an organic compound as a chemical compound that contains a carbon–hydrogen or carbon–carbon bond; others consider an organic compound to be any chemical compound that contains carbon. For example, carbon-co ...
, e.g. for the preparation of selenocarbamates (''O''-selenocarbamates and ''Se''-selenocarbamates, , where R is organyl and R' and R" are any group, typically H or organyl).


References

{{Carbon compounds Inorganic carbon compounds Oxides Selenides